• 제목/요약/키워드: non-polar

검색결과 431건 처리시간 0.026초

Effects of High-Intensity Ultrasound & Supercritical Nitrogen on PP-MA Reactive Extrusion

  • Sohn, Chang-Hee;Shim, Dong-Chul;Lee, Jae-Wook
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.369-369
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    • 2006
  • Compatibilizers contribute to many processes in polymer industry, such as manufacturing polymer blends and composites. They are usually designed to be block or graft form which is combined in polar and non-polar parts in the first synthesis process level, for example, the general form of maleic anhydride (MA) as a compatiblizer is a grafted counterpart. However, the process of making the compatibilizer is related to the first synthesis level and it has some problems, such as high cost, poor processability, limitation on use and properties, and so on. So, in order to improve its poor processability and overcome the limitation on use, we developed compatibilizers which have various chemical forms by high intensity ultrasound and super critical fluid nitrogen in polymer melt reactive extrusion.

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Estimation of Excited State Dipole Moment of Exalite Dyes by Solvatochromic Shift Studies

  • Inamdar, S. R.;Nadaf, Y.F.;Deshpande, D.K.;Karguppikar, A.M.
    • Journal of Photoscience
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    • 제9권1호
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    • pp.29-32
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    • 2002
  • The solvent effect in a series of polar and non-polar solvents of varying dielectric constants and refractive indices has been investigated by studying electronic spectra (S$_1$band) of a series of exalite laser dyes at room temperature (25$\pm$1$\^{C}$). These data are used to determine the magnitude ($\mu$$\_$e/) and direction ($\theta$) of the electric dipole moments in the first electronically excited state. The results indicate that the observed band systems in these compounds may be attributed to ←$\pi$ transition.

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Reaction of Methanol and Methyl Iodide on ZnO(0001) and ZnO(11-20) Single Crystal Surfaces

  • Doh, Won-Hui;Roy, Probir Chandra;Kim, Chang-Min
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.214-214
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    • 2011
  • The adsorption and reactions of methanol and methyl iodide on ZnO(0001) and ZnO(11-20) single crystal surfaces have been investigated using the temperature programmed desorption (TPD) technique. The interaction of methanol and methyl iodide with ZnO is stronger on the polar ZnO(0001) surface than the non-polar ZnO(11-20) surface. On ZnO(0001), methanol is decomposed to produce formaldehyde and hydrogen. Two desorption features of formaldehyde and hydrogen are observed at around 500 and 580 K. The interaction of methanol and pre-adsorbed hydrogen has been also investigated. The reaction mechanism of methanol on ZnO will be proposed.

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원관내 자성유체의 동적특성 (Dynamic Characteristic of Magnetic Fluids in a Circular Pipe)

  • 유신오;박정우;최병호;서이수
    • 한국자기학회지
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    • 제10권1호
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    • pp.42-47
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    • 2000
  • 본 논문에서는 원관내 횡방향 자장을 인가한 경우에 자성유체의 유동을 이론적으로 연구하였다. 이론식 도출에 있어서 Eringen의 극성이론과 Shliomis에 의해 유도된 지배방정식을 사용했다. 자기적 응답으로서 속도, 와도, 각속도의 분포 및 이론식을 통해서 자성유체는 비뉴우톤 유체임을 나타낸다. 또한, 인가자장이 종방향일때와 비교해서 자성유체의 동적특성을 조사한다. 즉, 자성유체에 영향을 주는 자장의 범위를 극성, 치수 및 자성효과 파라미터를 이용해서 조사한다.

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The $10-{\mu}m$ Noth-Polar Bightening of Juptier: A Dynamical Phenomenon?

  • Kim, Sang Joon;Seo, Haingja
    • 천문학회보
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    • 제40권1호
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    • pp.60.2-60.2
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    • 2015
  • Since its detection in 1980, the $8-{\mu}m$ north-polar brightening of $CH_4$ on Juptier has not moved from $180^{\circ}$ (SysIII) longitude. The $8-{\mu}m$ $CH_4$ brightening is mostly thermal and very similar to that of $13-{\mu}m$ $C_2H_2$ emissions, but the morphology of these hydrocarbon north-polar brightenings are very different from that of the $3-{\mu}m$ $H_3{^+}$ auroral oval suggesting a significantly different excitation process yet unknown heating mechanism. Recently, Kim et al. (submitted to Icarus, 2015) found that that the center of the $3-{\mu}m$ $CH_4$ northern bright spot is located at ${\sim}200^{\circ}$ (SysIII) longitude, which is ${\sim}20^{\circ}$ west from the center of the $8-{\mu}m$ north-polar bright spot, and it does not coincide with the $3-{\mu}m$ $H_3{^+}$ bright spot. They found significantly high temperatures (500 ~ 850K) from $CH_4$ rotational lines on the $3-{\mu}m$ bright spot above the $1-{\mu}bar$ pressure level, while we find cooler temperatures (<350K) over the the $8-{\mu}m$ spot. They also found that the upper states of the $3-{\mu}m$ $CH_4$ bands are mostly populated by non-thermal excitations, such as auroral particle precipitations and/or Joule heatings in contrast to the $8-{\mu}m$ thermal emission. This finding indicates that the $10-{\mu}m$ hydrocarbon brightening is confined to low altitudes below the $1-{\mu}bar$ level eliminating the long-suggested possibility of direct auroral bombardments while opening a new possibility of dynamical origin for the $10-{\mu}m$ brightening.

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남극크릴은 몸체축소를 월동기작으로 사용하는가? (Does Antarctic Krill Employ Body Shrinkage as an Overwintering Strategy?)

  • 주세종;;신형철;김예동;강성호
    • Ocean and Polar Research
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    • 제26권4호
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    • pp.679-684
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    • 2004
  • To determine if Antarctic krill employ body shrinkage as one of its overwintering mechanisms in the field, Euphauia superba and Euphausia crystallorophias were collected during fall and winter in and around Marguerite Bay through US Southern Ocean GLOBEC field programs during fall and winter 2001 and 2002. The relationships between the body length and weight of both krill species were exponentially correlated with no significant differences between the two species (p>0.05). The ratio between eye diameter and body length of individual krill was examined in an expectation that it could be used as an indicator of the body shrinkage as previously suggested by Shin and Nicol (2002). These ratios were significantly different between the two krill species. Especially, E . crystallorophias had bigger eyes than E. superba. In both krill species, eye diameters were highly correlated with body lengths (regression coefficients ${\geq}0.70$). For E. crystallorophias, no significant differences of the ratio of eye diameter/body length were detected between fall and winter. Even though the ratios for E. superba were seasonally varied, it was not clear whether body shrinkage was an actual and critical overwintering mechanism for the krill population found in this study area. These results suggest that some individuals of E. superba might experience the body shrinkage during a part of their liff, but this morphological index alone (eye diameter/body length) may be insufficient to unambiguously separate the shrunk krill from the non-shrunk ones in the field-collected animals.

마찰 저감을 위한 비극성 첨가제에 따른 acrylonitrile butadiene styrene계 플라스틱의 stick-slip 이음 저감 연구 (Study on the reduction of stick-slip noise in acrylonitrile butadiene styrene-based plastics using non-polar additives to reduce friction)

  • 여상준;정예원;최성욱;김효준;박건욱;손민영
    • 한국음향학회지
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    • 제43권1호
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    • pp.49-59
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    • 2024
  • 최근 환경규제가 강화되고 고유가 문제로 인하여 전기차 시장이 점차 커지고 있으며 또한 내연기관 자동차에서도 엔진의 Noise, Vibration, Harshness(NVH) 관련 소음이 저감되고 외부에서 유입되는 소음의 차폐 기술이 발전됨에 따라 Buzz, Squeak, Rattle(BSR) 이음의 민감도가 증가하는 추세이다. 본 연구에서는 자동차의 Panoramic Curved Display(PCD)에서 발생하는 Stick-slip 이음과 고분자 플라스틱의 표면에너지 및 극성 성분과의 상관관계에 대하여 분석하였다. 극성 고분자 소재인 Acrylonitrile Butadiene Styrene(ABS)와 PolyCarbonate-Acrylonitrile Butadiene Styrene(PC-ABS)를 대상으로 컴파운드 소재를 제작하여 평가하였다. 결과적으로 고분자 플라스틱의 극성성분이 3.86 mN/m 이상일 때 Stick-slip 거동이 발생하였으며, 시간에 따른 마찰 거동에서 absolute transition slope가 증가할수록 Stick-slip의 이음 가능성이 증가하고 마찰계수의 값 차이가 클수록 Stick-slip 이음의 세기가 증가하였다.

무극성 플라스틱 소재용 잉크 개발 및 소재의 부착성에 관한 연구 (A Study on Ink of Nonpolar Plastic Material and Material Adhesive Property)

  • 허경영;조가람;구철회
    • 한국인쇄학회지
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    • 제28권2호
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    • pp.13-30
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    • 2010
  • Existing domestic ink market had some problem because of dependence on CPP import, increasing cost, competitive price. For this reason, previous speed of research and developments are very slow. Therefore, develop the new waterborne type of non-chlorine resin, enhance the nation's position with manufacturing outstanding products. Through this thesis, the purpose is mix the polar resin and non-chlorine resin with many proportion and manufacturing better product than existing resin. Pilot production samples have run the test of adhesion, transparency, water resist and resist high pressure car washing. In conclusion, this thesis found that mix acryl Urethane resin and Non-Chlorine resin is the optimum condition.

Orthogonal NOMA Strong Channel User Capacity: Zero Power Non-Zero Capacity Transmission

  • Chung, Kyuhyuk
    • 전기전자학회논문지
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    • 제23권2호
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    • pp.735-738
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    • 2019
  • Recently, orthogonal non-orthogonal multiple access (O NOMA) with polar on-off keying (POOK) has been proposed to mitigate the severe effect of the superposition. However, it is observed that the performance of the O NOMA strong channel user is better than that of the perfect successive interference cancellation (SIC), i.e., the performance of a single user transmission with binary phase shift keying (BPSK). Can the performance of the BPSK modulation be better that that of itself? It is not normal. It should be clearly understood theoretically, with the ultimate bound, i.e., the channel capacity. This paper proves that the channel capacity of the O NOMA strong channel user is non-zero with zero power allocation. Thus, it is shown that the interference is transformed effectively into the meaningful signal.

인 결핍에 따른 하수배양 미세조류의 지방산 특성 분석 연구 (Effects of Phosphorus Starvation on Fatty Acid Production by Microalgae Cultivated from Wastewater Environment)

  • 우성근;박준홍
    • 대한토목학회논문집
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    • 제32권4B호
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    • pp.253-259
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    • 2012
  • 하수에서 배양된 미세조류인 Chlorella vulgaris AG10032, Ankistrodesmus gracilis SAG278-2, Scenedesmus quadricauda AG10308은 오폐수에서 질소 및 인 제거가 우수하고 높은 지질을 함유하고 있어서, 오폐수에서 바이오연료나 기타 바이오 기반의 자원 회수에 유용한 생물자원이다. 오폐수 환경에는 다양한 인의 농도가 존재하는데, 인의 농도 특히 인 결핍조건에 따른 조류의 지방산 특성에 대한 정보가 매우 제한적이다. 이는 표준 분석방법이 정립되어 있지 않은데 일부 기인한다. 본 연구에서는 미생물의 지방산을 분석하는데 일반적으로 사용되는 무극성 컬럼법과 식물성 지질을 분석하는데 널리 사용되는 극성 WAX-type 컬럼 GC-FID 방법의 미세조류 지방산 분석 성능을 비교 분석하였고, 하수배양 조류에 적용이 보다 적절한 방법을 이용해서 인 결핍에 의한 조류 지방산 생성특성에 미치는 영향을 평가하였다. 그 결과 무극성 컬럼 방법에 비해 극성 WAX-type 컬럼 GC 방법이 $C_{18:3}$ 지방산과 같은 고불포화지방산을 규명하는 분석능력이 우수하였고, 실제 하수배양에서 배양 분리된 미세조류의 지방산 분석에 보다 정확한 결과를 보이었다. 이 WAX-type 컬럼 방법으로 인 결핍 영향을 분석한 결과, 미세조류의 지방산 조성과 생성량은 인의 농도 변화에 크게 영향을 받지 않음을 밝히었다.