• Title/Summary/Keyword: ordered structure

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Crystal growth $Ca_{3}NbGa_{3}Si_{2}O_{14}$ compound for the piezoelectric application (압전응용을 위한 $Ca_{3}NbGa_{3}Si_{2}O_{14}$ 화합물의 단결정 성장)

  • 강용호;정일형;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.4
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    • pp.148-153
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    • 2001
  • New piezoelectric $Ca_{3}NbGa_{3}Si_{2}O_{14}$ (CNGS) single crystal was grown using the Czochralski technique. The crystal structure of CNGS was found to be isostructural with $A_{3}BC_{3}D_{2}O_{14}$. The unit cell parameters were a=8.087 and c=4.983 and the space group was P321. The distribution of each cation was found to be ordered in each site. Some piezoelectric properties of CNGS are showed.

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Hydrothermal Synthesis of Zeolite from Coal Fly Ash (석탄회를 이용한 제올라이트의 수열합성)

  • Bae, Kwang-Hyun;Hwang, Yeon;Cho, Sung-Baek
    • Korean Journal of Crystallography
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    • v.12 no.2
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    • pp.97-101
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    • 2001
  • Phillipsite-type zeolite powders were synthesized from domestic coal fly ash by hydrothermal reaction with 2.0 M-3.5M NaOH solution at $80^{\circ}C{\sim}120^{\circ}C$ for 24 h. The properties of zeolite were investigated by XRD, SEM and IR spectroscopy. The effects of chemical composition of fly ash, reaction temperature and NaOH concentration on the zeolite synthesis were well appeared on IR spectra. It is found that the $TO_4$(T=Si, Al) tetrahedra have a well ordered structure as the $SiO_2$ content, synthesis temperature and NaOH concentration become high.

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A New Control Scheme of Wind Farm Considering P,Q References (풍력 발전단지의 출력 지령값을 고려한 계통 연계 운영 방안)

  • Choi, Jung-Hyun;Park, Jin-Woo;Moon, Seung-Il
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1172-1173
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    • 2008
  • At the moment, the control ability of wind farms is a prime research concern for the grid integration of large wind farms, due to their required active role in the power system. As more wind turbines are installed, the power from wind energy will start to replace conventional generation units and its influence on power systems cannot be neglected. Besides, because of the intermittent nature of wind the output power of wind turbines fluctuates according to wind speed variation. Especially an isolated power system with small capacity such like Jeju needs more systematic solutions and regulations(grid code). This paper presents the idea of approach for centralized operating wind farm strategy to regulate the wind farm power production to the reference power ordered by the system operator. The doubly fed induction generator(DFIG) can control active and reactive power in feasible range. So wind farm comprised of DFIG has the possibility of a controllable component in the power system. The presented wind farm control has a hierarchical structure with both a wind farm control level and a wind turbine control level.

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Effects of Titanium, Hafnium and Zircornium Alloying Elements on Microstructures and $D0_3{\leftrightarrow}B2$ Transition Temperature of Fe-30Al-5Cr Alloys (Fe-30Al-5Cr 합금의 미세조직 및 $D0_3{\leftrightarrow}B2$ 천이온도에 미치는 Ti, Hf 및 Zr의 첨가효과)

  • Kim, Sung-Su;Joo, Sung-Min;Oh, Seon-Hun;Kim, Kwan-Hyu;Choi, Dap-Chun
    • Journal of Korea Foundry Society
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    • v.21 no.1
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    • pp.15-23
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    • 2001
  • The changes in the microstructures and $D0_3{\leftrightarrow}B2$ transition temperature were investigated for Fe-30at.%AI-5at.%Cr alloy with the ordered $D0_3$, structure when Ti, Hf and Zr were added respectively. The addition of Cr has no effect on the microstructure. However, as the amount of Ti addition increased, the grain size became smaller. Addition of Ti+Hf, Ti+Zr and Ti+Hf+Zr also showed the similar effect. When 20at.% of Ti was added, the second phase precipitates on the substrate. The addition of Cr, Hf and Zr alone has no effect on $D0_3{\leftrightarrow}B2$ transition temperature. However, as the amount of Ti addition increased by 5, 10, 15 and 20at.%, the transition temperatures showed 929, 930, 960 and $930^{\circ}C$ respectively.

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Growth, Structure, and Stability of Ag on Ordered ZrO2(111) Films

  • Han, Yong;Zhu, Junfa;Kim, Ki-jeong;Kim, Bongsoo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.204.2-204.2
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    • 2014
  • Among various metal oxides, ZrO2 is of particular interests and has received widespread attention thanks to its ideal mechanical and chemical stability. As a cheap metal, Ag nanoparticles are also widely used as catalysts in ethylene epoxidation and methanol oxidation. However, the nature of Ag-ZrO2 interfaces is still unknown. In this work, the growth, interfacial interaction and thermal stability of Ag nanoparticles on ZrO2(111) film surfaces were studied by low-energy electron diffraction (LEED), synchrotron radiation photoemission spectroscopy (SRPES), and X-ray photoelectron spectroscopy (XPS). The ZrO2(111) films were epitaxially grown on Pt(111). Three-dimensional (3D) growth model of Ag on the ZrO2(111) surface at 300 K was observed with a density of ${\sim}2.0{\times}1012particles/cm2$. The binding energy of Ag 3d shifts to low BE from very low to high Ag coverages by 0.5 eV. The Auger parameters shows the primary contribution to the Ag core level BE shift is final state effect, indicating a very weak interaction between Ag clusters and ZrO2(111) film. Thermal stability experiments demonstrate that Ag particles underwent serious sintering before they desorb from the zirconia film surface. In addition, large Ag particles have stronger ability of inhibiting sintering.

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Classification and Ultrastructure of Hemocytes in the Tunicate Halocynthia roretzi (Ascidiacea: Pyuridae) (멍게(Halocynthia roretzi) 혈구의 종류와 미세구조)

  • Shin, Yun Kyung;Jun, Je Cheon;Son, Maeng Hyun;Kim, Hyejin;Lee, Jung Sick
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.45 no.5
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    • pp.480-485
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    • 2012
  • The hemocytes of the tunicate Halocynthia roretzi are classified into six types based on their size, cellular form, and fine structure of the cytoplasmic granules: hyalinocytes, granulocytes, phagocytes, nephrocytes, morula cells, and multi-vacuole cells. Based on cell size, they are ordered multi-vacuole cells ($7.5{\mu}m$)>nephrocytes ($7.1{\mu}m$)>phagocytes ($6.8{\mu}m$)>granulocytes ($6.1{\mu}m$)>morula cells ($5.7{\mu}m$)>hyalinocytes ($5.4{\mu}m$). The proportion of hemocytes is ranked in the order multi-vacuole cells (54.8%)>nephrocytes (16.9%)>granulocytes (9.9%)>morula cells (8.8%)>phagocytes (6.1%)>hyalinocytes (3.5%).

The Fabrication and Evaluation of SMA Ribbons for Micro Actuator Application (마이크로 엑츄에이터용 형상기억 리본 제조 및 제특성 평가)

  • 이영수;장우양
    • 제어로봇시스템학회:학술대회논문집
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    • 2000.10a
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    • pp.554-554
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    • 2000
  • To improve mechanical properties of Cu-Al-Ni alloy by the grain refinement, Cu-Al-Ni SMA ribbons were fabricated by melt spinning apparatus. The variations of microstructure, mechanical properties and transformation characteristics with the condition of rapid solidification and annealing time-temperature were investigated in Cu-Al-Ni SMA ribbons. The ribbons fabricated by melt spinning obtained around 1.5nm in width and 50-60${\mu}{\textrm}{m}$ in thickness. With increasing wheel speed in order of 10m/s, 15m/s, 20m/s, 30m/s and 3m/s, the grain size was decreased in order of 10${\mu}{\textrm}{m}$, 6.25${\mu}{\textrm}{m}$, 5.5${\mu}{\textrm}{m}$, 3${\mu}{\textrm}{m}$ and 3${\mu}{\textrm}{m}$. $M_{s}$ and $A_{s}$ temperature were decreased with decreasing grain size. By X-ray diffraction test, ordered $\beta$$_1$ phase was observed in all the SMA ribbons and the volume friction of it was increased with increasing wheel speed. With increasing wheel speed, strain was increased from 4.2% to 5.8% and fracture mode has changed from mixture of intergranular and dimple fracture to mixture of fiber structure and dimple fracture. The grain size of ribbon heat-treated at $600^{\circ}C$ was increased with increasing time. In the heat-treated ribbons at 55$0^{\circ}C$, ${\gamma}$$_2$ phases were observed.d.d.

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Study on Tribological Behavior of Porous Anodic Aluminum Oxide with respect to Surface Coating (다공성 산화알루미늄의 표면코팅에 따른 트라이볼로지적 특성연구)

  • Kim, Young-Jin;Kim, Hyun-Joon
    • Tribology and Lubricants
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    • v.33 no.6
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    • pp.275-281
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    • 2017
  • In this work, we have fabricated anodic aluminum oxide (AAO) with ordered nanoscale porosity through an anodization process. We deposited gold and nano-organic thin films on the porous AAO surface to protect its structure and reduce friction. We investigated the tribological characteristics of the porous AAO with respect to the protective surface coatings using tribometers. While investigating the frictional characteristics of the samples by applying normal forces of the order of micro-Newton, we observed that AAO without a protective coating exhibits the highest friction coefficient. In the presence of protective surface coatings, the friction coefficient decreases significantly. We applied normal forces of the order of milli-Newton during the tribotests to investigate the wear characteristics of AAO, and observed that AAO without protective surface coatings experiences severe damage due to the brittle nature of the oxide layer. We observed the presence of several pieces of fractured particles in the wear track; these fractured particles lead to an increase in the friction. However, by using surface coatings such as gold thin films and nano-organic thin films, we confirmed that the thin films with nanoscale thickness protect the AAO surface without exhibiting significant wear tracks and maintain a stable friction coefficient for the duration of the tribotests.

Exponent Study of the p($2{\times}1$) Phase on an O/W(110) Surface (O/W(110) 표면의 p($2{\times}1$) 구조의 임계지수 연구)

  • 백두현;정석민;정진욱
    • Journal of the Korean Vacuum Society
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    • v.1 no.1
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    • pp.88-95
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    • 1992
  • Abstract-Using a high resolution low energy electron diffraction(HRLEED), we report an exponent study of 2d continuous phase transition from an ordered ~ ( 2 x 1 )ox ygen overlayer on a W(110) surface. Temperature dependence of a (% 0) superlattice diffraction spot, characteristic of the p(2X 1) structure, shows power-law like divergence of the susceptibility and the fluctuation correlation length at T,=708.765 K. By fitting the intensities as well as the line-shapes, we obtained exponents P=0.19* 0.05, y=1.48+ 0.34, v= 1.23i 0.27 and q=0.38+ 0.12. The non-universal character of the exponents are understood in terms of a 2d XY model with cubic anisotropy as suggested previously.

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Hydrogen-bonded Molecular Network of Anthraquinone on Au(111)

  • Kim, Ji-Yeon;Yoon, Jong-Keon;Park, Ji-Hun;Kim, Ho-Won;Kahng, Se-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.107-107
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    • 2011
  • Supramolecular structures of anthraquinone molecules on a metallic surface are studied using scanning tunneling microscope (STM) under ultrahigh-vacuum conditions. When we deposited anthraquinone molecules on Au(111) substrate, the molecules formed three different phases (Chevron type, tetragon type and disordered type) on the surface. Based on our STM measurements, we proposed models for the observed molecular structures. Chevrons are consisted of several molecular chains, which make well-ordered two-dimensional islands by some weak interrow interactions and we could observe tetragon structures which make array of (111) metallic surface. each molecular rows in the chevrons are stabilized by two parallel O-H hydrogen bonds and disordered structures are observed 1-dimensional phase with hydrogen bond. First-principles calculations based on density functional theory are performed to reproduce the proposed models. Distances and energy gains for each intermolecular bond are estimated. In this presentation, we explain possible origins of these molecular structures in terms of hydrogen bonds, Van der Waals interactions and molecule-substrate interactions.

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