• 대기
• /
• 제22권2호
• /
• pp.175-186
• /
• 2012

In this study, we investigate the effects of elliptical shape of Asian dust particles on the estimation of aerosol optical depth by implementing T-matrix method into WRF/Chem Dust Model. The phase function calculated by assuming elliptical particle shape near $110{\sim}160^{\circ}$ of scattering angle showed about 20 times larger than that calculated by assuming spherical particle shape. Significant difference of extinction efficiency was found with an increase of size parameter and aspect ratio. From the simulations of two Asian dust events occurred on 1 April 2007 and 16 March 2010, we found that the difference of extinction efficiency between elliptical and spherical particle shape was about 5~8%. The aerosol optical depth calculated by assuming elliptical particle shape with 1.6, 1.4 and 1.2 of aspect ratio was about $4.0{\pm}0.5%$, $2.0{\pm}0.2%$, and $1.0{\pm}0.1%$ larger than those estimated by assuming spherical particle shape.

• 한국분무공학회지
• /
• 제7권2호
• /
• pp.22-30
• /
• 2002

A number of droplet breakup models have been developed to predict the diesel spray. The capabilities of droplet deformation and breakup models such as TAB, ETAB, DDB and APTAB models are evaluated in modeling the non-evaporating diesel sprays injected into atmosphere. New methods are also suggested that take into account the non- spherical shape of droplets and the reduced drag force by the presence of neighbouring droplets. The KIVA calculations with standard ETAB, DDB, and APTAB models predict well the spray tip penetrations of the experiment, but overestimate the Sauter mean Diameter(SMD) of droplets. The calculation with non spherical droplets injected from the nozzle shows very similar results to the calculation with spherical droplets. The drag coefficient which is linearly increased with the time after start of injection during the breakup time gives the smaller SMD that agrees well with the experimental result.

• 한국재료학회지
• /
• 제15권8호
• /
• pp.496-502
• /
• 2005

Green-light emitting $BaMgAl_{10}O_{19}:Mn^{2+}$ (BAM:Mn) phosphor particles were prepared by spray Pyrolysis. The effect of reactor temperature and flow rate of carrier gas in the spray Pyrolysis on the morphology, crystallinity and photoluminescence characteristics under vacuum ultraviolet were investigated. The morphology of the as-Prepared Particles obtained by spray Pyrolysis had spherical shape and non-aggregation characteristics regardless of the reactor temperature. The spherical shape of the as-prepared Particles obtained by spray pyrolysis at low temperature disappeared after Post-treatment. On the other hand the as-Prepared Particles obtained by spray Pyrolysis at $1600^{\circ}C$ maintained spherical shape and non-aggregation characteristics after post-treatment at $1400^{\circ}C$ for 3 h under reducing atmosphere. The BAM:Mn Phosphor Particles Prepared by spray Pyrolysis at different reactor temperatures had pure crystal structure and high photoluminescence intensities under vacuum ultraviolet after post-treatment. BAM:Mn phosphor particles prepared by spray Pyrolysis at low How rate of carrier gas had complete spherical shape and filed morphology and high photoluminescence intensity after post-treatment under reducing atmosphere.

• 한국재료학회지
• /
• 제16권2호
• /
• pp.123-128
• /
• 2006

[ $BaMgAl_{10}O_{19}:Mn^{2+}$ ](BAM:Mn) phosphor particles with spherical shape were prepared by spray pyrolysis from colloidal solution with silica. The phosphor particles prepared by spray pyrolysis from aqueous solution had irregular morphology after high temperature post-treatment. On the other hand, the phosphor particles prepared from spray solution with colloidal silica had spherical shape after post-treatment. Colloidal silica used as additive improved the spherical shape and filled morphology of the precursor particles prepared by spray pyrolysis. The precursor particles with filled structure produced the BAM:Mn phosphor particles with spherical shape and non-aggregation characteristics after post-treatment at $1400^{\circ}C$ under reducing atmosphere. The phosphor particles prepared from colloidal solutions formed the crystal structure of BAM:Mn phosphor irrespective of the silica contents. The BAM:Mn phosphor particles prepared from aqueous and colloidal solutions had similar photoluminescence intensities under vacuum ultraviolet.

• 대한기계학회논문집A
• /
• 제38권9호
• /
• pp.1037-1041
• /
• 2014

반도체 연마용 슬러리를 이온교환법, 가압방법 및 다단계 주입방법으로 제조하여 입자 크기와 형상에 따른 화학적 기계적 연마에 미치는 영향을 연구하였다. 이온교환법을 이용하여 구형의 콜로이달실리카를 크기별로 입자로 제조하였다. 이렇게 제조한 구형의 실리카를 다시 가압방법을 이용해 입자간의 결합을 유도해 비구형의 형상을 가진 콜로이달 실리카를 제조하였고, 이온교환법과 가압방법의 특징을 살려 실리식산을 다단계로 주입하여 입자 표면과 실리식산의 반응으로, 2~3 개의 입자가 결합한 형상의 콜로이달 실리카를 제조하였다. 이렇게 제조한 입자를 CMP 에 적용하여 콜로이달 실리카의 입자 형상에 따른 연마율을 기존의 상용 슬러리와 비교하였다. pH 가 높을수록 연마율은 높아졌고, 입자가 결합한 비구형의 콜로이달 실리카는 가장 높은 연마율과 양호한 비균일도를 나타내었다.

• Korea-Australia Rheology Journal
• /
• 제15권1호
• /
• pp.19-25
• /
• 2003

Since the microstructure of functional thin films depends on the dispersion characteristics of dense slurry, it is important to control the agglomerative nature of slurries under processing. The present authors have been discussing the model prediction of agglomerative nature and local rate of agglomeration in dense suspensions. The experiments have been peformed under shear flow using the nearly spherical and oblate type graphite particles. In this study, the experiment has been conducted using water and glycerol as dispersion media. Stress control type rheometer was used to measure the slurry rheology. Local agglomeration of graphite particles has been predicted by using Usui's model. The experimental results show that both the shape and slurry processing method affect on the local dispersion condition. The agglomeration formed by oblate type graphite particles seems to be more difficult to break up than that of spherical particles.

• 한국환경과학회지
• /
• 제26권12호
• /
• pp.1333-1339
• /
• 2017

Coal-fired power plants emit various Particulate Matter(PM) at coal storage pile and ash landfill as well as the stack, and affect the surrounding environment. Field Emission Scanning Electron Microscopy and Energy Dispersive X-ray analyzer(FE-SEM/EDX) were used to develop identification factor and the physico-chemical analysis of PM emitted from a power plant. In this study, three samples of pulverized coal, bottom ash, and fly ash were analyzed. The pulverized coal was spherical particles in shape and the chemical composition of C-O-Si-Al and C/Si and C/Al ratios were 200~300 on average. The bottom ash was spherical or non-spherical particles in shape, chemical composition was O-C-Si-Al-Fe-Ca and C/Si and C/Al ratios were $4.3{\pm}4.6$ and $8.8{\pm}10.0$. The fly ash was spherical particles in shape, chemical composition was O-Si-Ai-C-Fe-Ca and C/Si and C/Al ratios were $0.5{\pm}0.2$ and $0.8{\pm}0.5$.

• 소성∙가공
• /
• 제25권3호
• /
• pp.195-202
• /
• 2016

Direct laser melting(DLM) is an additive manufacturing process that can produce parts by solidification of molten metallic powder layer by layer. The properties of the fabricated parts strongly depend on characteristics of the metallic powder. Atomized powders having spherical morphology have commonly been used for DLM. Mechanical ball-milling is a powder processing technique that can provide non-spherical solid powders without melting. The aim of the current study was to investigate the effect of powder morphologies on the deposition quality in DLM. To characterize the morphological effect, the performances of spherical and non-spherical powders were compared using both single- and multi-track DLM experiments. DLM experiments were performed with various laser process parameters such as laser power and scan rate, and the deposition quality was evaluated. The surface roughness, cross-section bead shape and process defects such as balling or non-filled area were compared and discussed in this study.

• 대기
• /
• 제30권1호
• /
• pp.75-89
• /
• 2020

Current in-situ airborne probes that measure the sizes of ice crystals smaller than 50 ㎛ are based on the concept that the measured intensity of light scattered by a particle in the forward and/or backward direction can be converted to particle size. The relationship between particle size and scattered light used in forward scattering probes is based on Mie theory, which assumes the refractive index of particle is known and all particles are spherical. Not only are small crystals not spherical, but also there are a wide variety of non-spherical shapes. Although it is well known that the scattering properties of non-spherical ice crystals differ from those of spherical shapes, the impacts of non-sphericity on derived in-situ particle size distributions are unknown. Thus, precise relationships between the intensity of scattered light and particle size and shape are required, as based on accurate calculations of scattering properties of ice crystals. In this study, single-scattering properties of ice crystals smaller than 50 ㎛ are calculated at a wavelength of 0.55 ㎛ using a numerically exact method (i.e., discrete dipole approximation). For these calculations, hexagonal ice crystals with varying aspect ratios are used to represent the shapes of natural small ice crystals to determine the errors caused by non-spherical ice crystals measured by forward scattering probes. It is shown that the calculated errors in sizing nonspherical ice crystals are at least 13% and 26% in forward (4~12°) and backward (168~176°) directions, respectively, and maximum errors are up to 120% and 132%.

• 한국재료학회지
• /
• 제4권8호
• /
• pp.927-933
• /
• 1994

비구형 입자들의 크기와 형태에 따른 침강 특성의 영향을 검토하였다. 비구형입자를 포함하는 서스펜션의 침강에서 $log \mu_{c}$대 $log \varepsilon$로부터 얻은 기울기 지표n값은 형태와 크기가 다른 입자는 같은 부피 농도에서 흡착되는유체량이 달라져 입자크기가 감소하거나 불균일한 경우 증가하는 경향을 나타내었다. 실험결고 비구형입자를 포함하는 서스펜션의 침강에서 기울기 지표 $n_{i}$값에 대하여 $n_{i}=n(a+b/d_{v})$와 같은 식을 얻었으며 이때 a, b는 입자형태에 따른 상수이다.