• 제목/요약/키워드: ordered structure

검색결과 385건 처리시간 0.033초

압전응용을 위한 $Ca_{3}NbGa_{3}Si_{2}O_{14}$ 화합물의 단결정 성장 (Crystal growth $Ca_{3}NbGa_{3}Si_{2}O_{14}$ compound for the piezoelectric application)

  • 강용호;정일형;오근호
    • 한국결정성장학회지
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    • 제11권4호
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    • pp.148-153
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    • 2001
  • 새로운 압전체인 $Ca_{3}NbGa_{3}Si_{2}O_{14}$(CNGS) 단결정은 Czochralski 법을 사용하여 결정성장을 이루었다. CNGS의 결정 구조는 $A_{3}BC_{3}D_{2}O_{14}$와 동방구조를 이루고 있음이 조사되어졌고, 단위 셀의 격자상수는 각각 a = 8.0873과 c = 4.979이었으며, 공간군은 P321이었다. 각각의 양이온의 분포는 각 자리에 규칙배멸을 이루고 있음을 보였다. CNGS 결정은 Langasite 보다 높은 품질계수, 전기기계결합계수, 압전성수를 나타내었으며, 이는 Langasite와 비교하여 낮은 탄성손실과 우수한 압전특성을 가짐을 보여주고 있다.

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석탄회를 이용한 제올라이트의 수열합성 (Hydrothermal Synthesis of Zeolite from Coal Fly Ash)

  • 배광현;황연;조성백
    • 한국결정학회지
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    • 제12권2호
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    • pp.97-101
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    • 2001
  • 국내의 화력발전소에서 발생하는 석탄회를 사용하여 $2.0M\sim3.5M$ 농도의 NaOH 수용액과 $80^{\circ}C{\sim}120^{\circ}C$에서 24시간 수열 반응시켜 필립사이트 형 제올라이트를 합성하였다. 합성된 제올라이트 분말의 특성을 XRD, SEM, IR 등을 이용하여 조사하였다. 석탄회의 산지에 따른 조성변화, 합성 시의 온도 및 NaOH의 농도 변화 등이 수열 합성된 제올라이트에 미치는 영향은 IR 흡수 스펙트럼에서 잘 나타났다. 석탄회의 $SiO_2$함량이 높고 합성온도와 NaOH 농도가 높을 수록 $TO_4$(T=Si, Al) 사면체가 규칙성이 높은 구조로 합성되었다.

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풍력 발전단지의 출력 지령값을 고려한 계통 연계 운영 방안 (A New Control Scheme of Wind Farm Considering P,Q References)

  • 최정현;박진우;문승일
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 제39회 하계학술대회
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    • pp.1172-1173
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    • 2008
  • At the moment, the control ability of wind farms is a prime research concern for the grid integration of large wind farms, due to their required active role in the power system. As more wind turbines are installed, the power from wind energy will start to replace conventional generation units and its influence on power systems cannot be neglected. Besides, because of the intermittent nature of wind the output power of wind turbines fluctuates according to wind speed variation. Especially an isolated power system with small capacity such like Jeju needs more systematic solutions and regulations(grid code). This paper presents the idea of approach for centralized operating wind farm strategy to regulate the wind farm power production to the reference power ordered by the system operator. The doubly fed induction generator(DFIG) can control active and reactive power in feasible range. So wind farm comprised of DFIG has the possibility of a controllable component in the power system. The presented wind farm control has a hierarchical structure with both a wind farm control level and a wind turbine control level.

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Fe-30Al-5Cr 합금의 미세조직 및 $D0_3{\leftrightarrow}B2$ 천이온도에 미치는 Ti, Hf 및 Zr의 첨가효과 (Effects of Titanium, Hafnium and Zircornium Alloying Elements on Microstructures and $D0_3{\leftrightarrow}B2$ Transition Temperature of Fe-30Al-5Cr Alloys)

  • 김성수;주성민;오선훈;김관휴;최답천
    • 한국주조공학회지
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    • 제21권1호
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    • pp.15-23
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    • 2001
  • The changes in the microstructures and $D0_3{\leftrightarrow}B2$ transition temperature were investigated for Fe-30at.%AI-5at.%Cr alloy with the ordered $D0_3$, structure when Ti, Hf and Zr were added respectively. The addition of Cr has no effect on the microstructure. However, as the amount of Ti addition increased, the grain size became smaller. Addition of Ti+Hf, Ti+Zr and Ti+Hf+Zr also showed the similar effect. When 20at.% of Ti was added, the second phase precipitates on the substrate. The addition of Cr, Hf and Zr alone has no effect on $D0_3{\leftrightarrow}B2$ transition temperature. However, as the amount of Ti addition increased by 5, 10, 15 and 20at.%, the transition temperatures showed 929, 930, 960 and $930^{\circ}C$ respectively.

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Growth, Structure, and Stability of Ag on Ordered ZrO2(111) Films

  • Han, Yong;Zhu, Junfa;Kim, Ki-jeong;Kim, Bongsoo
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.204.2-204.2
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    • 2014
  • Among various metal oxides, ZrO2 is of particular interests and has received widespread attention thanks to its ideal mechanical and chemical stability. As a cheap metal, Ag nanoparticles are also widely used as catalysts in ethylene epoxidation and methanol oxidation. However, the nature of Ag-ZrO2 interfaces is still unknown. In this work, the growth, interfacial interaction and thermal stability of Ag nanoparticles on ZrO2(111) film surfaces were studied by low-energy electron diffraction (LEED), synchrotron radiation photoemission spectroscopy (SRPES), and X-ray photoelectron spectroscopy (XPS). The ZrO2(111) films were epitaxially grown on Pt(111). Three-dimensional (3D) growth model of Ag on the ZrO2(111) surface at 300 K was observed with a density of ${\sim}2.0{\times}1012particles/cm2$. The binding energy of Ag 3d shifts to low BE from very low to high Ag coverages by 0.5 eV. The Auger parameters shows the primary contribution to the Ag core level BE shift is final state effect, indicating a very weak interaction between Ag clusters and ZrO2(111) film. Thermal stability experiments demonstrate that Ag particles underwent serious sintering before they desorb from the zirconia film surface. In addition, large Ag particles have stronger ability of inhibiting sintering.

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멍게(Halocynthia roretzi) 혈구의 종류와 미세구조 (Classification and Ultrastructure of Hemocytes in the Tunicate Halocynthia roretzi (Ascidiacea: Pyuridae))

  • 신윤경;전제천;손맹현;김혜진;이정식
    • 한국수산과학회지
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    • 제45권5호
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    • pp.480-485
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    • 2012
  • The hemocytes of the tunicate Halocynthia roretzi are classified into six types based on their size, cellular form, and fine structure of the cytoplasmic granules: hyalinocytes, granulocytes, phagocytes, nephrocytes, morula cells, and multi-vacuole cells. Based on cell size, they are ordered multi-vacuole cells ($7.5{\mu}m$)>nephrocytes ($7.1{\mu}m$)>phagocytes ($6.8{\mu}m$)>granulocytes ($6.1{\mu}m$)>morula cells ($5.7{\mu}m$)>hyalinocytes ($5.4{\mu}m$). The proportion of hemocytes is ranked in the order multi-vacuole cells (54.8%)>nephrocytes (16.9%)>granulocytes (9.9%)>morula cells (8.8%)>phagocytes (6.1%)>hyalinocytes (3.5%).

마이크로 엑츄에이터용 형상기억 리본 제조 및 제특성 평가 (The Fabrication and Evaluation of SMA Ribbons for Micro Actuator Application)

  • 이영수;장우양
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2000년도 제15차 학술회의논문집
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    • pp.554-554
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    • 2000
  • To improve mechanical properties of Cu-Al-Ni alloy by the grain refinement, Cu-Al-Ni SMA ribbons were fabricated by melt spinning apparatus. The variations of microstructure, mechanical properties and transformation characteristics with the condition of rapid solidification and annealing time-temperature were investigated in Cu-Al-Ni SMA ribbons. The ribbons fabricated by melt spinning obtained around 1.5nm in width and 50-60${\mu}{\textrm}{m}$ in thickness. With increasing wheel speed in order of 10m/s, 15m/s, 20m/s, 30m/s and 3m/s, the grain size was decreased in order of 10${\mu}{\textrm}{m}$, 6.25${\mu}{\textrm}{m}$, 5.5${\mu}{\textrm}{m}$, 3${\mu}{\textrm}{m}$ and 3${\mu}{\textrm}{m}$. $M_{s}$ and $A_{s}$ temperature were decreased with decreasing grain size. By X-ray diffraction test, ordered $\beta$$_1$ phase was observed in all the SMA ribbons and the volume friction of it was increased with increasing wheel speed. With increasing wheel speed, strain was increased from 4.2% to 5.8% and fracture mode has changed from mixture of intergranular and dimple fracture to mixture of fiber structure and dimple fracture. The grain size of ribbon heat-treated at $600^{\circ}C$ was increased with increasing time. In the heat-treated ribbons at 55$0^{\circ}C$, ${\gamma}$$_2$ phases were observed.d.d.

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다공성 산화알루미늄의 표면코팅에 따른 트라이볼로지적 특성연구 (Study on Tribological Behavior of Porous Anodic Aluminum Oxide with respect to Surface Coating)

  • 김영진;김현준
    • Tribology and Lubricants
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    • 제33권6호
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    • pp.275-281
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    • 2017
  • In this work, we have fabricated anodic aluminum oxide (AAO) with ordered nanoscale porosity through an anodization process. We deposited gold and nano-organic thin films on the porous AAO surface to protect its structure and reduce friction. We investigated the tribological characteristics of the porous AAO with respect to the protective surface coatings using tribometers. While investigating the frictional characteristics of the samples by applying normal forces of the order of micro-Newton, we observed that AAO without a protective coating exhibits the highest friction coefficient. In the presence of protective surface coatings, the friction coefficient decreases significantly. We applied normal forces of the order of milli-Newton during the tribotests to investigate the wear characteristics of AAO, and observed that AAO without protective surface coatings experiences severe damage due to the brittle nature of the oxide layer. We observed the presence of several pieces of fractured particles in the wear track; these fractured particles lead to an increase in the friction. However, by using surface coatings such as gold thin films and nano-organic thin films, we confirmed that the thin films with nanoscale thickness protect the AAO surface without exhibiting significant wear tracks and maintain a stable friction coefficient for the duration of the tribotests.

O/W(110) 표면의 p($2{\times}1$) 구조의 임계지수 연구 (Exponent Study of the p($2{\times}1$) Phase on an O/W(110) Surface)

  • 백두현;정석민;정진욱
    • 한국진공학회지
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    • 제1권1호
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    • pp.88-95
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    • 1992
  • 고분해능 저에너지 전자회절법(HRLEED)을 이용하여 O/W(110) 표면의 산소흡착층 의 정돈된 p(2 $\times$ 1) 구조가 보이는 2차원 연속적인 상전이계에관한 임계지수 연구를 보고 한다. 이 구조의 (1/2 0) 초격자 회절점의 세기 및 모양을 온도에 대한 함수로 구하여 Tc=708.765K에서 감수율 및 요동상관거리가 차수법칙(power law)에 따르는 발산을 보이는 것이 관측되었다. 이로부터 구한 임계지수는 $\beta$=0.19$\pm$0.05, $\Upsilon=1.48pm$0.34, v=1.23$\pm$0.27 그 리고 η=0.38$\pm$0.12이다. 이들 비보편성을 갖는 임계지수들은 이 계를 지배하는 입방이방성 (cubic anisotropy)를 갖는 2차원 XY 모델로 이해된다.

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Hydrogen-bonded Molecular Network of Anthraquinone on Au(111)

  • Kim, Ji-Yeon;Yoon, Jong-Keon;Park, Ji-Hun;Kim, Ho-Won;Kahng, Se-Jong
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.107-107
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    • 2011
  • Supramolecular structures of anthraquinone molecules on a metallic surface are studied using scanning tunneling microscope (STM) under ultrahigh-vacuum conditions. When we deposited anthraquinone molecules on Au(111) substrate, the molecules formed three different phases (Chevron type, tetragon type and disordered type) on the surface. Based on our STM measurements, we proposed models for the observed molecular structures. Chevrons are consisted of several molecular chains, which make well-ordered two-dimensional islands by some weak interrow interactions and we could observe tetragon structures which make array of (111) metallic surface. each molecular rows in the chevrons are stabilized by two parallel O-H hydrogen bonds and disordered structures are observed 1-dimensional phase with hydrogen bond. First-principles calculations based on density functional theory are performed to reproduce the proposed models. Distances and energy gains for each intermolecular bond are estimated. In this presentation, we explain possible origins of these molecular structures in terms of hydrogen bonds, Van der Waals interactions and molecule-substrate interactions.

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