• Bulletin of the Korean Chemical Society
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• v.20 no.6
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• pp.712-714
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• 1999

The rate constants for the nucleophilic addition of potassium cyanide to α,N-diphenylnitrone and its derivatives (p-OCH3, p-CH3, p-Cl, and p-NO2) were determined by ultraviolet spectrophotometer at 25℃, and the rate equations which can be applied over a wide pH range were obtained. On the basis of pH-rate profile, adduct analysis, general base catalysis and substituent effect, a plausible mechanism of this addition reaction was proposed: At high pH, the cyanide ion to carbon-nitrogen double bond was rate controlling, however, in acidic media, the reaction proceeded by the addition of hydrogen cyanide molecule to carbon-nitrogen double bond after protonation at oxygen of a,N-diphenylnitrone. In the range of neutral pH, these two reactions occured competitively.

• Bulletin of the Korean Chemical Society
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• v.12 no.3
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• pp.301-303
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• 1991

The rate constants for the nucleophilic addition of thiophenol to $\alpha$, N-diphenylnitrone and it's derivatives (p-$OCH_3$, p-Cl, p-$NO_2$) were determined from pH 3.0 to 13.0 by UV spectrophotometry and rate equations which can be applied over a wide pH range were obtained. On the basis of rate equation, general base and substituent effect a plausible addition mechanism of thiophenol to ${\alpha}$, N-diphenylnitrone was proposed: At high pH, the addition of sulfide ion to carbon-nitrogen double bond was rate controlling, however, in acidic solution, reaction was proceeded by the addition of thiophenol molecule to carbon-nitrogen double bond after protonation at oxygen of ${\alpha}$, N-diphenylnitrone.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.4 no.1
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• pp.81-91
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• 1968

To investigate the effects of foliage clipping time, degree, and nitrogen top-dressing after clipping on the growth and the agronomic characteristics, rice plants grown under ordinary cultural practices were clipped at the maximum tiller stage, 10 days prior to, and after that stage, respectively, with varying clipping, height, as 0, 1/3, 1/2, and 2/3 of plant height. And nitrogen was top-dressed at the rate of 0, 2, 4, 6 kg per 10 are immediately after clipping. The variety used was ＂Jinheung＂. The results obtained are outlined as follows: 1. Effect of clipping on the growth of rice plant: The subsequent growth was quite rapid during 10 days after clipping, and resulted, on the whole, in nearly complete recovery of defoliation by 20 days after clipping. a) Generally, the later the clipping time, the more growth accelerated. Rice plants clipped before the differentiation of ear primordia nearly recovered the damage, and in certain cases exceeded non-clipped plants in height. But the height of the rice plant clipped after the differentiation of ear primordia was somewhat smaller than that of non-clipped. b) Growth rate was rather rapid in the case of severe cutting, and the height of slightly clipped plants was taller than that of non-clipped plants. However, rice plants clipped to the extent of 2/3 of plant height did not fully recover the damage of defoliation compared to non-clipped plants. c) Nitrogen dressing was effective to rapid recovery of defoliation, the effect increasing with the increasing amount of application. d) Ear-heading was delayed in clipped plots, and this tendency was more apparent with later clipping time, more severe clipping, and increased amounts of nitrogen application after cutting. The range was 6 days at maximum. 2. Effect of defoliation on the yield and its components of rice plants: The yield response to clipping varied somewhat with its time, degree, and nitrogen application after cutting: yield increase of about 10% and decreasement of about 25% at maximum compared to the control plot. Grain yield of most plots was decreased. a) Clipping before the differentiation of ear primordia did not much affect the agronomic characteristics of rice plants. However, clipping after that growth stage decreased culm length, number of panicles, number of spikelets per panicle, and maturing rate of grain to some extent. Consequently this treatment resulted in decrease of about 10% in grain and straw production in spite of increase in panicle length and effective tillering rate. b) Slight, clipping decreased number of spikelets per panicle a little, and the yield of grain and straw by 4-5%, although effective tillering rate was somewhat increased. With severe clipping, panicle kngth, number of panicles, and number of spikelets per panicle decreased more, and the yield of grain and straw decreased about 10%. c) Nitrogen dressing after clipping at the rate of 2 kg per 10 are was effective in increasing grain yield. Nitrogen application over the rate of 4 kg per 10 are increased culm length, number of spikelets per panicle, and straw production, but this decreased the maturing rate, and the 1, 000-grains weight to some extent and resulted in decrease of grain yield.

• Journal of The Korean Society of Grassland and Forage Science
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• v.23 no.2
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• pp.71-76
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• 2003

In order to determine the influence of nitrogen on agronomic characters, forage yield and quality, Jeju Italian millet(Setaria italica Beauvis) was grown on the volcanic ash soil at the Experimental Farm of Cheju national university under the six levels of nitrogen rates (0, 50, 100, 150, 200, 250kg/ha) from May 1, 2000 to August 25, 2000. Days to heading was delayed 92∼98 days as nitrogen rate increased. Plant height was 96cm at 0kg N/ha. as N rate increased, grew gradually, was 134cm at 200kg N/ha, 135cm at 250kg N/ha, and was not significantly affected between the two plots. Fresh forage, dry matter, crude protein and TDN yield increased 18.88∼42.82MT/ha, 8.45 ∼12.25MT/ha, 0.76∼1.59MT/ha and 4.32∼6.79MT/ha, respectively, as the increasing of N rate, but were not significant between 200kg N/ha and 250kg N/ha. As N rate increased, crude protein, crude fat, NFE and TDN content increased 9.0∼13.0%, 1.4∼1.7%, 9% and 51.1∼55.5%, respectively, but crude ash and crude fiber content decreased 8.7∼8.2% and 34.9∼30.2%, respectively.

• Journal of Korean Society of Forest Science
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• v.103 no.4
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• pp.703-708
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• 2014

This study was conducted to investigate effects of soil amendments on survival rate and growth of seedlings in a semi-arid region, Mongolia. 2-year-old Populus sibirica and Ulmus pumila seedlings were planted in alkaline sandy soils and treated with 2 levels of nitrogen, elemental sulfur, artificial moisture retention and converted loess. After 4 months, the seedling survival rate of both species decreased as the amount of nitrogen increased. Nitrogen has been generally known to increase seedling survival rate and growth by supplying nutrients, however, reduced survival rate in this study might be affected by consequential increase in soil osmotic pressure, which was caused by excessive nitrogen fertilization. The root collar diameter (RCD) growth of both species increased significantly by the treatment of converted loess, and only RCD growth of P. sibirica increased by the artificial moisture retention treatment. Although P. sibirica is drought-tolerant, it is in the group of Populus spp. which requires a high capacity of available water. Conversely, the elemental sulfur treatment showed no effect on survival rate and RCD growth for both species due to the low oxidation of sulfur in arid soils. The extended monitoring of seedling growth and soil characteristics is required to elucidate the long-term effects of soil amendments in the semi-arid region, and the further studies are also needed to examine the appropriate amount of fertilizers for both species.

• Journal of Bio-Environment Control
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• v.4 no.2
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• pp.175-180
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• 1995

This study was conducted to establish the nondestructive nutrient diagnosis method for nitrogen in tomato leaf using SCDS(specific color difference sensor). NFT(nutrient film technique) system was used in this experiment and nitrogen concentrations treated in nutrient solution were 0, 10, 50, 100, 150, 200, 300 and 600ppm. As nitrogen concentration in nutrient solution was increased from 0ppm to 150ppm, the stomatal resistance of tomato leaf was decreased abruptly, the $CO_2$ assimilation rate was increased but there was no big difference in the range of 100-500ppm. As the SCDS value of tomato leaf was increased, the $CO_2$ assimilation rate was increased linearly but the total average fruit weight and marketable yield were increased quadratically. The $CO_2$ assimilation rate was largely increased in the 0-3% range of leaf nitrogen content, but photosynthetic saturation was shown in 3.3-3.5%. The leaf nitrogen content was closely related to SCDS value of tomato leaf. Considering physiological activity, growth and yield of tomato, the optimum ranges of leaf nitrogen content were found to be 3.0-3.8% and the SCDS values equivalent for those ranges were 40.0-52.2.

• Journal of Korean Society of Water and Wastewater
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• v.13 no.2
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• pp.55-65
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• 1999

AF(anaerobic filter)/BAF(biological aerated filter) system and UASB(upflow anaerobic sludge blanket)/BAF system, of which system effluents were recirculated to the anaerobic reactors in each system, were operated in order to investigate the performance in simultaneous removal of organics and nitrogen in high-strength dairy wastewater. Advanced anaerobic treatment processes of AF and UASB were evaluated on applicability as pre-denitrification reactors, and BAF was also evaluated on the performance in oxidizing the remaining organics and ammonia nitrogen. At system HRTs of 4.0 to 4.5 days and recirculation ratios of one to three, the AF/BAF system could achieve more than 99% of organics removals and 64 to 78% of total nitrogen removals depending upon the recirculation ratio. Although the UASB/BAF system also showed more than 99% of organics removals, total nitrogen removals in the UASB/BAF system were 53 to 66% which are lower than those in the AF/BAF system at the corresponding recirculation ratios. Optimum recirculation ratios considering simultaneous removal of organics and nitrogen and cost-effectiveness, were in the range of two to three. The upflow AF packed with crossflow module media, as a primary treatment of the anaerobic reactor/BAF system, showed better performances in denitrification, SS removals, and gas production than the UASB. Higher loading rate of suspended solids from the UASB increased the backwashing times in the following BAF. Especially, at a recirculation ratio of three in the UASB/BAF system, the increase in head loss due to clogging in the BAF caused frequent backwashing, at least once d day. The BAF showed the high nitrification efficiency of average 99.2% and organics removals more than 90% at organics loading rate less than $1.4KgCOD/m^3/d$ and $COD/NH_3-N$ ratio less than 6.4. It was proved that the simplified anaerobic reactor/BAF system could maximize the organics removal and achieve high nitrogen removal efficiencies through recirculation of system effluents to the anaerobic reactor. The AF/BAF system can, especially, be a cost effective and competitive alternative for the simultaneous removal of organics ana nitrogen from wastewaters.

• Korean Journal of Organic Agriculture
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• v.22 no.4
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• pp.719-730
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• 2014

This study was conducted to select proper soil amendments in order to reduce the occurrence of potato scab and maintaining soil health by applications of dolomitic lime, sulfur, potassium sulfate, shell meal fertilizer, silicate fertilizer, lime nitrogen and ammonium sulfate fertilizer in different pH levels of volcanic ash soil with continuous cultivation of potato. In potassium sulfate-applied plot with a low soil pH, the incidence rate and disease severity of scab were lowest at 84.4% and 28.4%, respectively. Those were lowest among the treatments. Value of potato scab control was 12.3% and marketable yield of potato was highest at 93.2%. In lime nitrogen-applied plot (60 kg/10a), the incidence rate was low at 38.3%, and control value was 23.8% and marketable yield of potato was high at 66.3%. In relatively higher pH soils, the incidence rate of scab was lowest at 38.3% in the lime nitrogen-applied plot (60 kg/10a). Value of potato scab control was 23.8%, which was four times higher than that in sulfur-applied plot. Marketable yield of potato was highest at 66.3% in the lime nitrogen-applied plot. In the lime nitrogen plot infected with potato scab pathogen such as S. acidiscabies and S. scabiei were remarkably lower than other soil amendments at 2.5, 5, and 10 g/L concentrations of lime nitrogen using Glucose Yeast Malt (GYM) medium. In conclusion, this study suggests that potassium sulfate application in low pH soil (less than pH 5) and lime nitrogen application in relatively higher pH soil (more than pH 6) before potato seeding might be helpful to reduce the occurrence of potato scab.

• Journal of Korean Society on Water Environment
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• v.22 no.1
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• pp.45-50
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• 2006

This study was performed to evaluate the air lift reactors (ALR) by variations of HRT and recycling rate. Air lift reactor was composed of bioreactor and clarifier above it. To remove organic matters and nitrogen through the formation of microbic film and filtration, bio-filter reactors were filled with clay, glass, bead, waste plastic, respectively. Influent wastewater was fed to biofilter reactor, and effluent wastewater from bio-filter reactor was injected ALR again, instead of adding external carbon source. Effluent BOD concentration was satisfied with lower than 10 mg/L in recycling rate 100% regardless of the variation of HRT and the kinds of media materials. In HRT 4 hr, recycling rate 100%, BOD removal efficiency rate was from about 85 to 90%, COD removal efficiency rate was higher than 90%. Effluent TN concentration was satisfied with less than 20 mg/L, if HRT was maintained by over than 6 hr regardless of recycling rate and media materials. Over than HRT was 4 hr, microbes concentration in air lift reactor was maintained over than 2,500 mg/L constantly, not sensitive to environmental condition, and organic removal was effective as it was higher.

• Korean Journal of Materials Research
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• v.17 no.12
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• pp.654-659
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• 2007

Austenite precipitation behavior was studied with solidification rates and alloying contents, N and Cr, in duplex stainless steels by directional solidification. Directional solidification experiments were carried out with solidification rates, $1{\sim}100mm/s$, and N and Cr contents, $0{\sim}0.27wt.%,\;25{\sim}28wt.%$ respectively, in a duplex stainless steel, CD4MCU. As the solidification rate increases, the dendrite spacing reduced and the austenite phase in the ferrite matrix became finer. The volume fraction of austenite phase increased and its shape went to be round with increasing nitrogen contents in duplex stainless alloys. The Cr alloying element, even though it is a ferrite former, showed to enhance the nitrogen solubility in the alloy and caused the austenite round and finer. Also, Cr was supposed to decrease the austenite volume fraction, but it increased the austenite slightly due to increasing nitrogen solubility during solidification.