• Title/Summary/Keyword: organic filler

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Fundamental Study on Developing Lignocellulosic Fillers for Papermaking(I) (목질계 제지용 충전제 개발을 위한 기초연구(I))

  • Shin, Tae-Gi;Kim, Chul-Hwan;Chung, Ho-Kyung;Seo, Jung-Min;Lee, Young-Rok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.2
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    • pp.8-15
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    • 2008
  • Wastewoods (logging residues) generated in Korea were used to make lignocellulosic fillers for papermaking. Lignocellulosic fillers could play great roles to increase retention efficiency and thus decrease turbidity of white water in papermaking process. In addition, lignocellulosic fillers could be used to improve physical properties of paper through their high affinity to cellulosic fibers, leading to the less use of chemical additives like retention aids. Wastewoods including Pinus densiflora and Quercus variabilis were chemically and mechanically treated for making fine particles passing through 100 mesh wire. The newly generated fillers showed larger particle size distribution than ground calcium carbonates but similar distribution to talc. In particular, pretreatment by hot water was more effective to generate smaller particle size than by alkali treatment. Lignocellulosic particles mixed with ground calcium carbonates under intense hybridizing condition greatly contributed to surface coverage of organic fillers in addition to filling to lumen and pits.

Preparation and Properties of Fireproofing Polyolefin Compound Using Nano Clay (Nano Clay를 이용한 난연성 Polyolefin Compound의 제조 및 특성에 관한 연구)

  • Kang, Doo-Whan;Huh, June
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.2
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    • pp.165-172
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    • 2003
  • Fireproofing polyolefin nanocomposite for the application of power distributing panel was prepared by compounding linear low density polyethylene(LLDPE), decabromodiphenyl oxide (DBDPO), $Sb_2O_3$ as flame retardant agents, and modified nano clay as filler. The optimized formulation ratio of compounds to prepare the fireproofing polyolefin nanocomposite was obtained. The flame retardant properties for nanocomposite prepared by compounding 22.5 phr of nano clay and 18 phr of DBDPO based on 100 phr of LLDPE were shown that the combustion time. 10${\sim}$18 s, combustion distance, 12${\sim}$15 mm and non-melt dropping characteristics. In particular. the content of DBDPO in nanocomposite could be decreased to 18 phr from 40 phr DBDPO for fireproofing composite containing 30 phr of clay. The electrical properties measured from tracking test, had an excellent antitracking properties by not showing the phenomenon of leakage current and sparking.

Enhanced adhesion properties of conductive super-hydrophobic surfaces by using zirco-aluminate coupling agent

  • Park, Myung-Hyun;Ha, Ji-Hwan;Song, Hyeonjun;Bae, Joonwon;Park, Sung-Hoon
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.387-392
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    • 2018
  • Various technical approaches and concepts have been proposed to develop conductive super-hydrophobic (SH) surfaces. However, most of these approaches are not usable in practical applications because of insufficient adhesion and cost issues. Additionally, durability and uniformity issues are still in need of improvement. The goal of this research is to produce a large-area conductive SH surface with improved adhesion performance and uniformity. To this end, carbon nanotubes (CNT) with a high aspect ratio and elastomeric polymer were utilized as a conductive filler and matrix, respectively, to form a coating layer. Additionally, nanoscale silica particles were utilized for stable implementation of the conductive SH surface. To improve the adhesion properties between the SH coating layer and substrate, pretreatment of the substrate was conducted by utilizing both wet and dry etching processes to create specific organic functional groups on the substrate. Following pretreatment of the surface, a zirco-aluminate coupling agent was utilized to enhance adhesion properties between the substrate and the SH coating layer. Raman spectroscopy revealed that adhesion was greatly improved by the formation of a chemical bond between the substrate and the SH coating layer at an optimal coupling agent concentration. The developed conductive SH coating attained a high electromagnetic interference (EMI) shielding effectiveness, which is advantageous in self-cleaning EMI shielding applications.

Synthesis and Properties of Nylon 6/PEG Random Block Copolymer/Clay Nanocomposite via in situ Polymerization (in situ중합을 통한 나일론 6-PEG 랜덤공중합체/점토 나노복합체의 합성 및 물성)

  • Angelica S. Lopez;Pio Sifuentes;Kim, Kap-Jin
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.72-74
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    • 2003
  • There has been extensive interest in the development of new nanocomposites. One kind of these systems is the hybrid based on organic polymers and inorganic minerals consisting of layered silicates. Some properties like stiffness, strength, barrier properties, thermal, and oxidative stability can be improved by the presence of the filler in the polymeric matrix[1]. It is reported that, in the nylon 6/clay nanocomposites, the modulus is increased, but impact strength and elongation at break are drastically decreased. (omitted)

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Oyster Shell waste is alternative sources for Calcium carbonate (CaCO3) instead of Natural limestone

  • Ramakrishna, Chilakala;Thenepalli, Thriveni;Nam, Seong Young;Kim, Chunsik;Ahn, Ji Whan
    • Journal of Energy Engineering
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    • v.27 no.1
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    • pp.59-64
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    • 2018
  • In this paper, we investigated the alternative sources of limestone. Oyster shell waste originated from aquaculture that causes a major disposal landfill problem in coastal sectors in southeast Korea. Their inadequate disposal causes a significant environmental problems araised. Bio mineralization leads to the formation of oyster shells and consists $CaCO_3$ as a major phase with a small amount of organic matter. It is a good alternative material source instead of natural lime stone. The utilization of oyster shell waste for industrial applications instead of natural limestone is major advantage for conservation of natural limestone. The present work describes the limestone and oyster shells hydraulic activity and chemical composition and characteristics are most similar for utilization of oyster shell waste instead of natural limestone.

Investigation of Adhesion Mechanism at the Metal-Organic Interface Modified by Plasma - Part I

  • Sun, Yong-Bin
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2002.11a
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    • pp.123-126
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    • 2002
  • For the mold die sticking mechanism, the major explanation is that EMC filler of silica wears die surface roughened, which results in increase of adhesion strength. As big differences in experimental results from semiconductor manufacturers are dependent on EMC models, however, chemisorptions or acid-base interaction is apt to be also functioning as major mechanisms. In this investigation, the plasma source ion implantation (PSII) using $O_2$, $N_2$, and $CF_4$ modifies sample surface to form a new dense layer and improve surface hardness, and change metal surface condition from hydrophilic to hydrophobic and vice versa. Through surface energy quantification by measuring contact angle and surface ion coupling state analysis by Auger, major governing mechanism for sticking issue was figured out to be a complex of mechanical and chemical factors.

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Investigation of Adhesion Mechanism at the Metal-Organic Interface Modified by Plasma Part I

  • Sun, Yong-Bin
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.4
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    • pp.31-34
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    • 2002
  • For the mold die sticking mechanism, the major explanation is that the silica as a filler in EMC (epoxy molding compound) wears die surface to be roughened, which results in increase of adhesion strength. As the sticking behavior, however, showed strong dependency on the EMC models based on the experimental results from different semiconductor manufacturers, chemisorption or acid-base interaction is apt to be also functioning as major mechanisms. In this investigation, the plasma source ion implantation (PSII) using $O_2, N_2$, and $CF_4$ modifies sample surface to form a new dense layer and improve surface hardness, and change metal surface condition from hydrophilic to hydrophobic or vice versa. Through surface energy quantification by measuring contact angle and surface ion coupling state analysis by Auger, major governing mechanism for sticking issue was figured out to be a complex of mechanical and chemical factors.

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A Study on Properties of Thermal Insulation Board Prepared by Porous Silica Aerogel (다공성 실리카 에어로겔을 이용한 복합단열재의 특성에 관한 연구)

  • Yoon, Jong-Kuk;Koo, Kyung-Wan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.9
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    • pp.1362-1367
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    • 2012
  • High porous silica aerogel/polyurethane polymer composite was manufactured by cross-linking polymerization of polyurethane foaming process. The properties of microstructure, mechanical strength, and thermal properties were investigated for its various applications. The superhydrophobic silica aerogel powders were used for highly thermal insulation filler materials. The thermal conductivities can be resulted 0.07 W/mK to 0.13 W/mK, by decreasing the contents of silica aerogels in composite materials. It is found that the polymerization formulation by organic binders can be applied to heavy industires, building materials, and various industries.

The Adsorption Characteristics of a Granular Active Carbon by the Physical Properties (입상 활성탄의 물리적특성 변화에 따른 흡착특성)

  • 김덕기;신창섭
    • Journal of the Korean Society of Safety
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    • v.11 no.1
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    • pp.84-89
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    • 1996
  • The adsorption characteristics of active carbon used as a cartridge filler of organic vapor respirator were examined by humidity, particle size, challenge concentration and specific surface area. As a result, the 1% breakthrough time of Carbon Tetrachloride($CCl_4$) was decreased with increase of relative humidity, challenge concentration and particle size (0.6~2.0mm) of active carbon. The adsorbed amount of $CCl_4$ was about 1. 1mg/$m^2$ at RH 40% and 0. 5mg/$m^2$ at RH 80% . However in the case of prehumidified active carbon, humidity did not affected to 1% breakthrough time up to RH 40%.

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A Review on Thermoelectric Technology: Conductive Polymer Based Thermoelectric Materials

  • Park, Dabin;Kim, Jooheon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.3
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    • pp.203-214
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    • 2022
  • Thermoelectric (TE) heating and cooling devices, which are able to directly convert thermal energy into electrical energy and vice versa, are effective and have exhibited a potential for energy harvesting. With the increasing consumer demands for various wearable electronics, organic-based TE composite materials offer a promise for the TE devices applications. Conductive polymers are widely used as flexible TE materials replacing inorganic materials due to their flexibility, low thermal conductivity, mechanical flexibility, ease of processing, and low cost. In this review, we briefly introduce the latest research trends in the flexible TE technology and provide a comprehensive summary of specific conductive polymer-based TE material fabrication technologies. We also summarize the manufacture for high-efficiency TE composites through the complexation of a conductive polymer matrix/inorganic TE filler. We believe that this review will inspire further research to improve the TE performance of conductive polymers.