• Resources Recycling
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• v.25 no.4
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• pp.23-31
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• 2016

It was found that there was no problem in recycling by-products (waste rock and tailings) from Yangyang iron mine themselves through matter conversion because they are not hazardous according to results of KSLT method. In case of using tailings as sub-materials of cement, it recommended the use of less than 3% tailings dosage not to exceed 0.6% of total alkali ($R_2O$) content based on standard quality of portland cement (KS L 5201). Non sintered eco-brick corresponding to class 1 quality of recycled clay brick (KS I 3013) can replace 15% of cement with tailings and 100% of general fine aggregate with waste rock from iron mine. As mentioned above, recycling the by-products (waste rock and tailings) as sub-materials of cement and non sintered eco-brick could gain both environmental and economic benefits, that is, reduction of scale and maintenance cost of tailing ponds, decrease of energy use and $CO_2$ emission.

• Restorative Dentistry and Endodontics
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• v.7 no.1
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• pp.77-83
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• 1981

The purpose of this study was to observe the bonding strength between tooth surface (enamel and dentin) and restorative filling materials which are two composite resins (Clearfil and Concise) and Glass ionomer cement, after etching with 50% phoshoric acid and 37% citric acid. To measure the bonding strength in enamel, the labial surface of upper anterior tooth was cut flatly with using carborundum disk and polished with sand paper disk, and to measure in dentin, the dentin surface was prepared by grinding upper part of posterior tooth horizontally. After washing the tooth surface with water and drying with air blast, the prepared tooth surface was etched. In glass ionomer cement, 50% phosphoric acid and 37% citric acid were used, in Clearfil 40% phosphoric acid was used and in Concise, 50% phosphoric acid and 37% citric acid were used as etchant for 1 minute. After the copper band which is 5 mm in diameter and 5 mm in height was fixed on the prepared surface and each filling material was inserted into the copper band, the hooking loop was inserted into filled material in the copper band before setting to make it easily that the load is applied on the specimen. After all specimens were immersed in water at $37^{\circ}C$ for 1 week, this specimen was placed on the load cell of tensile test apparatus, and specimen was pulled at the cross-head speed of 0.8 mm per minute. The following results were obtained 1) In glass ionomer cement, the bond strength obtained by 37% citric acid was higher than one obtained by 50% phosphoric acid in enamel and dentin surfaces. The bond strength obtained in non-etched surface was much less than one by etchants in enamel and dentin surface. 2) In Clearfil, the bond strength obtained by 40% phosphoric acid was 4 times more than one obtained by non etch ant. 3) In Concise, the bond strength obtained by 50% phosphoric acid was almost same as one obtained by 37% citric acid, and the bond strength obtained by non etch ant was much less than one obtained by etchants.

• Resources Recycling
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• v.3 no.3
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• pp.27-31
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• 1994

We tested the limestone sludge produced in Pohang Iron & Steel Co., Ltd. as a filler powder for the effective use of portland cement. Hydration process was investigated by measuring the hydration rate, the amounts of non-evaporable water and compressive strength of cement-limestone sludge paste prepared by mixing limes-tone sludge with cement. The results obtained in this study can be summarized as follows: 1. There is no significant difference between the cases of adding up to 10% limestone sludge and those of unmixed cement system. However the reaction rate increases in the 5% limestone sludge system(due to the effects of fine). 2. The compressive strength increases proportionally with increasing the measured amount of non-evaporable water, Adding 5% limestone sludge also increases the strength a little higher, and the compressive strength and calcium silicate hydrates. In the case of the mixed limestone sludge, $2\theta$=$11.7^{\circ}$ peak appears in the samples of 28 days hydration. This peak indicted the presence of calcium carboaluminate hydrate. Although limestone sludge is generally regarded as a inert materials, some kinds of cement can produce a calcium carboaluminate by reacting with aluminate in cement pastes.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.5
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• pp.95-102
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• 2022

Recently, there has been a growing interest in reducing greenhouse gases in all industrial fields. In the construction industry, studies have been conducted for the use of high-volume fly ash concrete to replace cement with fly ash. Quantitative measurements of cement hydration and fly ash reactivity enable a clear understanding of the strength development mechanism of high-volume fly ash concrete. It is very difficult to describe the reactivity in a simple way because the hydration and pozzolanic reactions of cement paste containing fly ash are very complex and the composition of the hydration product cannot be accurately determined. This study investigated the hydration and mechanical properties of high volume fly ash (HVFA) cement according to the substitution rate of fly ash (FA). The hydration degree of cement and the reactivity of FA were evaluated through the selective dissolution method and the non-evaporable water content of the paste according to age. In addition, compressive strength was measured using HVFA mortar specimens according to age. As a result of the experiment, as the substitution rate of fly ash increased, the hydration degree of cement increased, but the reactivity of FA decreased.

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.951-955
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• 2001

The experimental comparison between bonded and unbonded types stem-cement interface was carried out on axisymmetric stem-cement-aluminum model of the femoral component of a total hip replacement. Human femur was modeled in non-tapered and tapered($7.5^{\circ}$) aluminum hollow cylinders to emulate the diaphyseal and metaphyseal segments of the femur. For unbonded type, we tested stems with three different taper angles($5^{\circ},\;7.5^{\circ},\;10^{\circ}$). In every case, the cement-aluminum interface was designed to endure 8MPa shear strength. (a measured value at cement-bone interface) We tested aluminum models under axial loading for both cases. As an experimental result, it was found that unbonded stem sustained more axial load as bonded stem in both cases, diaphyseal and metaphyseal models. The unbonded types failed in cement mantle under axial compressive load, while the bonded ones failed in shear at cement-aluminum interface. These results suggest that a polished stem will sustain much higher axial load than a roughened stem. And a polished stem will make more stable cement-bone interface that may promote better osteosythesis around the stem.

• The Journal of Advanced Prosthodontics
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• v.9 no.2
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• pp.118-123
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• 2017

PURPOSE. To investigate the effect of non-thermal atmospheric pressure plasma (NTAPP) treatment on shear bond strength (SBS) between resin cement and colored zirconia made with metal chlorides. MATERIALS AND METHODS. 60 zirconia specimens were divided into 3 groups using coloring liquid. Each group was divided again into 2 sub-groups using plasma treatment; the experimental group was treated with plasma, and the control group was untreated. The sub-groups were: N (non-colored), C (0.1 wt% aqueous chromium chloride solution), M (0.1 wt% aqueous molybdenum chloride solution), NP (non-colored with plasma), CP (0.1 wt% aqueous chromium chloride solution with plasma), and MP (0.1 wt% aqueous molybdenum chloride solution with plasma). Composite resin cylinders were bonded to zirconia specimens with MDP-based resin cement, and SBS was measured using a universal testing machine. All data was analyzed statistically using a 2-way ANOVA test and a Tukey test. RESULTS. SBS significantly increased when specimens were treated with NTAPP regardless of coloring (P<.001). Colored zirconia containing molybdenum showed the highest value of SBS, regardless of NTAPP. The molybdenum group showed the highest SBS, whereas the chromium group showed the lowest. CONCLUSION. NTAPP may increase the SBS of colored zirconia and resin cement. The NTAPP effect on SBS is not influenced by the presence of zirconia coloring.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.2
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• pp.166-171
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• 2014

This experimental study considers manufacturing method of the non-portland cement matrix for the light-weight building materials using blast furnace slag, paper ash, fly ash and polysilicon sludge the industrial by-product. For the experiment, we used paper ash by means of the foaming agent and alkali activator to make non-portland cement light-weight matrix. Various specimens were prepared with different types and addition ratios of the alkali activator. Then, the properties of these specimens were investigated by compressive strength test, bulk specific gravity. As a results, it was judged that experiment results of non-portland cement matrix with specific waste resources and alkali activators were useful as basic data for mixtures design and evaluation properties of lightweight non-portland cement building material.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.609-612
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• 2006

The quality of the concrete compression strength can be determined after the passage of 28 days, but if any defect is found the quality of concrete after that length of time, there can be serious problems in dismantling and repair. Thus, in response to the use of concrete using non sintering cement (NSC), the present study purposed to propose a method of managing the strength of high strength concrete using NSC in comparison with high strength concrete using ordinary Portland cement (OPC) through early strength estimation using microwave, which enables the quick estimation of the strength of high strength concrete using NSC.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.329-332
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• 2004

This study aims to manufacture non-sintering cement(NSC) by adding phosphogypsum(PG) and waste lime(WL) to granulated blast furnace slag(GBFS) as sulfate and alkali activators. This study also investigates the pore structure of NSC Matrix. The result of experiment of pore structure properties, showed no considerable difference for total pore volume by cement mixing ratio but shows a large distinction in distribution of pore diameter. On the whole, pore-diameter of paste of NSC show that occupation ratio of pore diameter below 10mm is larger and is smaller than OPC and BFSC at pore diameter of over 10nm. Such a reason is that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

• Proceedings of the KOSOMBE Conference
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• v.1996 no.11
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• pp.337-346
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• 1996

Debonding of cement-femoral stem interface has been suggested as a initial focus of loosening mechanism in many previous studies of cemented total hip replacement. The purpose of this study was to investigate the effect of debonding of cement-femoral stem interface to the bone-cement interface by using three-dimensional non-liner finite element analysis. Three cases of partial debonded, full debonded, full bonded cement-bone interface were modelled with partial bonding of distal 70mm from the tip of femoral stem. Each situation was studied under loading stimulating one-leg stanced gait of 68kg patient. The results showed that under partial and full debonded cement-stem interface condition the peak von Mises stress(3.1 MPa) were observed at the cement of bone-cement interface just under the calcar of proximal medial of femur, and sudden high peak stresses(3.5MPa) were developed at the distal tip of femoral stem at the lateral bone-cement interface in all 3 cases of bonding. The stresses were transfered very little to the cement of upper lateral bone-cement interface in partial and full debonded cases. Thus, once partial or full debonded cement-femoral stem interface occured, 3 times higher stress concentration were developed on the cement of proximal medial bone-cement interface than full bonded interface, and these could cause loosening of cemented total hip replacement. Clinically, preservation of more rigid cement-femoral stem interface may be important factor to prevent loosening of femoral stem.