• 제목/요약/키워드: organic green EL

검색결과 41건 처리시간 0.029초

The study of new host materials for solution-processed green organic electrophosphorescence

  • Jung, Sung-Hyun;Lee, Ho-Jae;Kim, Young-Hoon;Kim, Hyung-Sun;Yu, Eun-Sun;Chae, Mi-Young;Chang, Tu-Won
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
    • /
    • pp.454-457
    • /
    • 2008
  • We report the syntheses, photophysical properties and device performances of solution processible host material for green-phosphorescent OLEDs. The butterfly-shaped new host materials with nonconjugated linkage of carbazole and fluorene moieties have large triple energy band gap around 2.8 eV. All of the EL devices exhibited turn-on voltages in the range of 4.8-5.0 V. GH-4 exhibited the best performance with a maximum current efficiency and power efficiency of 21.1 cd/A and 7.9 lm/W.

  • PDF

다층구조를 갖는 유기박막의 발광 및 전자물성 (Electroluminescence and Electronic properties of multi1ayer organic Thin Film)

  • 이청학;김정태;박복기;박대희
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
    • /
    • pp.792-794
    • /
    • 1998
  • The TPD and the $Alq_3$ film are widely used as a hole transport layer and an emitter layer respectively, in organic electroluminescent(EL) device (ITO Glass/TPD/$Alq_3$/metal). In this structure, we fabricated two models. Model(1) having ITO glass/$Alq_3$/Al structure and model(2) having ITO Glass/TPD/$Alq_3$/Al structure were fabricated by the vacuum evaporation. The comparison between model(1) and model(2) was made about the absorbance, the wave length, the current-voltage characteristic and the ln I - $V^{(1/2)}$characteristic respectively. Electroluminescence of green and wavelength of 510[nm] were observed in both model. We observed absorbance from 320[nm] to 430[nm] in $Alq_3$ material and from 250[nm] to 400[nm] in TPD material.

  • PDF

색변환법 유기전계발광 소자용 유기 발광 재료의 합성 및 특성 분석 (Synthesis and Characteristics of Organic Emitting Materials for OLEDs using Color Conversion Method)

  • 곽선엽;류정이;남장현;이태훈;김태훈;손세모
    • 한국인쇄학회지
    • /
    • 제23권1호
    • /
    • pp.77-97
    • /
    • 2005
  • Organic light-emitting diodes(OLEDs) have received considerable attention since they were first reported by Tang. Novel organic fluorescent materials have been reported on synthesis and application of new organic light-emitting materials. Despite of much recent progress, fabrication of full-color OLEDs still remained to be done. Many method have been proposed to full-color OLEDs displays such as using separated red, green and blue emitters, stacking separate rad, green and blue emitter, using a white emitter with individually pattered color filters, microcavity structures and using a blue emitter with individually patterned fluorescent materials. The last method has much attention because of easy fabrication of OLEDs and low-priced fabrication. This paper reports the optical and electrical characteristics of OLEDs using novel molecules containing biphenyl structure. Optical properties of biphenyl derivatives doped with poly(9-vinyl carbazole)(PVK) are measured and found Forster energy transfer process in the blends. And devices were fabricated as ITO/PEDOT/PVK doped with biphenyl derivatives/$Alq_3$/Li:Al and I-V-L characteristics and EL efficiency of devices were examined.

  • PDF

Cz-TPD를 음극접합층으로한 OELD의 발광특성 (Emission Properties of the OELD with Cathode Interface Layer for Cz-TPD)

  • 최완지;조민정;박철현;이정구;임기조;박수길;김현후
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2001년도 추계학술대회 논문집 전기물성,응용부문
    • /
    • pp.109-111
    • /
    • 2001
  • In this study, The cathode interface layer (CIL) was investigated using aromatic diamine derivatives. Cz-TPD (4,4'-biscarbazolyl (9)-biphenyl) used in the cathode interface layers is investigated emition charcaracteristics at the green organic electroluminescent devices TPD (N.N'-dyphenyl-N-N'-bis(3-methy phenyl)-1.1'-biphenyl-4.4'-diamine) as the hole transformer layer and $Alq_3$:tris (8-hydroxyquinoline) aluminium) as the electron transport layer and emiting layer maded use of the organic electroluminescent device. The Organic Electroluminescent Device with Ag, cathode and CIL of Cz-TPD(4,4'-biscarbazolyl(9)-biphenyl) showed good EL characteristics compare to a conventional Mg:Ag device and also an improved storage stability.[1] As the change in MgAg, Cz-TPD/Ag, Ag at the chthode, the electron and optical charcaracteriseics were investigated.

  • PDF

MULTISPECTRAL REMOTE SENSING ALGORITHMS FOR PARTICULATE ORGANIC CARBON (POC) AND ITS TEMPORAL AND SPATIAL VARIATION

  • Son, Young-Baek;Wang, Meng-Hua;Gardner, Wilford D.
    • 대한원격탐사학회:학술대회논문집
    • /
    • 대한원격탐사학회 2006년도 Proceedings of ISRS 2006 PORSEC Volume I
    • /
    • pp.450-453
    • /
    • 2006
  • Hydrographic data including particulate organic carbon (POC) from the Northeastern Gulf of Mexico (NEGOM) study were used along with remotely sensed data obtained from NASA's Sea-viewing Wide Field-of-view Sensor (SeaWiFS) to develop POC algorithms to estimate POC concentration based on empirical and model-based principal component analysis (PCA) methods. In Case I and II waters empirical maximized simple ratio (MSR) and model-based PCA algorithms using full wavebands (blue, green and red wavelengths) provide more robust estimates of POC. The predicted POC concentrations matched well the spatial and seasonal distributions of POC measured in situ in the Gulf of Mexico. The ease in calculating the MSR algorithm compared to PCA analysis makes MSR the preferred algorithm for routine use. In order to determine the inter-annual variations of POC, MSR algorithms applied to calculate 100 monthly mean values of POC concentrations (September 1997-December 2005). The spatial and temporal variations of POC and sea surface temperature (SST) were analyzed with the empirical orthogonal function (EOF) method. POC estimates showed inter-annual variation in three different locations and may be affected by El $Ni{\tilde{n}}o/Southern$ Oscillation (ENSO) events.

  • PDF

음극접합층으로 Cz-TPD를 사용한 OELD의 전기적 광학적 특성 (The electrical and optical Properties of the OELD using the Cz-TPD for cathode interface layer)

  • 최완지;임민수;정득영;이정구;임기조
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 디스플레이 광소자 분야
    • /
    • pp.124-127
    • /
    • 2002
  • In this study, The cathode interface layer (CIL) was investigated using aromatic diamine derivatives. Cz-TPD (4,4'-biscarbazolyl(9)-biphenyl) used in the cathode interface layers is investigated emition charcaracteristics at the green organic electroluminescent devices. TPD (N,N' -dyphenyl -N -N'-bis (3-methy phenyl)-1,1' -biphenyl-4,4' -diamine) as the hole transformer layer and $Alq_{3}:tris$ (8-hyd-roxyquinoline) aluminium) as the electron transport layer and emiting layer maded use of the organic electroluminescent device. The Organic Electroluminescent Device with Ag cathode and CIL of Cz-TPD(4,4'-biscarbazolyl(9)-biphenyl) showed good EL characteristics compare to a conventional Mg:Ag device and also an improved storage stability. [1] As the change in MgAg, Cz-TPD/Ag, Ag at the chthode, the electrical and optical charcaracteriseics were investigated.

  • PDF

유기물 적층 구조에 따른 유기 발광 소자의 발광 특성에 관한 연구 (A Study on the Emission Properties of Organic Electroluminescence Device by Various Stacked Organics Structures)

  • 노병규;김중연;오환술
    • 한국전기전자재료학회논문지
    • /
    • 제13권11호
    • /
    • pp.943-949
    • /
    • 2000
  • In this paper, the single and double heterostructure organic light-emitting devices(OLEDs) were fabricated. The single heterostructure OLED(TYPE 1) is consisted of TPD as a HTL(hole transfer layer) and Alq$_3$as an EML(emitting layer). The double heterostructure OLED(TYPE 2) is consisted of TPD as a HTL, Alq$_3$as an EML and PBD as an ETL(electron transfer layer). The another double heterostructure OLED(TYPE 3) is consisted of TPD as a HTL, PBD as an EML and Alq$_3$as an ETL. We obtained a strong green emission device with maximum EL emission wavelength 500nm in TYPE 3. When the applied voltage was 12V, the emission luminescence was 120.9cd/㎡. The chromaticity index of TYPE 3 was x=0.29, y=0.50. In the characteristic plot of current-voltage, TYPE 3 device was turned on at 6.9V. This voltage was a fairly low turn-on voltage. TYPE 1 and 2 device were turned on at 10V and 8.9V respectively. These types showed no good properties over that of TYPE 3.

  • PDF

주사슬에 설폰기를 함유하는 전기발광 공액 고분자의 합성과 특성분석 (Synthesis and Characterization of Electroluminescent Conjugated Polymers Containing Sulfone Group in the Main Chain)

  • 강민성;정호국;박수영;김장주
    • 폴리머
    • /
    • 제29권4호
    • /
    • pp.357-362
    • /
    • 2005
  • 중합체의 공액길이를 제어하고 이들이 갖는 에너지 준위를 조절하며, 발광성능향상과 발광파장을 조절하려는 목적으로 설폰기가 포함된 페닐렌-비닐렌계의 새로운 전기발광 고분자들을 Witting 중합을 통해 합성하였다. 합성된 고분자들은 일반 유기 용매에 좋은 용해성을 보였고 $400^{circ}C$ 정도의 초기분해온도와 $200^{circ}C$ 전후의 높은 유리전이온도를 가짐으로써 열적 안정성이 매우 높음을 확인하였다. 각각의 고분자는 용액과 필름상태에서 모두 설폰기의 꺾임에 의해 공액길이가 짧아질수록 UV 흡수와 발광 스펙트럼이 단파장으로 이동하였고 이를 통해 설폰기가 효율적으로 발광파장을 제어하는 것을 확인하였다. 또한 CV측정과 이론적인 계산을 통해 전자친화도가 큰 설폰기에 의해서 합성된 고분자들의 HOMO 및 LUMO 에너지 준위가 상대적으로 낮아짐으로써 소자의 전기발광특성이 향상됨을 확인하였다.

Spectrophotometric Determination of Some Fluoroquinolone Antibacterials through Charge-transfer and Ion-pair Complexation Reactions

  • El-Brashy, Amina Mohamed;Metwally, Mohamed El-Sayed;El-Sepai, Fawzi Abdallah
    • Bulletin of the Korean Chemical Society
    • /
    • 제25권3호
    • /
    • pp.365-372
    • /
    • 2004
  • Two simple, rapid and sensitive spectrophotometric methods for the determination of three fluoroquinolones, namely levofloxacin, norfloxacin and ciprofloxacin have been performed either in pure form or in their tablets. In the first method, levofloxacin and norfloxacin are directly treated with bromocresol green (BCG) in dichloromethane while ciprofloxacin is allowed to react with the same dye in aqueous acidic buffer. Highly yellow colored complex species were formed instantaneously in case of levofloxacin and norfloxacin or after extraction into dichloromethane for ciprofloxacin. The formed complexes are quantified spectrophotometrically at their absorption maxima at 411 nm for levofloxacin and 412 nm for norfloxacin and ciprofloxacin. The second method involves the reaction of levofloxacin with ${\rho}$-chloranilic acid ( ${\rho}$-CA) and norfloxacin with tetracyanoethylene (TCNE) in acetonitrile to give complexes with maximum absorbance at 521 and 333 nm for the two drugs, respectively. Adopting the first procedure, calibration graphs were linear over the range 1- 20 ${\mu}g\;mL^{-1}$ with mean percentage recoveries of 100.41 ${\pm}$ 0.72, 99.99 ${\pm}$ 0.54 and 100.23 ${\pm}$ 0.91 for the theree drugs, respectively. For the second procedure, the concentration ranges were 15-250 ${\mu}g\;mL^{-1}$ for levofloxacin using ${\rho}$-CA and 0.8-16 ${\mu}g\;mL^{-1}$ for norfloxacin using TCNE with mean percentage recoveries of 99.88 ${\pm}$ 0.45 and 100.26 ${\pm}$ 0.68 for the two drugs, respectively. The proposed methods were successfully applied to determine these drugs in their tablet formulations and the results compared favorably to that of reference methods. The proposed methods are recommended for quality control and routine analysis.

열처리조건과 기판이 $ZnGa_O_4:Mn$ 박막 형광체의 발광특성에 미치는 영향 (Effects of heat treatment and substrates on luminescent characteristics of $ZnGa_O_4:Mn$ thin film phosphor)

  • 정승묵;김영진
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2004년도 춘계학술대회 논문집 디스플레이 광소자분야
    • /
    • pp.181-184
    • /
    • 2004
  • The green emitting phosphor, $ZnGa_2O_4:Mn$ thin film with spinel structure were deposited by rf magnetron sputtering. Thin film phosphors were heat-treated in nitrogen, vacuum and air atmosphere, respectively. The effects of the substrates, heat-treatment conditions and the sputtering parameters were investigated. The growing behavior and luminescent properties of thin films depend on the crystallinity of the substrates. The Ga/Zn atomic ratios and luminescent characteristics were dependent on the annealing conditions.

  • PDF