• Title/Summary/Keyword: optimum mixture ratio

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Deduction of Optimum Factors for Hydrogen Production from Organic Resources using a Continuous Reaction Process (연속반응공정을 이용한 유기성자원으로부터 수소생산을 위한 최적인자도출에 관한 연구)

  • Kim, Choong Gon;Shin, Hyun Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.2
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    • pp.22-27
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    • 2011
  • This study was performed to find out the optimum condition for hydrogen production by changing mixture ratio from 3:7(food waste water : swine wastewater) without pre-treatment of food wastewater and swine wastewater using a continuous reaction process. It was confirmed that hydrogen generation according to pH is the highest in a condition of pH 5.5, and that the optimum pH for hydrogen production in case of mixing food wastewater with swine wastewater is 5.5 through this. Hydrogen generation according to HRT showed high hydrogen generation rate in case of 4 days rather than 3 days, and this involves largely in vitality of hydrogen producing bacteria according to variation of the HRT value, so it is judged that HRT also acts as an important factor to hydrogen producing bacteria. The organic removal efficiency recorded a removal efficiency of maximum TS 52%, VS 71%, TSS 83% and VSS 89% at the 6th day of operation, and it was confirmed that organic removal efficiency is possible even through an hydrogen production process.

The Effect of Fly Ash Composition and Reaction Conditions on Hydrothermal Synthesis of Zeolitic Materials (Fly ash 조성(組成)과 반응조건(反應條件)이 zeolite성(性) 물질(物質)의 열수합성(熱水合成)에 미치는 영향(影響))

  • Choi, Choong-Lyeal;Lee, Dong-Hoon;Park, Man;Choi, Jyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.1
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    • pp.39-46
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    • 1999
  • This study was performed to examine the effect of initial composition ratio and various reaction conditions on CEC and crystallinity of the product in hydrothermal synthesis of zeolitic materials from fly ash. Na-P1 zeolite was formed from the mixture with $SiO_2/Al_2O_3$ ratio above 2.55, however from the mixture with $SiO_2/Al_2O_3$ ratio below 2.25 hydroxy sodalite was formed. The CEC of reaction product(Na-P1 zeolite) treated with 3N-NaOH, $Na_2O/Al_2O_3$ ratio 2.55 and $SiO_2/Al_2O_3$ ratio 2.0 for 12 hours at $103^{\circ}C$ was about $285cmol^+kg^{-1}$, which was higher than those of the products of other reaction condition. The crystallinity of Na-P1 zeolite as high as 45.1% was attained at the optimum reaction condition of 2N-NaOH, $SiO_2/Al_2O_3$ ratio 2.55, $Na_2O/Al_2O_3$ ratio 1.5 for 12 hours at $103^{\circ}C$. The XRD peak of the reaction product could be measured at 7.16, 5.04, 4.12, 3.18, $2.69{\AA}$ and tetragonal pillar shape observed by SEM image be characteristic for Na-P1 zeolite. Judging from the result, it should be considered the optimum synthesis condition for Na-P1 zeolite from fly ash was 2~3N NaOH, $SiO_2/Al_2O_3$ ratio 2.55 and $Na_2O/Al_2O_3$ ratio 1.5~2.0 for 12 hours at $80{\sim}103^{\circ}C$.

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Characteristics on Shear Strength and Clogging Phenomenon of Bottom Ash and Rammed Aggregate Mixture Compaction Pile (쇄석과 저회의 혼합다짐말뚝의 전단강도와 Clogging 현상 규명)

  • Lee, Dongyeup;Kang, Hyongnam;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.3
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    • pp.33-41
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    • 2010
  • The rammed aggregate compaction pile method is widely used as soft ground improvement method because of the installed piles improve not only overall composite capacity but also discharge capacity. But the discharge capacity is declined when the clogging is generated due to the clay penetration into voids of rammed aggregate compaction pile with the time elapsed. The purpose of this study is to reduce the clogging problem occurred in rammed aggregate compaction pile constructed in the soft ground and to minimize voids of rammed aggregate compaction pile. The proper mixing ratio was determined which is based on the results of the large scale direct shear tests conducted to get strength and permeability as optimum mixing ratio of crushed stone and bottom ash. The test results indicated that the highest internal friction angle was obtained at 80:20 mixing ratio of crushed stone and bottom ash. The internal friction angle was declined when the mixing ratio of the bottom ash increased over 20%. The results of the clogging tests, presented that the mixture of 80:20 crushed stone and bottom ash is highest effective of clogging than ratio of pure crushed stone.

Separation of Hydrocarbon Mixture Using (O/W)/O Emulsion Liquid Membrane ((O/W)/O 에멀젼형 액막을 이용한 탄화수소 혼합물의 분리)

  • Jeong, M.C.;Park, H.Y.;Oh, J.T.;Kim, J.K.;Shin, M.H.;Kim, W.S.
    • Applied Chemistry for Engineering
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    • v.8 no.5
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    • pp.763-770
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    • 1997
  • The separation of benzene-cyclohexane mixture using (O/W)/O emulsion liquid membrane was studied. The operating parameters which can affect the selectivity, benzene yield, and emulsion size distribution were examined and determined by the batch type operation. The unsteady state and steady state extraction behavior in continuous pulse stirred reactor(CPSR) were verified. The optimum conditions for benzene selectivity and yield in batch operation were as follows; emulsion mixing intensity 4000 rpm, Tween 80 concentration 0.4%, volume ratio of membrane phase to internal phase 0.75, volume ratio of dispersed phase to continuous phase 0.5, and permeation time 10 minutes, As impeller speed increased and the microdrop holdup decreased, the Sauter mean diameter decreased. Turbulence damping parameter of modified Calabrease correlation considering microdrop holdup was 2.28. The optimum conditions of continuous operation were as follows; agitation speed 300 rpm, pulse frequence 2 times/sec, flow rate of continuous phase 30ml/min, and flow rate of emulsion phase 12.0ml/min.

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Zymological characteristics of Cheju folk wine made of foxtail millet (제주토속 좁쌀약주의 약조특성)

  • Koh, Jeong-Sam;Yang, Young-Taek;Ko, Young-Hwan;Kang, Yeung-Joo
    • Applied Biological Chemistry
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    • v.36 no.4
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    • pp.277-283
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    • 1993
  • In order to brew foxtail millet wine, a folk wine of Cheju, properties of raw materials, optimum brewing conditions were inveatigated. Carbohydrate and crude fat content of glutinuous foxtail millet are 71.27% and 3.47%, respectively. Since the ratio of water to steamed millet and ethanol concentration of wine showed negative correlation, less than 250% water had to added to steamed millet to maintain ethanol concentration in wine above 13%, Sugar consumption and ethanol production increased rapidly for the first 2 days, and main fermentation was done in 4 days. Ethanol concentrations were $13.0{\sim}13.4%$ when foxtail millet was used, and they were $14.0{\sim}14.3%$ for the mixture substrates of 90% millet and 10% rice or barley. Organic acids in millet wine were lactic acid, malic acid and succinic acid. The residual carbohydrates after fermentation were mainly xylose and oligosaccharides. A trace of methanol was detected in millet wine. The content of fusel oil was low, while the concnetration of organic acids was high. Optimum conditions for millet wine-making were as follows. Glutinuous foxtail millet with 10% rice as fermentation source need to be soaked in water and steamed for enough time. Water was added to steamed millet with the ratio of 2 : 1. The resulting mixture was stmnultaneously saccharified and fermented by Aspergillus orzae and Saccharomyces cerevisiae IAM 4274 at $20^{\circ}C$ for a week. Millet wine was prepared after filtering fermented broth while pressing for a week.

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Recovery of Calcium Phosphate from Sewage Sludge Ash (하수슬러지 소각재로부터 Ca-P 형태의 인 회수)

  • Jung, Jinmo;Yoon, Seok-Pyo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.1
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    • pp.29-37
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    • 2018
  • In this study, optimum extraction conditions for phosphorus recovery from sewage sludge ash(SSA) were investigated. For this purpose, an experiment was conducted to determine optimal recovery conditions for Ca-P type phosphorus by using calcium component in the recycled aggregate residue. The phosphorus content of sewage sludge ash was confirmed to be 5.0 %. When $H_2SO_4$ was used as an extract, concentration of 1 N $H_2SO_4$, L/S ratio of 10, and extraction time of 30 min were found to be the optimal extraction conditions. Phosphorus was extracted by using optimal extraction conditions, and then the heavy metals eluted with phosphorus were removed using 1~20 g of cation exchange resin. In 20 g of cation exchange resin, Fe 71.3%, Cu 82.4%, Zn 79.9%, and Cr 15% were removed. After that, the mixing ratio of the calcium extract obtained from the recycled aggregate residue (RAR) was changed to 1:1, 1:5, 1:10. The pH of the SSA to RAR mixture was adjusted to 2, 4, 8 and 12 by the addition of 5 N NaOH to the mixture of 1:5, and the phosphorus was recovered as Ca-P type precipitate. The optimum pH was 8. When recycled aggregate residues were used, the weight of calcium phosphate increased, but the amount of wastewater generated also increased. Therefore, it was concluded that the use of recycled aggregate residue was not economically feasible.

Development of Herbal Chicken Porridge and the Establishment of Optimizing the Mixing Ratio (한방 닭죽 개발 및 최적 배합비율 확립)

  • Kim, Kyung-Yeon;Baik, Moo-Yeol;Park, Cheon-Seok;Choi, Sung-Won;Kim, Chang-Nam;Kim, Byung-Yong
    • The Korean Journal of Food And Nutrition
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    • v.26 no.1
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    • pp.22-28
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    • 2013
  • The objectives of this study were to develop porridge with medicinal herbs and chicken breast meat and to find out the optimum mixing ratio. Several herb extracts such as Acanthopanacis senticosus, Rehmannia glutinosa, Disocorea japonica, and Poria cocos Wolf were used in the ratio of 2, 1, 1, and 1, respectively. The optimum processing condition for herbal chicken porridge was determined by a design expert program. Seventeen experimental points were selected, and herb extracts (82~101 g), chicken breast meat (30~50 g), and glutinous rice (40~60 g) were chosen as the independent variables. The measured responses were preference of taste, DPPH radical scavenging, SOD-like activity, and cost. The optimum formulation of herbal chicken porridge using the numerical analysis was set at herbal extracts (101 g), chicken breast meat (38.66 g), and glutinous rice (41.34 g) with a 0.714 desirability value. DPPH radical scavenging effect, preference of taste and the cost showed a linear model, whereas SOD-like activity showed a quadratic model indicating a higher interaction among the mixture. As a result of proximate composition of optimized herbal chicken porridge, the contents of moisture, carbohydrate, crude protein, crude lipid, and ash contents were 76.4, 9.0, 1.4, 0.5, and 1.6%, the calories of the porridge was 46.1 kcal/100 g.

Hydrolysis of Castor Oil with Lipases and Organic Solvents (Lipase와 유기용매를 이용한 Castor Oil의 가수분해)

  • Jeon, Gyu-Jong;Hur, Byung-Ki;Yang, Ji-Won
    • KSBB Journal
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    • v.14 no.6
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    • pp.696-701
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    • 1999
  • The enzymatic hydrolysis of Castor oil for the mass production of ricinoleic acid was studied to find out the optimum conditions such as solvents and the weight ratio of substrate to enzyme. Three different lipases were tested for the hydrolysis of castor oil: lipase from Porcine Pancrease(lipsase PP), lipase from Candida cylindracea(lipase CC), lipase from Candida Rugosa(lipase CR). The poor mass transfer in water caused a low degree of hydrolysis of castor oil. To overcome this problem, organic solvents were used. Among organic solvents tested, hydrophobic solvents gave better results of hydrolysis than hydrophilic solvents. Organic solvents also lowered or changed the effect of pH. Isopropyl ether made complete hydrolysis of castor oil. The ratio of water to isopropyl ether and the ratio of weight ratio of lipase to castor oil were important for the hydrolysis of castor oil. At 30$^{\circ}C$ castor oil was completely hydrolyzed by 4 wt% of lipase in the mixture of isopropyl ether and water(1:1 in volume).

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Effect of Flux on Recovery of Aluminum During Molten Metal Treatment of Aluminum Can Scrap (알루미늄 캔 스크랩의 용탕처리 시 알루미늄 합금 회수에 미치는 플럭스의 영향)

  • Han, Chulwoong;Ahn, Byung-Doo;Kim, Dae-Guen;Lee, Man Seung;Kim, Yong Hwan
    • Resources Recycling
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    • v.29 no.1
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    • pp.70-80
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    • 2020
  • This study investigates the effect of flux type and mixing ratio on efficiency in aluminum can scrap recycling using induction furnace. The removal of surface coating layer of aluminum can scrap was possible through heat treatment at about 500 ℃ for about 30 min. The temperature for the melting process was set to be slightly above the melting temperature of the aluminium can scrap. The molten metal treatment was performed with different types of flux and mixing ratio. As a result, The optimum efficiency of Al recovery ratio was revealed when the process was performed with at least 3 wt.% of the flux (Salt and MgCl2 mixture of ratio 70:30) at 750 ℃. The mechanical property of the recovered Al alloy showed that the tensile strength is about 249 MPa and elongation is about 14 %. This result was found to be similar to the mechanical property of the virgin Al 5083 alloy.

Chemical composition changes in fermented Doenjang depend on Doenjang koji and its mixture (된장 koji 및 그 혼합에 따른 된장 숙성 과정중의 화학성분 변화)

  • Joo, Hyun-Kyu;Kim, Dong-Hyun;Oh, Kyun-Teak
    • Applied Biological Chemistry
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    • v.35 no.5
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    • pp.351-360
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    • 1992
  • In order to improve the qualities of Doenjang were investigated on the enzyme activity in the koji and changes in chemical composition, flavors and sensory envaluation of Doenjang which were prepared with Rh. delemar koji, Asp. oryzae koji and traditional Meju with mixed koji and soybean as the ratio of optimum mixture. Asp. oryzae koji was indicated highest activities ${\alpha}$ and ${\beta}-amylase$ as 312 mg/ml, 235 mg/ml while Rh. delemar the lowest activities as 16 mg/ml, 38 mg/ml in aging for 40 days amino type ntrogen was the highest in the Asp. oryzae and Rh. delmear mixture koji(D group), Asp. oryzae(A group), and Asp. oryzae koji and Rh. delemar koji(C group) as 460 mg%, 440 mg% and 426 mg% in aging for 40 days. The main flavor components of Doenjang were detected as fellows phenol-2-kmethoxy, 4H-pyran-4-one-3-hydroxy-2-methyl, benzenthanol, 1-octan-3-ol, tetra-methyl pryrazine, 1,3,6 cyclooctatrien. Asp. oryzae(A) and Asp. oryzae koji with Rh. delemar koji mixture(C), group were the most excellent in taste, flavor color for fermented Doenjang at 40 days.

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