• Title/Summary/Keyword: organic component

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Studies on the Preparation of Organic Halogen Compounds Labelled by $^38 Cl$. (II)

  • Kim, You-Sun
    • Nuclear Engineering and Technology
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    • v.5 no.3
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    • pp.202-213
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    • 1973
  • In a continuation of the 1st series of these studies, a separation of the components in organic phases obtained from Szilard Chalmer reactions of aromatic chloro derivatives was attempted to clarify the conditions of isolating the main component. Though it was unable to isolate all constituents of organic phases, the main component was well isolated by means of a simple distillation or a thin layer chromatography. It was identified that the main component was a recombined product of the recoiled $^{38}$ Cl atom with the original sample. In cases of solid samples the main component amounted about 80-60% of the radio activity of the organic phase, whereas the main component from liquid samples gave less than 70% of the radio activity of the organic phase. A prolonged irradiation could increase the yield of a main component, but it was, in case of a radiation senintive compound, decreased as the irradiation is extended. The number of aide produets separated from an organic phase of a liquid sample was greater than that of a solid sample, and hence the main component of a solid sample was isolated easier. The overall fields of the labelled main products of 22 kinds of compounds were listed and a procedure of the separation of the main component by a thin layer chromatograply was proposed and evaluated. The feasibility of the present procedure for labelling purpose was also reviewed with respects to the chemical structure of a compound.

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Preparation of UV-Curable Organic-Inorganic Hybrid Hard Coating Films Using Alumina Sols and Acrylate Monomers (알루미나 졸과 아크릴레이트 단량체를 이용한 UV경화형 유-무기 하이브리드 하드코팅 막 제조)

  • Hwang, Ji-Hyeon;Song, Ki-Chang
    • Korean Chemical Engineering Research
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    • v.49 no.3
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    • pp.277-284
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    • 2011
  • In this study, UV-curing type organic - inorganic hybrid hard coating solutions were prepared from alumina sols and acrylate monomers. The mixture of alumina sols, prepared from aluminum isopropoxide, and a silane coupling agent, methacryloxypropyl trimethoxysilane(MPTMS), was used as an inorganic component. Also, the mixture of acrylate monomers, pentaerythritol triacrylate(PETA), 1,6-hexanediol diacrylate(HDDA) and dipentaerythritol hexaacrylate (DPEHA), was used as an organic component. The organic-inorganic hybrid coating solutions were obtained by mixing the inorganic component and organic component, deposited on polycarbonate substrates by spin coating and densified by UV-curing. The effect of the amount of MPTMS in the inorganic component and the irradiation time during UV-curing was studied on the properties of coating films. As a result, when 0.20 mole of MPTMS was used, the pencil hardness of coated films showed an excellent pencil hardness of 3H and also exhibited a good abrasion resistance of 2% in haze.

Degradation of Organic Component in MSW by Super-heated Steam (과열(過熱) 증기(蒸氣)를 이용한 국내 폐기물(廢棄物) 유기성(有機性) 성분의 분해(分解) 특성 연구)

  • Kim, Woo-Hyun;Roh, Seon-Ah;Min, Tai-Jin;Sung, Hyun-Je;Park, Seong-Bum;Jang, Ha-Na
    • Resources Recycling
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    • v.18 no.6
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    • pp.10-17
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    • 2009
  • Degradation of the organic component in the waste were carried out by superheated steam in a pressurized vessel. The effects of waste characteristics, reaction temperature and residence time on the degradation rate have been determined. The biodegradable organic components such as food and paper waste have been degraded, and plastics, wood and metal were remained without degradation. The degradation efficiency is decided by the desizing rate of the waste, and the waste mixture with 23% biodegradable organic component shows higher desizing rate than that of the 43% of the biodegradable organic component in a short residence time and the desizing rate is found to be 90% in the maximum condition.

Clinical application and classification of bone graft material according to component (임상가를 위한 특집 2 - 구성성분별 골이식재의 분류와 임상적용)

  • Kim, Young-Kyun
    • The Journal of the Korean dental association
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    • v.48 no.4
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    • pp.263-274
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    • 2010
  • I classified the bone graft material according to the component. Most bone graft material is composed of inorganic and organic constituent. Organic component such DBM is associated with osteoinduction. Inorganic components such as hydroxyapatite, $\beta$-TCP, calcium sulfate, bioactive glass, polymer are associated with osteoconduction. Autogenous bone graft is ideal material. We can select any biocompatible material for the restoration of small filling defect with intact bony wall. However, we should select first osteogenetic and osteoinductive material to regenerate the viable bone tissue.

The triple layer anode for flexible top emission organic lightemitting devices

  • Chung, Sung-Mook;Hwang, Chi-Sun;Lee, Jeong-Ik;KoPark, Sang-Hee;Yang, Yong-Suk;Do, Lee-Mi;Chu, Hye-Yong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.698-701
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    • 2007
  • A top emission organic light emitting diode comprising of a triple anode on polycarbonate $film/TNATA/NPB/Alq_3:C545T/cathodes$ has been fabricated. The triple layer structure of Cr/Al/Cr allowed for fabrication of a crack-free anode and provided better higher work function than ITO anode.The anode showed compatibility with flexible plastic substrate and no crack was formed during bending test while ITO anode showed crack.

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Dynamic Response of Organic Right-emitting Diodes in ITO/Alq3 Structure

  • Lee, Dong-Gyu;Lee, Joon-Ung
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.3
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    • pp.97-100
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    • 2005
  • Dynamic response of organic light-emitting diodes were analyzed in $ITO/Alq_3$(100 nm)/Al device structure with a variation of voltage an frequency. At low frequency region, complex impedance is mostly governed by resistive component, and at high frequency region by capacitive component. Also, we have evaluated resistance, capacitance and permittivity of devices.

Characteristics of Organic Matters in the Suyeong River During Rainfall Event (강우 시 수영강 유역 내 유기물질의 특성)

  • Kim, Suhyun;Kim, Jungsun;Kang, Limseok
    • Journal of Korean Society on Water Environment
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    • v.34 no.5
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    • pp.487-493
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    • 2018
  • Urban stormwater runoff is the one of the most extensive causes of deterioration of water quality in streams in urban areas. Especially, in the Suyeong River watershed, non-point sources from urban-residential areas are the most common cause of water pollution. Also, it has been ascertained that BOD and COD as indexes of organic matter, have limitation on management of Suyeong River's water quality. In this study, changes of organic matter properties of Suyeong River from inflow of non-point source during rainfall were investigated. Fractions of organic matters were analyzed using water samples collected at two sites (Suyeong River and Oncheon Stream) during a rain event. Variations of dissolved organic carbon (DOC) concentration by rainfall were similar to flow rate change in the river. Distribution of organic matter fraction according to change of rain duration revealed that while hydrophilic component increased at initial rainfall, the hydrophobic component was similar to change in dissolved organic carbon (DOC) concentration. Also, the relative proportion of hydrophilic components in organic matter in river water increased, due to rainfall. Results of biodegradation of organic matters revealed that decomposition rate of organic matters during rainfall was higher than that of during a non-rainfall event.

A Study on Analysis of Component and the States of Measurement of Airborne Organic Solvents in Korea (우리나라의 공기중 유기용제 측정실태 및 성분분석에 관한 연구)

  • 원정일;신창섭
    • Journal of environmental and Sanitary engineering
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    • v.14 no.3
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    • pp.139-149
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    • 1999
  • This study was performed to investigate components of organic solvents and present statues of environmental measurements with official records of working environmental measurements of 4,181 workplaces in 3,280 workshops used airborne organic solvents. 1. The mean working hour of 4,181 workplace producing airborne organic solvents in 3,280 workshops was 437±28.7min, but the mean sampling time for measurement of airborne organic solvents was identified to be 254±28.8min. In 73.0% of 4,181 samples the sampling frequencys were Full-period, single sample measurement. 2. The total 54 components of organic solvents were measured in total airborne samples of 4,181 workplace in 3,280 workshops in both of first and second half-year. These were divided into 38 components, Group 1 substances (5 components), Group 2 substances (31 components) and Group 3 substances (2 components), regulated by the Industrial Safety and Health Law, and other 16 components without legal duty of working environment measurement. The most common component in each half-year was Toluene (84.8%, 88.2%), which was followed by Xylene (464.4%, 51.7%), Methyl ethyl ketone (31.1%, 34.4%), n-Hexane (22.7%, 27.8%) and Benzene (20.4%, 21.5%) in frequency. Of legal duty free components, Ethyl benzen, Trimethyl benzene and Pentane were frequently detected. In conclusion, these results show that the present legal classification system of organic solvents needs to revise. Also these results suggest that it must be necessary to analyze the component of airborne organic solvents mixture and to evaluate their effects on workers' health for the effective management of working environment in workshops treating with organic solvents.

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Comparison of Soil Bacterial Community Structure in Rice Paddy Fields under Different Management Practices using Terminal Restriction Fragment Length Polymorphism (T-RFLP)

  • Kim, Do-Young;Kim, Chang-Gi;Sohn, Sang-Mok;Park, Sang-Kyu
    • Journal of Ecology and Environment
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    • v.31 no.4
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    • pp.309-316
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    • 2008
  • To develop a monitoring method for soil microbial communities in rice paddy fields, we used terminal restriction fragment length polymorphism (T-RFLP) to compare soil bacterial community structure in rice paddy fields experiencing different management practices: organic practices, conventional practices without a winter barley rotation, and conventional practices with a winter barley rotation. Restriction fragment length profiles from soils farmed using organic practices showed very different patterns from those from conventional practices with and without barley rotation. In principal component analyses, restriction fragment profiles in organic practice samples were clearly separated from those in conventional practice samples, while principal component analysis did not show a clear separation for soils farmed using conventional practices with and without barley rotation. The cluster analysis showed that the bacterial species compositions of soils under organic practices were significantly different from those under conventional practices at the 95% level, but soils under conventional practice with and without barley rotation did not significantly differ. Although the loadings from principal component analyses and the Ribosomal DNA Project II databases suggested candidate species important for soils under organic farming practices, it was very difficult to get detailed bacterial species information from terminal restriction fragment length polymorphism. Rank-abundance diagrams and diversity indices showed that restriction fragment peaks under organic farming showed high Pielou's Evenness Index and the reciprocal of Simpson Index suggesting high bacterial diversity in organically farmed soils.

Simultaneous Adsorption Characteristics of Binary-Component Volatile Organic Compounds (2성분계 휘발성유기화합물의 동시 흡착특성)

  • Park, Byung-Bae;Kim, Han-Su;Park, Yeong-Seong
    • Clean Technology
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    • v.7 no.2
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    • pp.133-140
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    • 2001
  • The adsorption characteristics of binary-component Volatile Organic Compounds(VOCs) with benzene and toluene were studied in a fixed bed backed with activated carbon. The adsorption intensites of benzene and toluene resulted from equilibrium adsorption capacity led to roll up phenomenon in a fixed bed and behaved benzene as non-key component which meant the smaller affinity to the activated carbon of the two. From comparion with breakthrough curves between binary-component and single component systems at the same concentration conditions, the stoichiomertic breakthrough time of toluene in both systems had no difference, but that of benzene as non-key component had a tendency to shorten 130min than 200min of single component. In the breakthrough characteristics of binary-component adsorbates, the magnitude of roll-up of the non-key component increased with the increasing of non-key component ratio and aspect ratio(L/D) of fixed bed, while decreased with the increasing of interstitial velocity. Especially, the roll-up phenomenon was more conspicuous with the increasing of mole fraction of key component.

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