• 제목/요약/키워드: oxidize

검색결과 205건 처리시간 0.029초

ALDH and CYP2E1 Single Nucleotide Polymorphism Distribution in Korean

  • Han, Dong-Hoon;Kim, Jeong-Hee
    • International Journal of Oral Biology
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    • 제31권3호
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    • pp.107-112
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    • 2006
  • Aldehyde dehydrogenase (ALDH) plays an important role in alcohol metabolism; ALDH is responsible for the oxidation of acetaldehyde generated during alcohol oxidation. ALDH is also known to oxidize various other endogenous and exogenous aldehydes. Cytochrome P-450 2E1 (CYP2E1), a liver microsomal enzyme, also metabolizes acetaldehyde and ethanol and can be induced by other inducers including acetone and ethanol. We examined single nucleotide polymorphisms (SNP) of ALDH and CYP2E1 genotypes in Korean. Restriction fragment length polymorphism (RFLP) method was used to determine ALDH and CYP2E1 SNP. Mutation in ALDH was 60% (heterozygote 46.7% and homozygote 13.3%) among 15 cases. CYP2E1 mutation was 52.7% (heterozygote 47.4% and homozygote 5.3%) among 19 cases.

5% $Cr_2O_3/{\gamma}-Al_2O_3$ Catalysts Synthesized as Research for Oxidation Activation of Trichloroethylene

  • Myung, So-Young;Suh, Myung-Gyo;Lee, Yong-Hee
    • 한국환경보건학회:학술대회논문집
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    • 한국환경보건학회 2005년도 Proceedings of KSEH.Minamata Forum
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    • pp.78-82
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    • 2005
  • The research addressed the ability of 5% $Cr_2O_3/{\gamma}-Al_2O_3$ to catalytically oxidize trichloroethylene(TCE). In order to determine which procedure gives the most active catalyst among the attempted several procedures, catalytic oxidation reaction of TCE was conducted to every catalysts synthesized according to different process in tubular reactor system, which had functional relationships with temperature and space velocity. The ratio of TCE conversion was analyzed by gas chromatography with electron capture detector.

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Methodology to Simultaneously Optimize the Inlet Ozone Concentration to Oxidize NO and Relative Humidity Composition for the $NO_x$ Degradation using Soil Bio-filter

  • Cho, Ki-Chul;Hwang, Kyung-Chul
    • Journal of Korean Society for Atmospheric Environment
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    • 제24권E2호
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    • pp.83-91
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    • 2008
  • This work investigated the methodology to simultaneously optimize the ozone and relative humidity composition for the $NO_x$ degradation using soil biofilter. Experiments were made as a function of inlet ozone concentration ($0{\sim}1,770\;ppb$) and relative humidity ($38{\sim}81%$). Factorial design ($2^2+3$) and response surface methodology by central composite designs were used to examine the role of two factors and optimal response condition on $NO_x$ degradation. It was found that a second-order response surface model can properly interpret the experimental data with an $R^2$-value of 0.9730 and F-value of 71.83, based on which the maximum $NO_x$ degradation was predicted up to 92.8% within our experimental conditions.

이산화티탄($TiO_2$ anatase) 분말을 광촉매로 사용한 노출 콘크리트의 VOCs(Benzene, Toluene)와 질소산화물(NOx) 제거 특성 연구 (The Properties of VOCs(Benzene, Toluene) with NOx Removal in Exposed Concrete With $TiO_2$(Anatase type) Powder as Photocatalyst)

  • 김광련;이동범;김화중
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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    • pp.588-591
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    • 2004
  • Generally, $TiO_2$ powders absorb ultraviolet rays and make oxidation/reduction reactions on its surface. Hydroxide radical(OH), a product of photocatalyst reactions, has so strong oxidation/reduction electric potential that it can oxidize noxious gas like VOCs(Volatile Organic Compounds) and NOx. In this study, $TiO_2$ was substituted for exposed concrete to investigate the purifying degree of VOCs(Benzene, Toluene) and NOx. Anatase types of $TiO_2$ were used as photocatalyst. The sun rays and the ultraviolet were used as a light source. Anatase type $TiO_2$ was better than rutile type in purifying performance. The sunray showed the best purifying performance among the light sources. $3\%$ substitution of $TiO_2$ with the sunray was enough to purify VOCs(Benzene, Toluene) and NOx efficiently.

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AC 스트리머 코로나 방전으로 생성된 O 라디칼과 매연 입자의 산화반응 (Oxidation of Soot Particles with O Radicals Generated in a AC Streamer Corona Discharge)

  • 김필승;이교승;황정호
    • 한국연소학회지
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    • 제8권1호
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    • pp.9-16
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    • 2003
  • Carbon soot emission from combustion processes, especially from diesel engines, is a subject of growing concern since soot is known to seriously affect human health. Efforts have been made to oxidize soot particles utilizing Non-Thermal Plasma(NTP) techniques. When oxygen is carried into a plasma device, electrons generated by the plasma dissociate the oxygen, resulting in the formation of oxygen atoms. These highly activated atoms, called O radicals, are known as strong oxidizing agent. This paper presents concentration variations of CO and $CO_2$ at the exit of the plasma device, resulting from the soot oxidation by O radicals, with variations of inlet oxygen concentration, gas temperature, and gas flow rate. Based on the data, Arrehenious rate constants of reactions between C(s)+O and C(s)+O+O were proposed.

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Community-acquired Achromobacter xylosoxidans infection presenting as a cavitary lung disease in an immunocompetent patient

  • Hwang, Chan Hee;Kim, Woo Jin;Jwa, Hye Young;Song, Sung Heon
    • Journal of Yeungnam Medical Science
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    • 제37권1호
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    • pp.54-58
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    • 2020
  • Achromobacter xylosoxidans is a gram-negative bacterium that can oxidize xylose. It is commonly found in contaminated soil and water but does not normally infect immunocompetent humans. We report a case of a cavitary lung lesion associated with community-acquired A. xylosoxidans infection, which mimicked pulmonary tuberculosis or lung cancer in an immunocompetent man. The patient was hospitalized due to hemoptysis, and chest computed tomography (CT) revealed a cavitary lesion in the superior segment of the left lower lobe. We performed bronchoscopy and bronchial washing, and subsequent bacterial cultures excluded pulmonary tuberculosis and identified A. xylosoxidans. We performed antibiotic sensitivity testing and treated the patient with a 6-week course of amoxicillin/clavulanate. After 2 months, follow-up chest CT revealed complete resolution of the cavitary lesion.

Oxidation of Dibenzothiophene Catalyzed by Surfactant-Hemoprotein Complexes in Anhydrous Nonpolar Organic Solvents

  • Ryu, Keun-Garp;Chae, Young-Rae;Kwon, O-Yul
    • Journal of Microbiology and Biotechnology
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    • 제13권5호
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    • pp.647-650
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    • 2003
  • In anhydrous organic solvents, the complexes formed between AOT (dodecylbenzene sulfuric acid sodium salt) and hemoproteins, such as hemoglobin, myoglobin, or cytochrome c, displayed remarkably higher activity than the hemoprotein powders to oxidize dibenzothiophene, a model compound of organic sulfurs contained in fossil fuels. In slightly hydrophobic organic solvents, such as ethyl acetate and butyl acetate, dibenzothiophene was completely oxidized catalytically by the cytochrome c-AOT complex with cumene hydroperoxide (${\alpha},{\alpha}-dimethylbenzyl$ hydroperoxide) as an oxidant. In highly hydrophobic organic solvents, such as decane and hexadecane, however, the activity of the cytochrome c-AOT complex decreased, presumably due to the aggregation of the hemoprotein-AOT complex in these solvents.

Manufacture of Vanadium pentoxide and nickel sulfate from heavy oil fly ash

  • Park, Gyeong-Ho
    • 자원리싸이클링
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    • 제2권4호
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    • pp.23-26
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    • 1993
  • This work is carried out to develop the recovery process of vanadium as vanadium pentoxide and nickel as nickel sulphate from the leaching solution of heavy oil fly ash. First, sodium chlorate solution was added to the leaching solution to oxidize vanadium ions. With adjusting pH of the solution and heating, vanadium ions(V) is hydrated and precipitated as red cake of $V_2O_5$ from the solution. After recovering vanadium, nickel is recovered as ammonium nickel sulfate with crystallization process. From this nickel salt, nickel sulfate which meets the specifications for the electroplating industry can be produced economically. More than 85% of vana-dium and nickel in the fly ash are recovered in this process.

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과산화수소를 이용한 몰리브덴(Mo.) 용해반응에 따른 청정기술 개발에 관한 연구(I) (A Clean Technic Development using the Molybdenum Dissolution Reaction with Hydrogen Peroxide(I))

  • 김재우;홍종순;신대윤
    • 환경위생공학
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    • 제14권2호
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    • pp.1-7
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    • 1999
  • In the tungsten industry as light source material, tungsten filament which used as light source material ould form after molybdenum wire which used as the center supporter for coil shape tungsten wire was removed. The purpose of this study is to develop new process named "hydrogen peroxide dissolution method". This process uses hydrogen peroxide, which is harmless to human body and oxidize molybdenum wire selectively. The results were as follows:1. The dissolution of molybdenum wire was proportion to a solution and contact surface of molybdenum wire. 2. The optimum $H_2O_2/H_2O$ were 1:0.5 ~ 1:1.75. 3. The time of dissolution was 65~70 minutes, and the PCS of sample were 20,800 PCS(1,820g). 4. Total cost($H_2O_2$, catalyst) was ₩19,088.

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Synthesis of Antioxidant and Evaluation of Its Oxidation Stability for Biodiesel

  • Park, Soo-Youl;Shin, Seung-Rim;Shin, Joung-II;An, Kyoung-Lyong;Jun, Kun
    • Tribology and Lubricants
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    • 제29권6호
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    • pp.392-396
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    • 2013
  • Biodiesel fuels contain unsaturated fatty acid ester, which can easily oxidize, especially when exposed to ultraviolet light. The products formed by this oxidation give rise to sediment or gum formation. As a result, the fuel can contribute to the corrosion and plugging of the filter pump. Antioxidants have been used in an effort to stabilize biodiesels, but there is still a need for a biodiesel composition with improved oxidation stability. In general, good fuel compositions should provide synergistic combinations of a biodiesel and antioxidants. Our work involved the synthesis of antioxidants to improve the oxidative stability of biodiesel fuel.