• Title/Summary/Keyword: organic dye

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Fabrication of Photoluminescent Dye Embedded PMMA Nanofiber and its Fluorescence Resonance Energy Transfer

  • Lee, Kyung-Jin;Oh, Joon-Hak;Kim, Young-Geun;Jang, Jyong-Sik
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.314-314
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    • 2006
  • The FRET property has been extensively studied from the theoretical view points to the practical applications. In case that the donor and acceptor are confined in nanodimension, the FRET effectively occurs, because of their distant dependent characteristic. However, there are no reports concerning FRET with one dimensional (1D) nanomaterial. We have successfully prepared the PMMA nanotubes using vapor deposition polymerization as the platform of FRET. The dye-PMMA composite nanofiber has also been produced without phase separation and any deterioration of properties of the dyes. The PMMA 1D nanocomposite doped two dyes with great spectral overlap between donor and acceptor displayed FRET property.

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Multilayer White Organic Light-Emitting Diodes with Blue Fluorescent and Red Phosphorescent Materials

  • Seo, Ji-Hoon;Kim, Jun-Ho;Lee, Kum-Hee;Kim, You-Hyun;Kim, Woo-Young;Yoon, Seung-Soo;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1067-1070
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    • 2006
  • We have demonstrated highly efficient WOLED with two separated emissive layers using a blue fluorescent dye and a red phosphorescent dye. The maximum luminous efficiency of the device was 11.2 cd/A at $20\;mA/cm^2$ and $CIE_{x,y}$ coordinates varied from (x = 0.33, y = 0.37) at 6V to (x = 0.25, y = 0.33) at 14V.

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Dyeing Properties of Ultra-fine Nylon Suede Non-woven Fabric with Sulphur Black Dye by Pad-steam Process (흑색 황화염료와 초극세사 나일론 스웨이드 부직포 직물의 Pad-steam 염색 및 염색성 평가)

  • Kim, Min Seok;Jung, Dae-Ho;Lee, Mikyung;Ko, Jae Wang;Lee, Jeong Hoon;Lee, Seung Geol
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.211-222
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    • 2017
  • In this study, we investigated the dyeing properties of the ultra-fine nylon suede non-woven fabric with Sulphur black dye regarding to the effect of dye concentrations, reducing agent contents, sodium carbonate contents, antioxidant contents, immersion temperature and exposure time in air by pad-steam process. The optimal conditions of dyeing for the ultra-fine nylon suede non-woven fabric were determined with dye concentration of 30% o.w.f., reducing agent content of $9{\sim}13g/{\ell}$, sodium carbonate content of $1{\sim}4g/{\ell}$, antioxidant content of $1{\sim}5g/{\ell}$, immersion temperature of $70^{\circ}C$, exposure time of 20 minutes in air and immersion time of 1 minute, respectively. Meanwhile, the colorfastness to washing, the colorfastness to light, and the colorfastness to perspiration for dyed ultra-fine nylon suede non-woven fabric were achieved in the range of 4-5 grades. The formaldehyde and arylamine were not detected on the ultra-fine nylon suede non-woven fabric by KC tests.

Aqueous Electrolytes Based Dye-sensitized Solar Cells using I-/I3- Redox Couple to Achieve ≥ 4% Power Conversion Efficiency

  • Choi, Hyeju;Han, Jinjoo;Kang, Moon-Sung;Song, Kihyung;Ko, Jaejung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1433-1439
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    • 2014
  • We report on the influence of water as an electrolyte on the photovoltaic performances. The photovoltaic performance was shown to be quite sensitive to the substituent on the donor group. An optimized efficiency of 4.41% in the presence of 100% water content using $I^-/I{_3}^-$ redox couple was obtained using the D21L6 organic dye.

Study on the reflectance characteristics of materials for dye sensitized solar cell materials

  • Jung, In-Sung;Park, Book-Sung;Kim, Il-Ho;Hong, Gen-Gi;Kim, Chul-Ju
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.447-447
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    • 2008
  • 본 논문의 목표는 염료감응 태양전지의 재료적 특성중 반사율을 측정하여 가장 투명한 dye sensitized solar cell을 제조하기 위한 기초자료를 도출하기 위함이다. 먼저 염료감응 태양전지의 재료중 산화물질인 TiO2,SnO2,ZnO,$Nb_2O_5$ 10~50nm두께로 ITO 기판위에 코팅하여 UV-VIS를 통해 파장별 반사 특성을 분석하였다. 또한, 동일한 시료를 사용하여 FESEM을 통한 표면 Morphology를 확인하였다. 기판제료인 TiO2,dye(염료),TCO,glass,ICO 에 대해서도 동일한 특성분석을 하였다.

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Novel Organic Sensitizers with a Quinoline Unit for Efficient Dye-sensitized Solar Cells

  • Choi, Hye-Ju;Choi, Hyun-Bong;Paek, Sang-Hyun;Song, Ki-Hyung;Kang, Moon-Sung;Ko, Jae-Jung
    • Bulletin of the Korean Chemical Society
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    • v.31 no.1
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    • pp.125-132
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    • 2010
  • Three organic sensitizers, JK-128, JK-129, and JK-130 containing quinoline unit are designed and synthesized. Under standard global AM 1.5 solar condition, the JK-130 sensitized solar cell gave a short circuit photocurrent density of 11.52 mA $cm^{-2}$, an open circuit voltage of 0.70 V, and a fill factor of 0.75, corresponding to an overall conversion efficiency of 6.07%. We found that the $\eta$ of JK-130 was higher than those of other two cells due to the higher photocurrent. The higher $J_{sc}$ value is attributed to the broad and intense absorption spectrum of JK-130.

Room-temperature synthesis of cobalt nanoparticles and their use as catalysts for Methylene Blue and Rhodamine-B dye degradation

  • Mondal, Arijit;Mondal, Asish;Mukherjee, Debkumar
    • Advances in nano research
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    • v.3 no.2
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    • pp.67-79
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    • 2015
  • Air stable nanoparticles were prepared from cobalt sulphate using tetra butyl ammonium bromide as surfactant and sodium borohydride as reductant at room temperature. The cobalt nanocolloids in aqueous medium were found to be efficient catalysts for the degradation of toxic organic dyes. Our present study involves degradation of Methylene Blue and Rhodamine-B using cobalt nanoparticles and easy recovery of the catalyst from the system. The recovered nanoparticles could be recycled several times without loss of catalytic activity. Palladium nanoparticles prepared from palladium chloride and the same surfactant were found to degrade the organic dyes effectively but lose their catalytic activity after recovery. The cause of dye colour discharge by nanocolloids has been assigned based on our experimental findings.

Direct Coloration using Self-assembly Fabrication Method on PET Fibers - Surface diazo coupling reaction -

  • Kim, Byung-Soon;Son, Young-A
    • Textile Coloration and Finishing
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    • v.19 no.5
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    • pp.37-40
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    • 2007
  • The electrostatic layer-by-layer technique provides a convenient way to control the construction of ultrathin films at nano-scale ranges and can be easily obtained. It can be also applicable to fiber substrate with dye compounds. We have fabricated multilayer dye films using diazonium resin and three couplers, which are prepared by self-assembly approach. This method is based on layer-by-layer deposition using electrostatic attraction between oppositely charged ions. Beside, the diazo coupling reaction proceeded to form azo dye layer on the PET fibers the same time. The corresponding results of the multilayer films have been discussed on the level of color strength (K/S).

Degradation and mineralization of violet-3B dye using C-N-codoped TiO2 photocatalyst

  • Putri, Reza Audina;Safni, Safni;Jamarun, Novesar;Septiani, Upita;Kim, Moon-Kyung;Zoh, Kyung-Duk
    • Environmental Engineering Research
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    • v.25 no.4
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    • pp.529-535
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    • 2020
  • The present study investigated the photodegradation of synthetic organic dye; violet-3B, without and with the addition of C-N-codoped TiO2 catalyst using a visible halogen-lamp as a light source. The catalyst was synthesized by using a peroxo sol-gel method with free-organic solvent. The effects of initial dye concentration, catalyst dosage, and pH solution on the photodegradation of violet-3B were examined. The efficiency of the photodegradation process for violet-3B dye was higher at neutral to less acidic pH. The kinetics reaction rate of photodegradation of violet-3B dye with the addition of C-N-codoped TiO2 followed pseudo-first order kinetics represented by the Langmuir-Hinshelwood model, and increasing the initial concentration of dyes decreased rate constants of photodegradation. Photodegradation of 5 mg L-1 violet-3B dye achieved 96% color removal within 240 min of irradiation in the presence of C-N-codoped TiO2 catalyst, and approximately 44% TOC was removed as a result of the mineralization.