• Title/Summary/Keyword: oxidizer

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A Numerical Analysis of the Characteristics with High Temperature Air Combustion in Counterflow Diffusion Flame (대향류 확산화염의 고온공기 연소특성에 관한 수치해석)

  • Cho, Eun Seong;Kobayashi, Hideaki;Chung, Suk Ho
    • Journal of the Korean Society of Combustion
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    • v.8 no.4
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    • pp.9-14
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    • 2003
  • High temperature air combustion technology has been utilized by using preheated air over 1100 K and excessive exhaust gas recirculation. Numerical analysis was performed to investigate the combustion characteristics with high temperature deficient oxygen air combustion by adopting a counterflow as a model problem accounting for detailed chemical kinetics. Methane($CH_4$) was used as a test fuel and calculated oxidizer conditions were low temperature high oxygen (300K, $X_{O2}=0.21$) and high temperature low oxygen (1300K, $X_{O2}=0.04$) conditions. The latter case showed that the flame temperature is lower than the former case and its profile showed monotonic decrease from oxidizer to fuel side, without having local maximum flame temperature at high stretch rate. Also, heat release rate was one order lower and it has one peak profile because of low oxygen concentration and heat release rate integral is almost same for stretch rate. High temperature low oxygen air combustion shows low NO emission characteristics.

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Spray Combustion Analysis for Unsteady State in Combustion Chamber of Liquid Rocket Engine Considering Droplet Fluctuation (액적변동을 고려한 액체로켓의 연소실 내 비정상 분무연소 해석)

  • Jeong, Dae-Kwon;Roh, Tae-Seong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.175-178
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    • 2006
  • A numerical study for spray combustion of fluctuated fuel and oxidizer droplets injected into combustion chamber has been conducted for the analysis of spray combustion considering characteristics of injector. The 2 dimensional unsteady state flow fields have been calculated by using QUICK Scheme and SIMPLER Algorithm. As the spray model, DSF model and Euler-Lagrange Scheme have been used. The sine Auction has been used for droplet fluctuation model of fuel and oxidizer, while the coupling effects of the droplets between gas phase and evaporated vapor have been calculated by using PSIC model.

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Design of Hybrid Rocket (Altitude 15km) Using Liquid Oxidizer ${N_2}O$ (${N_2}O$ 액체산화제를 사용한 고도 15km급 하이브리드 로켓 설계)

  • Heo, Jun-Young;Cho, Min-Gyung;Kim, Jong-Chan;Kim, Soo-Jong;Kim, Jin-Kon;Moon, Hee-Jang;Sung, Hong-Gye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.05a
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    • pp.97-100
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    • 2008
  • A hybrid sounding rocket carrying about 10kg payload reaching up to 15km altitude has been designed. The commercial seamless aluminium tube and liquid ${N_2}O$ without pressurization devices were chosen as rocket motor case and oxidizer supply system respectively. A hybrid rocket engine performing required propulsion impulse is designed with time dependent internal ballistic scheme. Engine performance, aerodynamic characteristics, and trajectory were predicted by a integral technique of internal ballistics and external ballistics. The design results were evaluated by comparison with previous experimental data, technical reports, and literatures.

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Quality control for the liquid oxygen as the oxidizer of launcher and the liquid oxygen filling system as ground facility (액체산소를 사용하는 발사체 산화제 및 산화제 지상공급시스템의 품질관리)

  • Kim, Ji-Hoon;Yoo, Byung-Il;Kang, Sun-Il;Oh, Seung-Hyub
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.309-312
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    • 2009
  • The various hazards should be eliminated before operations for the successful launches or tests. Using the contaminated propellants is one of the causes for the launch and test failures. Especially, the systems using liquid oxygen as an oxidizer have risks about fires and explosions not be forecasted if they are contaminated by oil, water and mechanical impurities. The procedure for the quality control of the liquid oxygen and the liquid oxygen filling system and the lessons learned from the first launch preparation with the system are introduced on this paper.

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A Study on Acceleration Aging Characteristics of B-KNO3 Igniter (B-KNO3 점화제의 가속 노화 특성 연구)

  • Paik, Jong Gyu;Ryu, Byung Tae;Kwon, Mira
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.166-174
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    • 2014
  • This research investigated the aging properties of the $B-KNO_3$ system as the igniter. The $B-KNO_3$ system showed the degradation in ignition properties depending on the method and period of storage. It should be found out the cause of the degradation to predict the reliability of the igniters. The changes of the properties by the degradation after aging tests were analyzed by microstructure analysis, XRD analysis and thermal analysis using DSC. It was found out that the lattice parameters of the $KNO_3$ as the oxidizer in the ignition system was changed into the JCPDS values as the aging time increased. Conclusively, the changes of the crystal structure of oxidizer affected the activation energy increasing as aging time increased.

Improvement of Chemical Mechanical Polishing (CMP) Performance of Nickel by Additions of Abrasive and Various Oxidizers (산화제 및 연마제 첨가를 통한 Nickel CMP 특성 개선 연구)

  • Choi, Gwon-Woo;Kim, Nam-Hoon;Seo, Yong-Jin;Lee, Woo-Sun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.7
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    • pp.605-609
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    • 2005
  • Chemical mechanical polishing (CMP) of Ni was performed by the various ratios of four kinds of oxidizers and an addition of alumina powders as an abrasive in each slurry with the different oxidizers. Moreover, the interaction between the Ni and the each oxidizer was discussed by potentiodynamic polarization measurement, in order to compare the effects of Ni-CMP and electrochemical characteristics on the Ni with the different oxidizers. As an experimental result, the removal rate of Ni reached a maximum at 1 $vol\%$ of $H_2O_2$. Also the removal rates of Ni increased with the audition of alumina abrasives in each slurry. The potentiodynamic polarization of Ni under dynamic condition showed a significant difference in electrochemical behavior by addition of $H_2O_2$ in solutions. Ni showed the perfect passivation behavior in solution without $H_2O_2$ under potentiodynamic polarization condition, while active dissolution dominates in solution with the addition of $H_2O_2$. The results indicate that the surface chemistry and electrochemical characteristics of Ni play an important role in controlling the polishing behavior of Ni.

A FLUID TRANSIENT ANALYSIS ON THE PIPE NETWORK OF BIPROPELLANT PROPULSION SYSTEM WITH AN UNSTEADY FRICTION (이원추진제 추진시스템의 배관망에 대한 비정상 마찰을 고려한 과도기유체 해석)

  • Chae, Jong-Won;Han, Cho-Young;Kim, Jung-Hoon;Jun, Hyoung-Yoll
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.487-490
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    • 2010
  • A fluid transient analysis on the pipe network of bipropellant propulsion system is conducted through numerical parametric studies in which unsteady friction results are compared with quasi-steady friction results and also show the pressure drop results during the liquid apogee engine firing. The fluid transient analysis program has verified through comparing with the original Zielke model, the full and recursive convolution model and quasi-steady model as a reference. And the pressure drop program also has verified through comparing with results of the well-known program, EPANET2. The bipropellant propulsion system has two different fluids as fuel and oxidizer, and mostly they are hypergolic combination so that the valve opening and closing of the thrusters, that cause the pressure waves, shall take place simultaneously to get proper performance. The different physical properties of the fuel and oxidizer result in the different responsive to the same valve opening and closing. The response results may be helpful to know the characteristics of the bipropellant propulsion system and design it.

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The Effect of Oxygen and Carbon Dioxide Concentration on Soot Formation in Nonpremixed Flames Using Time Resolved LII Technique

  • Oh, Kwang-Chul;Shin, Hyun-Dong
    • Journal of Mechanical Science and Technology
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    • v.19 no.11
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    • pp.2068-2076
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    • 2005
  • The influence of oxygen concentration and CO$_{2}$ as diluent in oxidizer side on soot characteristics was studied by Laser Induced Incandescence, Time Resolved LII and Transmission Electron Microscopy photography in non-premixed co flowing flames. Through the comparison of TEM photographs and the decay rate of LII signal, suitable two delay times of TIRE-LII method and signal sensitivity ($\Delta$S$_{TIRE-LII/) were determined. The effects of O$_{2}$ and CO$_{2}$ as diluent in oxidizer side on soot formation are investigated with these calibrated techniques. The O$_{2}$+CO$_{2}$, N$_{2}$, and [Ar+CO$_{2}$] mixture in co-flow were used to isolate CO2 effects systematically. The number concentration of primary particle and soot volume fraction abruptly decrease by the addition of CO$_{2}$ to the co-flow. This suppression is resulted from the short residence time in inception region because of the late nucleation and the decrease of surface growth distance by the low flame temperature due to the higher thermal capacity and the chemical change of CO$_{2}$ including thermal dissociation. As the oxygen concentration increases, the number concentration of soot particles at the inception region increases and thus this increase of nucleation enhances the growth of soot particle.

An Experimental Study on the Regression Rate of the Hybrid Rocket with $GO_2$/HTPB Propellant Combination ($GO_2$/HTPB를 사용하는 Hybrid Rocket의 추진제 침투율에 관한 실험적 연구)

  • Kim, S.J.;Han, J.S.;Kim, Y.;Ji, P.S.;Cho, S.
    • Journal of the Korean Society of Propulsion Engineers
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    • v.1 no.2
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    • pp.58-66
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    • 1997
  • To investigate the effect of the oxidizer mass flow rate on the fuel regression rate of the hybrid rocket, a laboratory size rocket was designed and ground fire test were carried out. Oxidizer was gaseous oxygen and HTPB was used as a fuel. Following correlation was obtained from the experiment. $\dot{r}$=$0.183G_o^{0.605}$

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Development and Evaluation of Fixed Abrasive Pad in Tungsten CMP (고정입자패드를 이용한 텅스텐 CMP 개발 및 평가)

  • Park, Boumyoung;Kim, Hoyoun;Kim, Gooyoun;Jeong, Haedo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.2 no.4
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    • pp.17-24
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    • 2003
  • Chemical mechanical polishing(CMP) has been applied for planarization of topography after patterning process in semiconductor fabrication process. Tungsten CMP is necessary to build up interconnects of semiconductor device. But the tungsten dishing and the oxide erosion defects appear at end-point during tungsten CMP. It has been known that the generation of dishing and erosion is based on the over-polishing time, which is determined by pattern selectivity. Fixed abrasive pad takes advantage of decreasing the defects resulting flam reducing pattern selectivity because of the lower abrasive concentration. The manufacturing technique of fixed abrasive pad using hydrophilic polymers is introduced in this paper. For application to tungsten CMP, chemicals composed of oxidizer, catalyst, and acid were developed. In comparison of the general pad and slurry for tungsten CMP, the fixed abrasive pad and the chemicals resulted in appropriate performance in point of removal rate, uniformity, material selectivity and roughness.

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