• Analytical Science and Technology
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• v.34 no.5
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• pp.202-211
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• 2021

Volatile organic compounds (VOCs) in hazardous air pollutants (HAPs) have been regulated by the Air Pollution Control Act (1978) and their atmospheric concentrations have been monitored in 39 monitor sites in Korea. However, measurement standards of volatile organic compounds (VOCs) in HAPs at ambient levels have not been established in Korea. Primary reference gas mixtures (measurement standards) at ambient levels are required for accurately monitoring atmospheric VOCs in HAPs and managing their emissions. In this study, primary reference gas mixtures (PRMs) at 5 nmol/mol were developed in order to establish primary national standards of VOCs in HAPs at ambient levels. Primary reference gas mixtures (PRMs) were prepared in pressurized aluminum cylinders with special internal surface treatment using gravimetric method. Analytical methods using gas chromatography-flame ionization detector (GC-FID) coupled with a cryogenic preconcentrator were also developed to verify the consistency of gravimetrically prepared HAP VOCs PRMs. Three different columns installed in the GC-FID were evaluated and compared for the retention times and separation of eighteen target components in a chromatogram. Results show that the HAP VOCs PRMs at 5 nmol/mol were consistent within a relative expanded uncertainty (k=2) of less than 3 % except acrylonitrile (less than 6 %) and the 18 VOCs were stable for 1 year within their associated uncertainties.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05a
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• pp.90-93
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• 2004

In this study, we have reported an organic-inorganic hybrid membrane, which exhibits an asymmetric structure consisted of a carbonized skin layer and a polyimide porous substructure, to synthesize a novel gas separation membrane combining high gas permeability and selectivity. Both the gas permeability and selectivity of the carbonized layer significantly enhanced when compared with those determined in the control polyimide.

• Journal of Mechanical Science and Technology
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• v.20 no.9
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• pp.1502-1513
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• 2006

This study analyzes the design and part load performance of a power generation system combining a micro gas turbine (MGT) and an organic Rankine cycle (ORC). Design performances of cycles adopting several different organic fluids are analyzed and compared with performance of the steam based cycle. All of the organic fluids recover greater MGT exhaust heat than the steam cycle (much lower stack temperature), but their bottoming cycle efficiencies are lower. R123 provides higher combined cycle efficiency than steam does. The efficiencies of the combined cycle with organic fluids are maximized when the turbine exhaust heat of the MGT is fully recovered at the MGT recuperator, whereas the efficiency of the combined cycle with steam shows an almost reverse trend. Since organic fluids have much higher density than steam, they allow more compact systems. The efficiency of the combined cycle, based on a MGT with 30 percent efficiency, can reach almost 40 percent. hlso, the part load operation of the combined system is analyzed. Two representative power control methods are considered and their performances are compared. The variable speed control of the MGT exhibits far better combined cycle part load efficiency than the fuel only control despite slightly lower bottoming cycle performance.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.5
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• pp.629-636
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• 2012

This study focuses on the feasibility of bio-gas production using anaerobic digestion by measuring methane generation and biodegradability through the BMP test of industrial organic wastes. Organic wastes consist of entrails of pigs and organic residues of rumen generated from slaughter houses, wastewater sludge from slaughter waste water, fish offal and residues of vegetables from public wholesale markets, and wastewater sludge from the process of wastewater treatment in paper mill. The cumulative methane production by BMP test ranges from 149.3 ml/g-VS to 406.6 ml/g-VS and this is similar to methane generation of the normal wastewater sludge and food waste. As a result of measurement of biodegradability, wastewater sludge (S1 ~ S4) is low, ranging from 27.1% to 58.9 % and organic residues of rumen (G1) is low at 49.6 %. In conclusion, it turned out that raising the hydrolysis by various pre-treatments is necessary in order to produce bio-gas by using industrial organic wastes.

• Economic and Environmental Geology
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• v.46 no.4
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• pp.359-373
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• 2013

Shale is considered as a source rock for conventional oil and gas exploration and development because shale is fine-grained detrital sedimentary rock which can preserve the organic matter better. Shale has a good sealing capacity for the petroleum trap due to its low permeability. Commercial recoveries of gas from shale in the North America based on the development of technologies of horizontal drilling and hydraulic fracturing reveal that shale also function as a effective reservoir rock. Geochemical techniques to evaluate generation potential of the hydrocarbons from organic matter in the source rocks can be applied for the exploration of the shale gas resources. To evaluate shale gas resources, it is important to understand various geochemical processes and shale characteristics controlling generation, storage and estimation of shale gas reserves. In this paper, the generation mechanism of the oil and gas from organic matter is reviewed, and geochemical techniques which can be applied for the evaluation and characterization of shale gas are introduced.

• Journal of Korean Society on Water Environment
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• v.20 no.1
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• pp.72-77
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• 2004

Laboratory studies were carried out to find out the characteristics of humic acid treatment by activated carbon and ionized gas, In order to increase oxidation power of ionized gas for treating organic matter, we used granular activated carbon. By using $UV_{254}$, easy analysis method, we calculated humic acid concentration and $SCOD_{cr}$ concentration. For an initial concentration of humic acid, 10, 50 and 100ppm, the reaction rate constant by $UV_{254}$ was $8.98{\times}10^{-3}$/min, $5.62{\times}10^{-3}$/min and $4.8{\times}10^{-3}$/min respectively due to the same flow rate of ionized gas. When we added activated carbon to the ionized gas for humic acid treatment, the reaction rate constant increased in 4.13, 3.65 and 3.15 times. So, by using activated carbon in treating humic acid by ionized gas, oxidation power of organic matter by ionized gas was increased. The hydrophobic fraction constitutes 98% of organic matter for humic acid at the beginning. After the treatment using ionized gas for humic acid, the hydrophobic fraction decreased by 63~65% and the hydrophilic one increased by 35~37%. So, it was proved that the treatment increased the hydrophilic fraction in organic matter.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.04a
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• pp.198-201
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• 1997

The new system for identification of organic vapours and analysis method of mechanism between organic vapours and sensitive materials were attempted using the resonant resistance and resonant frequency of Quartz Crystal Analyzer (Q. C. A.). The resonant resistance shift means rheological changes in sensitive LB films occurred by the adsorption of organic vapours, while the resonant frequency shift represent the mass of organic vapour loaded in or on the sensitive LB films. It is thought that we can obtain more accurate response mechanism of organic vapour using the resonant frequency and resonant resistance diagram. The polymeric sensitive material were quantitively depositied using the LB method. In the experimental results, the adsorption behavior of organic vapour response can be decided by two type ; surface adsorption and penetration into sensitive material. Organic vapours had different positions in the Frequency-Resistance (F-R) diagram as to the kinds and concentrations of organic vapours. Thus F-R diagram can be applied to the development of one channel gas sensing system using the Quartz Crystal Analyzer.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.5
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• pp.420-431
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• 2009

Characteristics and advantages of the thermal desorption-comprehensive two dimensional gas chromatography-time of flight mass spectrometry (TD-GCxGC-TOFMS) were discussed and the organic compound's analysis result was shown for the ambient $PM_{2.5}$ sample collected in Seoul, Korea. Over 10,000 individual organic compounds were separated from about $70{\mu}g$ of aerosols in a single procedure with no sample pre-treatment. Among them, around 300 compounds were identified and classified based on the mass fragmentation patterns and GCxGC retention times. Several aliphatic compounds groups such as alkanes, alkenes, cycloalkanes, alkanoic acids, and alkan-2-ones were identified as well as 72 PAH compounds including alkyl substituted compounds and 8 hopanes. In Seoul aerosol, numerous oxidized aromatic compounds including major components of secondary organic aerosols were observed. The inventory of organic compounds in $PM_{2.5}$ of Seoul, Korea suggested that organic aerosol were constituted by the compounds of primary source emission as well as the formation of secondary organic aerosols.

• Journal of Sensor Science and Technology
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• v.32 no.3
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• pp.147-153
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• 2023

Metal-organic frameworks (MOFs) of cobalt gallate were synthesized and deposited on gold electrodes using self-assembly monolayers (SAMs) and hydrothermal processing. These MOF films exhibit strong adsorption capabilities for gaseous particulates, and the use of SAMs allows the synthesis and deposition processes to be completed in a single step. When cobalt gallate is mixed with SAMs, a coordination bond is formed between the cobalt ion and the carboxylate or hydroxyl groups of the SAMs, particularly under hydrothermal conditions. Additionally, the quartz crystal microbalance (QCM) gas sensor accurately measures the number of particulates adsorbed on the MOF films in real-time. Thus, the QCM gas sensor is a valuable tool for quantitatively measuring gases, such as SO₂, NO₂, and CO₂. Furthermore, the QCM MOF film gas sensor was more effective for gas adsorption than the MOF particles alone and allowed the accurate modeling of gas adsorption. Moreover, the QCM MOF films accurately detect the adsorption-desorption mechanisms of SO₂ and NO₂, which exist as gaseous particulate matter, at specific gas concentrations.

• Korean Journal of Food Science and Technology
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• v.32 no.5
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• pp.997-1001
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• 2000

The organic acids in 3 kinds of medicinal herbal extracts were screened and compared each other according to their organic acid contents by an efficient gas chromatographic method. It involves solid-phase extraction of organic acids using Chromosorb P with subsequent conversion to stable tert-butyldimethysilyl derivatives for the direct analysis by capillary column gas chromatography and gas chromatography-mass spectrometry. Total of 24 organic acids were reproducibly identified from 3 kinds of herbal extracts. When the GC profiles were simplified to their retention index spectra, characteristic patterns were obtained for each herb sample. As expected, three kinds of herbal extracts showed three distinct patterns.