• Title/Summary/Keyword: organic matter nitrification

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Organic Matter and Hydraulic Loading Effects on Nitrification Performance in Fixed Film Biofilters with Different Filter Media

  • Peng, Lei;Oh, Sung-Yong;Jo, Jae-Yoon
    • Ocean and Polar Research
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    • v.25 no.3
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    • pp.277-286
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    • 2003
  • Nitrification performance of fixed film biofilters using coarse sand, loess bead, or styrofoam beads in biofilter columns 1 meter high and 30cm in diameter were studied at different hydraulic and organic matter loading rates. Synthetic wastewater was supplied to the culture tank in order to maintain desired TAN concentrations in inlet water to biofilters. All the biofilters were conditioned 5 months before start of sampling. TAN and $NO_2-N$ conversion rates increased with an increase in the hydraulic loading rate (HLR). However, the improvement in biofilter performance was not linearly correlated to HLR in styrofoam bead filters. This is mainly due to the characteristics of the styrofoam beads used. TAN conversion rates of sand filters increased with the increase of HLR up to $200m^3/m^2$. per day. No increase in the TAN conversion rate was observed at the highest HLR since flooding on the media surface took place. HLR had a significant impact on the TAN conversion rates in loess bead filter up to the highest HLR tested (P<0.05). TAN conversion rates were much less at organic matter loading rates of 9 and 18kg $O_2/m^3$ per day than those without the addition of organic matter in styrofoam bead filters. The addition of glucose resulted in a reduction of the TAN conversion rate from 540 to 284g $TAN/m^3$ per day. No significant difference of TAN conversion rates between the two organic matter loading rates was found (p<0.05). This indicates that the impact of organic matter on nitrification becomes less and less sensitive with an increase in the COD/TAN ratio. At an organic matter loading rate of 9kg $O_2/m^3$. per day, a great reduction of TAN conversion rates was observed in sand filters and loess bead filters. Clearly, organic matter can be one of the most Important Impacting factors on nitrification. $NO_2-N$ conversion rates showed a similar trend for TAN. Based on the TAN and nitrite conversion rates, styrofoam beads showed the best performance among the three filter media tested. Also, the low gravity and price of styrofoam beads make the handling easier and more cost-effective for commercial application. The results obtained at the highest organic matter loading rates can be used in the biofilter design in recirculating aquaculture system.

Performance of a submerged membrane bioreactor for wastewater mimicking fish meal processing effluent

  • Lopez, Guadalupe;Almendariz, Francisco J.;Heran, Marc;Lesage, Geoffroy;Perez, Sergio
    • Membrane and Water Treatment
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    • v.9 no.4
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    • pp.263-271
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    • 2018
  • The objective of this work was to analyze organic matter removal, nitrification, biomass growth and membrane fouling in a submerged flat-sheet membrane bioreactor, fed with synthetic wastewater, of similar composition to the effluents generated in a fish meal industry. After biomass acclimatization with saline conditions of 12 gNaCl/L and COD/N ratio of 15 in the bioreactor, results showed that the organic matter removal was higher than 90%, for all organic loading rates (0.8, 1, 1.33 and $2gCOD/L{\cdot}d$) and nitrogen loading rates (0.053, 0.067, 0.089 and $0.133gN/L{\cdot}d$) tested during the study. However, nitrification was only carried out with the lowest OLR ($0.8gCOD/L{\cdot}d$) and NLR ($0.053gN/L{\cdot}d$). An excessive concentration of organic matter in the wastewater appears as a limiting factor to this process' operating conditions, where nitrification values of 65% were reached, including nitrogen assimilation to produce biomass. The analysis of membrane fouling showed that the bio-cake formation at the membrane surface is the most impacting mechanism responsible of this phenomenon and it was demonstrated that organic and nitrogen loading rates variations affected membrane fouling rate.

The Role of Primary Clarifier in Biological Processes for Nutrient Removal (생물학적 질소·인제거 공정에서 일차 침전지의 영향)

  • Whang, Gye-Dae;Kim, Tae-Kyung
    • Journal of Korean Society on Water Environment
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    • v.23 no.1
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    • pp.19-26
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    • 2007
  • The lab-scale BNR processes fed with Municipal Wastewater Before or After Primary Clarifier (MWBPC or MWAPC) were operated to observe the behavior of particle organic matter in terms of nitrification and denitrification efficiency. As a result of the fractionation of the COD from MWBPC or MWAPC using an aerobic respirometric serum bottle reactor, the total mass of biodegradable organic matter from MWBPC is about 52% greater than the mass from MWAPC. Batch reactors were operated to observe the effect of the Particulate Organic Matter (POM) on substrate utilization for denitrification. Although the consumption of POM for denitrification was observed, the increment of the Specific Denitrification Rate (SDNR) was not great. In terms of the effect of POM on nitrification at different HRTs, activate sludge reactors were operated to determine the optimal HRT when MWBPC and MWAPC were fed relatively. All reactors showed a great organic matter removal efficiency. Reactors fed with MWAPC had obtained the nitrification efficiency above 90% when the HRT of 4 hr, at least, was maintained, while reactors fed with MWBPC had same efficiency when the HRT longer than 5 hr was kept. Three parallel $A^2/O$ systems fed with MWBPC or MWAPC relatively were operated to investigate the effects of POM on BNR processes with varying the HRT of an anoxic reactor. For all systems, the efficiency of organic matter removal and denitrification, respectively, was great and about the same. In case of denitrification efficiency, system with MWAPC had 1.5% lower than system with MWBPC at the same HRT of anoxic reactor of 2 hr, and the increasing the HRT of the anoxic reactor by 1 hr in systems fed with MWBPC resulted in a 3.5% increment. The denitrification rate was similar while the consumption of organic matter in systems fed with MWBPC was higher than system fed with MWBPC. It suggests that POM in MWBPC was not be used significantly as a substrate for denitrification in system with the HRT of 3 hr of an anoxic reactor.

Chemical Budgets in Intensive Carp Ponds

  • Peng Lei;Oh Sung-Yong;Jo Jae-Yoon
    • Fisheries and Aquatic Sciences
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    • v.6 no.4
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    • pp.194-202
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    • 2003
  • Budgets for water, nitrogen, and chemical oxygen demand (COD) were determined in two 0.012 ha earthy-bottom ponds stocked with Israeli strain common carp at an initial stocking density of $20\;fish/m^3$. Total ammonia nitrogen (TAN) concentrations increased continuously but later decreased in pond A as a consequence of high nitrification. COD concentrations increased during the experimental period due to the accumulation of feed input. Nutrient budgets showed that feed represented $94-95\%$ of nitrogen input and about 99% of organic matter input. Fish harvest accounted for $40\%$ of nitrogen and organic matter input. Seepage and water exchange removed $15-17\%$ of nitrogen input but only $1-2\%$ of organic matter. Draining of the ponds removed $20-26\%$ of input nitrogen, mostly in inorganic forms, but removed only minus organic matter. Fish and water column respiration accounted for $39\%$ of organic matter input, and benthic respiration accounted for $7-12\%$ of organic matter input. No significant change of nitrogen and organic matter in both pond bottoms were found during the three-month growth period. The unrecovered input nitrogen, about $6.3-13\%$, was lost through denitrification and ammonia volatilization. On a dry matter basis, fish growth removed $31\%$ of total feed input and left $69\%$ as metabolic wastes.

Effect of a Number of Organic Sources on the Ammonification and Nitrification of Urea and Soil Reaction (요소의 암모니아화 및 질산화와 토양반응에 미친 수종 유기물의 영향)

  • 오왕근;허지희;김재영
    • Asian Journal of Turfgrass Science
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    • v.5 no.1
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    • pp.47-53
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    • 1991
  • A laboratory experiment was conducted in order to learn the effect of a number of organic matters on the ammonification and nitrification of urea, and the reaction of soil, applied to a loamy upland soil poor in orgnic matter(<1.5%, without plants 1.The ammonification of urea was most pronounced in one week period immediatly after fertilizer and water treated, after which a rapid decrease of it was followed showing no accumulation at the end of 3rd week. Owing to the accumlation of ammonium, pHs of treated soils were read 7.0 to 7.3 from 6.8~6.9. 2.Nitrification was also progressed rapidly in the first one week period so that the accumulation of NO$_3$-N surpassed that of ammonia during this period. After the 1st week the accumulation of N0$_3$-N was continuously increased showing the maximum at the end of 4 weeks following a sharp decrease at the end of 5th weeks. The accumulation of NO$_3$-N dropped soil pH from 6.8-7.0 to 6. 0-6.2,but the decrease of NO-N at the end of 5th weeks brought up soil pH to 6.4-6.6. again. 3.Amino acid fermentation byproduct rich in salt, paticularly chloride, slowed down the ammonification and nitrification of urea. 4.The application of organic matter diminished the acidifying effect of chemical fertilizers. The diminishing effect of soluble humic acid and amion acid fermentation byproduct showed greater than that of solid organic matter in this experiment, which might be own to the application of a rather small amount of water soluble organic matters. Rice straw powder among solid organic matters appeared to be the least in the diminishing effect above. It may be reasoned that these soluble organic matters decomposes rapidly so as to affect Soil pH, but solid organic matters, particularly the rice straw powder, form acidic humus.

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소화신산의 화산분화후에 성립한 두메오리나무 임분의 질소무기화와 질화작용 - NH$_{4}$

  • 문현식;춘목아관
    • The Korean Journal of Ecology
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    • v.21 no.6
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    • pp.751-757
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    • 1998
  • Nitrogen dynamics in mineral soils of an alder (Alnus maximowiczii) stand established on volcano Mt. Showa-Shinzan were measured by laboratory incubation method in order to clarify characteristics of $NH_{4}^{+}$ mineralization and nitrification rate, from August 1994 to July 196. Contents of total N and organic matter were relatively low, but increased in May-July. Extractable $NH_{4}^{+}$ concentrations and $NH_{4}^{+}$ mineralization were high in June and July, and decreased in midsummer and fall. Extractable $NO_{3}^{-}$ concentrations did not vary seasonally. Negative values at $NH_{4}^{+}$ mineralization and nitrification rate were observed in August and September. $NH_{4}^{+}$ mineralization was positively correlated with soil organic matter, and nitrification rates were influenced by extractable $NH_{4}^{+}$ concentration and $NH_{4}^{+}$ mineralization.

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Effect of Hydraulic Retention Time on Biological Nitrogen Removal in Land-based Fish Farm Wastewater (육상양식장 배출수내 생물학적 질소처리시 수리학적 체류시간의 영향)

  • Park, Noh-Back
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.50 no.3
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    • pp.250-256
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    • 2017
  • This study investigated the removal efficiency of organic matter and nitrogen from fish farm effluent by hydraulic retention time (HRT) using an upflow biological filter (ANR system) reactor. The recycling time and influent flow in the reactor were controlled to 14.8, 7.4, 5.5 and 3.2 h to evaluate HRT. In addition, each reactor was coupled to a fixed bed upflow filter charged with media. The results showed that removal efficiency was ${\geq}95%%$ with an HRT of 5.5 h, and nitrification efficiency was reduced to 81% with an HRT of 3.2 h, although nitrification efficiency temporarily decreased due to the shock load as HRT decreased. Total nitrogen removal rate was also reduced to about 65% with an HRT of 3.2 h, which was considered a washout effect of nitrifying and denitrifying microorganisms by increasing the shearing force to the filter media, which decreased organic matter and nitrogen removal efficiency.

Comparison of Removal Characteristics of Organic Matter, Nitrogen and Phosphorus in Suspended-Growth and Hybrid Processes with Hydraulic Retention Time (수리학적 체류시간에 따른 부유성장 미생물을 이용한 공정과 하이브리드 공정의 유기물, 질소 및 인 제거 특성 비교)

  • Ryu, Hong-Duck;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.1
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    • pp.15-25
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    • 2006
  • This study was initiated to evaluate the effect of HRT(hydraulic retention time) on removal efficiencies of organic matter (C), nitrogen(N) and phosphorus(P) in municipal wastewater for suspenced-growth processes(MLE; Modified Ludzack-Ettinger) and hybrid process(Modified-Dephanox). M-Dephanox process was designed to improve the performance of Dephanox process on denitrification efficiency. As the results, removal efficiencies of C, N and P in M-Dephanox process, which is hybrid process, were higher than those in MLE, which is suspended-growth process. Especially, nitrification inhibition of MLE was observed more severely than M-Dephanox as hydraulic retention time was reduced from 6 hr to 3.5 hr. Nitrification in nitrification reactors on M-Dephanox, at short HRT, was so excellent that ammonia nitrogen removal efficiency in nitrification reactors of M-Dephanox was about 92% at 1.59 hr of HRT of nitrification reactors, however, nitrification in nitrification reactors on M-Dephanox was affected severely by organic matter entering to nitrification reactors from downstream settler. It was observed that reducing of HRT in whole process resulted from reducing of HRT in nitrification reactors on M-Dephanox.

A Study on the Removal Characteristics of Dissolved Organic and Ammonia Compounds in PFR of Aerated Submerged Bio-film (ASBF) Reactor (PFR 공정의 ASBF 구조에 의한 유기물제거와 질산화의 영향에 대한 연구)

  • Choi, Young-Ik
    • Journal of Environmental Science International
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    • v.17 no.11
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    • pp.1265-1271
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    • 2008
  • Aerated submerged bio-film (ASBF) pilot plant has been developed. The presented studies optimized an inexpensive method of enhanced wastewater treatment. The objectives of this research were to describe pilot scale experiments for efficient removal of dissolved organic and nitrogen compounds by using ASBF reactor in plug-flow reactor (PFR) and improve understanding of dissolved organic matter and nitrogen compounds removal rates with dynamic relationships between heterotrophs and autotrophs in the fixed-film reactor. This research explores the possibility of enhancing the performance of shallow wastewater treatment lagoons through the addition of specially designed structures. This direct gas-phase contact should increase the oxygen transfer rate into the bio-film, as well as increase the micro-climate mixing of water, nutrients, and waste products into and out of the bio-film. This research also investigated the efficiency of dissolved organic matter and ammonia nitrogen removals in the ASBF. As it was anticipated, nitrification activity was highest during periods when the flow rate was lower, but it seemed to decline during times when the flow rate was highest. And ammonia nitrogen removal rates were more sensitive than dissolved organic matter removal rates when flow rates exceeded 2.2 L/min.

Analysis of COD fraction and change of COD in nitritation reactor using various wastewater (다양한 하수를 대상으로 유기물 성상과 질산화 반응조 내 유기물 변화)

  • Im, Jiyeol;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.17 no.4
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    • pp.421-427
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    • 2015
  • In ASM model, organic matters are classified according to their characteristics and general classification into COD and BOD cannot satisfy conditions required by ASM. In this study, it was performed to study classification of organic matters required by ASM on the basis of microorganisms' respiration rate subject to wastewater and sludge treatment. As results of analysis of the organic matter's appearance, it was found that there were some differences in composition of organic matters between wastewaters. It is considered that it is an important characteristic of wastewater that should be understood in treating wastewater in each process. Therefore, it is considered that appearance of organic matters in each wastewater identified by this study will be used as important basic data for operation of municipal wastewater treatment plant. It was identified that SS was an important factor affecting nitrification through organic matter and ammonium nitrogen change analysis according to reaction time in the nitrification. It is considered that the nitrification has close relationship with choice of optimal retention time.