• Title/Summary/Keyword: oxidizer

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Flickering Frequency and Pollutants Formation in Microwave Induced Diffusion Flames (마이크로파가 인가된 화염에서의 주파수 특성과 오염물질 생성)

  • Jeon, Young Hoon;Lee, Eui Ju
    • Journal of the Korean Society of Safety
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    • v.31 no.3
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    • pp.22-27
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    • 2016
  • The use of electromagnetic wave has been interested in various energy industry because it enhances a flame stability and provides higher safety environments. However it might increase the pollutant emissions such as NOx and soot, and have harmful influence on human and environments. Therefore, it is very important to understand interaction mechanism between flame and electromagnetic wave from environmental point of view. In this study, an experiment was performed with jet diffusion flames induced by electromagnetic wave. Microwave was used as representative electromagnetic wave and a flickering flame was introduced to simulate the more similar combustion condition to industry. The results show that the induced microwave enhances the flame stability and blowout limit. The unstable lifted flickering flames under low fuel/oxidizer velocity is changed to stable attached flames or lift-off flames when microwave applied to the flames, which results from the abundance of radical pool. However, NOx emission was increased monotonically with increasing the microwave power as microwave power increased up to 1.0 kW. The effects might be attributed to the heating of combustion field and thermal NOx mechanism will be prevailed. Soot particle was examined at the post flame region by TEM grid. The morphology of soot particle sampled in the microwave induced flames was similar to the incipient soot that is not agglomerated and contain a lots of liquid phase hydrocarbon such as PAH, which soot particle formed near reaction zone is oxidized on the extended yellow flame region and hence only unburned young particles are emitted on the post flame region.

A Study on Recycle of Abrasive Particles in One-used Chemical Mechanical Polishing (CMP) Slurry (산화막 CMP 슬러리의 연마 입자 재활용에 관한 연구)

  • Park, Sung-Woo;Seo, Yong-Jin;Kim, Gi-Uk;Choi, Woon-Sik;Kim, Chul-Bok;Kim, Sang-Yong;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.145-148
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    • 2003
  • Recently, the recycle of CMP (chemical mechanical polishing) slurries have been positively considered in order to reduce the high COO (cost of ownership) and COC (cost of consumables) in CMP process. Among the composition of slurries (buffer solution, bulk solution, abrasive particle, oxidizer, inhibitor, suspension, antifoaming agent, dispersion agent), the abrasive particles are one of the most important components. Especially, the abrasive particles of slurry are needed in order to achieve a good removal rate. However, the cost of abrasives, is still very high. In this paper, we have collected the silica abrasive powders by filtering after subsequent CMP process for the purpose of abrasive particle recycling. And then, we have studied the possibility of recycle of reused silica abrasive through the analysis of particle size and hardness. Also, we annealed the collected abrasive powders to promote the mechanical strength of reduced abrasion force. Finally, we compared the CMP characteristics between self-developed KOH-based silica abrasive slurry and original slury, As our experimental results, we obtained the comparable removal rate and good planarity with commercial products. Consequently, we can expect the saving of high cost slurry.

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Development of a University-Based Simplified H2O2/PE Hybrid Sounding Rocket at KAIST

  • Huh, Jeongmoo;Ahn, Byeonguk;Kim, Youngil;Song, Hyunki;Yoon, Hosung;Kwon, Sejin
    • International Journal of Aeronautical and Space Sciences
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    • v.18 no.3
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    • pp.512-521
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    • 2017
  • This paper reports development process of a university-based sounding rocket using simplified hybrid rocket propulsion system for low-altitude flight application. A hybrid propulsion system was tried to be designed with as few components as possible for more economical, simpler and safer propulsion system, which is essential for the small scale sounding rocket operation as a CanSat carrier. Using blow-down feeding system and catalytic ignition as combustion starter, 250 N class hybrid rocket system was composed of three components: a composite tank, valves, and a thruster. With a composite tank filled with both hydrogen peroxide($H_2O_2$) as an oxidizer and nitrogen gas($N_2$) as a pressurant, the feeding pressure was operated in blowdown mode during thruster operation. The $MnO_2/Al_2O_3$ catalyst was fabricated for propellant decomposition, and ground test of propulsion system showed the almost theoretical temperature of decomposed $H_2O_2$ at the catalyst reactor, indicating sufficient catalyst efficiency for propellant decomposition. Auto-ignition of the high density polyethylene(HDPE) fuel grain successfully occurred by the decomposed $H_2O_2$ product without additional installation of any ignition devices. Performance test result was well matched with numerical internal ballistics conducted prior to the experimental propulsion system ground test. A sounding rocket using the developed hybrid rocket was designed, fabricated, flight simulated and launch tested. Six degree-of-freedom trajectory estimation code was developed and the comparison result between expected and experimental trajectory validated the accuracy of the developed trajectory estimation code. The fabricated sounding rocket was successfully launched showing the effectiveness of the simplified hybrid rocket propulsion system.

Development of Volatile Organic Compound Pretreatment Device for Removing Exhaust Gas from Display Manufacturing Process (Display 제조공정 배출가스 처리를 위한 휘발성 유기화합물 전처리 장치 개발)

  • Moon, Gi-Hak;Kim, Jae-Yong
    • Applied Chemistry for Engineering
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    • v.30 no.5
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    • pp.523-529
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    • 2019
  • In this study, we investigated the pretreatment technologies of volatile organic compounds (VOCs) which is a problem as the semiconductor and display industry develops recently. The conventional concentrator used in the direct combustion system, is easily contaminated by the exhaust gas in the manufacturing process of the display, resulting in the low treatment efficiency of generated VOCs. Physical/Chemical analyses of the exhaust gas showed high boiling point and viscosity in addition to a large amount of molecular weight alcohols and oil components. In this study, we tried to treat degrading materials by using the heat exchanger in a pretreatment facility and some materials degrading the concentrator were condensed more than 90%. In addition, it was also confirmed that an auxiliary device of the grease filter could remove the redispersion polymer oil from the heat exchanger.

Oscillating Boundary Layer Flow and Low Frequency Instability in Hybrid Rocket Combustion (하이브리드 로켓 연소에서의 경계층 진동 변화와 저주파수 연소불안정)

  • Kim, Jina;Lee, Changjin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.47 no.10
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    • pp.720-727
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    • 2019
  • Resonating thermal lags of solid fuel with heat transfer oscillations generated by boundary layer oscillation is the primary mechanism of the occurrence of the LFI (Low Frequency Combustion Instability) in hybrid rocket combustion. This study was experimentally attempted to confirm that how the boundary layer was perturbed and led to the LFI. Special attention was also made on oxidizer swirl injection to investigate the contribution to combustion stabilization. Also the overall behavior of fluctuating boundary layer flow and the occurrence of the LFI was monitored as swirl intensity increased. Fluctuating boundary layer was successfully monitored by the captured image and POD (Proper Orthogonal Decomposition) analysis. In the results, oscillating boundary layer became stabilized as the swirl intensity increases. And the coupling strength between high frequency p', q' diminished and periodical amplification of RI (Rayleigh Index) with similar frequency band of thermal lag was also decreased. Thus, results confirmed that oscillating axial boundary layer triggered by periodic coupling of high frequency p', q' is the primary mechanism to excite thermal resonance with thermal lag characteristics of solid fuel.

Change of Piping-System Dynamics with Installation of Pogo Suppression Device (포고억제장치 설치에 따른 배관계 동특성 변화)

  • Lee Jun Kyoung;Lee Sang Yong;Lee Han Ju;Oh Seung Hyub
    • Journal of the Korean Society of Propulsion Engineers
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    • v.9 no.2
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    • pp.32-39
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    • 2005
  • The effectiveness of the pogo suppression device (PSD) on the response of the piping system simulating the fuel (or oxidizer) supply lines of the rocket engines was investigated. The system response defined as the ratio of the flow rate to the pressure in the main tube was obtained for various PSD gas volumes $((0\~2)\times10^{-3}m^3)$ and three different baffle hole diameters (5, 50, 115mm). Existence of a gas volume in the PSD reduced the system resonance frequency. With a larger gas volume, the resonance frequency became lower, but only slightly, while the fluctuations of the main tube pressure and the flow rate damped down considerably. The resonance frequency decreased with the increase of the PSD inlet restriction (or the decrease of the baffle hole diameter), though slightly. However, with a larger inlet restriction, the PSD pressure wave showed a delayed response with the smaller amplitude compared to the pressure variation in the main tube.

Flow Characteristics of Cryogenic Oxidizer in Liquid Propellant Rocket Engine (액체로켓 엔진에서의 극저온 산화제의 유동 특성)

  • 조남경;정용갑;문일윤;한영민;이수용;정상권
    • Journal of the Korean Society of Propulsion Engineers
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    • v.6 no.4
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    • pp.15-23
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    • 2002
  • In most cryogenic liquid rocket engines, liquid oxygen manifold and injector are not thermally insulated from room temperature environment fur reducing system complexity and the weight. This feature of cryogenic liquid rocket engine results in the situation that cryogenic liquid oxygen flow is easy to be vaporized especially in the vicinity of the manifold and the injector wall. The research in this paper is focused on two-phase flow phenomena of liquid oxygen in rocket engine. Vapor fraction was estimated by comparing the measured two-phase flow pressure drop in engine manifold and the injector with ideal single phase pressure drop. Heat flux into cryogenic flow is estimated by measuring the wall temperature on the engine manifold to examine boiling characteristics. Suitable correlations for cryogenic two-phase flow were also reviewed to see their applicability. In addition, the effect of vapor generation in liquid rocket engine manifold and injector on engine performance and stability was considered.

Effect of Particle Loading Ratio on Fluid Characteristics and Particle Distribution in Particle-laden Coaxial Jet (입자부상 동축 분사기에서 입자로딩비가 유동 특성과 입자분포에 미치는 영향에 대한 연구)

  • Yoon, Jungsoo;Yoon, Youngbin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.3
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    • pp.9-19
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    • 2015
  • Experimental research on characteristics of particle-laden jet by using a coaxial injector was conducted in order to design fuel and oxidizer injectors of the supercavitation underwater vehicle. $1{\mu}m$ and $42{\mu}m$ particles was simultaneously injected to obtain particle and fluid velocity. Small particles($1{\mu}m$) and large particles represent fluid and fuel characteristics respectively. Small particles, which was processed using PIV algorithms, and one for the large particles processed using PTV algorithms. Fluid phase axial velocity increases according to particle loading ratio increases, and particles are located at the outside of the high vorticity region in a mixing layer of a coaxial injector.

Ignition Characteristics of Combustion Chamber with $LO_X$ Lead Cyclogram for Liquid Rocket Engine (액체로켓엔진 연소기 산화제 선공급 Cyclogram에 의한 점화특성)

  • Han, Yeoung-Min;Kim, Jong-Gyu;Lee, Kwang-Jin;Lim, Byoung-Jik;Ahn, Kyu-Bok;Kim, Mun-Ki;Seo, Seong-Hhyeon;Choi, Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.137-142
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    • 2008
  • Ignition characteristics of combustion chamber with LOx lead cyclogram for liquid rocket engine were described. The combustion chamber has chamber pressure of 60 bar, propellant mass flow rate of 89 kg/s, and nozzle expansion of 12. Cold flow test to determine the filling time of propellant for cyclogram with LOx lead supply, ignition test to check the ability to ignite starting fuel from the ignitor, low pressure combustion test to check the propagation of flame into main fuel-oxidizer mixture from starting fuel and the main combustion stage, and design point combustion test to check the combustion performance were performed. Ignition and combustion tests with LOx lead supply were successfully performed and the stable cyclogram of start sequence for combustion chamber was developed.

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Study on Pressure Fluctuations Observed in Combustion of Oxygen-Rich Preburners (산화제 과잉 예연소기 연소에서 관찰되는 압력섭동에 대한 연구)

  • Seo, Seonghyeon;Kang, Sang Hun;Lee, Soo-Yong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.2
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    • pp.122-127
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    • 2013
  • The paper includes the analytic results of pressure fluctuation data from the combustion of an oxidizer-rich preburner applicable to high-performance, closed-cycle liquid rocket engine systems. The combustion experiments went through two different steps of a chamber pressure during single run. Self-excited pressure fluctuations with a frequency of 78 Hz were observed only at the relatively low chamber pressure condition. These pressure fluctuations are regarded as a bulk mode. The intensity of pressure fluctuations by a root-mean-square value is 13.3% normalized by the chamber static pressure and no pressure excitation was observed at the design pressure condition. The bulk mode has an identical phase across the inside of the chamber and reveals the similar characteristics to the Helmholtz resonator.