• 제목/요약/키워드: non-aqueous dyeing

검색결과 11건 처리시간 0.022초

비수계 염색용 마이크로캡슐의 제조 및 성질 (Preparation and Characterization of Microcapsule for non-aqueous dyeing)

  • 최창남;박원규;변수진;이기영
    • 한국염색가공학회지
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    • 제15권5호
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    • pp.327-332
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    • 2003
  • In this study, the polyurethane microcapsules for non-aqueous dyeing containing iron oxide and disperse dyes were prepared by in-situ polymerization method using hexamethylene diisocyanate(HDI) with ethylene glycol(EG). And the size, shape, and particle size distribution of microcapsules prepared were investigated. The size and shape of microcapsule were observed by optical microscope and scanning elecron microscope. The particle size distribution was analyzed by particle size analyzer. The microcapsule size and its distribution were largely effected by the existance of surface active agent in the system. When a surfactant did not exist in the system, the size distribution of microcapsules prepared was much uneven. By adding a surfactant, this phenomenon was disappeared. And the size of microcapsule was also effeced by the hydrophobicity of core material(disperse dye). It was considered due to the difference of dispersity of core materials. And the size of microcapsule prepared was inversely proportional to the stirring speed.

향나무 심재 메탄올추출물의 염색성과 기능성 (Dyeing Properties and Functionality of Methanol Extract from Juniperus chinensis Heartwood)

  • 남기연;이정순
    • 한국염색가공학회지
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    • 제25권3호
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    • pp.194-205
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    • 2013
  • In this study, we report dyeing properties and functionality of cotton and silk fabrics dyed with methanol extract from Juniperus chinensis heartwood. Non-aqueous dye of Juniperus chinensis heartwood extracted with methanol was expressed reddish color. It showed relatively good affinity to silk than cotton. Dye uptake of cotton and silk continued to increase according to the increase of the dye concentration. Cotton was not affected by the dyeing temperature and time, however, dye uptake of silk was increased as the dyeing time and temperature were increased. Dye uptake of cotton and silk were the highest at pH 8 and pH 6 respectively. Dyed fabrics showed various colors depending on mordant types and mordant concentration. Washing, light and perspiration fastness were not good. However, rubbing and dry cleaning fastness showed relatively good grade. Dyed fabrics of ultraviolet-cut ability and deodorant ability were improved. Also, dyed fabrics showed very good antimicrobial abilities of 99.9%.

나일론/카티온화 면 혼방품의 산성염료/직접염료에 의한 1욕 2단 염색에 관한 연구 (A Study on the One Bath Two Step Dyeing of Nylon/ Cationized Cotton Blends with Acid Dye/Direct Dye)

  • 성우경
    • 한국염색가공학회지
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    • 제12권1호
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    • pp.44-51
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    • 2000
  • The conventional one bath exhaust dyeing system of nylon]/cotton blends with acid dye/direct dye involves a lot of neutral salt which affect dyeability of acid dyes. Because of conventional one bath exhaust dyeing system of nylonl/cotton blends with acid dye/direct dye needs acid dyes adjusted at a neutral liquor, suitable acid dye is limited. To improve dyeing property of nylon/cotton blends, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate dyeing possibilities of nylon/cationized cotton blends with acid dye/direct dye in a non-neutral salt dyebath by one bath two step method. The concentration of direct dye was 1.0%, 0.7%, 0.3%o.w.f. respectively at a non, 1%, 3%owf of reserving agent for being almost equal color strength between nylon and 3% cationized cotton when nylon/3% cationized cotton blends was dyed with acid dye/direct dye at concentration of acid dye(1%o.w.f.) by one bath two step method.

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폴리에스테르/카티온화 면 혼방품의 분산염료/반응성염료에 의한 일욕염색계에 관한 연구 (Studies on the One Bath Exhaust Dyeing System of Polyester/Cationized Cotton Blends with Disperse Dye/Reactive Dye)

  • 성우경
    • 한국염색가공학회지
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    • 제10권2호
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    • pp.18-28
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    • 1998
  • in order to overcome disadvantage of the conventional two bath dyeing method of polyester/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish sayings in time, energy and water usage. Also, when dyeing polyester/cotton blends by the one bath dyeing method, the high salt concentrations needed for the reactive dye can cause particles of disperse dye, used for the polyester component, to aggregate. A supplementary problem that can occasionally be happened is the change of hue that occurs on dyed polyester in an alkaline dyebath. To improve dyeing property of polyester/cotton blends, cotton component was pretreated with epichlolohydrine-trimethylamine hydrochloride in aqueous solution of sodium hydroxide to produce a cationized cotton that can be dyed under neutral conditions with reactive dye in a non-electrolytic or il little electrolytic dyebath. The one bath dyeing method of polyester/cationized cotton blends with disperse dye/reactive dye mixture resulted in a satisfactory dyeing property and color yield in comparison with ordinary two bath dyeing method.

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유기용매염색 (I) - C. I. Disperse Violet 1에 의한 PET 염색 - (Organic Solvent Dyeing (I) - The dyeing of PET by C. I. Disperse Violet 1 -)

  • Kim, Tae Kyeong;Heo, Jae Won;Lim, Yong Jin
    • 한국염색가공학회지
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    • 제9권4호
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    • pp.20-27
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    • 1997
  • As a non-aqueous dyeing method, organic solvent dyeing was discussed, The dye uptakes on PET and the solubilities of C. I. Disperse Violet 1 in 24 kinds of organic solvents including water were investigated, and the partition coefficients in PET- solvents system were also obtained from their isotherms. Contrary to in the other solvents, the dye uptake of C. I. Disperse Violet 1 on PET in hexane was even much higher, and also considerable in cyclohexane. The logarithmic plot of the dye uptakes versus the solubilities showed that the dye uptakes are linear and inversely proportional to the solubilities. The effect of $T_g$ decrease of PET in organic solvents to dye uptake seems to be very small relative to the effect of solubility, and so negligible.

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산성염료와 반응성염료에 의한 카티온화 나일론/비스코스레이온 교직물의 1욕1단 염색 (The One Bath One Step Dyeing of Cationized Nylon/Viscose Rayon Mixture Fabrics With Acid Dyes and Reactive Dyes)

  • 성우경
    • 한국의류산업학회지
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    • 제7권3호
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    • pp.339-345
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    • 2005
  • It is difficult to dye nylon/viscose rayon mixture fabrics by one-bath one-step dyeing method, because acid dyes and reactive dyes require acidic dyebath for adsorption and alkaline dyebath for fixation respectively. In order to overcome the disadvantage of the conventional two bath two step dyeing method of nylon/viscose rayon mixture fabric, it was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. The pretreated nylon/viscose rayon mixture fabrics produced cationized fabrics that could be dyed with acid dyes and reactive dyes under neutral condition. This study was carried out to investigate dyeing possibilities, surface reflectance spectra and color characteristics of cationized nylon/viscose rayon mixture fabrics with acid dyes and reactive dyes in a non-electrolytic and neutral dyebath by one bath one step dyeing method.

양모/카티온화 면 혼방품의 산성염료/직접염료에 의한 1욕2단 염색에 관한 연구 (A Study on the One Bath Two Step Dyeing of Wool/Cationized Cotton Blends With Acid Dye/Direct Dye)

  • 성우경;이춘길
    • 한국의류산업학회지
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    • 제3권2호
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    • pp.168-173
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    • 2001
  • In order to overcome the disadvantage of the conventional two bath dyeing method of wool/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish savings in energy, water usage and time. To improve the dyeability of cotton toward direct dyes in a non-electrolytic and acidic dyebath, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate almost equal color strength between wool component and cationized cotton component when wool/cationized cotton blends was dyed with acid dye/direct dye by the one bath two step method in a non-electrolytic and acidic dyebath.

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산수유의 염색성과 견뢰도에 관한 연구 (A Study on the Change of Dye-ability of Cornus officinalis with Mordanting Treatment and Colorfastness)

  • 배계인;최인려;박견순
    • 한국의상디자인학회지
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    • 제9권3호
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    • pp.47-57
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    • 2007
  • This study focused on the properties natural dyeing and natural material and on the development of functional material for well-being in apparel industry. Comus officinalis Siebold et Zuccarini is used as natural dyeing material which had been reported that have curable effect for unbalanced immunity, geriatric diseases like urinary tract system, diabetes, hypertension, arthritis, tinnitus, hyperhidrosis and women's diseases like hypermenorrhea. And this material also has anti-cancer effect so that can restraint cancer cells. 3 kinds tester of cotton, wool and silk are dyed by boiled with each dye (flower, fruits, bark of tree) as first dyeing and dried in the shade. These testers are done by post-mordanting method. Aluminium Potassium(Alk(SO4)2), Cuprie Sulfate($CuSO4{\cdot}5H2O$), Stannous Chloride($SnCl2{\cdot}2H2O$), Ferrous Sulfate($FeCl2{\cdot}4H2O$), Titanium Sulfate 24% aqueous solution(Ti(SO4)2) are used as mordants. Dyeing results of Comus officinalis Siebold et Zuccarini flower and bark are shown as yellow color series. And dyeing result of fruits is pink color series. Silk shows the best dyeing property. As the point of view for dyeing property, Ti, Sn, Fe would be the properchoice for mordant. Following results are extracted in this study. Yellow color is resulted in dyeing with Cornus officinalis flower as non-mordanting condition. Yellowish red color is come from dyeing with Comus officinalis fruit as non-mordanting condition. Grayish yellow tone is resulted in dyeing with bark as non-mordanting condition. Orange tone color with Ti-mordanting, green tone color with Sn-mordanting and gray tone color with Fe-mordanting is resulted respectively. However light-fastness of Comus officinalis(flower, fruit, bark) is very low as 1 or 2 level in non-mordanting condition, Comus officinalis flower dyeing is turned out 3 or 4 level and fruit dyeing is 4 or 5 level, bark dyeing is 2 or 3 level with Ti-mordanting respectively. Eventually Comus officinalis fruit has the best light-colorfastness property among all of dyes. dry cleaning colorfastness of Cornus officinalis(flower, fruit, bark) is good as 4 or 5 level in Ti-mordanting condition, perspiration-colorfastness of Cornus officinalis(flower, fruit, bark) is good as 4 or 5 level in Ti-mordanting condition, With these results, this study could conclude that dye-ability, colorfastness problem is getting better after mordanting process and practical usage would be possible.

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호도 내과피 추출액을 이용한 견직물의 염색성 (A Study on the Properties of Silk Fabrics Dyed with Walnut Shell Extract)

  • 전미선;장정대
    • 복식문화연구
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    • 제12권3호
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    • pp.407-414
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    • 2004
  • A natural dye aqueous walnut shell extract was obtained by extraction of walnut shell using water at various conditions in this study. Silk fabrics were dyed at various dyeing and mordanting conditions using walnut shell extract and various mordants (Al, Cu, Fe ions). Studies have been made on the effects of dyeing and mordanting conditions on the dyeing properties and fastness (light, water and dry cleaning fastness) of dyed silk Fabric. The results obtained in this study were as follows;. The dye content in the walnut shell extract increased with increasing extraction temperature to 90℃ and extraction time to 120min, and thereafter the dye content decreased a little. The dry cleaning and water fastness of non-mordanted silk fabrics were better than those of mordanted silk fabrics.

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