• 한국응용과학기술학회지
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• 제32권4호
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• pp.661-668
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• 2015

The surface rheological properties of polymer monolayer show complicated non-linear viscoelastic flow phenomena when they are subjected to spreading flow. These spreading flow properties are controlled by the characteristics of flow units. The kinetics of the formation of an interfacial film obtained after spreading poly(diisobutylene maleic acid) at air-water interface were studied by measuring of the surface pressure with time. The experimental data were analyzed theoretically according to a nonlinear surface viscoelastic model. The values of dynamic modulus, static modulus, surface viscosities and rheological parameters in various area/ monomer were obtained by appling experimental data to the equation of nonlinear surface viscoelastic model.

• Macromolecular Research
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• 제17권12호
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• pp.943-949
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• 2009

A highly dispersed W/O emulsion of silicone oil (cyclomethicone)/water system was prepared with a nonionic surfactant. The surface and interfacial tension between the oil and water were characterized in terms of the droplet size distribution and viscosity change of the emulsion. When the dispersed phase concentration was relatively high, the viscosity of the emulsion was rapidly increased and the droplet size of the emulsion was decreased. The rheological behavior of the emulsion system showed non-Newtonian and shear thinning phenomena depending upon the content of the dispersed phase. The droplet size of the emulsion was decreased with increasing surfactant content and water concentration. The relative viscosity of the emulsion was better predicted with the Choi-Schowalter model than with the Taylor model. The value of the complex modulus increased with increasing surfactant concentration. The linear viscoelastic region was expanded with a dispersed phase concentration. According to the change in the viscosity, the behavior was classified into three distinct regions: [I] linear viscoelastic, [II] partially viscoelastic, and [III] viscous. The creep/recovery behaviors in each region were characterized.

• Structural Engineering and Mechanics
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• 제51권2호
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• pp.277-297
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• 2014

Since the isolation bearings undergo large displacements in base-isolated structures, impact with adjacent structures is inevitable. Therefore, in this investigation, the effect of impact on seismic response of isolated structures mounted on double concave friction pendulum (DCFP) bearings subjected to near field ground motions is considered. A non-linear viscoelastic model of collision is used to simulate structural pounding more accurately. 2-, 4- and 8-story base-isolated buildings adjacent to fixed-base structures are modeled and the coupled differential equations of motion related to these isolated systems are solved in the MATLAB environment using the SIMULINK toolbox. The variation of seismic responses such as base shear, displacement in the isolation system and superstructure (top floor) is computed to study the impact condition. Also, the effects of variation of system parameters: isolation period, superstructure period, size of seismic gap between two structures, radius of curvature of the sliding surface and friction coefficient of isolator are contemplated in this study. It is concluded that the normalized base shear, bearing and top floor displacement increase due to impact with adjacent structure. When the distance between two structures decreases, the base shear and displacement increase comparing to no impact condition. Besides, the increase in friction coefficient difference also causes the normalized base shear and displacement in isolation system and superstructure increase in comparison with bi-linear hysteretic behavior of base isolation system. Totally, the comparison of results indicates that the changes in values of friction coefficient have more significant effects on 2-story building than 4- and 8-story buildings.