• 제목/요약/키워드: nitrogen-doped

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Study of thermal stability of Nitrogen doped Nickel Germanosilicide (Nitrogen 도핑된 Nickel Germanosilicide의 열안정성 연구)

  • Oh Soon-Young;Yun Jang-Gn;Hwang Bin-Feng;Kim Yong-Jin;Ji Hee-Hwan;Kim Ui-Sik;Cha Han-Seob;Heo Sang-Bum;Lee Jeong-Gun;Wang Jin-Suk;Lee Hi-Deok
    • Proceedings of the IEEK Conference
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    • 2004.06b
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    • pp.513-516
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    • 2004
  • 본 논문에서는 $20\%$ Ge 조성 비율을 갖는 SiGe 200nm 에 $1\%$-Nitrogen doping 된 Nickel 을 이용하여 새로운 Nickel Germanosilicide 방법을 제안하여 Ni-Germanosilicide 의 단점인 열 안정성 개선에 대해 연구하였다. Nitrogen atom 이 grain boundary 에 존재하여 Nickel의 diffusion을 억제시키는 역할을 하여 shallow한 실리사이드와 uniform 한 실리사이드 계면 특성을 얻게 되었다. 그리고 실리사이드 형성 후, 고온로 열처리 $600^{\circ}C$, 30min 후에도 낮고 안정한 면 저항 특성으로 열안정성 개선 할 수 있다.

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Argon and Nitrogen Implantation Effects on the Structural and Optical Properties of Vacuum Evaporated Cadmium Sulphide Thin Films (CdS 박막의 구조적 및 광학적 물성에 미치는 아르곤 및 질소 이온 주입 효과)

  • ;;D. Mangalaraj
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.6
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    • pp.471-478
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    • 2002
  • Vacuum evaporated cadmium sulphide (CdS) thin films were implanted with $Ar^+$ and $N^+$ for different doses. The properties of the ion implanted CdS thin films have been analysed using XRD, optical transmittance spectra, and Raman scattering studies. Formation of Cd metallic clusters were observed in ion implanted films. The band gap of $Ar^+$ doped films decreased from 2.385 eV of the undoped film to 2.28 eV for the maximum doping. In the case of $N^+$ doped film the band gap decreased from 2.385 to 2.301 eV, whereas the absorption coefficient values increased with the increase of implantation dose. On implantation of both types of ions, the Raman peak position appeared at $299\textrm{cm}^{-1}$ and the FWHM changed with the ion dose.

Binary Doping of N-B and N-P into Graphene and Graphene Nanoribbons: Structural, Electronic, and Transport properties

  • Kim, Hyo Seok;Kim, Han Seul;Kim, Seong Sik;Kim, Yong Hoon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.647-647
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    • 2013
  • We apply a density functional theory (DFT) and DFT-based non-equilibrium Green's function approach to study the structures, energetics and charge transport characteristics of nitrogen-doped graphene and graphene nanoribbons (GNRs) with additional doping of phosphorus or boron atoms. Considering graphitic, pyridinic, and porphrin-like N doping sites and increasing N-doping concentration, we analyze the structures of N-P and N-B doped graphene and particularly focus on how they affect the charge transport along the lateral direction. For the GNRs, we also consider the differences between defects formed at the edge and bulk regions. Implications of our findings in the context of electronic and energy device applications will be also discussed.

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Ab initio Study for Electronic Property and Ferromagnetism of (Cu, N, or F)-codoped ZnO

  • Kang, Byung-Sub;Chae, Kwang-Pyo
    • Journal of Magnetics
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    • v.17 no.3
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    • pp.163-167
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    • 2012
  • The effects on the ferromagnetism of the O or Zn defect in Cu-doped ZnO with the concentration of 2.77-8.33% have been investigated by the first-principles calculations. The Cu doping in ZnO was calculated to be a kind of p-type ferromagnetic half-metals. When the Zn vacancy exists in Cu-doped ZnO, the Cu magnetic moment increases, while for the O vacancy it is reduced. It is noticeable that the ferromagnetic state was originated from the hybridized O(2p)-Cu(3d)-O(2p) chain formed through the p-d coupling. The carrier-mediated ferromagnetism by nitrogen or fluorine does not depend on their concentration.

Selective Nitrogen Doping of Carbon Nanotubes Through Different Mechanical Mixing Methods with Melamine (멜라민과의 기계적 혼합을 통한 탄소나노튜브의 선택적 질소 도핑)

  • Seon-Yeon Kim;Taewoo Kim;Seung-Yeol Jeon
    • Composites Research
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    • v.36 no.6
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    • pp.408-415
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    • 2023
  • The formation of bonding configurations such as pyridinic-N, pyrrolic-N, and graphitic-N by nitrogen doping plays a crucial role in imparting distinct physical properties to carbon nanomaterials. In this study, we propose a simple and cost-effective approach to regulate nitrogen dopant configurations in carbon nanotubes (CNTs) by mixing melamine as a dopant source. We employed three distinct mechanical mixing techniques, namely magnetic stirring, bath sonication and tip sonication. The higher the ratio of melamine to CNT, the higher the ratio of Pyrrolic-N, and when mixed through stirring, the highest ratio of Pyridinic-N was shown. The facile method proposed in this study, which can easily form various types of nitrogen dopants in carbon nanotubes, is expected to facilitate the application of nitrogen-doped carbon nanomaterials.

Preparation and Heating Characteristics of N-doped Graphite Fiber as a Heating Element (질소가 도핑 된 흑연섬유 발열체의 제조 및 발열특성)

  • Kim, Min-Ji;Lee, Kyeong Min;Lee, Sangmin;Yeo, Sang Young;Choi, Suk Soon;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.80-86
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    • 2017
  • In this study, nitrogen functional groups were introduced on graphite fiber (GF) to modify their electrical properties, and heating properties were investigated according to the treatment conditions. GF was prepared by a thermal solid-state reaction at $200^{\circ}C$ for 2 h. Surface properties of the nitrogen doped GF were examined by XPS, and its resistance and heating temperature were measured using a programmable electrometer and thermo-graphic camera, respectively. The XPS result showed that the nitrogen functional groups on the GF surface were increased with increasing of urea contents, and the heating property of the GF was also improved as nitrogen functional groups were introduced. The maximum heating temperature of GF treated by urea was $53.8^{\circ}C$ at 60 V, which showed 55% improved heating characteristics compared to that of non-treated GF. We ascribe this effect to introduced nitrogen functional groups on the GF surface by thermal solid-state reaction, which significantly affects the heating characteristics of GF.

Photocatalysis of Anodized $TiO_2$ Film Co-doped with Nitrogen and Europium

  • Choe, Jin-Uk;Jeong, Yong-Su;O, Han-Jun;Ji, Chung-Su
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.191-191
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    • 2009
  • 최근 많은 환경오염물질을 제거하기 위한 방법으로 광촉매를 이용한 기술들이 다양하게 활용되고 있다. 본 연구에서는 높은 비표면적을 갖는 관촉매를 제조하기 위해, 전기화학적인 방법인 양극 산화법을 사용하여 기지 Ti 금속 표면에 pore 형태의 광촉매용 $TiO_2$를 제조하고, 염료분해 반응을 통해 광촉매의 효율을 조사하였다. 또한 염료분해 효율을 높이기 위해 $Eu(NO_3)_3$를 첨가하여 염료분해 반응에 미치는 영향에 대해 조사하였다.

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