• Title/Summary/Keyword: overall conversion

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Conversion of Beef Tallow and Its Mixed Fat into Biodiesel by Alkali Catalysts (알칼리 촉매에 의한 우지(Beef Tallow)와 그 혼합지방의 Biodiesel화)

  • Hyun, Young-Jin;Kim, Hae-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.2
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    • pp.190-195
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    • 2007
  • The transesterifications of beef tallow and the mixture of beef tallow and rapeseed oil were conducted at $65^{\circ}C$ respectively using TMAH, NaOH and their mixed catalysts. The reactants were emulsified with 1vol% emulsifier and propylene glycol. The overall conversion of beef tallow was 95% at such optimum conditions as the 1:8 of molar ratio and 0.8 wt% TMAH. The overall conversion of mixed fat at the 1:8 of molar ratio and mixed catalyst of 70 wt% TMAH 30 wt% NaOH was close to 97% which appeared at 0.8 wt% TMAH in 80min. And the kinematic viscosity of biodiesel mixture using the mixed catalyst was $6.5mm^2/s$ at $40^{\circ}C$.

Overall Conversion Efficiency for Dimethylsulfide to Sulfur Dioxide in the Marine Boundary Layer-An Overview

  • Shon, Zang-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E2
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    • pp.107-120
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    • 2002
  • Dimethyl sulfide (DMS) is the major sulfur gas released from the ocean. The atmospheric DMS released from the ocean is oxidized mainly by hydroxyl (OH) radical during the day and nitrate (NO$_3$) radical at night to form sulfur dioxide (SO$_2$) as well as other stable products. The oxidation mechanism of DMS via OH has been known to proceed by two channels; abstraction and addition channels. The major intermediate product of the addition channel has been known to be dimethylsulfoxide (DMSO) based on laboratory chamber studies and field experiments. However, a branching ratio for DMSO formation is still uncertain. The reaction of DMSO with OH ultimately produces SO$_2$and dimethylsulfone. The major product of the abstraction channel has known to be SO$_2$from laboratory chamber studies. But overall conversion efficiency for DMS to SO$_2$from DMS oxidation is still inconsistent in the literature. Based on laboratory and field studies, the conversion efficiency from the abstraction channel is likely to be greater than 0.5, while that from the addition channel is likely to be greater than 0.6. Overall conversion efficiency from DMS to SO$_2$might be greater than 0.5 based on the above two values in the remote marine boundary layer (MBL). This high efficiency in the remote MBL is supported by strong coupling between DMS and SO$_2$measurements with high temporal resolution.

Conversion of Mixed Fat into Biodiesel in Plug Flow Reactor Using Alkali and Mixed Catalysts (관형반응기에서 알칼리 및 혼합촉매를 사용한 혼합지방의 바이오디젤화)

  • Hyun, Young-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.2
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    • pp.123-128
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    • 2010
  • The continuous transesterification of mixed fat was done on the plug flow reactor packed with the static mixers. The transesterification using 0.5 wt% KOH, 0.8 wt% TMAH and mixed catalyst[40 v/v% KOH(0.5 wt%)+60 v/v% TMAH(0.8 wt%)] was conducted with the changes of molar ratios, weight percentage of beef, flow rates and number of static mixer's elements at $65^{\circ}C$. The overall conversion of mixed fat at 1:8 molar ratio, 50 wt% of beef and 24 of static mixer's elements increased until 0.7mL/min of flow rate. The overall conversion of mixed fat showed 96% at those conditions. So, the optimum operating conditions on tublar reactor were 1:8 molar ratio, 50 wt% of beef, 0.7 mL/min of flow rate and 24 of static mixer' s elements.

Effect of Zeranol Injection on Dry Matter and Nutrient Intake Requirements at Growth Stages of Holsein Steer (Zeranol 투여가 홀스타인 거세우의 성장 단계별 건물 및 양분 섭취량에 미치는 영향)

  • 김현섭;권응기;윤상기;신종서;홍병주
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.17 no.4
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    • pp.399-406
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    • 1997
  • This research was carried out to investigate the effect of zeranol injection on dry matter(DM) and nutrient intake requirement by growth stage of early castrated bull with 3 treatments(bul1, steer, steer+zeranol) with 28 Holstein bull at National Livestock Research Institute. The main results were as follows: DM intake at growing and fatting stage was the highest in steer groups, that the highest in bull groups at finishing stage and overall mean DM intake was 5% lower at steer+zeranol groups compared to bull and steer, respectively. Net energy intake at finishing stage was the highest as 35.49 Mcal at bull groups, while overall mean net energy intake was 101 - 109% of NRC requirement without significant difference. Concentrate intake to body weight was 1.68- 1.82, 1.91 -2.08 and 1.81 -2.05% at growing, fatting and finishing stage, respectively. Overall mean concentrate intake to body weight at steer groups was 1.94%, which is 1.8 and 1.81% higher compared to bull and steer+zeranol groups, respectively. Feed conversion ratio(DM) during overall period was the worst at steer groups as 9.321g, and also net energy conversion ratio was similar to DM conversion ratio.

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Biomass Conversion Efficiencies of Fish Pond Fertilization and Feed Supplementation

  • Mahboob, Shahid;Sheri, A.N.
    • Asian-Australasian Journal of Animal Sciences
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    • v.11 no.2
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    • pp.192-195
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    • 1998
  • Biomass conversion efficiencies (B.C.E) of six fish species viz, Catla catla, Labeo, rohita, Cirrhina mrigala, Hypophthalmicthys molitrix, Ctenopharyngodon idella and Cyprinus carpio cultured under artificial feed (T1), broiler manure (T2), buffalo manure (T3), N:P:K (25:25:0) (T4) and control pond (T5) have been determined for the period of one year. The overall biomass conversion efficiencies under the influence of T2, T3, and T4 were statistically similar. However, the best (0.40) efficiency was determined under feed supplement-ation (T1).

Conversion of Rapeseed Oil Containing Palmitic Acid into Biodiesel by Acid/Alkali Catalysts (산/알칼리 촉매에 의한 팔미트산 함유 유채유의 Biodiesel화)

  • Hyun, Young-Jin;Kim, Hae-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.4
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    • pp.300-306
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    • 2006
  • The esterification of palmitic acid in rapeseed oil and methanol emulsified by propylene glycol with PTSA(p-toluene sulfonic acid) was followed by the transesterification of rapeseed oil into biodiesel with 1(w/v)% GMS(glycerol monostearate) as an emulsifier using TMAH(tetramethyl ammonium hydroxide) catalysts at $60^{\circ}C$. The former reaction was optimized at the 1:20 of molar ratio of oil to methanol and 5wt% PTSA, and the latter was optimized at the 1:8 of molar ratio of oil to methanol and 0.8wt% TMAH. The overall conversion into biodiesel was 98% after 60min of reaction time at the 1:8 of molar ratio, 0.8wt% TMAH and $60^{\circ}C$. TMAH was a good catalyst to control the viscosity of biodiesel mixture.

Conversion of Jatropha Oil into Biodiesel in Continuous Process Using Alkali and Mixed Catalysts (연속공정에서 알칼리 및 혼합촉매를 사용한 자트로파유의 바이오디젤화)

  • Hyun, Young-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.4
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    • pp.394-399
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    • 2009
  • The esterification of palmitic acid in Jatropha Oil using 8wt% p-TSA catalyst was done at the 1:8 molar ratio of oil to methanol and $65^{\circ}C$. The conversion of palmitic acid appeared to be 95.3% in 60min. After that, the continuous transesterification of the oil using 0.5wt% KOH, 0.8wt% TMAH mixed catalyst[40vol% KOH(0.5wt%) + 60vol% TMAH(0.8wt%)] and 1.1wt% TMAH was conducted with the flow rates and the molar ratios at $65^{\circ}C$. The overall conversion of Jatropha Oil increased with the decrease of flow rate and showed 95.6% with 9ml/min of flow rate at the 1:8 molar ratio of oil to methanol and $65^{\circ}C$. But it showed 87% with 15ml/min of flow rate at the same conditions. The recovery of methanol(%) appeared to be 86% at the 1:8 molar ratio of oil to methanol, mixed catalyst and $65^{\circ}C$.

Test on Characteristics of Delta Conversion UPS System (델타변환 무정전전원장치 시스템의 특성 시험)

  • Ji Jun-Keun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.6
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    • pp.491-496
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    • 2005
  • In this paper, test on characteristics of 3-phase line-interactive UPS system, known as delta conversion UPS system, is studied. Delta conversion UPS system is new line-interactive UPS system using two series-parallel PWM converters instead of using series inductor in conventional single conversion line-interactive UPS system. It is known that the characteristics of input and output in delta conversion UPS system is much improved by controlling source current of AC lines directly. Here the results on load test, normal/backup mode test, and normal/bypass mode test, which are very important in the test on characteristics of UPS system, is presented. And finally overall evaluation on delta conversion UPS system is given.

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Voltage Clamped Tapped-Inductor Boost Converter with High Voltage Conversion Ratio (고승압비를 갖는 전압 클램프 탭인덕터 부스트 컨버터)

  • Kang, Jung-Min;Lee, Sang-Hyun;Hong, Sung-Soo;Han, Sang-Kyoo
    • The Transactions of the Korean Institute of Power Electronics
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    • v.17 no.1
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    • pp.34-40
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    • 2012
  • In this paper, voltage clamped tapped-inductor boost converter with high voltage conversion ratio is proposed. The conventional tapped-inductor boost converter has a serious drawback such as high voltage stresses across all power semiconductors due to the high resonant voltage caused by the leakage inductor of tapped inductor. Therefore, the dissipative snubber is essential for absorbing this resonant voltage, which could degrade the overall power conversion efficiency. To overcome these drawbacks, the proposed converter employs a voltage clamping capacitor instead of the dissipative snubber. Therefore, the voltage stresses of all power semiconductors are not only clamped as the output voltage but the power conversion efficiency can also be considerably improved. Moreover, since the energy stored in the clamp capacitor is transferred to the output side together with the input energy, the proposed converter can achieve the higher voltage conversion ratio than the conventional tapped-inductor boost converter. Therefore, the proposed converter is expected to be well suited to various applications demanding the high efficiency and high voltage conversion ratio. To confirm the validity of the proposed circuit, the theoretical analysis and experimental results of the proposed converter are presented.

Improving the Performances of Dye-Sensitized Solar Cell by the Optimal $TiO_2$ Photoelectrode Thickness and Light-Scattering Enhancement (최적 $TiO_2$ 전극 두께 및 광산란 증가에 의한 염료감응형 태양광전지의 효율 개선)

  • Niu, Zeng Yuan;Kweon, Hyun Kyu;Park, Chang Yong
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.2
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    • pp.37-44
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    • 2014
  • In this study, the performance of dye-sensitized solar cells with different thickness of the photelectrode film was simulated by using the electron-diffusion differential model. Through this simulation, the relationships between the thickness of the photoelectrode film and the performances (open-circuit voltage, short-circuit current density, and overall photoelectric-conversion efficiency) of cells were understood and the performances with different thickness of the photoelectrede film were also examined. For considering the refractive index in the liquid electrolyte and exploring the scattering effect of titanium dioxide particles with different sizes using the Mie light-scattering theory, the highest scattering effect of each particles was found out and the optimal size of the titanium dioxide particle was determined for light scattering in the photoelectrode film of dye-sensitized solar cell. Through experiment, the mixed titanium dioxide cell was better than the single titanium dioxide cell and generated a higher overall conversion efficiency because the optimal titanium dioxide particles in the phoelectrode film as light scattering.