• 한국염색가공학회지
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• 제26권3호
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• pp.151-158
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• 2014

The oil sorption capacities and biodegradability of nonwoven fabrics(pads) of PP and PP/kapok(10/90wt%) blend prepared in this study and commercial pad(T2COM: 100% PP) were compared. The biodegradability(58.5%) of PP/kapok(10/90wt%) blend pad was about 5times higher than those(11%) of PP and T2COM pads after 45days. The oil sorption rates of oil sorbent pads for various oils(diesel, lubricant and Bunker C oils) were markedly increased with increasing dipping time up to about 5min and then levelled off. The oil sorption rate and oil sorption capacity were found to increase in the order of PP/kapok(10/90wt%) blend>PP>commercial(T2COM) and Bunker C>lubricant>diesel.

• KSBB Journal
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• 제19권2호
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• pp.132-137
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• 2004

생산된 바이오디젤 (지방산 메틸에스테르)을 기반으로 한 여러가지 합성윤활유 베이스를 분석대상으로 하여 생분해도를 분석평가하였다. 또한 기존 석유디젤과 바이오디젤의 생분해성을 함께 비교 검토하였다. 호기적인 조건하에 생분해성 윤활유의 수상에서는 생분해성을 이산화탄소 발생량을 기준으로 생분해성을 조사하는 OECD 301 B에 근거하여 윤활유를 분석한 결과 펜타에리스리톨계 윤활유 베이스들의 28일째의 최종 생분해도는 61.1∼80.3%로서 모두 생분해도가 있음을 알 수 있었으며, 바이오디젤은 생분해도가 가장 높았다(83.5%). 분석의 상대오차, 독성대조군, 분석절차대조군과 관련된 규정에 의해 석유디젤을 제외하고 모두 타당한 절차에 의해 분석되었음을 입증할 수 있었다.

• 대한화학회지
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• 제57권3호
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• pp.377-381
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• 2013

Thevetia peruviana (Yellow Oleander) seed oil was extracted with n-hexane in a soxhlet extractor. The ethanolysis and methanolysis of the oil were carried out with 50% of potassium hydroxide in ethanol and methanol respectively by weight of oil, as catalyst. The biodiesel was tested for biodegradability using E. coli. The percentage yield of the FAEE and FAME were 84.8% and 91.6% respectively. The biodegradability values of 81.4% and 86.2% were obtained for FAEE and FAME respectively after a period of 28 days. Other fuel quality parameters determined are the cetane index of 47.19 (FAEE) and 58.97 (FAME), flash point of $198^{\circ}C$ (FAEE) and $175^{\circ}C$ (FAME), kinematic viscosity at $40^{\circ}C$ of 5.21 $mm^2s^{-1}$ (FAEE) and 5.10 $mm^2s^{-1}$(FAME), pour point of $4^{\circ}C$ (FAEE) and $-2^{\circ}C$ (FAME) and a cloud point of $6^{\circ}C$ (FAEE) and $3^{\circ}C$ (FAME). Thus, Thevetia peruviana oil has a high potential for use in production of environmentally friendly biodiesel.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2003년도 학술대회지
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• pp.139-148
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• 2003

In this study, biodegradable base Li-greases were prepared by using Li-soap thickener and vegetable oils such as soybean oil, rapeseed oil, castor oil and synthetic ester. Also, EP-greases were formulated by blending base Li-greases, anti-wear additives, EP additives, anti-oxidants and corrosion inhibitor etc. And EP-greases were characterized by analysing physical properties such as worked penetration, dropping point, 4-ball wear, extreme pressure, thermal properties etc. Biodegradability of base Li-greases and EP-greases were evaluated by CEC-L-33-A-93 method using several inoculums of domestic sewage treatment plant. As the results, biodegradability of vegetable oils were shown at the range of 97.1 to $98.4\%$. And biodegradability of base Li-greases and EP-greases were $86.2\%\;\~\;89.3\%\;and\;83.4\%\;\~\;90.0\%$ which were lower value than those o( vegetable oils due to effect of Li-soap thickener, respectively. Therefore, the EP-greases prepared in this study were easily biodegraded by microorgnism.

• 한국수산과학회지
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• 제29권6호
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• pp.787-796
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• 1996

The biodegradation experiment, the TOD analysis and the element analysis for dispersant, Bunker-A oil and Bunker-B oil were conducted to study the biodegradation characteristics of a mixture of Bunker-A oil with dispersant and a mixture of Bunker-B oil with dispersant in the seawater. The results of biodegradation experiment showed 1mg of dispersant to be equivalent to 0.26 mg of $BOD_5$ and to 0.60 mg of $BOD_{20}$ in the natural seawater. The results of TOD analysis showed each 1 mg of dispersant, Bunker-A oil and Bunker-B oil to be equivalent to 2.37 mg, 2.94 mg and 2.74 mg of TOD, respectively. The results of element analysis showed carbon, hydrogen, nitrogen and phosphorus contents of dispersant to be $82.1\%,\;13.8\%,\;1.8\%\;and\;2.2\%$, respectively. Carbon and hydrogen contents of Bunker-A oil were found to be $73.3\%\;and\;13.5\%$, respectively, and carbon, hydrogen and nitrogen contents of Bunker-B oil to be $80.4\%,\;12.3\%\;and\;0.7\%$, respectively. Accordingly, the detection of nitrogen and phosphorus in dispersant shows that dispersants should be used with caution in coastal waters, with relation to eutrophication. The biodegradability of dispersant expressed as the ratio of $BOD_5/TOD$ was found to be $11.0\%$. As the mix ratios of dispersant to Bunker-A oil (3 mg/l) and a mixture of Bunker-B oil (3mg/l) were changed from 1 : 10 to 5 : 10, the biodegradabilities of a mixture of Bunker-A oil with dispersant and Bunker-B oil with dispersant increased from $2.1\%\;to\;7.2\%$ and from $1.0\%\;to\;4.4\%$, respectively. Accordingly, the dispersant belongs to the organic matter group of middle-biodegradability while mixtures in the mix ratio range of $1:10\~5:10$ belong to the organic matter group of low-biodegradability. The deoxygenation rate constant $(K_1)$ and ultimate biochemical oxygen demand $(L_0)$ obtained from the biodegradation experiment and Thomas slope method were found to be 0.125/day and 2.487 mg/l for dispersant (4 mg/l), respectively. $K_1\;and\;L_0$, were found to be $0.079\~0.131/day$ and $0.318\~2.052\;mg/l$ for a mixture of Bunker-A oil with dispersant and to be $0.106\~0.371/day$ and $0.262\~1.106\;mg/l$ for a mixture of Bunker-B oil with dispersant, respectively, having $1:10\~5:10$ mix ratios of dispersant to Bunker-A oil and Bunker-B oil. The ultimate biochemical oxygen demands of the mixtures increased as the mix ratio of dispersant to Bunker-A, B oils changed from 1 : 10 to 5 : 10. This suggests that the more dispersants are applied to the sea for the cleanup of Bunker-A oil or Bunker-B oil, the more decreases the dissolved oxygen level in the seawater.

• 전기학회논문지
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• 제61권8호
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• pp.1148-1152
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• 2012

The vegetable-based insulating oils are substitutes for mineral oils in oil-filled transformer. The important properties of vegetable insulating oil is their higher flash/fire point and biodegradability than conventional mineral oils. The large oil-filled transformer eliminate the risk of explosion and fire should the transformer fail and oil ignite owing to high flash/fire point of vegetable insulating oil. In addition, higher biodegradability of vegetable insulating oils can let the oil spill damage reduced. In this experiment, the real oil-filled transformers using mineral oil and vegetable oil have accelerated aging. After working on the 100% accelerated aging experiment were conducted comparing the transformer. The hottest-spot temperature using thermal coefficients were calculated to determin the degree of accelerated aging. As a result, apply mineral oil transformer in accordance with the accelerated aging life come to an end. In contrast, vegetable insulating oils showed the opposite characteristics. Vegetable insulating oil compared to the mineral oil are found to be an long life. As a result, the vegetable oil has a long-term stability.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.1
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• pp.453-456
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• 2004

This paper surveys the latest findings on vegetable-oil-based dielectric coolants in power systems. In recent years, environmental concerns have been increased on the use of poorly biodegradable mineral oils in distribution and power transformers in regions where spills from leaks and equipment failure could contaminate the surroundings. In addition, there are demands to improve equipment efficiencies in power systems. In this reason, researches were started in the mid 1990s to develop a fully biodegradable dielectric coolants. Vegetable oil was considered the most likely candidate for a fully biodegradable dielectric coolants. Vegetable-oil-based dielectric coolants provide the advantages of high level of biodegradability, renewable natural resource, non-toxic properties, enhanced fire safety, more effective cooling and good dielectric strength for many electrical equipment.

• 대한화학회지
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• 제55권4호
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• pp.680-684
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• 2011

Balanites Aegyptiaca 씨기름으로부터 바이오 디젤유를 생산하고 기름 품질 및 생분해성을 조사하였다. 비중, 밀도와 인화점은 각기 0.897, 0.89 g/$cm^3$ and $163^{\circ}C$이었다. 이 바이오 디젤유는 $D_2$ 디젤유(27.02%, 27.33%)에 비해 월등하게 82.58%, 86.98% 생분해 되었다.

• 한국수산과학회지
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• 제26권6호
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• pp.519-528
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• 1993

해수중에서 유처리제에 의해 유화${\cdot}$분산된 Bunker-C유의 생분해도와 이로 인해 나타나는 용존산소소비를 연구할 목적으로 국내에서 시판 중인 유처리제 및 국내 연안에 있어 유류오염사고의 주종을 이루고 있는 Bunker-C유에 대한 TOD분석과 원소분석을 행하고, 또한 Bunker-C유/유처리제 혼합물에 대해 천연해수를 이용한 생분해 실험을 행한 결과를 요약하면 다음과 같다. 1. 1mg의 Bunker-C유는 3.16mg의 TOD를 나타내는 반면에 1mg의 유처리제는 2.80mg의 TOD값을 나타내었다. 2. Bunker-C유는 $87.3\%$의 탄소와 $11.5\%$의 수소를 함유하였으며, 유처리제는 $76.5\%$의 탄소와 $12.2\%$의 수소를 함유하였다. Bunker-C유와 유처리제 중 어느 시료에서도 질소는 검출되지 않았다. 3. 천연해수 중에서 일정량의 Bunker-C유(4mg/l)에 대하여 유처리제를 $10:1{\sim}10:5$의 혼합비율로 첨가한 Bunker-C유/유처리제 혼합물에 관해서 정리하면, 혼합물의 $BOD_5$는 $0.34{\sim}2.06mg/l$였고 $BOD_{20}$는 $1.05{\sim}5.47mg/l$였다. 또한 혼합비율이 증가함에 따라 혼합물의 BOD는 증가하였다. 혼합물은 생분해도($BOD_5$/TOD)가 $3{\sim}11\%$로서 저율 분해군에 속하였다. 또한 혼합비율이 10:1에서 10:5로 증가함에 따라 혼합물의 생분해도는 $3\%$에서 $11\%$로 증가하였다. 혼합물의 탈산소계수($K_1$)는 $0.072{\sim}0.097/day$였으며, 혼합물의 최종산소요구량($L_o$)은 $1.113mg/l{\sim}6.746mg/l$로서 혼합비율이 증가함에 따라 최종산소요구량도 증가하였다.

• 한국환경과학회지
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• 제14권10호
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• pp.973-978
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• 2005

Biodegradable oil gelling agent was prepared, and their oil absorption capacities using light oil, lubricant oil and corn oil were investigated. The result showed that the oil absorption capacity was depended on the amount of surfactant and starch added, and was increased in the order of light oil, lubricant oil and corn oil. Also, the oil-absorption capacity was saturated within 30 min at $18^{\circ}C$. The biodegradability of the prepared biodegradable oil gelling agent was also studied by determination of reduced sugar produced after enzymatic hydrolysis. Their surface morphologies and thermal properties of the prepared biodegradable oil gelling agent were observed by scanning electron microscopy (SEM) and thermogravimetric analysis (TGA), respectively.