• Proceedings of the Korean Fiber Society Conference
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• 1999.04a
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• pp.173-176
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• 1999

• Journal of the Korean Society of Clothing and Textiles
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• v.23 no.7
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• pp.1064-1072
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• 1999

Nylon fabric was grafted for the purpose of the development of detergency against the hemoglobin as a protein soil. By free-radical producing chemical initiator systems the graft using acrylic acid(AA) as a hydrophilic vinyl monomer was performed to change surface energies in the presence of ammonium persulfate(APS) as an initiator and then acrylic acid grafted Nylon was treated with NaOH solution. The surface morphology for Nylon-g-NaAA with changing graft rate were studied by scanning electron microscopy (SEM) The properties of the Nylon such as diameter tenacity elongation contact angle and the hemoglobin removal were also investigated. The diameter of grafted Nylon fiber increased as the graft ratio increased. The tenacity of grafted Nylon also increased with increasing graft ratio up to 15% The elongation however decreased gradually according to graft, The contact angle decreased after graft and alkaline treatment. The amount of hemoglobin on the grafted Nylon increased in proportion to the graft ratio. Hemoglobin was easily removed from grafted Nylon while it was difficult to be removed from ungrafted Nylon. The detergency of hemoglobin for grafted Nylon decreased when the graft ratio exceeded 15% The removal of hemoglobin increased markedly with increasing hemoglobin content and revolution speed. Therefore the removal of hemoglobin was improved due to graft and alkaline treatment.

• Textile Coloration and Finishing
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• v.28 no.4
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• pp.231-238
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• 2016

We investigated the evolution of crystal formation as a function of drawing ratio in poly(1,4-diaminobutane-co-adipic acid-co-${\varepsilon}$-caprolactam-co-diethylenetriamine)(nylon 466T) copolymer formed by four monomers, i.e 1,4-diaminobutane, adipic acid, ${\varepsilon}$-caprolactam, diethylenetriamine(DETA), using synchrotron X-ray scattering measurement. In case of pristine(as spun) nylon 466T fiber, it was consisted with unoriented nylon $6{\alpha}$ and unoriented nylon $46{\alpha}$ phases. As increase the drawing ratio, unoriented nylon $6{\alpha}$ was transformed to oriented ${\gamma}$ phase, while unoriented nylon $46{\alpha}$ changed to oriented $46{\alpha}$ phase. The effect of the addition of DETA was not observed in the pristine fibers. However, DETA affected to restrict the formation of crystals at the maximum drawing condition, and as a result it had a role to increase the moisture regain.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.1
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• pp.814-821
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• 2015

The purpose of this study is to estimate crack reduction properties of covering concrete with fibers in basement. Air contents, slump, compressive strength, tensile strength and plastic shrinkage has been tested to conduct the optimum addition ratio and type of fiber. The results is a following. For the properties of air contents, all of the specimens added fibers shown the higher than plain concrete. For the flowability, slump decreased about 40-80% when all of the specimens added fibers. For the strength properties, the specimens added nylon fiber shown higher compressive and tensile strength about 5-15% comparing with other concrete. For the plastic shrinkage, cracking decreased when the fiber added comparing with plain concrete. Especially, when nylon fiber added in the concrete, the plastic shrinkage did not occurred. For the overall consideration, when the addition ratio of nylon fiber is 0.6%, the press concrete is identified as showed optimum properties.

• The Korean Journal of Rheology
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• v.8 no.2
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• pp.69-77
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• 1996

장섬유강화 열가소성 고분자 복합재료 (FRTP)의 난연성과 개선을 위하여 polyhenylene sulfide(PPS)를 첨가한 polyamide 6(PA6)/glass fiber (GF)의 FRTR를 제조하 였다. 고점성수지내에 보강섬유를 균일하게 분산시키고 함침성을 높임과 동시에 보강섬유의 손상을 방지하기 위하여 섬유상 수지와 보강섬유를 분섬비동장치에서 직접혼방시키고 이를 압축성형하는 독특한 공정을 도입하였다. 제조된 복합재료의 유변학적 특성 형태학적특성 인장 및 충격특성 열적특성, 난연성, 내약품성에 관한연구를 수행한 결과 복합재료와 기계적 특성을 약화시키지 않으면서도 난연성가 내약품성을 현격히 향상시킬수 있는 FRTP의 제조 가 가능함을 확인하였다.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.33 no.3
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• pp.273-279
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• 2023

Objectives: Objectives of this study were: 1) to introduce industrial situation and health hazards of synthetic fiber, 2) to review a case of chronic obstructive pulmonary disease in a worker exposed to synthetic fiber reported to the Korea Occupational Disease Surveillance Center, and 3) to suggest supplementary measures for the occupational health system for workers exposed to synthetic fibers. Methods: Respiratory exposure, health hazards, and exposure standards for synthetic fiber dust in Korea and other countries were reviewed. In addition, a case of chronic obstructive pulmonary disease due to exposure to nylon dust reported to the Korea Occupational Disease Surveillance Center was reviewed and summarized. Results: The worker was a 53-year-old non-smoking male who had been involved in the nylon weaving process for 26 years. He had shortness of breath from three years ago. He was diagnosed with chronic obstructive pulmonary disease. PM1.0, PM_2.5, and PM10 were measured at 26.6 ㎍/m³, 48.2 ㎍/m³, and 91.7 ㎍/m³, respectively. Fiber components estimated as nylon fiber were detected in the microscopic examination of a solid sample. Conclusions: For workers exposed to synthetic fiber dust, special health examinations of the respiratory system, regular work environment measurement, and work environment management through workplace health management should be performed. It is necessary to research on health effects of synthetic fibers.

• Textile Coloration and Finishing
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• v.13 no.5
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• pp.41-41
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• 2001

In this study, synthetic fiber fabrics such as polyester, nylon 6, acrylic and acetate were dyed with indigoid vat dye. The effects of the composition of alkaline reduction, dyeing time and dyeing temperature on color strength and color fastness of the fabrics were investigated. Also the color fastnesses to wash and light of the dyed fabrics were studied. In dyeing of polyester, nylon, acrylic and acetate fiber fabrics with indigo vat dyes, it appears that these fabrics have high values of K/S up to Ig/L of sodium hydroxide and 6g/L of reducing agent. Indigo vat dyeing for synthetic fiber fabrics was verb fast, and lead to dyeing equilibrium within twenty minutes. The K/S values of dyed fabrics did not changed in dye concentration more than 10% o.w.f.. Synthetic fiber fabrics dyed with indigoid dyes had bad light fastness.

• Textile Coloration and Finishing
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• v.13 no.5
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• pp.329-335
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• 2001

In this study, synthetic fiber fabrics such as polyester, nylon 6, acrylic and acetate were dyed with indigoid vat dye. The effects of the composition of alkaline reduction, dyeing time and dyeing temperature on color strength and color fastness of the fabrics were investigated. Also the color fastnesses to wash and light of the dyed fabrics were studied. In dyeing of polyester, nylon, acrylic and acetate fiber fabrics with indigo vat dyes, it appears that these fabrics have high values of K/S up to Ig/L of sodium hydroxide and 6g/L of reducing agent. Indigo vat dyeing for synthetic fiber fabrics was verb fast, and lead to dyeing equilibrium within twenty minutes. The K/S values of dyed fabrics did not changed in dye concentration more than 10% o.w.f.. Synthetic fiber fabrics dyed with indigoid dyes had bad light fastness.

• Proceedings of the Korean Fiber Society Conference
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• 1996.04a
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• pp.158-161
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• 1996

Microfibers of Poly(ethylene terephthalate)(PET)/Nylon 6 (P/N) was heat set at 170C in a fixed state and then treated with hydrazine at 30C for 5, 10, 15, 20, 30 and 40 h. Weight loss from the hydrazine treatment increased according to the hydrazine concentration(Fig.1). In order to investigate in detail the effect of the electrostatic attraction between the dye anion and hydrazide groups in cooperated by hydrazinolysis, -potential of P/N fiber was measured by streaming potential method. The surface charge density, o, of the fiber was evaluated from the -potential.

• Textile Coloration and Finishing
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• v.14 no.6
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• pp.328-334
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• 2002

Nylon 6 staple ultramicrofiber(UMF, 0.074) and regular staple fiber (Regular, 2.0d) were annealed at In, 130, 160 and $180^\circ{C}$ under tension free for 10 min and U min. The treated fibers were dyed with Acid Red 18 and Blue n3. They were adjusted at PH 5.0 of dye bath in buffer solution of $CH_3COOH/CH_3/COONa(0.1mo1/1)$. Liquor ratio was kept at 1000:1. Dyeing rate of UMF annealed at $100^\circ{C}$ was decreased, but was increased for regular nylon. Also dye equilibrium of UMF at $100^\circ{C}$ was increased for Acid Red 18, but was decreased for Acid Blue 83. The intensities of X-ray diffraction peaks of UMF increased with increasing annealing temperature. Also the crystallinity of heat-sotted fibers by DSC thermogram was well agreed with the tendency of density Amino end group, moisture regain and water absorbency were decreased with increasing annealing temperature.