• 제목/요약/키워드: nylon 4

검색결과 502건 처리시간 0.021초

흑색 황화염료에 의한 나일론 스웨이드 직물의 염색 특성 연구 (Dyeing Property of Nylon Suede Fabric Dyed with Sulphur Black Dye)

  • 이민주;이정훈;정대호;이미경;고재왕;이승걸
    • 한국염색가공학회지
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    • 제29권3호
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    • pp.115-121
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    • 2017
  • Demands for nylon suede as an artificial leather are increasing due to its functionality and aesthetics. To achieve high value added nylon suede based on green technology, this study was carried out in order to obtain useful data for the nylon suede fabrics with eco-friendly dyeing process by a pad-steam method instead of a dip dyeing process using sulphur black dye to reduce the industrial waste of water. The dyeability of the nylon suede was investigated according to reducing temperatures, dye concentrations, and reducing agent's concentrations. Throughout the results of the CIE $L^*a^*b^*$ and Munsell values, the optimized dyeing conditions of the nylon suede using sulphur black dye are $70^{\circ}C$ of dyeing temperature, 30% o.w.f. of dye concentration, and $9g/{\ell}$ of reduction agent concentration, respectively. Furthermore washing colorfastness, light colorfastness and perspiration colorfastness were achieved in the range of 4-5 grades.

폴리우레탄/나일론 6 용융블렌드의 인장특성 및 충격거동에 관한 연구 (A Study on the Tensile Properties and Impact Behavior of Polyurethane/Nylon 6 Melt Blends)

  • 지동선;김지혜;윤철수
    • 폴리머
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    • 제26권4호
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    • pp.483-491
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    • 2002
  • 나일론 6의 상온 및 저온에서의 내충격성을 개선할 목적으로 폴리우레탄 (PU)/나일론 6 용융블렌드를 Haake Rheomix를 사용해 제조한 후 PU 함량 (10, 20, ,30, 40, 50 wt%) 및 블렌딩 시간 (5, 10, 15, 20분)에 따른 결정구조, 동역학적 특성, 인장특성 및 충격거동을 WAXD, DMA, UTM 및 notched Izod 충격시험기 등을 이용하여 조사하였다. PU 함량 및 블렌딩 시간이 증가할수록 블렌드의 결정회절피크의 형태는 넓어지고 회절피크의 강도는 감소하였다. 블렌드의 유리전이온도, 인장강도, 인장탄성률로 감소하였으며, 신도는 증가하였다. 또한 PU 함량이 블렌딩 시간보다 결정구조, 동역학적 특성 (tan $\delta$) 및 인장특성 등에 더 큰 영향을 미침을 알 수 있었다. PU/나일론 6 (10/90 wt%) 블렌드 상온 ($20^{\circ}C$) 및 저온 ($-35^{\circ}C$)에서의 충격강도가 크게 향상될 수 있음을 확인하였다.

Open Pulled Straws, EM Grid, Nylon Loop법에 의한 돼지성숙난자의 유리화동결 비교

  • 안미현;김인덕;석호봉
    • 한국동물번식학회:학술대회논문집
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    • 한국동물번식학회 2003년도 학술발표대회 발표논문초록집
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    • pp.83-83
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    • 2003
  • 돼지 난자의 유리화 동결 처리 방법 중 난자를 담는 용기(loading vessel)의 재료로 최근에 알려진 것으로 open-pulled straws(OPS)[Vajta등, Mol Reprod Dev, 51:53-58, (1998)], electron microscope grids(EMG) [Martino등,Biol Reprod, 54:1059-1069, (1996)〕, nylon loop system(NLS) [Lane등, Fertil Steril,72: 1073-1078, (1999)] 등이 보고되고 있다. OPS는 1/4cc straws를 열을 가하여 길게 뽑아 내벽을 얇게 함으로써 filing된 난자나 수정란이 액체 질소와 접촉했을 때 유리화가 신속하게 되도록 하는 방법으로 돼지에서는 별로 보고된 것이 없다. EMG는 열전도가 예민한 전자현미경용 copper grid를 이용한 방법으로 최근 국내 기술진의 연구성적을 포함한 몇몇 학자들에 의하여 보고되었고 NLS는 0.5mm직경의 nylon loop를 이용하여 급속 동결한 성적이 보고되었으나, 돼지 난자에 응용 된 것은 없다. 따라서 이와 같은 동결 재료는 사람과 반추류, mouse외에 돼지 난자에 대하여는 전혀 시도되지 않았지만 유리화 동결기술에서 가장 중요한 실험으로 생각된다. 성공적인 유리화 동결을 위해서는 수정란이 냉각의 전도성이 빠르고, 작은 용액을 수정란과 같이 filling해야 하며 모든 동작이 신속 간편해야 하며 융해 방법도 초급속도의 융해가 요구되므로 이에 부합되어야 한다. 연구 목적은 돼지 난자를 유리화 동결/융해 시 동결 재료-straw/glass, copper grid, nylon 3가지에 대한 제작 방법, 난자 loading, 동결 처리, 보관 방법, 융해 방법 등을 난자의 회수, 수정 후 생존율을 비교 조사하여 가장 우수한 방법을 선택할 목적이었다. 수행 내용은 3가지의 재료의 sample을 제작하고 소독한 다음 준비된 돼지 COCs을 40시간동안 IVM한 후 난자를 5~l5개 정도로 선정 하여 준비된 VS 용액에 평형처리 하였다. 각 재료의 용기에 loading 한 후 동결/보관하였고, 융해는 역순으로 평형하여 maturation 배지에 3~4시간 배양한 다음 경검하고 IVF한 후 NCSU-23 배지에 담아 IVC 배양하면서 cell cleavage상태를 확인하였다.

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고무 공기 스프링용 CR/Nylon 6 코드 고무 슬리브에 대한 연구 (Research on CR/Nylon 6 Cord Rubber Sleeve of Rubber Air Spring)

  • 서재찬;김대진;박해윤;서관호
    • Elastomers and Composites
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    • 제49권4호
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    • pp.293-304
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    • 2014
  • 고무 공기 스프링(rubber air spring)은 자동차, 철도차량 등 수송기기의 서스펜션 장치로 사용되고 있다. 고무 공기 스프링은 고무 에어백의 압축과 팽창을 통한 탄성효과로 스프링의 역할을 한다. 고무 공기 스프링의 주요 구성요소 중 하나가 고무 슬리브(rubber sleeve)이다. 고무 슬리브는 주요 구성성분인 클로로프렌 고무와 나일론 6 코드 간의 접착이 매우 중요하다. 본 연구에서는 첨가제의 영향을 고려한 고무 슬리브의 최적 배합조성과 조건을 찾기 위해 다양한 물성시험을 하였다. 또한, 보강섬유의 최적 배향을 선정하기 위해 유한요소해석법을 이용한 수치해석을 수행하였다. 고무 공기 스프링을 제조하여 실제 차량에 장착하여 기초물성과 피로수명 및 기밀성을 시험하였다.

알루미늄 스퍼터링 처리 의류소재의 스텔스 특성과 전자파 차단 및 전기적 특성에 관한 연구 - 밀도 변화를 중심으로 - (Stealth, electromagnetic interception, and electrical properties of aluminum sputtered clothing materials - Focusing on the density change -)

  • 한혜리
    • 복식문화연구
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    • 제30권4호
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    • pp.579-593
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    • 2022
  • This study examines the surface characteristics, electrical conductivity, electromagnetic wave blocking characteristics, infrared (IR) transmittance, stealth function, thermal characteristics, and moisture characteristics of IR thermal imaging cameras. Nylon film (NFi), nylon fabric (NFa), and 5 types of nylon mesh were selected as the base materials for aluminum sputtering, and aluminum sputtering was performed to study IR thermal imaging, color difference, temperature change, and so on, and the relationship with infrared transmittance was assessed. The electrical conductivity was measured and the aluminum-sputtered nylon film demonstrated 25.6kΩ of surface resistance and high electrical conductivity. In addition, the electromagnetic wave shielding characteristics of the sputtering-treated nylon film samples were noticeably increased as a result of aluminum sputtering treatment as measured by the electromagnetic wave blocking characteristics. When NFi and NFa samples with single-sided sputtering were placed on the human body (sputtering layer faced the outside air) and imaged using IR thermographic cameras, the sputtering layer displayed a color similar to the surroundings, showing a stealth effect. Moreover, the tighter the sample density, the better the stealth function. According to the L, a, b measurements, when the sputtering layer of NFi and NFa samples faced the outside air, the value of a was generally high, thereby demonstrating a concealing effect, and the △E value was also high at 124.2 and 93.9, revealing a significant difference between the treated and untreated samples. This research may be applicable to various fields, such as the military wear, conductive sensors, electromagnetic wave shielding film, and others.

단분산린 Polyamide 6(Nylon 6) 미세입자의 제조 (Preparation of Mono-dispersed Polyamide 6(Nylon 6) Micro-particle)

  • 조항구;김형중
    • 폴리머
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    • 제31권4호
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    • pp.322-328
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    • 2007
  • 촉매인 potassium(K)을 2회 분할 투입하는 음이온 개환중합반응으로 ${\varepsilon}-caprolactam$을 분산매인 liquid paraffin 내에서 분간 중합하여 $4{\sim}7\;{\mu}m$의 직경을 가지는 단분산된 구형의 polyamide 6 (Nylon 6) micro-particle를 제조하였다. 융착 방지제의 농도, 촉매의 양, 개시제의 양에 따라 생성된 입자 크기, 형태, 그리고 분포의 변화를 비교 분석하였다. 그 결과 개시제인 $PCl_3$의 양이 단량체의 $0.97{\sim}1.17\;wt%$일 때 약 90.6%의 수율을 얻었으며, 또한 촉매를 $1.3{\sim}1.4\;wt%$ 정도로 투입하였을 경우 가장 안정된 구형의 미세입자가 제조되고 높은 수율이 얻어짐을 알 수 있었다.

머위 추출액에 의한 직물의 염색성과 자외선 차단성 (Dyeing Properties and Ultraviolet-cut Ability of Dyed Fabrics with Petasites japonicus Extract)

  • 최인려;전미선
    • 복식문화연구
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    • 제19권1호
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    • pp.96-103
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    • 2011
  • It is well known that the Petasites japonicus has been used for a long time medicine for the treatment of allergic diseases such as lacquer poisoning. However, the exact components and dyeing properties of its effects is still not known. Therefore, the purpose of this study was to investigate the dyeing property and ultraviolet-cut ability of silk and nylon fabrics that was dyed variously with the Petasites japonicus. The Petasites japonicus extract was done by boiling with distilled water at $100^{\circ}C$ for 1 hour. As mordanting agent, we used Aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$), Copper(II) sulfate pentahydrate ($CuSO_5{\cdot}5H_2O$), Iron(II)Chloride ($FeCl_2{\cdot}4H_2O$). The best K/S value of dyeing temperature and time, all the fabrics were $100^{\circ}C$, 90min. Silk fabric was dyed yellow(0.8Y 7.6/2.2) and nylon fabric was dyed reddish yellow(10.1 YR 7.4/3.0). Silk fabric and nylon fabric was changed greenish yellow on mordanting with $CuSO_5{\cdot}5H_2O$ and $FeCl_2{\cdot}4H_2O$ respectively. And the colorfastness of washing and dry-cleaning was improved by using mordanting agent(4~5 grade). Ultraviolet-cut ability(UV-B) was showed more 90% in dyed nylon fabrics.

대전방지처리된 합성섬유의 대전성에 관한 연구 (Anti-static behavior of Synthetic fabrics treated by anti-static agents)

  • 최석철;김미성
    • 한국의류학회지
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    • 제11권1호
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    • pp.51-62
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    • 1987
  • In this study, electrostatic behavior of polyester and nylon fabric treated with anti-static agents were investigated. The effects of the concentration of the agents and curing conditions on the electrostatic charge of the fabrics were studied. And washfastness, lightfastness and physicalproperties of the treated fabrics were also investigated. The results were as follows: 1) Polyethylene glycol alkylester was more effective in antistatic behavior than polyethylene laurylphosphate, and polyester is more effective in anti-static behavior than nylon. 2) Concentration of anti-static agents were suitable in concentration of $4\%$. 3) Glyoxal resin was more effective in anti-static behavior than melamine resin, and it was also good in the retaing anti-static behavior after treatments of lightfastness and washfastness. 4) As the condition of curing treatment, $190^{\circ}C$, 1min. for glyoxal resin and $130^{\circ}C$, 4min. for melamine resin is appropriate. 5) In comparison of anti-static behavior according to treating conditions, the simultaneous treatment was more effective than any other treatments. 6) Change of electrostatic charge of anti-static nylon cloths after treatments of lightfastness and washfastness increased greatly in above 10 laundering time and 20 fade-O-meter time. 7) In physical properties according to concentration of treating agents. decrease of physical properties scarcely appeared in concentration of treating agents $4\~5\%$.

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STUDIES ON PROTEIN DEGRADABILITIES OF FEEDSTUFFS IN BANGLADESH

  • Khandaker, Z.H.;Tareque, A.M.M.
    • Asian-Australasian Journal of Animal Sciences
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    • 제9권6호
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    • pp.637-642
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    • 1996
  • This experiment was conducted to determine RDP values of locally available feedstuffs that are commonly used in ruminant rations in Bangladesh. Four cattle were fistulated in the rumen for the in situ nylon bag studies. Seventeen different feedstuff sample (9 roughages and 8 concentrates) were evaluated in $4{\times}14cm$ nylon bags and incubated in the rumen for different periods of time (2, 6, 12, 24, 48 and 72 h). The variation in crude protein (CP) contents reflected on the average CP disappearance value throughout the rumen incubation. Soluble fraction (a), insoluble but degradable fraction (b) along with the rate of degradation also varied widely among the various feedstuffs. Under 2% of rumen outflow rate, the percentages of the calculated protein degradabilities of roughages were rice straw, 16.7; maize grass, 70.6; oat grass, 70.8; dhal grass, 71.1; sunhemp, 78.4; napier grass, 62.4; matikalai grass, 72.1; khesarikalai grass, 76.9 and daincha browse, 78.4, respectively. The results in the protein degradabilities (%) in 8% ruminal outflow rate of concentrates were wheat bran, 61.6; rice polish (red), 61.3; rice polish (auto), 30.9; mustard oil cake, 71.8; sesame oil cake, 74.2; coconut oil cake, 57.9; soybean meal, 49.2 and fish meal, 37.9, respectively.

미성숙 돼지 난자의 유리화 동결에 관한 연구: Open Pulled Straw(OPS), Electron Microscopic Grid(EMG) 및 Nylon Loop System(NLS)의 비교 (Study of Vitrification of Immatured Pig Oocytes: Compared with Open Pulled Straw(OPS), Electron Microscopic Grid(EMG) and Nylon Loop System(NLS))

  • 김인덕;안미현;석호봉
    • 한국수정란이식학회지
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    • 제19권1호
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    • pp.27-34
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    • 2004
  • This study evaluated the efficiency and compared with different materials of loading vessels for vitrification-plastic/glass, copper grid and nylon. The loading method, vitrification, cryop-reservation and warming method of the oocytes were examined. The loading samples prepared in manual or company-made and sterilized, loaded the COCs selected on each samples and cultured for maturation during 40 hours, and then exposed sequentially to ethylene glycol solution. Thawing method was reversely treated and exposed for warmed oocytes. After oocytes were thawed, fertilized and cultured in vitro for 3-4 hours, rates of development and morphological appearance were examined. The results were as summarized: ㆍOPS from company-made or hand-made of the hematocrit micropipettes, NLS from fishing line and EMG from company-made for EM were used for loading oocytes, respectively. ㆍThe efficiency of freezing method and loading convenience were orderly higher in OPS, NLS and EMG. The optimal capacity per vessel was orderly lowered in NLS, EMG and OPS, respectively. ㆍAfter oocytes were warmed, the recovery rate, morphology and rate of development were orderly higher in OPS, NLS and EMG, respectively. ㆍIn conclusion, OPS has the advantages of achieving a little more survival and preserving results than other two loading methods.