• Title/Summary/Keyword: organosolv pulping

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Preliminary Study on Organosolv Pulping of Acacia Hybrid

  • Chong, Eunice Wan Ni;Liew, Kang Chiang;Phiong, Siaw Kian
    • Journal of Forest and Environmental Science
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    • v.29 no.2
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    • pp.125-130
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    • 2013
  • An attempt was made on pulp production from the fast growing plant, Acacia hybrid to determine the total yield, screened yield, Kappa number, and fibre morphology of organosolv Acacia hybrid pulp. Uniform-sized chips were taken to undergo pulping in a digester with five different concentrations of ethanol, 50%, 60%, 70%, 80% and 90% (v/v) with 1 M of sodium hydroxide as catalyst. All chips were digested in a temperature-controlled digester with constant amount of water added and temperature of $185^{\circ}C$ with the duration of three hours cooking time and correspond pressure 1.1-1.2 MPa. It was observed that increasing of ethanol concentration has led to pulp yield increment and decreased in the degree of delignification at the same time. This study was aimed to focus on the effect of the varied concentration of organic solvent towards the pulp yield and its relationship with Kappa number and pulp yield.

Evaluation of Defiberation by Organosolv Ethanolamine Pulping for Integral Utilization of Oil Palm EFB (오일팜 바이오매스 EFB 고도 활용을 위한 Organosolv 에탄올아민 펄핑에 따른 섬유화 특성평가)

  • Kim, Chul-Hwan;Kim, Dong-Seop;Sung, Yong Joo;Hong, Hae-Eun;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.67-74
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    • 2013
  • Organosolv ethanolamine pulping for oil palm empty fruit bunches(EFB) were evaluated in this study. The screen yield by the ethanolamine pulping were higher than that by the soda pulping at the same operation conditions. The higher concentration of ethanolamine solvent resulted in the higher yield and the lower contents of residual lignin. The EFB pulp fibers were the narrower in fiber width but the higher in coarseness than those of the hardwood pulp fiber, while the fiber length of the EFB pulp fiber were similar to that of the hardwood fiber. The intrinsic zero span tensile testing showed the EFB pulp fiber by the 80% ethanolamine pulping were the stronger than the fiber by the soda pulping. The results of this study supported that the ethanolamine pulping could be used as an alternative pulping method for the EFB.

Separation and Utilization of Main Components of Hardwood by Organosolv Pupling (Organosolv 방법(方法)에 의(依)한 활엽수(闊葉樹) 주요(主要) 조성분(組成分)의 분리(分離) 및 이용(利用))

  • Paik, Ki-Hyon;An, Byoung-Jun;Nahm, Won-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.16 no.4
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    • pp.70-78
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    • 1988
  • To separate and utilize the main components of hardwood (Quercus mongolica) by organosov pulping (ester pulping), chips were cooked at various conditions such as; the solvent ratio (acetic acid: ethylacetate: water, 50:25:25; 33:33:34; 25:50:25), maximum temperature (165, 170, $175^{\circ}C$), and cooking times (2, 2.5, 3 hr). The pulps were bleached by the sequences of CEDED, C/DEDED, PEDED. Lignin, sugars, and acetic acid were separated from black liquor and washing liquors. 1. The selective delignification at optimal pulp yield (43-45%) was obtained by cooking at acetic acid: ethylace tate: water ratio of 33:34:34 for 3 hr at $170^{\circ}C$. But in this case, kappa no. of the pulp was not reduced under 60 points. 2. Kappa no. of the pulp could be dropped by an acetone wash to remove reprecipitated lignin a t cooked pulp. 3. The unbleached pulps had a brightness of 45-50%, whereas the bleached pulps gave at 88-93% brightness. Tensile, burst, and tear strengths of the bleached pulps were lower than those of kraft pulp, especially in tear strength. The pulps which were bleached with CEDED sequence were higher in strengths than another bleaching sequences. 4. Lignin of 90-95%(lignin base on wood)was separated from black liquor and washing liquors, while the purified sugars and recovery of acetic acid were a low. An organic phase composed of acetic acid, ethylacetate, and water was separated to a two-phase system by proper adjustment of the solvent ratios.

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Delignification of Lignocellulosic Biomass with High-Boiling Point Solvent and Acidic Catalyst (고비점 용제와 산 촉매에 의한 목질 바이오매스의 탈리그닌)

  • Kim, Kang-Jae;Jung, Jin-Dong;Jung, Soo-Eun;Hong, Sung-Bum;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.119-126
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    • 2016
  • In this study, we separated the lignin from the wood by using the high boiling point solvent for developing more environmental friendly pulping method. High boiling point solvents as Ethers, glycols and ketones were used to remove the lignin in the pine wood meals. The Yield and lignin content of residual wood meals was reduced according to the input of the catalyst. Me-C, E-Ca, TEG and MIBK had the best delignification rate of 9 kinds of high-boiling point solvents. At the hydrolysis ratio of the selected solvents, The TEG was highest remain ratio of carbohydrates and the E-Ca was lowest remain ratio of lignin. And the Me-C was most excellent lignin hydrolysis ratio at the low catalyst. The selectivity of delignification of Me-C, E-Ca, TEG and MIBK solvents were 49.6, 49.9, 53.8 and 53.1%, respectively, and its values were similar to those of the commercial Kraft Pulp.