• 한국환경보건학회지
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• 제23권3호
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• pp.27-39
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• 1997

This study, collaborated Gifu University, Japan, was performed to analyze chemical pollutants and microorganism and to clarify the distribution of sulfate-reducing bacteria and their insolubilization of heavy metal ions in leachates sampled seasonally between 1994 and 1996 from Nanjido waste landfill site, sampled 4 times between 1995 and 1996 from Pusan and Daejeon waste landfill site, and sampled 1 time between 1992 and 1994 from Hokkaido, Nagoya, Osaka and Hukuoka waste landfill site in Japan. The results were as follows: 1. The temperatures of internal leachate and leachate effluent were 40$\circ$C and 30$\circ$C, respectively, and the pH values of both leachates were about 8.0 at Nanjido waste landfill site. The concentration of SO$_4^{-2}$ gradually increased with the degree of stabilization and that of NO$_3$-N was detected in a part of sampling sites at one and half years, and in all sampling sites at 3 years after completion of landfill. 2. The organic substances in leachate of Nanjido waste landfill site decreased with the degree of stabilization and they were very fluctuated with measuring point and time. The concentration of organic substance and heavy metals in internal leachate were higher than in leachate effluent and those of Cd, Hg, and Pb were lower than detection limit except a part of samples in 1996. 3. APCs in internal leachate and leachate effluent were not much different and the minimum of APCs in internal leachate and leachate effluent were $1.0\times 10^4$/ml and $4.0\times 10^1$/ml, respectively. 4. The maximums of SRBs in Nanjido, Pusan, and Daejeon waste landfill site were 9180 MPN/ml, 24000 MPN/ml, and 348 MPN/ml, respectively and the maximum of SRBs in Japan waste landfill site was 9300 MPN/ml. 5. During 2-week-SRB culture, the values of MPN were high at 50$\circ$C for initial culture period and at 30$\circ$C for last culture period. MPN started to appear at first day and rapidly increased between 7th day and 9th day. 6. Cadmium and copper were insolubilized by SRB within 6 hr and iron and zinc were done within 48 hr. The rates of insolubilization of Cd, Cu, Fe, Zn, T-Cr were 100%, 99.5%, 95.0%, 99.8%, 16.1% after 48 hr treatment with SRB, respectively.

• 상하수도학회지
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• 제24권6호
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• pp.763-773
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• 2010

The removal efficiencies and a total oxygen transfer coefficient for food waste leachate(FWL) were estimated by using Jet Loop Reactor(JLR). Pure oxygen was used instead of air to improve oxygen concentration in the JLR for high total chemical oxygen demamd(TCOD) in FWL. In JLB, in order to examining the oxygen transfer characteristic, the circulation flowrate and oxygen flowrate were controlled with 7~10 L/min(1.5 L/min interval) and 0.2~0.5 L/min (0.1 L/min interval) and we experimented according to the each condition. As a result, Oxygen uptake rate(OUR) and oxygen transfer rate could be maximized than the oxygen flowrate to increase the circulation flowrate. In addition, it determined that JLR using the pure oxygen which can obtain the greatest oxygen transfer rate as it was the high-concentration organic wastewater like the food waste leachate through the continuous experiment was appropriate.

• 한국환경보건학회지
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• 제33권5호
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• pp.470-477
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• 2007

This research was conducted to evaluate the effect of moisture content on direct landfilling prohibition of organic sludge. Organic sludges with moisture content (Me) of 75 and 85% were filled in two lysimeters. The lysimeters were named as Exp.75 and Exp.85, respectively. LFG of 2,064 l was generated greatly for Exp.85, compared to 1,500 l for Exp.75. LFG generations in Exp.75 and Exp.85 were 64.1 l/kg and 157.1 l/kg as dry TS basis, and 113.6 l/kg and 266.2 l/kg as dry VS basis. Total $CH_4$ generation in LFG for Exp.85 was 1,238 l, while 1,050 l for Exp.75. $H_2S$ of $3{\sim}150$ ppmv was generated from Exp.85, which was 5 times higher than $2{\sim}30$ppmv from Exp.75. Leachate was not generated from Exp.75 during operation time. However, 420 ml of leachate was generated from Exp.85. From the results of gas generation, composition, odorous compounds, and leachate generation, landfilling of organic sludge with high MC was more harmful to the environment in spite of great LFG generation. However, direct landfilling of organic sludges without great difference of MC made a severe odor problem. Therefore, it was thought that current direct landfilling prohibition law for all organic sludge was appropriate.

• 유기물자원화
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• 제20권1호
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• pp.61-70
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• 2012

본 연구에서는 하수슬러지, 돈분뇨, 음식물쓰레기 탈리액을 단독 또는 혼합 주입한 회분식 혐기성 소화를 수행하여 바이오가스 생산 및 유기물 저감 효율 비교 평가를 통해 병합소화의 타당성을 검토하였다. 타당성 검토 대상은 M시에서 발생하는 하수슬러지 178 톤/일, 돈분뇨 해양 투기량 및 축산폐수처리장 유입량 150 톤/일, 음식물쓰레기 탈리액 소각량 8톤/일이다. 유기성 폐기물 별 혐기성 소화 특성을 회분식 실험을 통해 고찰한 결과, 검토된 보조기질(돈분뇨, 음식물쓰레기 탈리액)이 메탄수율, 메탄 생산성, 유기물 제거 효율 측면에서 하수슬러지에 비해 우수한 성능을 나타내었다. 하수슬러지, 돈분뇨, 음식물쓰레기 탈리액의 병합 소화를 수행한 결과, 대상 유기성 폐기물 전량을 하수처리장 소화조로 투입하는 경우, 하수슬러지 단독 소화 대비, 5.6 배$(530\;m^{3}\;CH_{4}/d\;{\rightarrow}\;2,968\;m^{3}\;CH_{4}/d)$ 높은 메탄생산 잠재량을 보일 것으로 나타났다. 다만 소화조 유출수가 기존에 비해 1.88 배 증가하고, 유출수 내 오염물질 부하(COD, T-N, T-P)가 3.79-4.92배 증가하는 것으로 나타났다. 병합소화는 하수처리장 에너지 자립화에 큰 기여를 할 수 있으나, 적용 시 하수처리장으로의 반송 등 소화조 유출수 처리 방안의 확보 방안이 함께 마련되어야 할 것으로 사료된다.

• 유기물자원화
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• 제26권2호
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• pp.19-32
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• 2018

본 연구는 침출수 재순환에 의한 매립가스에 대한 메탄가스 농도에 어떠한 영향이 있는지 분석하였다. 실험대상 매립장 지역의 2010~2016년간 월평균 총강수량은 130.9mm, 2017년 6월 총강수량 73.7mm 이었다. 이러한 기상청 자료를 근거로 실험대상 매립장의 수분함수율은 낮을 것으로 예상되었다. 실험대상 매립장에 10개의 포집공을 선정하여 5톤의 침출수를 나누어서 투입하면서 매립가스 변화특성을 조사하였다. 침출수 투입하기 전 10개의 메탄가스 농도(평균) 투입전 30.14%, 투입후 메탄가스 농도(평균) 24.66%(6월 21일), 31.51%(6월 24일), 36.68%(7월 1일), 52.47%(7월 25일)로 메탄가스 농도가 증가하였다. 본 실험대상 매립장의 경우 5톤의 침출수를 투입한 결과 매립지의 유기물질 분해에 필요한 최적 함수율 50~65% 범위를 유지하는 것으로 판단된다.

• 유기물자원화
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• 제24권1호
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• pp.31-40
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• 2016

본 연구에서는 침출수 재순환 시스템을 적용한 중온 혐기성소화를 이용하여 음식물류 폐기물을 분해하여 메탄가스를 생산하였다. 실험은 $36^{\circ}C$로 유지되는 항온수조 내에 생물반응조와 침출수 저장조로 구성된 2개의 동일한 시스템(System A, System B)을 사용하였고, 생물반응조 하단 30 mm위에는 스크린이 있어 고액분리를 하여 침출수 저장조로 침출수를 이송하였다. 침출수 재순환은 매일 수행하였으며, 침출수 재순환 시에는 생물반응조 하단에서 침출수 저장조로 2.5 L를 30분간 이송한 뒤 다시 침출수 저장조에서 생물반응조 상부로 2.5 L를 30분간 주입하였다. 주입된 음식물류 폐기물은 수집되기 전 한 번 세척하였으며 반응조에 주입되기 전에 $36^{\circ}C$로 온도를 올렸다. System A에 49.1 g VS, System B에 54.0 g VS을 2주 간격으로 투입하였다. 저해인자로 측정된 항목은 $NH_4{^+}-N$과 염도였으며, 두 가지 항목의 농도 모두 시스템에 끼친 영향은 없는 것으로 나타났다. System A는 112일간, System B는 140일 동안 운전하였는데, 각 시스템에서 인발된 슬러지는 없었다. 음식물류 폐기물의 혐기성 소화를 통한 평균 메탄 발생량은 System A의 경우 0.439 L $CH_4/g$ VS, System B의 경우 0.368 L $CH_4/g$ VS로 나타났다.

• Environmental Engineering Research
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• 제20권4호
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• pp.363-369
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• 2015

This study aims to characterize solid household waste and to present physicochemical characteristics of fresh leachate before landfilling in Kasba Tadla city, Morocco. Obtained results show that household waste produced in 2013 were about 11,787 tons, or 0.27 tons/capita/year. These wastes were composed essentially of organic materials (74%), paper (8%), plastics (9%), metals (1%), and glass (0.5%). However, monthly produced leachate ranges from a maximum of $130.92m^3$ during summer and a minimum of $21.88m^3$ in winter. Moreover, leachate treatment using Upflow Anaerobic Sludge Blanket technique was accompanied by a decrease in electrical conductivity, certainly related to leachate-sediment chemical exchanges. Otherwise, the same acidity reduction phenomenon occurs when pH value increased from 4.49 to 6.17 after 24 hours, confirming the system response since the early stages of treatment. In addition, temporal evolution of the treatment efficiency in terms of COD highlighted a very important reduction which reached 94% after 5 days with an average temperature of $25^{\circ}C$.

• 유기물자원화
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• 제22권2호
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• pp.57-66
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• 2014

침출수 순환형 음식물류 폐기물 혐기성 소화 공법은 기존의 일상 혐기성 소화 공법에 비해 투입되는 유기물 부하량 대비 발생하는 메탄가스 수율이 높다는 장점이 있다. 본 연구는 분리 수거된 교내 기숙사 식당 음식물류 폐기물과 하수처리장 혐기성 소화조의 혐기성 미생물을 이용하여 신재생 에너지인 메탄가스를 더욱 효율적으로 얻기 위해 음식물류 폐기물/혐기성 슬러지 비를 달리하여 실험을 실시하였다. 음식물류 폐기물/혐기성 슬러지 비가 2:8이고 유기물 부하율이 9 gVS/L인 침출수 순환형 음식물류 혐기성 소화 반응조의 바이오 가스 발생이 가장 높았다. 또한 이 혐기성 반응조에서 발생하는 바이오가스 내부의 $H_2S$와 $NH_3$가 지속적으로 감소하였고 바이오 가스의 수율은 평균 $1.395m^3$ Biogas/kg VS added로 나타났다. 이에 비해 나머지 음식물류 폐기물/혐기성 슬러지 비가 3:7, 8:2인 실험의 반응조에서는 바이오 가스 발생이 멈추었다.

• 산업기술연구
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• 제19권
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• pp.189-195
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• 1999

A study on the separation Cu, Ni, and Co was carried out using LIX 84 leachate, chelate extractant. For this test, artificial test solution was prepared by varing concentrations of Cu, Ni, Co, $(NH_4)_2CO_3$ and $(NH_4)_2SO_4$. It found that pH of the solution was very important factor for the separation of nickel from copper. The results showed that nickel was effectively extracted from copper by using LIX 84 at pH 1.0 to 1.2. The volume ration or organic to aqueous phases was 1.0. According to the McCabe-Thiele diagram, the extraction rate of copper was 99 percents at the equal ratio of organic to aqueous phase in three stages.

• 한국환경과학회지
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• 제7권3호
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• pp.383-392
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• 1998

Pollution characteristics of leachate and underground soul of the two landfill states were Investigated Domestic wastes were dumped In the two adjacent landfill states. Only small portion of S landifill site was filled with domestic wastes at the first stage of dumping, and most portion of the site was filled with construction wastes. However Y landfill strate was filed with mostly domestic wastes. Higher concentrations of organic pollutants including VOCs were measured In Y landfill site leachate than In S tendon site. Underground souls of the two linam states were analyzed by the two kinds of leaching methods, KEP (Korean Extraction Processl and Acid Digestion. Underground souls of the both landfill states were not polluted by leachates. Underground soils of the two were composed of firie salty material. Thus It Is fecund that fine silty soul layer of the sea shore may be used as a landfillsite.