• Title/Summary/Keyword: order of reaction

Search Result 4,352, Processing Time 0.036 seconds

Studies on the Bleaching of Rice-Straw chemical Pulp(I) (볏짚화학펄프의 표백에 관한 연구)

  • 강진하;박성종
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.32 no.3
    • /
    • pp.65-74
    • /
    • 2000
  • This study was carried out to acquire basic data necessary for the use of rice-straw chemical pulp. It investigated the proper bleaching conditions when rice-straw chemical pulps(alkaline sulfite-Na2S2O4 pulp) were bleached with the various kinds of bleaching agents. And physical properties of bleached pulps were tested. The results of this study were as follows; 1, The proper conditions of chlorine sequence were determined to be 4% concentration of chlorine 25$^{\circ}C$ of reaction temperature and 50 minutes of reaction time. 2. For calcium hypochlorite sequence the proper conditions of chemical concentration reac-tion temperature and reaction time were 3% 25$^{\circ}C$ and 20 minutes respectively. 3. For chlorine dioxide sequence the proper conditions were 1% concentration of chlorine dioxide 70$^{\circ}C$ of reaction temperature and 2hr. of reaction time. 4. The proper conditions of hydrogen peroxide sequence were 1.5% concentration of hydro-gen peroxide 70$^{\circ}C$ of reaction temperature and 1hr. of reaction time respectively. 5. When the rice-straw chemical pulp were bleached with four kinds of bleaching agents methioned above in the proper conditions respectively brightnesses were the order of chlorine dioxide calcium hypochlorite, chlorine, hydrogen peroxide. And strengthes of pulps bleached with chlorine dioxide and hydrogen peroxide were higher than those of pulps bleached with other bleaching agents.

  • PDF

Disinfection of Water by Ultrasonic Irradiation (초음파 검사에 의한 수중의 살균처리)

  • 손종렬;유병성
    • Journal of environmental and Sanitary engineering
    • /
    • v.14 no.1
    • /
    • pp.54-61
    • /
    • 1999
  • The industrial techniques of ultrasound have been used in the various fields, such as cleaning, medical surgery, emulsification, cell disruption etc. Especially the application of cell disruption was interested in the field of disinfection process in water by ultrasonic irradiation. It has been recognized that the ultrasounds are irradiated in aqueous solution, cavitation bubbles are generated and shock waves of high temperature and pressure are emitted as the bubbles are developed and finally broken, which function as a energy source to promote reaction efficiencies of various kinds of chemical reactions such as disinfection reaction in water. Therefore, this study was performed to apply the ultrasound for the disinfection method of infected drinking raw water and to discuss the limiting factors such as pH, sample volume and reaction temperature influenced on the removal efficiency of E. coli from experimental analysis of the results obtained in bench-scale plant. For the experiments to measure the influence of reaction parameters in the ultrasonic disinfection process, escalated reactivity of aqueous solutions was excellent when pH in aqueous solution was low, and sample volume was small. On the contrary, the reactivity of disinfection became elevated when reaction temperature was high. It was found that the rate constant of disinfection reaction was applied by Chick's law, reaction kinetics of Chick's law was irreversible and pseudo-first order at all the tested conditions.As a conclusion it appeared that the technology using ultrasonic irradiation can be applied to the treatment of disinfection in infected water which are difficult to be treated by conventional methods.

  • PDF

Liquid Phase Oxidation of Xylenes: Effects of Water Concentration and Alkali Metals

  • Jhung, Sung-Hwa;Lee, Ki-Hwa;Park, Youn-Seok
    • Bulletin of the Korean Chemical Society
    • /
    • v.23 no.1
    • /
    • pp.59-64
    • /
    • 2002
  • A facile and precise batch oxidation reaction system allows continuous monitoring of the oxidation rate and cumulated oxygen conversion of xylenes, and the side reactions to carbon monoxide and carbon dioxide may also be studied. The oxidation reaction can be analyzed precisely with the rate and amount of oxygen consumed. The reaction reveals that 4-carboxybenzaldehyde is an unstable intermediate of p-xylene oxidation as the reaction proceeds instantaneously from p-toluic acid to TPA (terephthalic acid). The alkali metals accelerate oxidation, even though they retard the reaction initially. The oxidation rate increases with decreasing water concentration. However, in the later part of reaction, the reactivity decreases a bit if the water concentration is very low. This retarding effect of water can be overcome partly by the addition of potassium. The oxidation of o-xylene, compared with the oxidation of p-xylene and m-xylene, proceeds quite fast initially, however, the oxidation rate of xylene isomers in the later stage of reaction is in the order of p-xylene > mxylene > o-xylene.

A Study on the Removal Reaction Characteristics of Sulfur Dioxide (대기오염 물질인 $SO_2$ 제거반응 특성 연구)

  • 강순국;정명규
    • Journal of Environmental Science International
    • /
    • v.4 no.1
    • /
    • pp.41-52
    • /
    • 1995
  • The effects of reaction temperature, SO2 and CO2 concentration in an air gas stream, particle sizes of limestone on the reactivity and capacity of SO2 removal have been determined in a thermogravimetric analyser(TGA). The apparent reaction order of sulfation reaction of pre-calcined lime(CaO) with respect to SO2 is found to be close to unity. The apparent activation energies are found to be 17,000 kcal/kmol for sulfation of pre-calcined lime and 19,500 kcal/kmol for direct sulfation of limestone(CaCO3). The initial sulfation reaction rate of pre-calcined lime increases with increasing temperature, whereas the sulfur capture capacity exhibits a maximum value at 90$0^{\circ}C$. In direct sulfation of limestone, sulfation reactivity and sulfur capature capacity of sorbent increase with increasing temperature and decreasing CO2 concentration in a gas bulk stream. The main pare of pre-calcined lime is shifted to the larger pore sizes and pore volume decreases with increasing sulfation time and temperature. The surface area of lime decreases with increasing calcination temperature under an air atmosphere, whereas is yearly constant under a CO2(5, 10%) atmosphere in a gas stream.

  • PDF

Evaluation of Hand Grip Strength and EMG Signal on Visual Reaction (시각 반응에 대한 악력과 EMG 신호의 평가)

  • Shin, Sung-Wook;Jeong, Sung-Hoon;Chung, Sung-Taek
    • Korean Journal of Applied Biomechanics
    • /
    • v.24 no.2
    • /
    • pp.161-166
    • /
    • 2014
  • Hand grip strength has been utilized as an indicator to evaluate the motor ability of hands, responsible for performing multiple body functions. It is however difficult to evaluate other factors (other than hand muscular strength) utilizing the hand grip strength only. The purpose of this study was analyzed the motor ability of hands using EMG and the hand grip strength, simultaneously in order to evaluate concentration, muscular strength reaction time, instantaneous muscular strength change, and agility in response to visual reaction. In results, the average time (and their standard deviations) of muscular strength reaction EMG signal and hand grip strength was found to be $209.6{\pm}56.2$ ms and $354.3{\pm}54.6$ ms, respectively. In addition, the onset time which represents acceleration time to reach 90% of maximum hand grip strength, was $382.9{\pm}129.9$ ms. Results in visual reaction (on) indicate the differences in muscular strength agility and concentration of participants in regards to visual reaction.

Computational Study of Intermetallic Reaction Propagation in Nanoscale Boron/Titanium Metallic Multilayers (보론/티타늄 나노박막다층 내 이종금속간 화학반응 전파특성 해석연구)

  • Kim, Kyoungjin;Park, Joong-Youn
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.21 no.3
    • /
    • pp.10-17
    • /
    • 2017
  • The analytical modeling has been established on the self-propagation of intermetallic reaction in the spanwise direction of highly reactive boron and titanium nanoscale multilayers. Assuming that the reaction obeys Arrhenius kinetics, two-dimensional computations are carried out for heat and atomic species diffusion with exothermic reaction model in order to simulate the self-propagation of intermetallic reaction. The effects of bimetallic layer thickness and thickness ratio on the reaction propagation speed are tested and discussed in addition to the assessment of pre-mixing zone effects.

Effect of $Ca^{2+}$ on Phvsiological Activites of the Acrosome Reaction on Spermatozoa ($Ca^{2+}$이 정자 첨체반응의 생리적 활성에 미치는 영향)

  • 장재호;오영근
    • The Korean Journal of Zoology
    • /
    • v.39 no.2
    • /
    • pp.182-189
    • /
    • 1996
  • It has been known that spermatozoa should obtain their fertilizing ability through capacitation and acrosome reaction, and that in these processes of fertilization, Ca2+ platys an important role for their conjugation. Therefore the present study has been designed in order to clarify the effect of fluctuation of the media Ca2+ level and the intracellular concentration of the spermatozoa on the acrosomes. During the incubation of spermatozoa, a considerable fluctuation in the media Ca2+ level has been observed after the BSA administration and the media concentration of Ca2+. It is deduced that these fluctuation rates may have an effect on the acrosome reaction. The fluctuation of K+ flux has been observed in accordance with the incubation period over time, and it's concentration seems to be closely related with the acrosomal reaction. The respiratory exchange rate (RERI of the spermatozoa is kept more regular in the BSA and Cacl2 administration groups than the non-administration group. Based on the experimental findings, it is possible to deduce a hypothesis from these findings that physiological activities of the acrosome reaction are not functionally related to the media Ca2+ level and the intracellular influx of Ca2+ concentration, although Ca2+ platys an important role as a stimulating factor in the acrosome reaction.

  • PDF

The Effects of Alloying Elements on the Formation of Interfacial Reaction Layer between Molten Aluminium Alloys and STD61 Tool Steel (알루미늄 합금 용탕/STD61 공구강의 계면 반응층 형성에 미치는 합금원소의 영향)

  • Park, Heung-Il;Park, Ho-Il
    • Journal of Korea Foundry Society
    • /
    • v.25 no.4
    • /
    • pp.161-167
    • /
    • 2005
  • The experiment of hot dip interaction tests was carried out in order to study the formation behavior of interfacial reaction layer between as-received STD61 hot work tool steel and a commercial pure aluminum melt, Al-xwt.%Fe(x=0.2, 0.5, 0.8 and 1.1) alloys melt and Al-xwt.%Si(x=1.0, 4.0, 7.0 and 10.0) alloys melt, respectively. The results show that the reaction layer, over 300 ${\mu}m$ in thickness, is easily formed by the dissolution of silicon from as-received tool steel. When the iron content in the aluminum alloy is higher than 1.1 wt.%, the thickness of reaction layer decreases below 180 ${\mu}m$ by preventing iron dissolution from the tool steel. The silicon dissolved from tool steel acts as a strong promoter on the formation of reaction layer, but the alloyed silicon in molten aluminum alloys acts as an inhibitor on the formation of reaction layer.

The Estimation of the Depth of Anesthetic Using Higher-Order Spectrum Analysis of EEG Signals

  • Park, Jong-Duk;Ye, Soo-Young;Jeon, Gye-Rok;Huh, Young
    • Journal of Biomedical Engineering Research
    • /
    • v.28 no.2
    • /
    • pp.287-293
    • /
    • 2007
  • The researchers have studied for a long time about the depth of anesthesia but they don't make criteria for the depth of anesthesia. Anesthetists can't make a prediction about patient's reaction. Therefore, patients have potential risk such as poisonous side effect, late-awake, early-awake and strain reaction. In this study, the distributed characteristics on the bispectrum and bicoherence, the type of nonlinear signal processing, as a result of the coupling of EEG were presented according to depth of anesthesia. These results were consistent with a trend of delta ratio that the index of evaluation for the depth of anesthesia. The higher-order spectrum (HOS), the bispectrum and bicoherence, gives the useful information about depth of anaesthesia than other indexes.

A Study on the Stability of Carbamide Peroxide Solution (Carbamide Peroxide 용액(溶液)의 안정성(安定性))

  • Rhee, Gye-Ju;Yu, Byung-Sul
    • YAKHAK HOEJI
    • /
    • v.28 no.6
    • /
    • pp.299-303
    • /
    • 1984
  • In order to eluciate the effect of humidity and organic solvent on the decomposition of carbamide peroxide, the kinetic study was carried out. The carbamide peroxide was prepared from urea and 30%-hydrogen peroxide. The accelerated stability analysis for carbamide peroxide crystal in various relative humidity, and for 10%-carbamide peroxide solution of organic solvents were investigated. Both humidity and temperature were important factors influencing the decomposition rate of carbamide peroxide crystal. The higher the humidity and temperature, the greater was the reaction rate. The breakdown rate of crystal was observed as an apparent zero-order, and was faster than the rate of decomposition in dilute propylene glycol, glycerine or sorbitol solutioos which were measured as an apparent first-order reaction. The more dilute to 10% the organic solvents of 10%-carbamide peroxide, the slower was breakdown rate. It is, therefore, useful in the aspects of stability and economics to substitute solvent of carbamide peroxide topical solution (USP XXI) with 10%-propylene glycol or glycerine instead of anhydrous glycerine.

  • PDF