• Title/Summary/Keyword: oxidized

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Physicochemical Characteristics of Waste Catalyst and Their In-Process Products from Recycling (폐촉매 및 재활용 중간생성물의 물리화학적 특성 평가)

  • Park, Joon-Seok;Jeun, Byung-Do;Kim, Joung-Dae
    • Journal of Environmental Health Sciences
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    • v.37 no.2
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    • pp.150-158
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    • 2011
  • This research was conducted to estimate the physicochemical characteristics of waste catalyst and its in-process product from recycling and to suggest fundamental data for religious systems such as quality standards. Mo and V contents were increased from the waste catalyst to calcinated material and oxidized material. In the results of a heavy metals leaching test, Pb was not detected in any catalyst, calcinated and oxidized materials. Cu was not detected in the catalyst. However, it was detected in ${\leq}$1.16 mg/l for calcinated material and in 1.34~13.73 mg/l for $MoO_3$ oxidezed material. Concentrations in recycling in-process products (calcinated and oxidized materials) were higher than those of waste catalyst. Oil content of catalyst waste ranged from 0.01-14.03 wt%. Oil contents of calcinated and oxidized materials were greatly decreased compared to the catalyst waste. Carbon and sulfur contents as chemical poisoning material of catalyst waste ranged from 0.33-76.08 wt% and 5.00-22.00 wt%, respectively. The carbon contents of calcinated and oxidized materials showed below 20 wt%. The sulfur content showed below 8wt% for calcinated material and below 0.22 wt% for oxidized material.

Biocompatibility of oxidized alginate/gelatin/BCP -based hydrogel composites

  • Phuong, Nguyen Thi;Min, Young-Ki;Yang, Hun-Mo;Song, Ho-Yeon;Lee, Byong-Teak
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.40.2-40.2
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    • 2010
  • In this study, oxidized alginate/gelatin/biphase calcium phosphate (BCP)- based hydrogel composites were fabricated. Alginate sodium was oxidized by periodate. The oxidized product was confirmed by using $^1H$ and $^{13}C$ NMR spectra. The number average molecular weight ($M_n$), the average molecular weight ($M_w$) of the oxidized alginate were determined by Gel Permeation Chromatography (GPC). The hydrogel was formed from the oxidized alginate and gelatin solution via Schift-base reaction. The hydrogel showed a highly porosity by a Scanning Electron Microscope (SEM) and Mercury Intrusion Porosimetry (MIP). Crosslinked density of the gel matrix were assessd by trinitrobenzene sulfonic acid (TNBS) assay that shows a high effect on swelling ratio. Increment of the crosslinked desity resulted in enhancing compressive strength of the hydrogel composite. The cytotoxity of hydrogel was assessed with osteoblast MG-63. The hydrogel composites show a high compatibility. The obtained results showed a potential application for bone regeneration in future.

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Effects of Powdered Siho(Bupleuri Radix) on Serum and Liver Lipid Composition and Antioxidative Capacity in Rat Fed High Oxidized Fat (시호(Bupleuri Radix)분말이 과산화지질을 급여한 흰쥐의 혈장 및 간장지질구성과 항산화능에 미치는 영향)

  • 이은주;최무영;오혜숙
    • Journal of Nutrition and Health
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    • v.33 no.5
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    • pp.502-506
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    • 2000
  • Effects of powdered siho(bupleuri radix) on serum and liver lipid composition and antioxidative capacity were investigated in rat fed high oxidized fat. Sixty male Sprague-Dawley rats weighing 161.25$\pm$2.51g were blocked into four groups according to body weight and raised seven weeks with basal diet(normal group), basal diet and 10% oxidized fat(control group), basal diet, 10% oxidized fat and 2% powdered siho(2% powdered siho group) and basal diet, 10% oxidized fat and 3% powdered siho(3% powdered siho group). Feed intake, body weight gain and feed efficiency were not significantly different among oxidized fat diet groups. The values of total cholesterol and triglyceride in plasma and liver showed no significantly different(p>0.05) in the oxidized fat diet groups. Plasma HDL-cholesterol showed atendency to increase in powdered siho diet groups. The values of thiobarbituric acid in plasma and liver were lower in the powdered siho diet groups than control group. Plasma GOT and GPT activity showed a tendence to decrease in powdered siho groups. Liver glutathione peroxidase activity showed a tendence to increase in powdered siho diet groups. Thus, it seems that powdered siho had some antioxidative elements.

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Physicochemical Properties of Oxidized Waxy Maize Starches with Sodium Hypochlorite (찰옥수수 산화전분의 이화학적 특성)

  • Chung, Man-Gon;Jeon, Young-Seung;Lee, Sur-Koo;Park, Jong-Moon;Lim, Bun-Sam
    • Korean Journal of Food Science and Technology
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    • v.30 no.1
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    • pp.42-48
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    • 1998
  • Physicochemical properties of waxy maize starch and oxidized waxy maize starch with sodium hypochlorite $(0{\sim}60\;mg\;CL_2/g\;starch,40^{\circ}C,\;pH\;10,\;3.0\;hr)$ were studied. As sodium hypochlorite concentration was increased, the content of crude lipid and crude protein of the oxidized starch were decreased. And crude protein content and whiteness was considered to show negative regression. However, the crude ash content of the oxidized starch increased significantly with oxidation and bore a positive regression to the chlorine content. There was a progressive increase in the carboxyl content with increasing oxidant level. After pasting in hot water and cooling, viscosity of the oxidized starches were drastically lower than that of native starch . As carboxyl contents of the oxidized starch increased, the solubility and swelling power was increased. When waxy maize starch treated with 0, 1.5, 3.0 and 6.0% sodium hypochlorite, temperature of initial gelatinization of oxidized starch was shown to 65, 65, 60 and $50^{\circ}C$, respectively. The oxidized waxy maize starches also form clearer pastes. Water binding capacity of the oxidized starch decreased as the degree of carboxyl group substitution increased. Waxy maize starch has polygonal and some round granules which range from about 3.7 to $20\;{\mu}m$ in diameter. Surface appearance of the waxy maize starch became rough when oxidized with sodium hypochlorite. When homogenate of the oxidized waxy maize starch solution and corn germ oil was stored under room temperature for 24 hours, the emulsion stability was considered to depend on starch concentration and degree of substitution.

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A Wavepacket Study on Translational Energy Distributions of the Photo-stimulated Desorbed Xe from an Oxidized Si(001) Surface

  • Abe, Atsutoshi;Yamashita, Koichi
    • Bulletin of the Korean Chemical Society
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    • v.24 no.6
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    • pp.691-694
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    • 2003
  • We report a quantum wavepacket study on the characteristic bimodal translational energy distribution of photostimulated desorbed Xe from an oxidized silicon (001) surface observed by Watanabe and Matsumoto, Faraday Discuss. 117 (2000) 203. We have simulated the theoretical translational energy distributions based on wavepacket calculations with a sudden transition and averaging model to reproduce the experiment. We discuss the desorption mechanism and suggest a very strong position dependence of the deexcitation processes for Xe/oxidized Si(001).

Effects of Vitamins and Glycyrrhizin Added to Oxidized Diets on the Growth and on the Resistance to Edwardsiella Infection of Nile Tilapia, Oreochromis niloticus (산화된 사료에 첨가한 비타민과 Glycyrrhizin이 나일틸라피아의 성장 및 Edwardsiella 감염시 저항력에 미치는 영향)

  • JANG Seon-Il;JO Jae-Yoon;LEE Joo-Seok
    • Journal of Aquaculture
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    • v.5 no.2
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    • pp.143-155
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    • 1992
  • Effects of vitamin E, C and/or glycyrrhizin in the artificially oxidized feed on the growth and on the resistance aganist Edwardsiella tarda infection to Nile tilapia, Oreochromis niloticus, were examined. The thiobarbitric acid (TBA) values of the oxidized feed were $80\~88$ mg/kg. The fingerling fish were fed the oxidized feed with or without the mixture of vitamin E (50 mg), C (60 mg) and/or glycyrrhizin ($25\~200$ mg) per 100 g of the feed for 7 weeks. The fish fed the oxidized feed with vitamin E, C and/or glycyrrhizin showed better growth than the fish fed the oxidized feed only. But growth rates among the fish fed different amount of vitamins or glycyrrhizin mixed feed were not different. Glutamic oxaloacetic transaminase (GOT) and glutamic pyruvic transaminase (GPT) levels in the serum increased only in the fish which were fed oxidized feed without vitamin E, C and/or glycyrrhizin. With the fish artificially infected with E. tarda: they showed low survival rate when fed oxidized feed and oxidized feed plus 25 mg glycyrrhizin per 100 g feed. The fish fed oxidized feed plus vitiamin E, C and/or glycyrrhizin ($50\~200$ mg/100 g), showed higher survival. These results show that the supplementation of oxidized lipids depress the growth and liver activity, while the addition of vitamin E, C and/or glycyrrhizin in the diet accelerated the growth, liver activity, and the resistance to E. tarda infection.

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Effect of Dietary Oxidized Squid Liver oil and DL-${\alpha}$-Tocopherol Level on Growth and Body Composition of Juvenile Flounder (Paralichthys olivaceus) (사료내 산패 지질 및 비타민 E 첨가가 넙치 치어의 성장 및 체조성에 미치는 영향)

  • Kim Kyoung-Duck;Kang Yong-Jin;Lee Moon Hae-Young;Kim Kang-Woong;Lee Sang-Min
    • Journal of Aquaculture
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    • v.19 no.2
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    • pp.140-146
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    • 2006
  • This study was conducted to investigate the effect of dietary oxidized oil and ${\alpha}$-tocopherol level on growth and body composition of juvenile flounder. To prepare oxidized diets, squid liver oil was oxidized by aeration at $25^{\circ}C$ for 30 days. The six diets were prepared to contain 6% fresh or oxidized squid liver oil as the lipid sources in combination with three levels of ${\alpha}$-tocopheryl acetate at 0, 80 and 800 mg/kg diet. Triplicate groups of fish ($3.9{\pm}0.1$) were fed to apparent satiation twice a day for 8 weeks. Survival was not significantly different among treatments. Weight gain, feed efficiency, daily feed intake, protein efficiency ratio and condition factor of fish fed the fresh oil diets were significantly higher than those of fish fed the oxidized oil diets (P<0.05). The increase of the vitamin E level in diets did not result in any significant improvement on growth performance of fish fed both oil diets. The vitamin E content of the liver and dorsal muscle increased with increasing dietary vitamin E level at both oil diet groups. A decreasing trend in vitamin E content of the tissues was observed in fish fed the oxidized oil diets at the same dietary vitamin E level. Significantly higher moisture content and lower crude lipid content were observed in the whole body of fish fed the oxidized oil diets than fish fed the fresh oil diets (P<0.05). Dietary lipid source affected the fatty acid content of the whole body; higher contents of saturated and monoenoic fatty acids, and lower n-3 HUFA contents such as 20:5n-3 and 22:6n-3 were observed in fish fed the oxidized oil diets than those of fish fed fresh oil diets. The results of this study suggest that the dietary oxidized oil may impair the growth performance, and an increase in ${\alpha}$-tocopheryl acetate supplementation have no beneficial effect on growth and feed efficiency of juvenile flounder.

Immune response and antioxidant status of broilers as influenced by oxidized vegetable oil and pomegranate peel

  • Ghasemi-Sadabadi, Mohammad;Ebrahimnezhad, Yahya;Maheri-Sis, Naser;Ghalehkandi, Jamshid Ghiasi;Shaddel-Teli, Abdolahad
    • Journal of Animal Science and Technology
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    • v.63 no.5
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    • pp.1034-1063
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    • 2021
  • The experiment was designed as a 3 × 3 × 2 factorial arrangement of treatments, including (i) pomegranate peel (zero, 4%, and 8 percent), (ii) oxidized soybean oil (zero, 2%, and 4 percent), and (iii) alpha-tocopherol (zero and 200 mg/kg). Supplementation of 8% pomegranate peel in diets significantly decreased the growth performance of broiler chickens. The supplementation of 4% oxidized oil in diets significantly reduced body weight gain and Feed intake whole experimental period (p < 0.05). The results showed that supplementation of 4% pomegranate peel in the diet was associated with low aspartate transaminase (AST), alanine transaminase, and malondialdehyde (MDA). However, 4% pomegranate peel increased the total antioxidant capacity (TAC) and superoxide dismutase (SOD) and glutathione peroxidase (GPx) activities. The supplemental 4% oxidized oil increased the serum AST, alanine aminotransferase (ALT), and MDA concentrations. TAC, SOD, and Catalase (CAT) activities were affected by 4% oxidized oil and alpha-tocopherol. The use of oxidized oil and vitamin E decreased MDA concentration. The serum glucose and globulin concentrations were significantly lower in the 8% pomegranate peel. The results showed that supplementation with 4% pomegranate peel in diets reduced serum low-density lipoprotein (LDL). The inclusion of 4% oxidized oil in diets reduced serum glucose and increased the blood lipid concentration such as triglyceride, cholesterol and LDL. Vitamin E supplementation reduced the serum cholesterol and LDL concentrations. The use of 8% pomegranate peel reduced red blood cell (RBC), hemoglobin, and packed cell value (PCV). The results indicated that supplementation with 8% pomegranate peel and 4% oxidized oil in diets decreased the immunoglobulin concentration in broilers. In addition, it was found that the inclusion of 4% pomegranate peel in diets resulted in higher IgG, IgM and total immunoglobulin. Pomegranate peel supplementation significantly decreased meat MDA concentration. Supplementation of 4% oxidized oil increased MDA of meat (p < 0.05). Vitamin E supplementation (200 mg/kg) significantly decreased MDA of meat (p < 0.05). Consequently, the results of this experiment showed that supplementation with 4% pomegranate peel had beneficial effects on broiler chickens. It was also found that feeding 2% oxidized oil in diets had no adverse effect on broilers.

Study on Commercialization of Ready-to-Eat Pear Products by Development of Anti-browning Agents (갈변방지제 개발을 통한 신선편이 조각 배 상품화 연구)

  • Kim, Mi Young;Zhang, Cheng Yu;Lee, Jin Ju;Huang, Ying
    • The Korean Journal of Food And Nutrition
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    • v.30 no.1
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    • pp.139-147
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    • 2017
  • The objective of this study was to develop anti-browning agents for commercial ready-to-eat pear products, which are preferred not only to maintain the flavor, color and texture of pears, but also to increase consumers' preference. The sliced 'Shin-go (Niitaka)' pears were immersed in 5% and 10% oxidized starch, 1% citric acid, and 5% and 10% oxidized starch with addition of 0.1% sucralose for 3 minutes, and then they were packaged in vacuum sealed bags at $1^{\circ}C$ for 9 days. In order to evaluate the quality of packaged sliced pears, the quality index was determined in terms of color, firmness, soluble solids, and sensory quality. With the passage of storage time, no specific variation in firmness and soluble solids was observed. However, the ${\Delta}E$ value of the sliced pears treated with 5% oxidized starch solution was significantly lower than that of the other pears. Also, the Hunter L and b values of the sliced pears treated with 5% oxidized starch solution remained nearly constant from the beginning of storage. This observation shows that 5% oxidized starch solution was effective in reducing surface browning of sliced pears. Moreover, sliced pears treated with oxidized starch solution with addition of 0.1% sucralose were given an overall liking score which was slightly higher than that given to the other pears because of the sweetness of sucralose. In conclusion, 5% oxidized starch solution with addition of 0.1% sucralose was effective in reducing browning of sliced pears and in improving the taste of sliced pears.

Effect of Antioxidants and Oxidized Fat on the Performance of Broiler Chicks (항상화제와 산패지방이 육계의 생산성에 미치는 영향)

  • 남궁환;스티브리슨;백인기
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2000.11a
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    • pp.36-53
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    • 2000
  • Five experiments were conducted to investigate the effects of antioxidants(Santoquin and Oxiban) using fresh or oxidized fat on the performance of broiler chicks. Day-old broiler chicks (except for Experiment 5 in which 6-d-ol birds were given experimental diets for 10 d) were fed diets containing fresh or oxidized fat (animal-vegetable fat blend in Experiments 1, 4, and 5 and corn oil in Experiments 2 and 3) with or without graded concentrations of Santoquin (0,250, 500 ppm in Experiments 1 and 2 and 0, in Experiment 4 and 400 ppm with 0.1% lipase in Experiment 5) of 2wk. In all experiments, birds fed fresh fat gained more weight, had better feed/gain, together with higher AME$_{n}$ and apparent fat digestibility (Experiments 1 and 2) than birds fed oxidized fat(P<0.05). There was no interaction among fat sources and antioxidants on the performance of chicks in any experiment. In Experiment 3, Santoquin more than 200 ppm resulted in a reduction in weight gain and feed intake(P<0.05). The livers of chicks fed oxidized fat in Experiments 2 and 5 had higher malondialdehyde (MDA) values (P<0.05) Chicks fed oxidized fat with 250 ppm Santoquin in Experiment 2 had lower liver MDA values, although this situation did not occur in Experiments 1, 4, and 5. These results indicate that antioxidant supplements can alleviate most deleterious effects of feeding oxidized fat and that supplementation of Santoquin more than 200 ppm has a negative effect on the performance of broiler chicks.s.

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