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Fundamental Properties and Hydration Characteristics of Mortar Based on MgO Added Industrial By-products (산업부산물을 첨가한 MgO 기반 모르타르의 기초물성 및 수화특성에 관한 연구)

  • Hong, Sung-Gul;Kim, Do-Young;Lee, Dong-Sik
    • Journal of the Korea Concrete Institute
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    • v.25 no.5
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    • pp.565-572
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    • 2013
  • Hydration and physical characteristics of chemically-bonded phosphate ceramic (CBPC) binder based on dead-burned Mg-O with six different blends are investigated for efficient repair construction material by retarding set phase with $H_3BO_3$. The test specimen of the blender with silica fume shows higher compressive strength after 75 days. The CBPC with silica fume results in higher modulus of rupture that others. The test specimens of CBPC eludes lower calcium ion than that of OPC (Ordinay Portland Cement). The X-ray diffraction pattern shows that hydration results in the formation of magnesium hydroxide, M-S-H gel and $MgCO_3$ for the specimen with silica fumes. Combination with calcium for MgO is not desirable due to no formation of chemical bond between two components. Based on the experimental program, the mixture of MgO and silica fume shows efficient performance in strength and durability.

AN EXPERIMENTAL STUDY ON BOND STRENGTH OF SILICOATED RESIN BONDED RESTORATION (Silicoating이 수지접합 수복물의 결합력에 미치는 영향에 관한 실험적 연구)

  • Shin, Hyeon-Soo;Han, Dong-Hu;Lee, Keun-Woo;Lee, Ho-Yong
    • The Journal of Korean Academy of Prosthodontics
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    • v.27 no.2
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    • pp.101-121
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    • 1989
  • This study investigated the effects of Silicoating procedure on the tensile bond strength of resin-bonded prostheses. The Rexillium III specimens were treated with electrochemical etching and Silicoating procedure, followed by thermocycling and the NNB, Pors-on 4, and Degudent-U specimens were treated with Silicoating procedure. The specimens were debonded in tension with a Tensilon machine. Also, all specimens were observed with SEM, concentration of Si elements was analyzed with EPMA, and the mode of failure was recorded. The results of this study were obtained as follows: 1. In the Rexillium III specimens, the tensile bond strength of the Silicoated specimens was higher than that of the electrochemically etched specimens, and significant differences were observed (P<0.05). 2. The tensile bond strength of electrochemically etched Rexillium III specimens, significant differences were observed between the thermocycled and nonthermocycled specimens (P<0.05), but no significant differences were observed in the Silicoated specimens (P>0.05). 3. The tensile bond strength of the Silicoated specimens decreased NNB, Pors-on 4, Rexillium III, and Degudent-U in that order named. 4. Unlike the electrochemically etched specimens, the Silicoated specimens showed gap-free metal-resin interfaces with SEM. 5. Compared to the electrochemically etched specimens, the Silicoated specimens showed higher concentration of Si elements at the metal-resin interfaces and resin cement. 6. Photographic evaluation (X2) of the fractured sites revealed mainly cohesive failures with the Silicoated specimens, and adhesive failures with the electrochemically etched specimens.

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In vitro evaluation of the fracture resistance and microleakage of porcelain laminate veneers bonded to teeth with composite fillings after cyclic loading

  • Sadighpour, Leyla;Geramipanah, Farideh;Allahyari, Somayeh;Sichani, Babak Fallahi;Fard, Mohamd Javad Kharazi
    • The Journal of Advanced Prosthodontics
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    • v.6 no.4
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    • pp.278-284
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    • 2014
  • PURPOSE. There is insufficient data regarding the durability of porcelain laminate veneers bonded to existing composite fillings. The aim of the present study was to evaluate the fracture resistance and microleakage of porcelain laminate veneers bonded to teeth with existing composite fillings. MATERIALS AND METHODS. Thirty maxillary central incisors were divided into three groups (for each group, n=10): intact teeth (NP), teeth with class III composite fillings (C3) and teeth with class IV cavities (C4). Porcelain laminate veneers were made using IPS-Empress ceramic and bonded with Panavia F2 resin cement. The microleakage of all of the specimens was tested before and after cyclic loading ($1{\times}10^6$ cycles, 1.2 Hz). The fracture resistance values (N) were measured using a universal testing machine, and the mode of failure was also examined. The statistical analyses were performed using one-way ANOVA and Tukey post hoc tests (${\alpha}=.05$). RESULTS. There was a significant difference in the mean microleakage of group C4 compared with group NT (P=.013). There was no significant difference in the fracture loads among the groups. CONCLUSION. The microleakage and failure loads of porcelain laminate veneers bonded to intact teeth and teeth with standard class III composite fillings were not significantly different.

Prediction of flexural behaviour of RC beams strengthened with ultra high performance fiber reinforced concrete

  • Murthy A, Ramachandra;Aravindan, M.;Ganesh, P.
    • Structural Engineering and Mechanics
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    • v.65 no.3
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    • pp.315-325
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    • 2018
  • This paper predicts the flexural behaviour of reinforced concrete (RC) beams strengthened with a precast strip of ultra-high performance fiber-reinforced concrete (UHPFRC). In the first phase, ultimate load capacity of preloaded and strengthened RC beams by UHPFRC was predicted by using various analytical models available in the literature. RC beams were preloaded under static loading approximately to 70%, 80% and 90% of ultimate load of control beams. The models such as modified Kaar and sectional analysis predicted the ultimate load in close agreement to the corresponding experimental observations. In the second phase, the famous fatigue life models such as Papakonstantinou model and Ferrier model were employed to predict the number of cycles to failure and the corresponding deflection. The models were used to predict the life of the (i) strengthened RC beams after subjecting them to different pre-loadings (70%, 80% and 90% of ultimate load) under static loading and (ii) strengthened RC beams after subjecting them to different preloading cycles under fatigue loading. In both the cases precast UHPFRC strip of 10 mm thickness is attached on the tension face. It is found that both the models predicted the number of cycles to failure and the corresponding deflection very close to the experimental values. It can be concluded that the models are found to be robust and reliable for cement based strengthening systems also. Further, the Wang model which is based on Palmgren-Miner's rule is employed to predict the no. of cycles to failure and it is found that the predicted values are in very good agreement with the corresponding experimental observations.

Studies on Cd, Pb, Hg and Cr Values in Dog Hairs from Urban Korea

  • Park, S.H.;Lee, M.H.;Kim, S.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.8
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    • pp.1135-1140
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    • 2005
  • Dogs are a very good indicator of the pollution load on the environment. They share people's environment and are exposed to the action of the same pollutants. This study was to estimate the heavy metal contents in dog hairs in domestic districts, and to assess effects of age, sex, feed habits, living area, breeding environment and smoking habit of owner. The mean concentrations of heavy metals in 204 samples were 0.09${\pm}$0.10 ${\mu}g$/g, 0.21${\pm}$0.09 ${\mu}g$/g, 0.82${\pm}$0.09 ${\mu}g$/g and 0.48${\pm}$0.07 ${\mu}g$/g (Cadmium (Cd), Mercury (Hg), Lead (Pb) and Chromium (Cr)) in dog hairs, respectively. Concentrations of Pb, Cd, Hg and Cr in dog hairs in Yeongnam including Ulsan and Seoul, were higher than in Chungchong and Honam, and concentrations of Pb were significantly different (p<0.01). Concentrations of Cd, Hg, Pb and Cr in dog hairs increased with age (p<0.05). Only dogs fed commercial pet foods had significantly higher Cd and Cr concentrations in hairs than dogs fed dog feed and human diet (p<0.01 in Cd and p<0.05 in Cr). Cr concentrations of dog hairsfrom dogs kept on cement floors were the highest of the other environments (p<0.01). Heavy metal concentrations of dogs owned by smokers, were higher than dogs of non-smokers, but there were no significant differences.

Anterior Dislodgement of a Fusion Cage after Transforaminal Lumbar Interbody Fusion for the Treatment of Isthmic Spondylolisthesis

  • Oh, Hyeong Seok;Lee, Sang-Ho;Hong, Soon-Woo
    • Journal of Korean Neurosurgical Society
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    • v.54 no.2
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    • pp.128-131
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    • 2013
  • Transforaminal lumbar interbody fusion (TLIF) is commonly used procedure for spinal fusion. However, there are no reports describing anterior cage dislodgement after surgery. This report is a rare case of anterior dislodgement of fusion cage after TLIF for the treatment of isthmic spondylolisthesis with lumbosacral transitional vertebra (LSTV). A 51-year-old man underwent TLIF at L4-5 with posterior instrumentation for the treatment of grade 1 isthmic spondylolisthesis with LSTV. At 7 weeks postoperatively, imaging studies demonstrated that banana-shaped cage migrated anteriorly and anterolisthesis recurred at the index level with pseudoarthrosis. The cage was removed and exchanged by new cage through anterior approach, and screws were replaced with larger size ones and cement augmentation was added. At postoperative 2 days of revision surgery, computed tomography (CT) showed fracture on lateral pedicle and body wall of L5 vertebra. He underwent surgery again for paraspinal decompression at L4-5 and extension of instrumentation to S1 vertebra. His back and leg pains improved significantly after final revision surgery and symptom relief was maintained during follow-up period. At 6 months follow-up, CT images showed solid fusion at L4-5 level. Careful cage selection for TLIF must be done for treatment of spondylolisthesis accompanied with deformed LSTV, especially when reduction will be attempted. Banana-shaped cage should be positioned anteriorly, but anterior dislodgement of cage and reduction failure may occur in case of a highly unstable spine. Revision surgery for the treatment of an anteriorly dislodged cage may be effectively performed using an anterior approach.

Analysis of Mechanical Properties and Micro structure of Fly Ash Based Alkali-activated Mortar (플라이애쉬 기반(基盤) 알칼리 활성(活性) 모르타르의 역학적(力學的) 특성(特性) 및 미세구조(微細構造) 분석(分析))

  • Ryu, Gum-Sung;Koh, Kyung-Taek;Chung, Young-Soo
    • Resources Recycling
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    • v.21 no.3
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    • pp.28-38
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    • 2012
  • The purpose of this paper is to develop the alkali-activated concrete which uses 100% fly ash as a binder without any cement. The compressive strength of the mortar was examined depending on the chemical change in alkali-activator through SEM and SEM/EDS observations and the XRD analysis. It was found from the test that the higher molar concentration induced the greater effect on the initial strength, and that $Si^{4+}$ and $Al^{3+}$ were eluted relative to the compressive strength of mortar. In addition, it was confirmed that Al and Si were determined to be most influential ingredients on the microstructural development of the mortar, and that the different ingredient of the activator was almost no change in solidity from the XRD analysis.

AUTORADIOGRAPHIC STUDY ON SEALING ABILITY OF VARIOUS ROOT CANAL SEALERS (수종(數種) 근관충전재(根管充填材)의 근관폐쇄(根管閉鎖) 효과(效果)에 관(關)한 자기(自記) 방사법적(放射法的) 연구(硏究))

  • Choi, Woong-Dai;Park, Sang-Jin;Min, Byung-Soon;Choi, Ho-Young
    • Restorative Dentistry and Endodontics
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    • v.14 no.1
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    • pp.161-171
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    • 1989
  • The purpose of this study was to evaluate and compare the sealing ability of ZOE, FR and Sealapex, as a root canal sealer. Ninety six extracted anterior or premolar human teeth with single root were instrumented by using conventional method. After instrumentation, the teeth were divided into three groups and thirty two teeth in each group were filled as follows: ZOE group: ZOE cement as a root canal sealer in combination with guttapercha cone FR group: FR root canal sealer in combination with guttapercha cone Sealapex group: Sealapex root canal sealer in combination with guttapercha cone $^{45}Ca$ in the form of calcium chloride, was employed as the tracer in this study and produce the auto-radiograph. The depth of isotope penetration into the root canal was evaluated by method by Yates and Hembree at the intervals of 1 day, 7 days, 14 days and 30 days. The following conclusions were derived from the results obtained; 1. After 1 day, ZOE group exhibited the greatest penetration degree of radioisotope (p < 0.05). 2. After 14 days, there was some difference of the radioisotope penetration between each group, but its difference was not significant statistically. 3. After 30 days Sealapex group exhibited the least penetration degree of radioisotope (p < 0.025). 4. In ZOE and Sealapex groups, there was no change of the degree of radioisotope penetration with time.

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A STUDY ON THE FRACTURE STRENGTH OF THE IPS-EMPRESS CERAMIC CROWN ACCORDING TO MARGIN TYPE (IPS-Empress 도재관의 변연형태에 따른 파절강도에 관한 연구)

  • Kim, Hyun-Soo;Ju, Tae-Hun;Oh, Sang-Chun;Dong, Jin-Keun
    • The Journal of Korean Academy of Prosthodontics
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    • v.35 no.2
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    • pp.296-307
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    • 1997
  • The purpose of this study was to compare the fracture strength of the IPS-Empress ceramic crown according to margin types such as bevel, shoulder, rounded shoulder, shoulder with bevel, rounded shoulder with bevel and bevel with groove. After 10 metal dies were constructed for each group, the IPS-Empress ceramic crown were fabricated and each crown was cemented on each metal die with Bistite resin cement. The cemented crowns mounted in the testing jig were inclined 30 degree and universal testing machine (Zwick 1456 41, Zwick Co., Germany) was used to measure the fracture strength. The obtained results were as follows : 1. The fracture strength of the crown with rounded shoulder was the highest of all. The mean fracture strength was 484N in rounded shoulder, 357N in bevel, 341N in rounded shoulder with bevl, 300N in shoulder with bevel, 280N in shoulder and 275N in bevel with groove. 2. The fracture strength of rounded shoulder was statistically different from those of shoulder with bevel, shoulder and beve41 with groove. 3. In the strain at fracture, there was no significant difference among each group. 4. The fracture mode of the crown was similar and most of fracture line began at the loading area and extended through proximal surface perpendicularly to the margin, irrespective of margin type.

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A STUDY ON FRACTURE STRENGTH OF CONVENTIONAL AND COPY-MILLED IN-CERAM CROWNS (Copy-milled Celay In-Ceram 전부도재관의 파절강도에 관한 연구)

  • Hwang, Jung-Won;Yang, Jae-Ho;Lee, Sun-Hyung;Chung, Hun-Young
    • The Journal of Korean Academy of Prosthodontics
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    • v.35 no.2
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    • pp.417-430
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    • 1997
  • The purpose of this study was to compare the fracture resistance of copy-milled and conventional In-Ceram crown. Four groups of ten uniform sized all-ceramic crowns were fabricated. In-Ceram Spinell and In-Ceram Alumina crowns were fabricated as control group, Celay In-Ceram Spinell and Celay In-Ceram Alumina crowns were fabricated as test group. All specimen were cemented on stainless steel master die with resin cement, and stored in $37^{\circ}C$ water for 1 day prior to loading in Instron testing machine. Using a steel ball at a crosshead surfed of 0.5mm/min, the crowns were loaded at $30^{\circ}C$ angle until catastrophic failure occurred. The results obtained were as follows : 1. With the value of $984.8N{\pm}103.67N$, the strength of Celay In-Ceram Alumina crowns had a significantly higher fracture strength than conventional In-Ceram Alumina crowns ($876.2N{\pm}92.20N$) (P<0.05) 2. The fracture strength of Celay In-Ceram Spinell crowns($706.3{\pm}70.59N$) was greater than that of conventional In-Ceram Spinell crowns($687.4{\pm}90.26N$), but there was no significant difference(P>0.05). 3. The In-Ceram Alumina crowns had a significantly higher fracture strength than In-Ceram Spinell crowns in both methods(P<0.05). 4. Ther order of fracture strength was as followed : Celay In-Ceram Alumina, In-Ceram Alumina, Celay In-Ceram Spinell and In-Ceram Spinell crowns

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