• Title/Summary/Keyword: norbornane

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A Study on the Synthesis and Property of Norbornane Type Carbocyclic Compounds that Include 3-membered Fused Ring System (삼각고리를 포함한 Norbornane 골격을 가진 화합물의 합성 및 물성에 관한 연구)

  • Oh Chang-Ho;Han Jeong-Sik;Park Dai-In;Ryu Joong-Hyun;Cho Joon-Hyun
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.202-205
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    • 2006
  • Some advanced nations have already developed and utilized high performance carbocyclic compounds as liquid fuel components. The common point of these compounds includes polycycles. We synthesized some promising compounds which include multiplex ring form. According to three kinds of cyclopropanation method, we could synthesize five target materials and measure their physical properties.

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Polymaleimide Copolymers with Norbornane units for Polymeric Optical Waveguides

  • Park, Ki-Hong;Kim, Won-Lae;Lee, Chul-Joo;Han, Kwan-Soo;Han, Hak-Soo
    • Journal of Photoscience
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    • v.9 no.1
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    • pp.23-28
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    • 2002
  • In order to obtain thermal-stable, low birefringent, and low optical loss waveguiding materials, we synthesized several fluorinated poly (maleimide-co-glycidylmethacrylate)s using a pentafluorophenylmaleimide (PEM) and two kinds of methacrylate derivatives as comonomers and glycidylmethacrylate as a crosslinker. One comonomer is a linear fluorinated methacrylate (HFBM) and another is a bulky norbornane-derived methacrylate (NMMA). These copolymers could be self-crosslinked by heating due to epoxy groups of glycidylmethacrylates. As a maleimide contents increased to 50 mol%, these copolymers showed high decomposition temperatures of above 300$^{\circ}C$. The refractive index could be precisely controlled by the variation of PFM/HFBA or PFM/NMMA feed ratio in the range of 1.410∼1.508 at 643 nm. The copolymers had very low birefringence in the range of 1∼5${\times}$10$\^$-4/.

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Study on Properties of High Energetic and High Dense Cyclic Hydrocarbons by the Structure (고에너지 고밀도 고리탄화수소 화합물의 구조에 따른 물성 연구)

  • Cho, Joon-Hyun;Kwon, Tae-Soo;Jeong, Deok-Jin;Oh, Chang-Ho;Park, Dae-In;Han, Jeong-Sik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.463-466
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    • 2008
  • The weapon systems with a liquid propulsion engine have been used for various purposes and demands of the liquid fuel with variety of properties for its operational purposes and environment. The cyclic hydrocarbons including norbornane or dicyclopentane structures have many applications to the guided weapon systems due to the high density and high energy characteristics, also efforts have been given in many fields. In this study, the cyclic hydrocarbons that we designed and fabricated were investigated to obtain tendency on the structures.

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