• Title/Summary/Keyword: non-peroxide

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Ultraviolet Microscopic Study on Lignin Distribution in the Fiber Cell Wall of BCTMP

  • Yoon, Seung-Lak;Yasuo Kojina
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.1
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    • pp.61-66
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    • 2004
  • Bleached chemithermomechanical pulp (BCTMP) was produced from CTMP of Betula maximowicziana Regel by two staged ozone-hydrogen peroxide bleaching in order to improve the optical properties of high yield pulp. This pulp was used for the evaluation of optical properties improvement, chemical characteristics of lignin in fiber and the relationship between lignin and optical properties in fiber cell wall. Hydrogen peroxide treatment improved the brightness, but the post color number (PC No.). There was little improvement on optical properties by ozone treatment, but this could be improved more by using two staged ozone-hydrogen peroxide bleaching. The hydrogen peroxide treatment did not make any change on chemical characteristics of lignin in cell wall, but by ozone treatment, it was found that the non-aromatic conjugated structure was existed in the surface of cell wall, but this could be removed by hydrogen peroxide treatment in two staged ozone-hydrogen peroxide treatment. Therefore, the optical properties was significantly improved, due to the removal of non-aromatic conjugated structure.

Determination of Hydrogen Peroxide Concentration by Portable Near-Infrared (NIR) System (근적외분광분석법을 이용한 과산화수소의 농도 측정)

  • 임현량;우영아;장수현;김경미;김효진
    • YAKHAK HOEJI
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    • v.46 no.5
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    • pp.324-330
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    • 2002
  • This experiment was carried out to determine non-destructively the hydrogen peroxide concentration of 3% antiseptic hydrogen peroxide solutions by portable near-infrared (NIR) system. Hydrogen peroxide standards were prepared ranging from 0 to 25.6 w/w% and the NIR spectra of hydrogen peroxide standard solutions were collected by using a quartz cell in 1 mm pathlength. We found the variation of absorbance band due to OH vibration of hydrogen peroxide depending on the concentration around 1400 nm in the second derivatives spectra. Partial least square regression (PLSR) and multilinear regression (MLR) were explored to develop a calibration model over the spectral range 1100-1720 nm. The model using PLSR was better than that using MLR. The calibration showed good results with a standard error of prediction (SEP) of 0.16%. In order to validate the developed calibration model, routine analyses were performed using commercial antiseptic hydrogen peroxide solutions. The hydrogen peroxide values from the NIR calibration model were compared with the values from a redox titration method. The NIR routine analyses results showed good correlation with those of the redox titration method. This study showed that the rapid and non-destructive determination of hydrogen peroxide in the antiseptic solution was successfully performed by portable NIR system without very harmful solvents.

ULTRAVIOLET MICROSCOPIC STUDY ON LIGNIN DISTRIBUTION IN THE FIBER CELL WALL OF BCTMP

  • Seung-Lak YooN;Yasuo KOJIMA;Lee, Seon-Ho
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04b
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    • pp.375-380
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    • 1999
  • In order to improve the optical properties of high yield pulp, bleached chemi-thermo-mechanical pulp (BCTMP) was produced from CTMP of Betula maximowicziana Regel by two staged ozone-hydrogen peroxide bleaching. This pulp was used for the evaluation of the improvement of optical properties, chemical characteristics of lignin in fiber, and the relationship between lignin and optical properties in fiber cell wall. By hydrogen peroxide treatment, the brightness was improved, but the post color number (PC No.) was not. There was little improvement on optical properties by ozone treatment, but his could be solved by using two staged ozone-hydrogen peroxide bleaching. The hydrogen peroxide treatment did not make nay change on chemical characteristics of lignin in cell wall, but by ozone treatment, it was found that the non-aromatic conjugated structure was existed in the surface of cell wall, but this could be removed by hydrogen peroxide treatment in two staged ozone-hydrogen peroxide treatment. Therefore, the optical properties was significantly improved due to the removal of non-aromatic conjugated structure.

Antioxidant potential of silk protein sericin against hydrogen peroxide-induced oxidative stress in skin fibroblasts

  • Dash, Rupesh;Acharya, Chitrangada;Bindu, P.C.;Kundu, S.C.
    • BMB Reports
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    • v.41 no.3
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    • pp.236-241
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    • 2008
  • The antioxidant potential of silk protein sericin from the non-mulberry tropical tasar silkworm Antheraea mylitta cocoon has been assessed and compared with that of the mulberry silkworm, Bombyx mori. Skin fibroblast cell line (AH927) challenged with hydrogen peroxide served as the positive control for the experiment. Our results showed that the sericin obtained from tasar cocoons offers protection against oxidative stress and cell viability is restored to that of control on pre-incubation with the sericin. Fibroblasts pre-incubated with non-mulberry sericin had significantly lower levels of catalase; lactate dehydrogenase and malondialdehyde activity when compared to untreated ones. This report indicates that the silk protein sericin from the non-mulberry tropical tasar silkworm, A. mylitta can serve as a valuable antioxidant.

BLEACHING EFFECT OF CARBAMIDE PEROXIDE GEL ON DISCOLORED NONVITAL TEETH (변색 실활치에 대한 carbamide peroxide gel의 표백효과)

  • Park, Sun-Ah;Kim, Sun-Ho;Hwang, Yun-Chan;Oh, Byung-Ju;Youn, Chang;Park, Yeong-Joon;Jeong, Sun-Wa;Hwang, In-Nam;Oh, Won-Mann
    • Restorative Dentistry and Endodontics
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    • v.27 no.4
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    • pp.441-447
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    • 2002
  • The bleaching of discolored nonvital teeth is conservative treatment that satisfy the cosmetic desire. The most common method for this treatment, walking bleaching, is using 30% hydrogen peroxide and sodium perborate. Many alternatives are suggested for preventing the external cervical root resorption that is the common complication of the nonvital teeth bleaching with 30% hydrogen peroxide The same extent of oxidation reactions as that resulted by the bleaching with the application of 30% hydrogen peroxide and sodium perborate can also be acquired more safely by materials that contain 10% carbamide peroxide, used primarily for the bleaching of vital teeth. Therefore, this study was performed to evaluate the efficacy of 10% and 15% carbamide peroxide bleaching gel in nonvatal teeth bleaching. The internal bleaching of intentionally discolored teeth was performed in vitro with 10% carbamide peroxide (Group 1), 15% carbamide peroxide (Group 2), mixture of distilled water and sodium perborate (Group 3), and mixture of 30% hydrogen peroxide and sodium perborate (Group 4). The bleaching materials were refreshed following 3, 6, 9 and 12 days. To evaluate the bleaching effect, the color change of the crowns was measured at 1, 2, 3, 4, 7 and 15 days of bleaching using the colorimeter. The results were as follows:1. L$^*$ and $\Delta$E$^*$ values were increased with time in all bleaching agents (p<0.01). 2. There was no significant difference in L$^*$ and $\Delta$E$^*$ value among bleaching agents. 3. $\Delta$E$^*$ value higher than 3 was shown after 3 days of bleaching with 10% carbamide peroxide gel, 1 day with 15% carbamide poroxide gel, 4 days with mixture sodium perborate and distilled water and 4 days with mixture sodium perborate and 30% hydrogen peroride, respectively. These results revealed that the use of 10% and 15% carbamide peroxide bleaching gel in non-vital teeth bleaching is as effective as mixture of distilled water and sodium perborate and mixture of 30% hydrogen peroxide and sodium perborate. Accordingly, carbamide peroxide could be used clinically to bleach discolored non-vital teeth.

Feasibility of Energy Generation from Chemical Reaction between Hydrogen Peroxide/Hydride (고농도 과산화수소와 수소화물의 지속적인 반응에 대한 연구)

  • SEO, SEONGHYEON
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.3
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    • pp.271-277
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    • 2015
  • The present paper discusses about noble idea on various reactions including hydrides, hydrogen peroxide and nano-sized metal powders, which do not emit toxic materials as well as carbon dioxide. Here in this paper, the very first-ever concept that heat energy can be generated from the direct reaction between sodium borohydride and hydrogen peroxide is presented. Sodium hydride as fuel can supply hydrogen reacting with oxygen provided by the decomposition of hydrogen peroxide solution. Solid sodium borohydride can be resolved in water and treated as liquid solution for the easy handling and the practical usage although its solid powder can be directly mixed with hydrogen peroxide for the higher reactivity. The thermodynamic analysis was conducted to estimate adiabatic reaction temperatures from these materials. The preliminary experiment on the reactions conducted using sodium borohydride powder and hydrogen peroxide water solution revealed that the self-propagating reaction can occur and that its reactivity increases with an increase of hydrogen peroxide concentration.

Hydrogen Peroxide Gas Generator with Dual Catalytic Bed for Non-preheating Start-up (비예열 시동특성을 갖는 이원 촉매 베드 과산화수소 가스발생기)

  • Lim, Ha-Young;An, Sung-Yong;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.163-167
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    • 2007
  • Silver is widely used for catalytic decomposition of hydrogen peroxide, but start-up at room temperature is difficult and cannot withstand at high temperature. In this paper, to overcome these short-comings, a dual catalytic bed which consists of a vaporizer catalyst and a high temperature catalyst was studied. Platinum was selected as the vaporizer catalyst and perovskite type catalyst was selected for the high temperature catalyst. Preliminary test demonstrated start-up capability with non-preheating at room temperature and good thermal stability at high temperature.

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Characteristics of Bovine Teeth Whitening in Accordance with Gas Environments of Atmospheric Pressure Nonthermal Plasma Jet

  • Sim, Geon Bo;Kim, Yong Hee;Kwon, Jae Sung;Park, Daehoon;Hong, Seok Jun;Kim, Young Seok;Lee, Jae Lyun;Lee, Gwang Jin;Lim, Hwan Uk;Kim, Kyung Nam;Jung, Gye Dong;Choi, Eun Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.250.2-250.2
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    • 2014
  • Currently, teeth whitening method which is applicable to dental surgery is that physician expertises give medical treatment to teeth directly dealed with a high concentration of hydrogen peroxide and carbamide peroxide. If hydrogen peroxide concentration is too high for treatment of maximized teeth whitening effect [1], it is harmful to the human body [2]. To the maximum effective and no harmful teeth whitening effect in a short period of time at home, we have observed the whitening effect using carbamide peroxide (15%) and a low-temperature atmospheric pressure plasma jet which is regulated by the Food and Drug Administration. The gas supplied conditions of the non-thermal atmospheric pressure plasma jet was with the humidified (0.6%) gas in nitrogen or air at gas flow rate of 1000 sccm. Also, the measurement of chemical species from the jet was carried out using the optical emission spectroscopy (OES), the evidence of increased reactive oxygen species compared to non-humidified plasma jet. We have found that the whitening effect of the plasma is very excellent through this experiment, when bovine teeth are treated in carbamide peroxide (15%) and water vapor (0.2 to 1%). The brightness of whitening teeth was increased up to 2 times longer in the CIE chromaticity coordinates. The colorimetric spectrometer (CM-3500d) can measure color degree of whitening effect.

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The Study on Bleaching of Kenaf Fibers (Part I) -Effect of Bleaching- (케냐프 섬유의 표백에 대한 연구 (제1보) -표백효과를 중심으로-)

  • Jang Hyunsook;Lee Hyeja;Yoo Hyeja;Han Youngsook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.9_10 s.146
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    • pp.1295-1305
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    • 2005
  • The study was based on a three-stage, non-repetitive factorial experiment in which chemical-rotted kenaf fibers were treated separately with hydrogen peroxide concentrations of $0.5\%,\;1\%\;and\;2\%$, with pH solutions of 7, 9 and 11, and treatment times of 30, 60 and 90 minutes. Under optimal conditions, the study was conducted to determine the bleaching efficiency by the addition of chelators, penetrants and surfactants. The bleaching effects on the kenaf fibers were high in high hydrogen peroxide concentration, high in alkali solution pH, low in long treatment time. The optimal level of hydrogen peroxide on bleaching effects were at $2\%$ hydrogen peroxide concentration, with pH of 11 and treatment time of 60 minutes. Under the conditions of $2\%$ hydrogen peroxide concentration, pH 11 and treatment time of 60 minutes, the addition of chelator: Sodim Pyrophosphate(SP), Citric Acid(CA) made the bleaching effects of the kenaf fibers high.