• Applied Chemistry for Engineering
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• v.16 no.4
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• pp.549-555
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• 2005

To evaluate the posterior and anterior restoration of polymeric dental restorative composite (PDRC), PDRC was prepared using a silica filler treated by heat at various temperatures. Compressive strength (CS) and diametral tensile strength (DTS) values were investigated to study the effect of a heat-treated silica on the mechanical properties of PDRC using the recommended dental specifications. Both the particle size and specific volume of silica were decreased upon increasing the heat treatment temperature. CS and DTS values of PDRC containing a heat-treated silica showed 1.2 and 1.3 times, respectively, higher than that of the PDRC containing a neat silica. Also, it was found that the lower heat treatment temperature, the better mechanical properties of PDRC were observed because there was less agglomeration between silica particles. Specially, PDRC using a silica treated at $600^{\circ}C$ showed superior mechanical strength.

• Applied Chemistry for Engineering
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• v.9 no.4
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• pp.608-613
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• 1998

The purpose of this experiment was the physical properties of rubber compounds with DPCB and pure carbon black. Si-O peak in the silcia surface was observed at the range of wavenumber from 1,100 to 1,200 in the DPCB by FT-IR analysis. Cure rate of rubber compounds containing DPCB and organic silane coupling agent were (Si69) delayed compared with those containing pure carbon black. 300% modulus and interaction coefficient of DPCB with silane coupling agent were higher than those of pure carbon black and PICO weight loss amount showed constant value. It was found that $0^{\circ}C$ tan$\delta$ of rubber compounds with DPCB was larger than those of pure carbon black at 2.0% silane coupling agent based on 50 phr DPCB and $60^{\circ}C$ tan$\delta$ of rubber compounds with DPCB decreased as increasing the usage coupling agent. Consequently, it is postulated that DPCB is strong candidate material for lowering rolling resistance under constant abrasion resistance.

• Elastomers and Composites
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• v.35 no.2
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• pp.98-105
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• 2000

Using FT-IR and contact angle measurements it is observed that the chemical surface treatments on virgin carbon blacks lead to a change of the surface properties, including surface functionality and surface free energy It is found that the developments of surface functional groups on acidically and basically treated (ACB and BCB in this study, respectively) carbon blacks are largely correlated with the specific component of surface free energy of the carbon blacks. However, a significant advantage of compounding composites is gained by BCB or NCB (nonpolar chemical treatment) specimens, resulting in improving the hardness, elongation at break, and tensile strength. Particularly, it is seen that the tensile strength of the composites are greatly depended on the London dispersive component of surface free energy determined from the contact angle measurements. It is then concluded that the London dispersion component of carbon blacks plays an important role in an organic rubbers-based compounding composite system.

• Elastomers and Composites
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• v.48 no.2
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• pp.125-132
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• 2013

In this work, we have discussed new engineering systems for preparing carbon master batch composed by carbon black and various organic compounds. In general, polymer resin, which applied for automobile tire, household items, and various industry items, is used with the fillers including carbon black and silica to control the color or properties. Domestic part and material industry has been remarkably developed in that the development of materials including the compounding of raw materials. Meanwhile, the engineering technique for mass production has not reached to a requirement of industry due to slow technique development and high dependence on foreign. Thus, we will focus on the introduction of new engineering technique developed by domestic company for preparing carbon master batch.

• Membrane Journal
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• v.22 no.5
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• pp.318-325
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• 2012

PTMSP-PMMH-NaY zeolite composite membranes were prepared by the addition of 10, 20, 30, and 40 wt% NaY zeolite contents to PTMSP containing 20 wt% PMMH dendrimer. To investigate the physico-chemical characteristics of composite membranes, the analytical methods such as FT-IR, TGA, and SEM have been utilized, and the gas permeability and selectivity properties of hydrogen and nitrogen were evaluated. The permeability of the PTMSP-PMMH-NaY zeolite composite membranes increased as NaY zeolite content increased, the permeabilities of hydrogen and nitrogen gases were observed being 3,950~592,000 barrer and 1,550~143,000 barrer, respectively. Simultaneously, selectivity of hydrogen against nitrogen did not show a discernible difference at 0~30 wt% range of NaY zeolite contents and increased from 2.2 to 4.2 at 30~40 wt% range.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.1
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• pp.28-38
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• 2014

The organic-inorganic composite membrane in polymer exchange membrane fuel cells (PEMFCs) have several fascinating technological advantages such as a proton conductivity, thermal stability and mechanical properties. As the inorganic filler, silicon carbide (SiC) fiber have been used in various fields due to its unique properties such as thermal stability, conductivity, and tensile strength. In this study, composite membrane was successfully fabricated by modified-silicon carbide fiber. Modified process, as a novel process in SiC, takes reaction by phosphoric acid after oxidation process (generated homogeniusly $SiO_2$ layer on SiC fiber). The mechanical property which was conducted by tensile test of the 5wt% modified-$SiO_2@SiCf$ composite membrane was better than that of Aquivion casting membrane as well as ion cxchange capacity(IEC) and proton conductivity. In addition, the single cell performance was observed that the 5wt% modified-$SiO_2@SiCf$ composite membrane was approximately $0.2A/cm^2$ higher than that of a Aquivion casting electrolyte membrane and electrochemical impedance was improved with the charge transfer resistance and membrane resistance.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.5
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• pp.79-87
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• 2014

The enrichment with nutrients in rivers and lakes becomes serious problems in Korea. As the environmental friendly solution, the phytoremediation are getting more attention and the water hyacinth could be a strong candidate plant for this. Water hyacinth is a free floating freshwater plant proven to be a effective plant used for a purification of a polluted lakes, sewage wastewater, and livestock wastewater. The biggest obstacles for application of water hyacinth in Korea could be the disposal of the water hyacinth before winter, because there is no feasible use for the water hyacinth until now. In this study, the characteristics of water hyacinth were deeply investigated for providing background data to develop appropriate application of the water hyacinth. The water hyacinth was fractioned three parts, leaf, air blader, root of which morphological properties were evaluated with microscope and field emission scanning electron microscope (FE-SEM). The water contents of each parts of the water hyacinth were 87% for leaf, 96.5% for air bladder, 94.6% for root. The chemical compositions of each parts were also measured and showed around 29% of hot water extract in leaf and air bladder, 42% holocellulose for leaf, 47% holocellulose for air bladder. The application of water hyacinth biomass without root parts to papermaking provided bulkier structure, but the tensile strength was decreased.

• Journal of Conservation Science
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• v.28 no.2
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• pp.141-151
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• 2012

It was the 1900s that the damaged materials of stone heritages began to be preserved and managed for the purpose of reuse, especially since cement, an inorganic material, began to be used during the Japanese colonial period. Epoxy resin, an organic material, was introduced to architecture around the turn of the 1990s, and has been being used across the board. In particular, filler mixtures began to be aggressively used for the structural reinforcement of severed materials. The problem was metal stiffeners used for structural reinforcement. The anchorage length varied depending in different conservation scientists, and as a result the secondary damage was apt to occur in the materials. In this study, hereat, a calculation was made of the most effective anchorage length with the minimization of material damage. The results were as in the following: the anchorage length of an 8-milimeter-across (ø8) metal stiffener was found to be most effective at 60.88mm. Those of ø12 and ø16 were 60.88mm and 91.32mm respectively. In the case of other calibers, the anchorage length was calculated by a formula ${\ell}_d=a_tf_y/u{\Sigma}_0$. In the experiment, helically-threaded round bars were used as metal stiffeners in order that they could bear surcharge loads such as bending, shear and constriction.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.29 no.1
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• pp.36-42
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• 1997

The fiber wall filling(FWF) technology, which is based on Precipitatin of fillers in the micropores of the cell wall structure of never-dried chemical pulp fiber, has been developed to improve filling and loading process in papermaking. In presenting FWF technique here, micropores of pulp fiber are first impregnated with an ionic solution of water soluble salt and consecutively impregnated with the second salt solution. This procedure generates an insoluble precipitate within the micropores of cell wall by chemical interaction of these two ionic salt solutions This is the first attempts to use FWF technology for the quality of waste paper grade which is recycled in papermaking, even though this FWF technology has been impressively improved for never-dried chemical pulp in filling and loading process of papermaking. The precipitated amount of CaCO$_3$ and SrCO$_3$ reached 5-6% and 4-5% of the waste paper weight respectively, which was measured by ash content of the burned waste paper fiber. On the other way the precipitated amounts of those materials impregnated into never-dried chemical pulp fiber have reached 17-18% and 16-18% respectively. The micropore loading technique gives optical and physical properties to the handsheets formed with celt-wall-filled fibers which are better than those handsheet properties resulting from conventional loading. The papers made from the cell-wall-filled pulps are stronger than those with the customary location of filler between the fibers.

• Polymer(Korea)
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• v.36 no.2
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• pp.229-234
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• 2012

This paper studied the effects of the content and the orientation of the disk shape fillers on the modulus of PP composites. The experimental results were compared with the theoretical calculations which included the three dimensional ellipsoids and analyzed by two aspect ratios, ${\rho}_{\alpha}=a_1/a_3$and ${\rho}_{\beta}=a_1/a_2$proposed by Lee and his researchers. Mica and talc were used as disk shape fillers in the composites. The shapes of mica and talc were observed by SEM and aspect ratios were statistically calculated. For the case of mica, the average aspect ratios were ${\rho}_{\alpha}=13.5$ and ${\rho}_{\beta}=1.8$, and for the case of talc, they were ${\rho}_{\alpha}=3.8$ and ${\rho}_{\beta}=1.4$. Also, the effects of two aspect ratios and the content of filler on the mechanical properties were studied: For 30 wt% of mica, $E_{11}$ increased up to about 2.7 times, and for the other case of talc, $E_{11}$ increased up to about 2.3 times, respectively.