• Korean Journal of Ecology and Environment
• /
• v.40 no.2
• /
• pp.193-200
• /
• 2007

The objective of this study was to estimate uncertainty of online TOC analyzer in water quality monitoring system. A procedure for the estimation of measurement uncertainty of total organic compounds (TOC) based on the ISO approach is presented. It is based on a mathematical model that involves 4 input parameters (standardization, sensitivity, solute effect and representativeness). In this study, a major problem in estimating the uncertainty of online TOC analyzer was the solute effect. It was strongly depends on organic materials. So homogeneity of the sample is the most important consideration. Modified concentration and combined standard uncertainty was $4.71{\pm}0.36$ mg $L^{-1}$ by model modified in this study.