• Title/Summary/Keyword: oxidized

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Recovery of Heavy Metals using Oxidized Undaria pinnatifida in Plating Wastewater

  • Park, Jae-Yeon;Jeon, Chung;Yu, Yeong-Je
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.357-360
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    • 2000
  • Biosorption process is an economic and potential process for metal sequestering from the water. The oxidized Undaria pinnatifida by nitric acid had high uptake capacity for heavy metals of 4 - 6 meq / g dry mass. For the application of oxidized Undaria pinnatifida, recovery of metal in plating wastewater was studied. The uptake capacity of the oxidized Undaria pinnatifida was high compared to the ion exchanger IR-120 plus. The treatment efficiency of chromium and copper in the wastewater was 85% In batch. Activated carbon was used to assist the recovery of water by removing organic matters of the wastewater.

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The Shrinkage Characteristics of Concrete in Using Oxidized Electric-Furnace Slag Aggregate (전기로산화슬래그 골재를 사용한 콘크리트의 수축 특성)

  • Sohn, Yu-Shin;Park, Chan-Gyu;Lee, Seung-Hoon;Choi, Sung-Woo;Ryu, Deug-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.253-254
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    • 2010
  • This study is about evaluation of shrinkage of concrete used oxidized EFS(electric-furnaceslag) aggregate. As a result, the shrinkage of concrete used oxidized EFS aggregate is decreased to about 40% in proportion to replacement of oxidized EFS aggregate in total aggregate volume.

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Modification and Inactivation of Human Ceruloplasmin by Oxidized DOPA

  • Kang, Jung-Hoon
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.625-628
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    • 2004
  • Ceruloplasmin (CP), the blue oxidase present in all vertebrates, is the major copper-containing protein of plasma. It has been proposed that oxidation of L-3,4-dihydroxyphenylalanine (DOPA) may contribute to the pathogenesis of neurodegenerative disorders. The effect of the oxidized products of DOPA on the modification of human CP was investigated. When CP was incubated with the oxidized L-DOPA, the protein was induced to be aggregated and ferroxidase activity was decreased in a time-dependent manner. Radical scavengers and catalase significantly inhibited the oxidized DOPA-mediated CP aggregation. Copper chelatrors, Diethylenetriaminepenta acetic acid (DTPA) and Diethyldithiocarbamic acid (DDC), also inhibited the oxidative modification of CP. The results suggested that DOPA oxidation led to the formation of free radical and induced the CP aggregation.

Oxidized Cholesterols in Dried Alaska Pollacks (건조 명태 중 콜레스테롤 산화물의 생성)

  • 이일숙;박선영;이주희;성낙주
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.5
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    • pp.822-826
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    • 1997
  • This study attempted to establish the basic data for ensuring the safety of dried Alaska pollack. The changes of such compounds in the curse of drying as cholesterol, malonaldehyde, 7-ketocho-lesterol, 7$\alpha$-, 7$\beta$-hydroxycholesterol and 25-hydroxycholesterol were analyzed. The contensts of cholesterol decreased rapidly in the samples durint sun, hot-air and frozen drying and the decreased levels of cholesterol in dried products were about 134.0~191.3mg/100gas compared with 307.1mg/100g in raw samples. 4.8~6.1$\mu\textrm{g}$/100g in dried samples. In the raw samples, oxidized cholesterols were not detected hydroxycholesterol(34.1~41.7$\mu\textrm{g}$), 7$\beta$-hydroxycholesterol(26.8~40.2$\mu\textrm{g}$/g) and 25-hydroxycholesterol(0.3~1.3$\mu\textrm{g}$/g) were detected. Frozen drying was formed to be the most effective to minimize the formation of oxidized cholesterol in Alaska pollacks.

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Oxidation of Alkane Derivatives by Corynebacterium sp. (Alkane 유도체의 미생물학적 산화 제1보)

  • 이종근;이상준
    • Korean Journal of Microbiology
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    • v.21 no.4
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    • pp.185-190
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    • 1983
  • Twelve Microorganisms capable of utilizing diaminododecane were isolated from the soil by enrichment culture technique. Seven strains of these were identified as Corynebacterium. The isolated strains were tested for the ability to utilize as carbon source, 10 different kind of alkane derivatives containing CN, $NH_2$, Cl, and SH groups. Laurylcyanide, dicyanooetane, chlorodecane, and dichlorodecane were not utilized by any of the isolated strains; putrescine dihydrochloride, cadaverine dihydrochloride, diaminododecane, and n-dodecane were utilized by all of the isolated strains; and all of the isolated strains except DAD 2-3 could utilize dodecylmercaptan. The alkane derivatives that did not serve as ,growth substrates were tested further in oxidation tests using resting cell preparation. Alkane derivatives that are being oxidized by all of the isolated strains are laurylcyanide and dichlorodecane. Dicyanooctane was also oxidized by all of the isolated strains except DAD 30L, chlorodecane was the only oxidized by the three isolated strains. The most remarkable substrate that is being oxidized is dichlorodecane containing CN groups diterminally. Evidence obtained with thin layer chromatography of ,ethyl acetate extracts of culture broth of isolated strains grown in some alkane derivatives shows that these alkane derivatives are degraded.

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Adsorption behaviour of film-forming amine on pre-oxidized carbon steel surface

  • Genxian, Lin;Yun, Sun;Canshuai, Liu;Jun, Fang;Lijun, Song;Bin, Liu
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1185-1194
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    • 2022
  • The maintenance of condenser main pipe is the key to achieve film-forming amine maintenance effectiveness. In this work, oxygen content, pH and temperature of the solution were controlled to simulate the condition of condenser main pipe, and magnetite coated carbon steel sample was prepared by pre-oxidization. CAM was used to characterize the hydrophobicity of film formed samples. Hydrophobic film was formed on pre-oxidized carbon steel samples when octadecylamine concentration reaches 20 mg/kg. SEM, EDS, EIS, and PD were used to characterize the influence of octadecylamine concentration on maintenance effectiveness. It was found that the maintenance effectiveness was enhanced and the corrosion rate was suppressed with the increase of octadecylamine concentration. FIB and TEM were used to detect the adsorbed octadecylamine film thickness founding that octadecylamine adsorbed onto the surface of pre-oxidized carbon steel by multi-layer adsorption mechanism.

Facile Synthesis of Co3O4/Mildly Oxidized Multiwalled Carbon Nanotubes/Reduced Mildly Oxidized Graphene Oxide Ternary Composite as the Material for Supercapacitors

  • Lv, Mei-Yu;Liu, Kai-Yu;Li, Yan;Wei, Lai;Zhong, Jian-Jian;Su, Geng
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1349-1355
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    • 2014
  • A three-dimensional (3D) $Co_3O_4$/mildly oxidized multiwalled carbon nanotubes (moCNTs)/reduced mildly oxidized graphene oxide (rmGO) ternary composite was prepared via a simple and green hydrolysishydrothermal approach by mixing $Co(Ac)_2{\cdot}4H_2O$ with moCNTs and mGO suspension in mixed ethanol/$H_2O$. As characterized by scanning electron microscopy and transmission electron microscopy, $Co_3O_4$ nanoparticles with size of 20-100 nm and moCNTs are effectively anchored in mGO. Cyclic voltammetry and galvanostatic charge-discharge measurements were adopted to investigate the electrochemical properties of $Co_3O_4$/moCNTs/rmGO ternary composite in 6 M KOH solution. In a potential window of 0-0.6 V vs. Hg/HgO, the composite delivers an initial specific capacitance of 492 $Fg^{-1}$ at 0.5 $Ag^{-1}$ and the capacitance remains 592 $Fg^{-1}$ after 2000 cycles, while the pure $Co_3O_4$ shows obviously capacitance fading, indicating that rmGO and moCNTs greatly enhance the electrochemical performance of $Co_3O_4$.

Adsorption of Heavy Metal Ions onto Chemically Oxidized Ceiba pentandra (L.) Gaertn. (Kapok) Fibers

  • Chung, Byung-Yeoup;Cho, Jae-Young;Lee, Min-Hee;Wi, Seung-Gon;Kim, Jin-Hong;Kim, Jae-Sung;Kang, Phil-Hyun;Nho, Young-Chang
    • Journal of Applied Biological Chemistry
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    • v.51 no.1
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    • pp.28-35
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    • 2008
  • The physico-chemical properties of kapok fibers were altered via the combination processes of chlorite-periodate oxidation, in order to assess their efficacy as a heavy metal adsorbent. The chemically-oxidized kapok fibers were found to harbor a certain amount of polysaccharides, together with lowered lignin content. This alteration in lignin characteristics was clearly confirmed via FTIR and NBO yield. Moreover, chemically oxidized kapok fibers retained their hollow tube shape, although some changes were noted. The chemically oxidized kapok fibers evidenced elevated ability to adsorb heavy metal ions with the best fit for the Langmuir adsorption isotherm model. Three cycles of adsorption-desorption were conducted with in-between regeneration steps. Our experimental results indicated that chemically oxidized kapok fibers possessed excellent adsorption characteristics, and the modified kapok fibers could be completely regenerated with almost equimolar diluted sodium hydroxide. Pb, Cu, Cd and Zn ions evidenced adsorption rates of 93.55%, 91.83%, 89.75%, and 92.85% on the chemically oxidized kapok fibers. The regeneration efficiency showed 73.58% of Pb, 71.55% of Cu, 66.87% of Cd, and 75.00% of Zn for 3rd cycle with 0.0125N NaOH.

Effects of Boonsimgieum aqua-acupuncture on Serum and Liver Lipid Composition and Antioxidative Capacity in Rats Fed High Oxidized Fat (분심기음약침(分心氣飮藥針)이 과산화지질(過酸化脂質)을 투여한 흰쥐의 혈장(血漿) 및 간장(肝臟)지질구성과 항산화(抗酸化)에 미치는 영향 -태충혈(太衝穴)과 내관혈(內關穴)을 중심으로-)

  • Lee, Jun-Mu;Kim, Min-Ki
    • Journal of Pharmacopuncture
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    • v.7 no.3
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    • pp.37-46
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    • 2004
  • Effects of Boonsimgieum aqua-acupuncture at $Naegweun(HP_6)$ and $Taecheung(LV_3)$ on liver and plasma lipid composition and antioxidative capacity were investigated in rat fed high oxidized fat. Concentrations of plasma triglyceride, total cholesterol and LDL-cholesterol showed a tendency to increase in the high oxidized fat diet group. However these values showed a tendency to decease in aqua-acupuncture groups. HDL-cholesterol showed no significantly different in all the treatment groups. Liver total cholesterol values showed a high in control group, however other treatment groups showed no significantly different. Liver triglyceride concentration showed a high value in control group and $Naegweun(HP_6)$ aqua-acupuncture group showed lower value than $Taecheung(LV_3)$ aqua-acupuncture group. Plasma GOT and GPT values showed a tendency to increase in high oxidized fat diet group. However aqua-acupuncture groups showed a lower values than control group. The concentration of TBARS in liver and plasma showed a high values in high oxidized fat diet group, however these values showed a tendency to decrease in aqua-acupuncture group. Glutathione peroxidase, superoxide dismutase and catalase activity values showed a low values in high oxidized fat diet group, however these values showed a tendency to increase in aqua-acupuncture groups and in aqua-acupuncture groups, these values showed no significantly different.

Effect of Coatings of Oxidized Starch on Properties of Linerboard (산화전분 코팅이 골판지 원지의 물성에 미치는 영향)

  • Ahn, Byoung-Kuk;Ahn, Won-Yung
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.1
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    • pp.71-79
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    • 2000
  • Two linerboards consisting of corrugated board were coated with oxidized starch solutions to investigate the change of their properties and analyze the effect of coating on them. The coating of linerboards with oxidized starch resulted in improvement in the properties related to corrugated board properties by increasing fiber bonding and rigidity. The improvement of ring crush strength by coating was greater in inside linerboard than in outside linerboard. Burst index of linerboards rapidly increased with an initial increase of coating weight, but as the coating weight further increased, there was no increase in burst index. Coating on linerboards with oxidized starch at low coating weight improved stiffness of them. There were no significant changes in tearing resistance of linerboards by coating of oxidized starch. The coating resulted in increase in air resistance and sizing degree of linerboards.

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