• Title/Summary/Keyword: oil release

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A Study on the Fire Hazard of Transportation Oil (수송기관용 오일의 화재위험성에 관한 연구)

  • Park, Young Ju;Hwang, Me Jung;Lee, Hae Pyeong;Lee, Seung Chul;Lee, Chang Hyun
    • Journal of the Korean Society of Safety
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    • v.29 no.3
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    • pp.114-120
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    • 2014
  • The purpose of this study is to conduct the study of the combustion and thermal characteristics through transportation oil for the analysis of fire hazard. Transportation oil breaks down into fuels such as diesel for civilian demands, gasoline, DF1(diesel for military), high sulfur diesel(for marine), kerosene and JP1(for aviation), and lubricants like brake fluid, power steering oil, engine oil, and automatic and manual transmission oil. The experiments of flash point, ignition point, flame duration time, heat release rate were carried out using TAG closed cup flash point tester(AFP761), Cleveland open cup auto flash point analyzer(AFP762), KRS-RG-9000 and Dual cone calorimeter. As a result, the fuel's ignition points were lower than lubricants, especially that of gasoline was not conducted as it has below zero one. Gasoline has the highest ignition point of about $600^{\circ}C$, while the other fuels showed $400{\sim}465^{\circ}C$. For flame duration time, lubricants had over 300 seconds, but fuels had less than 300 seconds except high sulfur diesel(350 seconds). Total heat release rate ranged $287{\sim}462kW/m^2$ for lubricants and gasoline showed the highest total heat release rate, $652kW/m^2$.

Current Issues on the Oil UST Management and Future Directions for the Prevention of the Subsurface Contamination (현행 주유소 지하유류저장시설 관리의 문제점과 토양${\cdot}$지하수 오염 방지를 위한 개선방안 연구)

  • Kim Meejeong
    • Journal of Soil and Groundwater Environment
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    • v.9 no.4
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    • pp.62-73
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    • 2004
  • The current status and problems of UST management in gas stations were reviewed, and suggestions were made for possible improvement of UST management. Regulations and programs relevant through the whole life cycle of the UST, such as construction, installation, operation, and disclosure are insufficient to prevent oil release. The UST requirements are less stringent compared to those of the U.S. and EU members. Current soil test does not seem to be practically effective in detecting soil contamination caused by oil release. The potential for subsurface contamination due to oil release from the UST is estimated from available data other than soil test results. Much higher following future directions and suggestions are made to improve current unsatisfactory UST management: Firstly, increasing the UST requirements - establishing more stringent standards for new UST facilities, and adding new regulatory requirements for existing UST facilities; secondly, replacing current soil test with the tank and piping tests; thirdly, reinforcing programs for supervising the tank construction and installation; fourthly, constructing a system in which independent gas stations can properly manage the USTs; and lastly, educating UST owners and operators, and constructing DB of UST facilities.

Effects of Slow Release Fertilizer and Dispersant on Biodegradation of Oil Contaminated in Sand Seashore Mesocosms (지속성 영양염제와 유분산제가 해변모래에 오염된 유류의 생분해에 미치는 영향)

  • 손재학;권개경;김상진
    • Korean Journal of Microbiology
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    • v.39 no.1
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    • pp.8-15
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    • 2003
  • To evaluate the effects of slow release fertilizer and chemical dispersant on oil biodegradation, mesocosm studies were conducted on sand seashore. The rapid removal rates (85%) of aliphatic hydrocarbons and the simultaneous decreases of n-$C_{17}$/pristane (69%) and $n-C_{18}/phytane$ (61%) ratios by the addition of slow-release fertilizer (SRF) within 37 days of experiment indicated that SRF could enhance the oil degrading activity of indigenous microorganisms in sand mesocosm. Although the growth of heterotrophic bacteria and petroleumdegrading bacteria in the mesocosm treated with $Corexit 9527^{R}$ was stimulated, the biological oil removal based on the ratios of $Corexit 9527^{R}$ and $n-C_{18}/phytane$ was inhibited. Removal rates of aliphatic hydrocarbons (56%), and n-$C_{17}$/pristane (27%) and $n-C_{18}/phytane$ (17%) ratios by the addition of chemical dispersant $Corexit 9527^{R}$ were similar or lower than those values of control (50, 60, 46%), respectively. The biodegradation activity, however, when simultaneously treated with SRF and $Corexit 9527^{R}$, was not highly inhibited and even recovered after the elimination of chemical dispersant. From these results it could be concluded that the addition of SRF enhanced the oil removal rate in oligotrophic sand seashore and chemical dispersant possibly inhibit the oil biodegradation. Hence, in order to prevent the unrestrained usage of chemical dispersant in natural environments contaminated with oil, the National Contingency Plan of Oil Spill Response should be carefully revised in consideration of the application for bioremedaition techniques.

Analysis of performance and combustion characteristics of D.O./butanol blended fuels in a diesel engine (디젤기관에서 경유/부탄올 혼합연료의 기관성능 및 연소특성 해석)

  • KIM, Sang-Am;WANG, Woo-Gyeong
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.55 no.4
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    • pp.411-418
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    • 2019
  • In this study, to investigate the effect of physical and chemical properties of butanol on the engine performance and combustion characteristics, the coefficient of variations of IMEP (indicated mean effective pressure) and fuel conversion efficiency were obtained by measuring the combustion pressure and the fuel consumption quantity according to the engine load and the mixing ratio of diesel oil and butanol. In addition, the combustion pressure was analyzed to obtain the pressure increasing rate and heat release rate, and then the combustion temperature was calculated using a single zone combustion model. The experimental and analysis results of butanol blending oil were compared with the those of diesel oil under the similar operation conditions to determine the performance of the engine and combustion characteristics. As a result, the combustion stabilities of D.O. and butanol blending oil were good in this experimental range, and the indicated fuel conversion efficiency of butanol blending oil was slightly higher at low load but that of D.O. was higher above medium load. The premixed combustion period of D.O. was almost constant regardless of the load. As the load was lower and the butanol blending ratio was higher, the premixed combustion period of butanol blending oil was longer and the premixed combustion period was almost constant at high load regardless of butanol blending ratio. The average heat release rate was higher with increasing loads; especially as butanol blending ratio was increased at high load, the average heat release rate of butanol blending oil was higher than that of D.O. In addition, the calculated maximum. combustion temperature of butanol blending oil was higher than that of D.O. at all loads.

Study of Development of a Dust-proof Oil Cooler (내분진형 오일 쿨러 개발에 관한 연구)

  • Lee, Young-Lim;Jeon, Euy-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.3
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    • pp.60-65
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    • 2008
  • A typical louvered-fin oil cooler can be easily contaminated under dusty environment hence resulting in poor performance of a heat exchanger. Thus, in this study, a dust-proof oil cooler has been studied with a unique shape of a 3-dimensional wavy fin since non-louvered fins could have better performance under dusty environment compared to louvered fins. Recently, they have been introduced to commercial and constructional vehicles in Japan. At first numerical analysis has been done to optimize the angle of the wavy fin so that the oil cooler developed can satisfy the target performance. The wavy fin has been then made with roll-forming and roll-pitch stands, and a prototype of an oil cooler with the wavy fin has been finally built with brazing. The performance test showed that the heat release rate of the oil cooler was well beyond the target, 4.94kW and the air-side pressure drop was below the criterion, 0.19kPa. In addition, the results showed that the numerical prediction was effective enough to design the dust-proof oil cooler that satisfies the performance criteria.

Preparation and Characterization of Calcium Alginate Microcapsules by Emulsification-Internal Gelation (에멀션-내부 젤화에 의한 알긴산 칼슘 마이크로캡슐의 제조 및 특성)

  • Park Soo-jin;Kang Jin-Young
    • Polymer(Korea)
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    • v.29 no.4
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    • pp.369-374
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    • 2005
  • In this work, the calcium alginate microcapsules containing lemon oil were prepared by emulsification-internal gelation and their potential use as aromatherapy was examined by the controlled release system. The lemon oil encapsulated in the alginate was successfully observed by Fourier transform (FT-IR) spectroscopy and differential scanning calorimeter (DSC) measurements. Analysis of the diameters and shapes of microcapsules was conducted by scanning electron microscopy (SEM). The mean diameters ranging from 4 to 7 um and encapsulation yield ranging from 50 to $85\%$ were obtained. The controlled release of the lemon oil at $37^{circ}$ was demonstrated by the infrared moisture determination (IMDB). It was found that the amount of released lemon oil decreased with increasing concentrations of alginate and $CaCl_2$ due to the higher the cross-linking density of the capsules prepared. The oil release from the capsule was measured as a function of physical force. We confirmed that the external factor could control the collapse of capsule wall and the release rate.

Study on the Combustion Characteristics of Tulip Tree (Liriodendron tulipifera) for Use as Interior Building Materials

  • Min Ji KIM;Sang-Joon LEE;Sejong KIM;Myung Sun YANG;Dong Won SON;Chul-Ki KIM
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.5
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    • pp.410-418
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    • 2023
  • In this study, the combustion characteristics of the Tulip tree, which is the representative broad-leaved afforestation tree in Korea, were analyzed. The flame retardant performance of the Tulip tree was analyzed by analyzing combustion characteristics on a total of three test samples; flame retardant treated, both flame retardant and oil stain-treated, and untreated. Then the flame retardance grade was classified for each of them. According to the result, test samples showed the strongest flame retardance were in order of flame retardant treated (C), both flame retardant and oil stain-treated (B), and untreated (A). As a result of analyzing the total heat emission and maximum heat emission rates, which is the evaluation standard for interior materials of Korean domestic buildings, test samples with flame retardant treat or flame retardant and oil stain treat were qualified for the flame-retardant standard. Both flame retardant and oil stain-treated samples showed higher total heat release (THR) and heat release rate compared to flame retardant-treated samples as the oil causes combustion with oxygen. On the other hand, they didn't qualify the THR in Quasi-non-combustible standards. To determine the correlation between the physical and combustion characteristics of wood, the combustion characteristics of other diffuse porous wood species, with which the Tulip tree is affiliated were analyzed, and noticed that the characteristic correlates with the density and quantity of wood. The results of this study are expected to be used as basic information on the combustion characteristics of the Tulip tree.

An experimental study on adhesion of concrete form release agent (콘크리트 거푸집 박리제의 부착력에 대한 실험적 연구)

  • Seo, Hyun-Jae;Park, Jong-Pil;Nam, Sun-Hwa;Gong, Min-Ho;Sng, Jae-Young;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.77-78
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    • 2018
  • Form-work is a must for construction work. In order to secure the best condition of the form surface and to increase the number of times, the form releasing agent is applied during the process of the form-work. The base oil of the form release agent which has been used already uses the oil which directly or indirectly affects the natural environment and the concrete. In this study, the basic study on the form release agent for concrete was carried out only for the effect of adhesion. The adhesive force of the tile is measured by the mortar to determine the change of the releasing agent and the adhesive strength.

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Controlled Release of Doxazosin in Multi-layered Pellet Using Polymer Blending (고분자 블렌딩을 이용하여 제조된 독사조신 다중층 펠렛의 약물방출제어)

  • Youn, Ju-Yong;Park, Sang-Wook;Lee, Soo-Young;Kim, Moon-Suk;Lee, Bong;Khang, Gil-Son;Lee, Hai-Bang
    • Polymer(Korea)
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    • v.32 no.4
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    • pp.322-327
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    • 2008
  • In this study, a multi-layered pellet was composed of a seed layer including a water-swellable agent and a drug layer containing doxazosin as a model drug, a porous membrane and a castor oil layer to control drug release. The pellet is prepared by a fluidized bed coating method. To confirm drug release from polymer blending in multi-layered pellet system, it is prepared by containing different ratio such as hydroxypropylmethylcellulose (HPMC) : ethyl cellulose (EC) in drug layer and cellulose acetate(CA) : Eudragit RS in membrane. Also, to confirm the effect of oil in drug release, castor oil is coated. As a result, we observed regularly spherical pellet with diameter of $1500{\mu}m$. Release pattern of drug is confirmed by dissolution tester in aqueous media. The more the ratio of EC in drug layer, CA in membrane, and castor oil layer in pellet, the less the drug release is observed. Formation and the amount of pores in membrane is observed by SEM.

Drug Release Characteristics and Skin Irritancies of Topical Gels and Multiple Emulsion Creams Containing Kojic Acid (외용겔 및 다중유제크림의 코지산 방출특성과 피부자극성)

  • Yu, Sung-Un;Park, Eun-Woo;Choi, Young-Wook
    • Journal of Pharmaceutical Investigation
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    • v.28 no.2
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    • pp.87-92
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    • 1998
  • Kojic acid (KA) is an antimelanogenic agent which has been widely used in cosmetics to whiten the skin color. However, it has the drawbacks of the skin irritancy and the instability against the pH, temperature, and light. In order to overcome these problems, various topical gels and multiple emulsion creams which can control the release of active ingredient, KA, were formulated employing cream bases of mineral oil with caprylic capric triglyceride and hydrophilic polymers such as chitosan, carbopol. and pluronics. Using Franz diffusion cells mounted with a synthetic cellulose membrane (MWCO 12,000), drug release characteristics of the formulations were evaluated by the HPLC assay of KA concentration in the receptor compartment of pH 7.4 phosphate buffered saline solution. Drug release from chitosan-based gels (ChitoGel) obeyed to the first order kinetics with a rapid release especially in the initial period. However, pluronic-based gels (PluGel) and carbopol-based gels (CarboGel) revealed controlled release of drug to some extent, followed by the square root-time kinetics. Moreover, the release of KA was further controlled with the W/O/W multiple emulsion creams (MultiCream), showing the apparent zero order release kinetics by virtue of dynamic ratecontrolling membrane of the oil layer. The flux $(J,\;{\mu}g/cm^2/hr)$ of ChitoGel. CarboGel. PluGel. and MultiCream in the initial period of 6hr were 73.30, 28.67. 24.04 and 7.72, respectively. On the other hand, the skin irritancy score of ChitoGel and MultiCream were observed as 2.5 and 2.3 respectively, in the rabbit skin irritation test. Although there were insignificant differences at p<0.05 between those formulations, it was possible to conclude that the W/O/W multiple emulsion creams containing KA might be a good candidate for an antimelanogenic drug delivery system due to the controlled release of acidic drug molecules.

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