• 제목/요약/키워드: one-stage reaction

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수산 지역의 규회석과 그 용해 거동 (Wollastonite from and Its Dissolution Behaviors)

  • 김수진;현성필;이성근
    • 한국광물학회지
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    • 제9권1호
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    • pp.1-6
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    • 1996
  • Woolastonite from Susan occurs as intercalations in limestone beds of Lower Paleozoic Joseon Supergroup. It is a thermal metamorphic product of impure limestone. Electron microprobe analysis shows that it is considerably pure wollastonite. It has triclinic cell with a=7.932$\AA$, b=7.328$\AA$, c=7.069$\AA$, $\alpha$=89.995$^{\circ}$, $\beta$=$95.255^{\circ}$, and $ \Upsilon=103.367^{\circ}$.Dissolution behaviors of wollastonite have been studied conducting three different dissolution experiments; two different reactions with HC1 (one batch and one re-initialization experiment) and one traction with distilled water. In the batch type powder wollastonite-HCl reaction, pH of solution rapidly increases in the early stage and then its rate of increase slows down to reach plateau resulting in parabolic relationship with time. It is represented by the early rapid rise and fall in pH giving a sharp pH-edge and succeeding slow rise in the re-initialization experiment. The early rapid rise in pH is due to the rapid sorption of H- in solution to oxygens on the reactive surface of wollastonite and the fall in pH means that all reactive surface sites are occupied by H- ions and no more H- adsorption occurs. The slow rise in pH following the pH- edge is due to the dissolution of wollastonite as evidenced by the correlation of pH variation and cation concentration. Dissolution of powder wollastonite in HCl shows linear trend with time. Si is dissolved predominantly over Ca at a constant rate. Ca is dissolved predominantly in the very early stage. Dissolution rate of coarse-grained wollastonite fragments in distilled water is parabolic with times howing a rapid reaction in the early stage and a slow reaction in the advanced stage. The Ca/Si ratio in solution is high in the case of coarse-grained wollastonite fragment as compared with powder wollastonite. The coarse-grained wollastonite fragment-water (acid) reaction resulted in the solution with an elevated constant pH value (alkaline) giving an important significance on the environmental view point.

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Role of KOH in the One-Stage KOH Activation of Cellulosic Biomass

  • Oh, Gyu-Hwan;Yun, Chang-Hun;Park, Chong-Rae
    • Carbon letters
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    • 제4권4호
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    • pp.180-184
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    • 2003
  • The role of KOH in the one-stage KOH-activation of rice straws was studied using FTIR, XPS, TGA, and DTG techniques. It was found that at the impregnation, KOH extracts to some extent the lignin component from rice straw and reacts with hydroxyl groups. On heat-treatment, the impregnated KOH facilitates intermolecular condensation reaction on one hand but retards the thermal degradation of cellulose molecules on the other hand. The oxygen-containing surface functional groups newly created by oxidation of KOH may facilitate the bulk, not controlled, consumption of carbon atoms so that the effective porosities may not be able to be developed by the one-stage activation process.

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실험적 치아 이동 시 나타나는 백서 치주조직의 변화에 대한 조직학적 및 조직화학적 연구 (A HISTOLOGICAL AND HISTOCHEMICAL STUDY ON THE PERIODONTAL TISSUE REACTION DURING EXPERIMENTAL TOOTH MOVEMENT IN THE RAT)

  • 임진환
    • 대한치과교정학회지
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    • 제6권1호
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    • pp.33-38
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    • 1976
  • For the purpose of evaluating the response of the periodontal tissue in relation to the experimental tooth movement, orthodontic force was applied to 15 female rats. The animals were investigated histopathologically and histochemically by several staining methods. Findings were as follows: 1. The application of 60gm on the rat's molar caused mesial tipping movement and undermining resorption. 2. One day after the insertion of the appliance, the osteoblast was increased in activity but not in number. 3. The osteoclastic activity was decreased as soon as removing the appliance. 4. With the P.A.S. staining, osteoclasts Stained mildly in the initial stage and stained more intensely in the last stage. Osteoclasts revealed negative reaction in the initial stage and stained mildly in the last stage. 5. Slides stained with toluidine blue revealed no conclusive variations between osteoblasts and osteoclasts.

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발사체 상단 자세제어용 추력기시스템 명령생성방식 연구 (A Study on Command Generation Methods of Reaction Control System for Upper Stage Attitude Control of Launch Vehicles)

  • 선병찬;박용규;오충석;최경준;노웅래
    • 항공우주기술
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    • 제13권1호
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    • pp.44-54
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    • 2014
  • 본 논문에서는 3구 추력기 2모듈 형태의 추력기시스템 기준으로 발사체 상단 자세제어용 추력기시스템 명령생성방식 2가지를 제시한다. 하나는 혼합오차함수를 이용하는 방식이고, 다른 하나는 명령혼합함수를 이용하는 방식이다. 시뮬레이션을 통해 두 방식을 비교 분석한 결과, 제어축 간의 상호 간섭, 각축 제어기의 독립적인 설계와 분석 용이성, 비행성능 예측 가능성 등의 관점에서 명령혼합 알고리듬이 상대적으로 유리함을 보인다.

알킬 알킬포스피네이트와 알킬 페닐포스피네이트들의 염기성 가수분해 (Alkaline Hydrolysis of Alkyl Alkylphosphinate and Alkyl Phenylphosphinates)

  • 양일우;정영진
    • 한국응용과학기술학회지
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    • 제19권3호
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    • pp.161-166
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    • 2002
  • The alkaline hydrolysis of alkyl alkylphosphinate and alkyl phenylphosphinates have been studied at room temperature. The hydrolysis proceeded as an one-stage reaction($S_{N}$ 2) and involved a nucleophilic attack of the hydroxyl ion on the phosphorus atom. And the length of the alkoxy group in the phosphinate esters affected on hydrolysis. Therefore, the alkaline hydrolysis may be used as a method to decompose the chemical agents.

해외 상용발사체의 RCS 개발 동향 (Current technology status for the Reaction Control System of Launch Vehicle)

  • 김인태;이재원;서혁
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2008년도 제31회 추계학술대회논문집
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    • pp.72-77
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    • 2008
  • 발사체 RCS는 발사체의 롤, 피치, 요방향의 자세제어뿐만 아니라 상단의 자세제어를 담당하는 핵심부품으로서 발사체의 임무요구조건에 따라 하이드라진을 이용한 단일추진제, UDMH/NTO를 이용한 이원추진제, 그리고 소형발사체의 경우 GN2를 이용한 냉가스시스템 등으로 분류된다. 본 연구에서는 해외 상용발사체를 중심으로 발사체에 대한 간략한 소개 및 RCS에 적용되는 최신 기술, 개발현황 등에 대해 기술하였다.

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Hybrid Plasma Processing에 의한 Si3N4-SiC계 미립자의 합성과정 제어 (Process Control for the Synthesis of Ultrafine Si3N4-SiC Powders by the Hybrid Plasma Processing)

  • 이형직
    • 한국세라믹학회지
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    • 제29권9호
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    • pp.681-688
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    • 1992
  • Ultrafine Si3N4 and Si3N4+SiC mixed powders were synthesized through thermal plasma chemical vapor deposition(CVD) using a hybrid plasma, which was characterized by the supersposition of a radio-frequency plasma and arc jet. The reactant SiCl4 was injected into an arc jet and completely decomposed in a hybrid plasma, and the second reactant CH4 and/or NH3 mixed with H2 were injected into the tail flame through double stage ring slits. In the case of ultrafine Si3N4 powder synthesis, reaction efficiency increased significantly by double stage injection compared to single stage one, although crystallizing behaviors depended upon injection speed of reactive quenching gas (NH3+N2) and injection method. For the preparation of Si2N4+SiC mixed powders, N/C composition ratio could be controlled by regulating the injection speed of NH3 and/or CH4 reactant and H2 quenching gas mixtures as well as by adjusting the reaction space.

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촉매에 의해 안정화된 희박 예혼합기의 연소 (THE CATALYTICALLY SUPPORTED COMBUSTOR FOR LEAN MIXTURE)

  • 서용석;강성규;신현동
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
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    • pp.59-67
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    • 1998
  • The aim of this study is to investigate advantages that the catalytically supported combustor can have. For this purpose, the catalytic combustor was prepared which consisted of the catalyst bed and the thermal combustor at the downstream of the catalyst bed. The catalyst bed consisted of two-stage. Pd catalyst was installed in the first stage of the catalyst bed, and Pt catalyst was placed in the second stage. Results showed that the catalytically supported combustion had some advantages. One was that auto-ignition occurred in the thermal combustor. This can give merit that an igniter is not necessary to start flame ignition. Other was that the catalytically supported combustion was stable for lean mixture. When combustion of lean mixture was not supported by surface reaction it became unstable so that big combustion noise was created. Therefore, it is desirable to support flame by catalytic surface reaction to obtain the stable combustion of lean mixture.

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대곡(大谷) W-Sn-Cu 광상(鑛床)의 열수변질작용(熱水變質作用) (Wall-rock Alteration Relating to Tungsten-Tin-Copper Mineralization at the Ohtani Mine, Japan)

  • 김문영
    • 자원환경지질
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    • 제21권3호
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    • pp.209-221
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    • 1988
  • The ore deposit of the Ohtani mine is one of repesentatives of plutonic tungsten-tin veins related genetically to acidic magmatism of Late Cretaceous in the Inner zone of Southwest Japan. Based on macrostructures of vein filling on the order of ore body, three major mineralization stages, called stage I, stage II, and stage ill from earliest to latest, are distinguished by major tectonic breaks. The alteration zories are characterized by specific mineral associations in pseudomorphs after biotite. The alteration zones can be divided into two parts, i. e. a chlorite zone and a muscovite zone, each repesenting mineralogical and chemical changes produced by the hydrothermal alteration. The chloritic alteration took place at the beginning of mineralization, and muscovite alteration in additions to chloritic alteration took place at stage II and ill. The alteration zones are considered to be formed by either of two alteration mechanism. 1) The zones are formed by reaction of the rock with successive flows of solution of different composition and different stage. 2) The zones are formed contemporaneously as the solution move outward. Reaction between the solution and the wall-rock results in a continuous change in solution chemistry. The migration of the successive replacement of the fresh zone$\rightarrow$the chlorite zone$\rightarrow$the muscovite zone may have transgressed slowly veinward, leaving metasomatic borders between the different zones.

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아라베스크 회전동작 시 지면반력 활용방법에 관한 연구 (The Research for Using Method of GRF (Ground Reaction Force) on Rotational Movement in Arabesque)

  • 권안숙;이건범
    • 한국운동역학회지
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    • 제15권2호
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    • pp.1-10
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    • 2005
  • G. B. LEE, A. S. GWON, The Research for Using methodof GRF (Ground Reaction Force) on Rotational Movement in Arabesque. Korean Journal of Sport Biomechanics, Vol. 15, No. 2, pp.1-10, 2005. As, in relation to all movements of a human being, the movements such as mutually walking, running, rotating, and jumping are attained endlessly through the ground amid the interaction with the ground, in terms of the harmonious movement of the upper limbs and the lower limbs, related to the basic movement in ballet, the type of a movement depends on the size and direction of the force that presses down the ground (Fz, Fx, Fy) amid the interaction with the ground. Therefore, aiming to correctly and efficiently perform a rotational movement in Arabesque, this study analyzed factors of the force manifestation through GRF (Ground Reaction Force), by dividing into preparing, stepping, standing, rotating, and finishing stages (events (1) ${\sim}$ (5)), targeting the subjects of 4 elite female students who majored in ballet. 1. At the No.5 position of the preparing stage, It is necessary that support the ground with left and right foot balance, 2. As the stepping stage is the phase ranging from the event (2), in which a plie movement of bending a knee is started, to the event (3) of stretching a knee, Rebunding motion is not good, and One have a position with ankle and knee flextion condition in order to stretch strengthly in event (3) position 3. At the event (1) position, It is necessary that exert the Fz reaction force at the event (3) position. Because large stretch force help to have a toe on position easily and show a active motion 4. In order to have a stand and rotation motion smoothly, One need a muscle strength training for ankle extension, knee extension, control horizental force