Laboratory-scale experiments were conducted using a three-stage rotating biological contactor unit followed by lime precipitation and sedimentation with effluent recycle to the first stage. The purpose of this study was to evaluate the effects of hydraulic loadings of 0.031-0.076 $m^3/m^2/d and recycle ratio of 1 to 3 on the simultaneous removal of organics and nutrients from domestic wastewater. Lime was added to maintain pH of 10.4-11.0 in the coagulation-flocculation reactor. Results showed that the highest nitrogen removal rate of 70.5% occurred at the lower hydraulic loading of 0.031 $m^3/m^2/d at a recirculation rate of 300%, and similarly, highest nitrification occurred at the same hydraulic loading and recycle ratio. Concentration of ammonia nitrogen in the effluent was less than 1 mg/l at the same operating conditions for higher nitrogen removal. Whereas, high BOD and COD removal was observed at hydraulic loading rate of 0.054 $m^3/m^2/d, and high removal of organic matter was evident from the consistent low COD and BOD value. Results obtained from the operating condition of higher loading rate, 300% of recycle rate showed the highest removals. Increasing in recycle rate and hydraulic loading rate increased the volatile solids fraction of the sludges generated to the extent of 47% at 0.076 $m^3/m^2/d hydraulic loading and 300% recirculation rate. Since pH in the flocculator was maintained at the pH of 10.4-11.0, above 90% removal of phosphorus was obtained. Average concentration of suspended solids was always maintained over 40 mg/l in the effluent. Therefore an RBC unit operating at a hydraulic loading near 0.031 $m^3/m^2/d with a recycle rate of 300% is a viable and feasible alternate conditions to produce an effluent with relative low organic matter and phosphorus, provided that there is a neutralization unit to control the pH and SS of the effluent.
Journal of the Korea Academia-Industrial cooperation Society
/
v.17
no.11
/
pp.186-195
/
2016
We investigated phytoplankton and vertical inorganic nutrients at two stations around water of Ulleungdo and Dokdo in the East Sea, Korea. Nutrient addition experiments (+N, +P, +NP and +Fe) were also conducted to determine the growth response and nutrient consumption of the phytoplankton assemblage using the surface water of St. UD3 and St.50. In the field, although inorganic nutrients were low in the euphotic layer, these nutrients were increased at depths below 100 m. The total phytoplankton abundances in St. UD3 and St.50 were $4.9{\times}10^5cells\;L^{-1}$ and $1.9{\times}10^5cells\;L^{-1}$, respectively. The dominant species at St. UD3 was observed to be Raphidophyta Heterosigma akashiwo, Cryptophyta Crytomonas spp., and diatom Leptocylindrus danicus, while L. danicus and H. akashiwo including small diatom species Chaetoceros socialis were dominant at St. 50. In the nutrient addition experiments, phytoplankton growth (in vivo flourescence) in the +N and +NP treatment was 2-3 times higher than that in the +P treatment, indicating that the natural phytoplankton can respond to pulsed nutrient loading events. In addition, in vivo fluorescence in +Fe treatment was not statistically (p>0.05) different from that of the non-Fe treatments, indicating that the phytoplankton growth response in +Fe treatment was not significant. Dominant H akashiwo and L. danicus in the field showed a rapid response in nutrient additional bio-algal assay, particularly L. danicus in the +Fe treatments.
The Keum river is one of the important river in Korea and has a drainage area of 9,873$\textrm{km}^2$. The Keum river is deepening pollution state due to development of the lower city and construction of a industrial complex. The water quality of the Keum river come to eutrophication state and belong to III grade of water quality standard. The concentration BOD in river is affected by the organic loading from a tributary and the algae biomass that largely happen to under eutrophication state. In the eutrophic water mass such as the Keum river, the autochthonous BOD was very important part for making a decision of water quality management, because it was accounted for majority of the total BOD. The purpose of this study was to survey the chatacteristics of water quality in summer and to estimate reaction coefficient. Also, we studied to correlationship between chlorophyll a and BOD(COD) for estimation of the autochthonous BOD. The correlationship between chlorophyll a and BOD(COD) were obtained through the culture experiment of phytoplankton in the laboratory. The results of this study may be summarized as follows ; The characteristics of water quality in summer were belong to III~IV grade of water quality standard as BOD and nutritive condition is very high. The BOD, ammonia nitrogen and phosphate loadings in Miho stream which inflowing untreated sewage from Chungju city was occupied with 64.07%, 26.36%, 46.08%, respectively. Maximum nutrient uptake (Vmax) was 0.4400$\mu$M/hr as substrate of ammonia nitrogen, 0.1652$\mu$M/hr as substrate of phosphate. Maximum specific growth rate ($\mu$max) was 1.2525$hr^{-1}$ as substrate of ammonia nitrogen, 1.5177$hr^{-1}$ as substrate of phosphate. The correlation coefficient between chlorophyll a and BOD by the culture experiment were found to be 0.911~0.935 and 0.942~0.947 in the case adding nutrient and no adding nutrient, respectively. The correlation coefficient between chlorophyll a and COD through the culture experiment were found to be 0.918~0.977 and 0.880~0.931 in the case adding nutrient and no adding nutrient, respectively. The autochthonous BOD(COD) was estimated to the relationship between BOD(COD) and chlorophyll a. The regression equation were found to be autochthonous BOD=(0.045~0.073)${\times}chlorophyll$ a and autochthonous $COD=(0.137~0.182){\times}chlorophyll$ a.
This study was carried out to develop the new process for RBC process which is capable of nutrient removal and to obtain its design parameters for Sludge Settling Type Rotating Biological Contactors by comparing RBC with RBC combined with HBR (Hanmee Bio-Reactor). To achieve more than 90% of organic removal efficiency, organic loading rate less than $6.0g\;BOD/m^2/d$ is recommended. Nitrification rate was about 90% at $6.0g\;BOD/m^2/d$. TN removal efficiency of RBC+HBR was higher than those of RBC1 and RBC2. TN removal efficiency at condition of $5.0g\;BOD/m^2/d$ was about 60% in RBC1. When BOD loading rate was $6.0g\;BOD/m^2/d$. TN removal efficiencies in RBC2 and RBC+HBR were about 70%, 80%, respectively. TP removal efficiency was more than about 67% for RBC1, about 63% for RBC2 and about 71 % for RBC+HBR at the same loading rate. From the blank experiment to observe removal efficiency in the first stage, it can be known that COD removal efficiency was about 30% and suspend solids settling rate was about 45%. It was proved that RBC+HBR is much better in sludge dewatering than RBC.
These experiments investigated the conditioning pattern and the nitrification efficiency of a fluidized sand biofilter (FSB) for seawater application. The FSB fed artificial nutrient was fully conditioned within 22 weeks. The maximum nitrification efficiency of the FSB was achieved at a superficial water velocity (SWV) of 1.0 cm/sec. After fixing the superficial water velocity at 1.0 cm/sec, the nitrification rates of the FSB were assessed at 3 total ammonia nitrogen (TAN) loading rates (250, 500, 1,000 g TAN/$m^3$/day) and 3 water temperatures (12, 16, $20^{\circ}C$). The TAN concentration in the simulated culture tank ranged from 2.87 to 9.72 mg/L at TAN loading rate of 1,000 g TAN/$m^3$/day, while that ranged from 0.45 to 1.26 mg/L at TAN loading rate of 500 g TAN/$m^3$/day. The ranges of TAN concentration in the former were too high for aquatic organisms and those in the latter were acceptable. Therefore, the safe TAN loading rate for the FSB in seawater conditions was decided as 500 g TA/$m^3$/day. From these results, daily TAN removal rates (g TAN/$m^3$/day) of FSB under conditions of inlet TAN concentration (C, mg/L) and water temperature (T, $^{\circ}C$) were calculated by the following non-linear multi-regression equation: TAN removal rate: f(z)=-1,311.295+655.714LnT+225.775LnC ($r^2=0.962$).
Kim, Ye-Jin;Ahn, Yu-Ga;Kim, Hyo-Su;Shin, Jung-Phil;Kim, Chang-Won
Journal of Korean Society of Environmental Engineers
/
v.31
no.2
/
pp.102-108
/
2009
DO, ORP and pH values measured during SBR operation can provide information about removal reaction of organic contaminants and nutrient materials in the reactor. It is already generalized control strategy to control reaction phase time using their special patterns indicating the end of the removal reactions. However, those informations are limited to point out the end time of oxidative reaction in the aerobic phase or reductive reaction in the anoxic phase without giving quantitative value of influent loading level. In this research, a diagnosis algorithm which can estimate the loading level of carbon and ammonia as high, medium and low was developed using the basic measurements like DO, ORP, and pH. It will be possible to know the level of influent loading rate from those online measurements without experimental analysis.
Animals are one of the important memberships of the food chain. The low-efficiency rule of nutrient transfer from one member to the next in the food chain determines the low efficiency of animal agriculture for human food. On the average, about 20% feed proteins and 15% feed energy can be converted into edible nutrients for humans. The rest proportion of feed nutrients is exposed to the environment. Environmental pollution, therefore, is inevitable as animal agriculture grows intensively and extensively. The over-loading of the environment by nutrients such as nitrogen, phosphorus from animal manure results in soil and water spoilage. The emission of gases like $CH_2$, $CO_2$, $SO_2$, NO, $NO_2$ by animals are one of the contributors for the acidification of the environment and global warming. The inefficient utilization of natural resources and the probable unsafety of animal products to human health are also a critical environmental issue. Improving the conversion efficiency of nutrients in the food chain is the fundamental strategy for solving environmental issues. Specifically in animal agriculture, the strategy includes the improvements of animal genotypes, nutritional and feeding management, animal health, housing systems and waste disposal programs. Animal nutrition science plays a unique and irreplaceable role in the control of nutrient input and output in either products or wastes. Several nutritional methods are proved to be effective in alleviating environmental pollution. A lot of nutritional issues, however, remain to be further researched for the science of animal nutrition to be a strong helper for sustainability of animal agriculture.
This study was performed to investigate the reaction characteristics of piggery wastewater for biological nutrient removal. The reaction characteristics were discussed the fraction of organics, the behavior of nitrogen, nitrification, denitrification, and the behavior of phosphorus. The fraction of readily biodegradable soluble COD was 11-12 percent. The ammonia nitrogen was removed via stripping, nitrification, autotrophic cell synthesis, and heterotrophic cell synthesis. The removal percents by each step were 12.1%, 68.9%, 15.0%, and 4.0%, respectively. Nitrification inhibition of piggery wastewater was found to occur at an influent volumetric loading rate over 0.2 NH$_{3}$-N kg/m$^{3}$/d. Denitrification rates were the highest in the raw wastewater and the lowest in the anaerobic effluent. The denitritation of piggery wastewater came out to be possible, and the rate of organic carbon consumption decreased about 10 percent. The phosphorus removed was released in the form of ortho-p in the aerobic fixed biofilm reactor, it was caused by autooxidation. The synthesis and release of phosphorus were related to the ORP and the boundary value for the phase change was about 170mV. In the synthesis phase, the phosphorus removal rate per COD removed was 0.023mgP$_{syn}$/mgCOD$_{rem}$. The phosphorus contents of the microorganism were 4.3-6.0% on a dry weight basis.
Nonpoint source pollution has become a concern for water quality in the Han River system, especially during the high runoff events during the monsoon season. The patterns in nonpoint source runoff the relationships with land use, rainfall intensity, and stream nutrients concentrations were surveyed in 19 streams in the Han River watershed. The results show that the magnitude of NPS inputs of nutrients and sediment in the Han River watershed are of a serious concern. In the South Han River watershed, event mean concentrations (EMC) for biochemical oxygen demand (BOD), suspended sediment (SS), dissolved organic carbon (DOC), dissolved total phosphorus (DTP), total nitrogen (TN) Nitrate ($NO_3$-N) and total phosphorus (TP) were $1.94mg{\cdot}L^{-1},\;251mg{\cdot}L^{-1},\;2.75mg{\cdot}L^{-1},\;0.076mg{\cdot}L^{-1},\;2.82mg{\cdot}L^{-1},\;2.40mg{\cdot}L^{-1}$ and $0.232mg{\cdot}L^{-1}$, respectively. In the North Han River watershed, EMCs for BOD, SS, DOC, DTP, TN, $NO_3$-N and TP were $1.34mg{\cdot}L^{-1},\;172mg{\cdot}L^{-1},\;2.63mg{\cdot}L^{-1},\;0.032mg{\cdot}L^{-1},\;1.97mg{\cdot}L^{-1},\;1.55mg{\cdot}L^{-1}$ and $0.148mg{\cdot}L^{-1}$, respectively. The specific export coefficients of nutrient and sediments were much higher than those of other reports. Our study also found that the proportion of agricultural field area was significantly correlated with the EMCs for nutrients. Therefore, efforts to reduce NPS loading must focus on agricultural practices in the watershed. The relationships between land use and nutrient and sediment export found in this study can be used to derive estimates of runoff coefficients for agricultural field and as input data for modeling works and to develop total maximum daily load and best management practices in the Han River watershed.
Water quality model applicable paddy field was developed using field experiment during 1999 ${\sim}$ 2002. This model involves inputs from fertilization and sediment release as dirac delta function and continuous source function, respectively, and can simulate various processes such as ponded depth, surface drainage, total nitrogen concentration and total phosphorus concentration in a daily basis. The model was calibrated using data collected from field experiments which was irrigated with ground water and validated from field experiments which was irrigated with surface water. The nutrient concentration of surface water depended on the fertilization and dirac delta function can efficiently explain the valiance of nutrient concentration of surface water by fertilizer. As a result of calibration and validation, this model demonstrates good agreement. The model fit efficiencies ($R^2$) of ponded depth, surface concentration of TN and TP were 0.93,0.98 and 0.95, respectively for calibration, and those of TN and TP were 0.99 and 0.70, respectively for validation. We can apply lake and reservoir model to analysis paddy field considered with shallow ponded system, but it will need so many parameters and have much uncertainty. Fortunately, paddy field have a series of cultural practices yearly basis, such as irrigation-fertilization-forced drain-harvest with a similar time , so simple model may explain the mechanism for paddy field. Water quality model for paddy field developed in this study is simply, needs little parameters, but appeared high applicability to evaluate paddy filed drainage. We recommend this model to estimate nutrient loading from paddy field and establish best management practice.
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