Volcanic Ash Soils are widely distributed in Jeju island, and constitute the important upland soils which are either presently being cultivated or are suitable for reclaiming. The characteristics of Volcanic Ash Soils according to data made available by previous studies in Jeju and the outside of the country are as following: The most conspicuous mineralogical property is the presence of amorphous mineral colloids. The colloids have large and highly reactive surface to which the common physical and chemical properties are related. Soils are low in bulk density and higher both in porosity and permeability. Accumulation of humus in the upper part of soil is found in great quantity. Cation exchange capacity is high mainly due to high humus content, but the absorbing intensity of ammonium and potassium is weaker than that of crystalline clays. The phosphate absorption coefficient is extremely high and deficiency of minor element may occur both crops and animals. Soils are densely populated with actinomycetes and anaerobic bacteria. Nitrification and activity of urease are distinctly stronger than that of non-Volcanic Ash Soils.
The effect of soil forming factors on the pedogenesis of basaltic volcanic ash soils and the influence of allophane material on soil properties have been investigated on 5 chronosequence soils situated from at the near sea coast up to the foot slope of Mt. Halla in Jeju Island. Time seems to be the important soil forming factor which today differentiates soil of the Island. Songag and Donghong soils developed in lower elevations are older and somewhat less influenced by ash shower. However, soils developed at higher elevations, Pyeongdae and Heugag, are rather younger and strongly influence by the ash. It is also proved that the parent materials are very heterogeneous. They mainly are basaltic with some contamination of acidic volcanic ashes and continental aeolian deposits where a considerable amount of quartz encountered in most soils studied. Many physico-chemical properties of soil, such NaF pH, phosphate sorption power, pH and extractable acidity are parameters to differentiate andepts and non-andeptic soils.
This study was conducted to determine effects of composted livestock manure application on soil nutrient change. PVC pot $(30\times100cm)$ was filled with either volcanic ash soil (Gujwa series) or non-volcanic ash soil (Aewol series) and the 20 cm surface soils were applied with composted livestock manures of cattle pig and poultry at the rates of 0, 50, 100 and 150 ton/ha, respectively. After 210 days soils samples of phosphate, potassium, calcium, and magnesium affected by application of the compost. The applied composted were equivalent to the application of organic matter of $23\sim111$ ton/ha and nitrogen of $80\sim450$ ton/ha. Availability rate of phosphate after the application of composted livestock manures ranged from 1.6 to 91.7% according to the different composted. It was much higher in the non-volcanic ash soil than in the volcanic ash soil. Availability rate of potassium fractional recovery rate change ranged from 22 to 94% according to the different manures. It was larger in the composted Availability rate of calcium 38 to 93% and $9\sim90%$ in volcanic ash soil and non-volcanic ash soil, respectively, It was higher in the composted manures followed by cattle and composted pig manures. Availability rate magnesium ranged from 12 to 41% and $1\sim9%$ in volcanic ash soil and non-volcanic ash soil, respectively. The rate was higher in the composted poultry manure followed by pig and composted cattle manures.
Recently, saw dust manure has been widely used in horticultural crop production in Korea. Animal manure is produced by decaying of livestock manure mixed with saw dust, and contained higher nutrients and ion concentration than the traditional manure made from rice straw and grasses. Therefore, a continuous application of the animal manure disregarding to soil characteristics may be ruined the soil conditions. This study was conducted to investigate the transportation of the nitrogen, phosphate, potassium, and ion concentration of the animal manure applied to volcanic and non-volcanic soils in Jeju islana Soil chemical analysis were done before and 180 days after animal manure application. After animal manure application, $NO_3$-N moved up to 90cm in volcanic soil, while the movement was limited to 60 cm in non-volcanic soil. Phosphate concentration was high up to 30 cm, where crop roots are mainly distributed, in volcanic soil, however, the phosphate moved up to 60 cm in volcanic soil. Exchangeable potassium moved up to 90 cm in volcanic soil, but the movement wns limited up to 60 cm in non-volcanic soil. For both soil types, no significant different in ion concentrations was observed up to 60 cm in soil depth, though the concentrations were higher in volcanic ash soils as compared to the non-volcanic ash soils.
Capacitance soil moisture sensor is extensively used by soil research and irrigation management with its convenience and accuracy. This experiment was conducted to evaluate the acceptability of capacitance soil moisture sensor, named EnviroSCAN made by Sentek Ltd., in Jeju Island where volcanic ash soils are widely distributed, and to calibrate it to various soils with different amount of soil organic matter. For sensor calibration equation of volcanic ash soils, a logarithm function is better than a typical power function of non-volcanic ash soils. So there are possibilities of under evaluated in soil water contents in very wet and very dry conditions by using typical power function with volcanic ash soil areas. We suggested practical coefficients of typical calibration equation for using capacitance sensor in volcanic ash soils, also suggested equations for estimation of them with soil organic matter contents. The measurement of soil water content with a capacitance sensor can be affected by some soil characteristics such as porosity, soil organic matter content, EC, etc. So those factors should be controlled for improving the accuracy of measurement.
Contamination of groundwater by agrochemicals used in the regional-scale Is now a major environmental problem, and this is especially true for Cheju island where virtually all potable water is from groundwater. The objective of this study was to assess leaching potential of eight pesticides in soils of citrus orchards using groundwater ubiquity score (GUS), retardation factor (RF) and attenuation factor (AF). Considering GUS estimated in 30 citrus orchard soils, metribuzin and metolachlor were classified as leacher, alachlor in volcanic ash soils and linuron in non-volcanic soils were classified as leacher, but chlorothalonil and chlorpyrifos were classified as non-leacher. For RF values, metribuzin was classified to be mobile in soils of low organic carbon, metolachlor and alachlor were classified to be moderately immobile in most soils, but linuron, diuron, diniconazole, chlorothalonil and chlorpyrifos were all classified to be very immobile. For AF values, diniconazole, chlorothalonil, and chlorpyrifos were classified to be very unlikely leachable in all of the soils, metribuzin was classified to be likely leachable, and metolahclor, alachlor, linuron and diuron were classified to be leachable only in non-volcanic soils. Although there were some variations in the relative potential of teachability of pesticides estimated with the three different indices, the ranking was essentially determined on the base of the intrinsic properties of the chemicals and environmental properties. Among the eight pesticides, metribuzin, metolachlor, and alachlor, which have high water solubility and low $K_{oc}$ values, have a significant leaching potential especially in non-volcanic ash soils of low organic carbon. But diniconazole, chlorothalonil, and chlorpyrifos, which have low water solubility and high $K_{oc}$ values, were classified to be very immobile in all of the soils. Therefore, to lower the possibility of pesticide contamination of the groundwater in Cheju island, those pesticides which have high water solubility and low $K_{oc}$ values should be used with care in soils of low organic carbon including non-volcanic ash soils.
Laboratory experiments on the phosphorus adsorption by soil were conducted to evaluate the parameters for determination of phosphorus adsorption capacity of soil, which serve as a basis for establishing the amount of phosphorus required to improve newly reclaimed soil and volcanic ash soil. The calculated Langmuir adsorption maxima varied from 6.2-32.9, 74.7-90.4 and 720-915mg p/100g soil for cultivated soils, non-cultivated soils, and volcanic ash soils respectively. The phosphorus absorption coefficient ranged from 116-179, 161-259 and 1,098-1,205mg p/100g soil for cultivated soils, non-cultivated soils, and volcanic ash soils respectively. The ratio of the phosphorus absorption coefficient to Langmuir adsorption maximum was low in soils of high phosphorus adsorption capacity (1.3-1.5) and high in soils of low phosphorus adsorption capacity (2.2-18.7). Changes in the amount of phosphurus adsorption induced by liming and preaddition of phosphorus were hadly detected by the phosphorus absorption coefficient, which is measured using a test solution with a relatively high phosphorus concentration. The Langmuir adsorption maximum was a more sensitive index of the phosphorus adsorption capacity. The Langmuir adsorption maxima of the non-cultivated soils, which were treated with an amount of calcium hydroxide equivalent to the exchangeable Al and incubated ($25-30^{\circ}C$) for 40 days at field capacity, were lower than the original soils. The change in the adorption maximum on incubation following the liming of soils was insignificant for other soils. The secondary adsorption maximum of soils, which received phosphorus equivalent to the Langmuir adsorption maximum of the limed soils incubated ($25-30^{\circ}C$) for 50 days at held capacity, was 74.5, 5.6 and 23.8% of the primary adsorption maximum for volcanic ash soils, non-cultivated soils, and cultivated soils respectively. The amount of phosphorus adsorbed by soils increased quadratically with the concentration of phosphorus solution added to the soils. The amount of phosphorus adsorbed by 5-g soil samples from 100ml of 100- and 1,000mg p/l solution for the mineral soils and volcanic ash soils respectively was found to be close to the Langmuir adsorption maximum. The amount of the phosphorus adsorbed at these concentrations is defined as a saturation adsorption maximum and proposed as a new parameter for the phosphorus adsorption capacity of the soil. The evaluation of the phosphorus adsorption capacity by the saturation adsorption maximum is regarded as a more practical method in that it obviates the need for the various concentrations used for the determination of the Langmuir adsorption maximum.
The volcanic ash soils from the Jeju province have low available phosphate because of the high phosphate fixing power of the soils. Phosphorus fertilizerwas dressed after cultivating green manure crops and before cultivating potatoes in order to investigate potato yields, the available phosphate contents, and phosphorus balance in the soils. Green manure crops cultivated in this study were hairy vetch alone and hairy vetch and rye. During potato cultivation, four treatments were conducted in the experiments; NF (non fertilizer), P fertilizer ($N-P-K=0-25-0kg\;10a^{-1}$), NK fertilizer ($N-P-K=18-0-19kg\;10a^{-1}$), and NPK fertilizer ($N-P-K=18-25-19kg\;10a^{-1}$). There were no differences in the yields of potato stem and tuber from the cultivation plots of different green manure crops. However, in the plots with single-sown hairy vetch and mixed-sown hairy vetch and rye, the yields of potato stem and tuber were higher in the P fertilizer plot than in NF plot. The yield of tuber among the treatments with mixed-sown hairy vetch and rye was the highest in the NPK fertilizer plot. The available phosphate content in soils initially increased with time in all plots, but began to decrease gradually after Oct. 18. The available phosphate contents were high in the plots for phosphate fertilization, and the difference in available phosphate content between non-phosphorus fertilizer plots and phosphorus fertilizer plots increased with time. In the single-sown hairy vetch and mixed-sown hairy vetch and rye plot, the phosphorus balances in NF plot and NK fertilizer plot were very low, while those in the P fertilizer plot and NPK fertilizer plot were high. In conclusion, available phosphate contents in soil and the potato yields were increased by phosphorus fertilization when potatoes planted after cultivating hairy vetch and rye together, compared to hairy vetch alone.
This study was conducted in Jeju Island to find the effects of livestock manure application on the changes in soil salt concentration and $NO_3-N$ contents. Soil samples were collected from Goojua-Tong (volcanic ash soil) and Aewol-Tong(non-volcanic ash soil) to 50 cm depth and were mixed with livestock manure to 20 cm depth in PVC container(30 cm diameter, 1 m height). Animal manures of cattle, pig, and fowl were adjusted to 0, 50, 100,150 ton/ha. Animal manure applications increased the salt concentrations in soil. The salt concentration was increased as the fowl manure amount was increased The effects were larger in order of fowl manure > cattle manure $\fallingdotseq$ pig manure. $NO_3-N$ contents in soil showed a sharp increase by applications of fowl manure, but the increase was slow when the cattle and pig manures were applied. In volcanic ash soil, there was no change in phosphate contents by application of animal manures, but the phosphate contents increased in non-volcanic ash soil with the application of animal manure, especially by fowl manure.
A pot experiment was conducted to find out suitable method in determining the rate of phosphorus application. Soybean was planted under optimum moisture condition. The soils used in this experiment were cultivated and non-cultivated mineral soils, and volcanic ash soils. The results were summarized as follows: 1. Phosphorus adsorption maximum(PAM) was the good parameters to determine phosphorus adsorption capacity of all tested soils. 2. Phosporus adsorption maximum was increased with the content of ammonium acetate extractable aluminum, and the organic matter effects on PAM was considerably high in volcanic ash soils. 3. Requirement of phosphorus for maximum yields were in the range of 30~35% of PAM for tested soils. 4. PAM was considered as a suitable criteria to determine the rate of the phosphorus application and it was also considered to be more attractive than phosphorus absorption coefficient.
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