• Title/Summary/Keyword: nitrogen mass balance

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Estimation of Mean Air Exchange Rate and Generation Rate of Nitrogen Dioxide Using Box Model in Residence (주택에서 Box Model을 이용한 평균 환기율 및 이산화질소 발생량 추정)

  • Bae, Hyeon Ju;Yang, Won Ho;Son, Bu Sun;Kim, Dae Won
    • Journal of Environmental Science International
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    • v.13 no.7
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    • pp.645-653
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    • 2004
  • Indoor air quality is affected by source strength of pollutants, ventilation rate, decay rate, outdoor level, and so on. Although technologies measuring these factors exist directly, direct measurements of all factors are not always practical in most field studies. The purpose of this study was to develop an alternative method to estimate these factors by application of multiple measurements. For the total duration of 30 days, daily indoor and outdoor $NO_2$ concentrations were measured in 30 houses in Brisbane, Australia, and for 21 days in 40 houses in Seoul, Korea, respectively. Using a box model by mass balance and linear regression analysis, penetration factor (ventilation divided by sum of air exchange rate and deposition constant) and source strength factor (emission rate divided by sum of air exchange rate and deposition constant) were calculated, Sub-sequently, the ventilation and source strength were estimated. In Brisbane, the penetration factors were $0.59\pm0.14$ and they were unaffected by the presence of a gas range. During sampling period, geometric mean of natural ventilation was estimated to be $l.l0\pm1.5l$ ACH, assuming a residential $NO_2$ decay rate of 0.8 hr^{-1}$ in Brisbane. In Seoul, natural ventilation was $1.15\pm1.73$ ACH with residential $NO_2$ decay rate of 0.94 hr^{-1}$ Source strength of $NO_2$ in the houses with gas range $(12.7\pm9.8$ ppb/hr) were significantly higher than those in houses with an electric range $(2.8\pm2,6$ ppb/hr) in Brisbane. In Seoul, source strength in the houses with gas range were $l6.8\pm8.2$ ppb/hr. Conclusively, indoor air quality using box model by mass balance was effectively characterized.

Experiment of Natural Circulation Loop Using a Cryocooler (극저온냉동기를 이용한 자연순환 루프의 실험)

  • Kim, M.J.;Chang, H.M.
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2194-2199
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    • 2007
  • An experimental study is performed to investigate the thermal and flow characteristics of subcooled liquid nitrogen in a natural circulation loop. Experimental apparatus is designed and constructed such that a closed loop is cooled at the top by a cryocooler and heated nearly at the bottom by cartridge heaters. Steady state is obtained by controlling the heating power to the cartridge heaters and a thin-film heater to reduce the cooling power of the cryocooler. Temperature is measured at several locations of the loop and the mass flow rate through the loop is estimated from the energy balance in terms of the measured temperatures. Experiment is repeated for various values of the vertical height between the cooling and heating parts. The results show that the heat transfer capability of the loop has a maximum at a certain value of height. The optimal height to maximize the heat transfer is in a good agreement with analytical prediction to take into account the buoyancy and viscous forces in the loop.

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Rice growth and Nutrient change in paddy soil with reclaimed sewage irrigation (오수처리수 관개방법에 따른 수도 생육과 토양내 영양물질 변화)

  • 윤춘경;황하선;우선호
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.43 no.6
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    • pp.154-162
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    • 2001
  • This study was performed to examine the rice growth and nutrient change in paddy soil with reclaimed sewage irrigation. Total nitrogen and total phosphorus in the experimental system were analyzed before and after rice culture. The experiment lasted three consecutive years, and this paper presents results of the last year. Additional supply of nutrients to the rice culture by reclaimed sewage irrigation was significant and it increased the yield. Nutrient uptake by rice plant increased with more nutrient supplied, however. there was limit in plant uptake. Nutrient accumulation occurred in the soil and it was more apparent for the phosphorus where most of the remaining quantity was accumulated while substantial amount of nitrogen was lost during the growing season. This study suggested that additional nutrient supply by reclaimed sewage irrigation might be a supplemental benefit to the rice culture, and it can help the fertilization management. However, long term effects of continual reclaimed sewage irrigation should be assessed carefully including nutrient mass balance in the paddy rice culture system.

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Anaerobic/oxic Treatment of Slurry-type Swine Waste

  • Won, Chul-Hee;Rim, Jay-Myoung
    • Environmental Engineering Research
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    • v.13 no.4
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    • pp.203-209
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    • 2008
  • This paper presents the experimental results in five months operation from a combined anaerobic/oxic system treating swine waste with average concentrations in organic matter and nitrogen of 7,930 mgCOD/L and 671 mgTKN/L, respectively. The system was formed using an upflow anaerobic sludge blanket (UASB) reactor and oxic reactor connected in series with a recycling line of oxic effluents to UASB for its denitrification. The UASB reactor was operated at an organic volumetric loading rate (VLR) of $2.1{\sim}4.5\;kgTCOD/m^3$/day and the removal efficiency of TCOD was $66.3{\sim}85.4%$. The overall removal efficiency of TCOD was more than 99%. The oxic reactor was operated at a nitrogen VLR of $0.10{\sim}0.20\;kgTKN/m^3$/day and the nitrification efficiency was 75%. However, the complete denitrification was observed in the UASB reactor that was due to the optimal temperature and sufficient carbon source. The overall removal rate of TN was about 80%. About 76.2% of the influent COD mass was accountable in a COD mass balance at a level of VLR $3.64\;kgCOD/m^3$/day. The production rate of methane was $0.32\;LCH_4/gCOD_{removed}$ when influent organics, VLR, were recorded by $3.4{\sim}4.5\;kgCOD/m^3$/day.

Experimental Study of the Evaporation of Spreading Liquid Nitrogen (확산하는 액체질소의 증발에 관한 실험적 연구)

  • KIM, MYUNGBAE;CHOI, BYUNGIL;KIM, TAE-HOON;DO, KYHYUNG;HAN, YONGSHIK;CHUNG, KYUNGYUL
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.5
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    • pp.466-472
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    • 2018
  • The investigation of cryogenic liquid pool spreading is an essential procedure to assess the hazard of cryogenic liquid usage. In this experimental study, to measure the evaporation velocity when the pool is spreading, liquid nitrogen was continuously released onto unconfined concrete ground. Almost all of the reported results are based on a non-spreading pool in which cryogenic liquid is instantaneously poured onto bounded ground for a very short period of time. A simultaneous measurement of the pool location using thermocouples and of the pool mass using a digital balance was carried out to measure the evaporation velocity and the pool radius. A greater release flow rate was found to result in a greater average evaporation velocity, and the evaporation velocity decreased with the spreading time and the pool radius.

Runoff Characteristics of the Livestock Manure as Fertilizer at Farmland (가축분뇨 비료의 농지 유출 특성)

  • Oa, Seong-Wook
    • Journal of Korean Society on Water Environment
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    • v.26 no.5
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    • pp.775-780
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    • 2010
  • Over 90% of the livestock excretions were treated and utilized by land application in Korea. Excessive application of the livestock manure as fertilizer has been issued as a main pollutant source in groundwater and watersheds. This study was seasonally conducted to identify the discharging characteristics with a certain artificial rainfall intensity (13 mm/hr) in terms of surface runoff, groundwater, and soil residue mass depending on the livestock manure types. A experimental field was constructed with three different sites that pig liquid fertilizer (LF), cattle manure (CM), and standard (S). The pig liquid fertilizer of 1,200 L and cattle manure of 900 kg were sprayed on each site ($50m^2$). The standard area was firmly prevented from any other contaminants. In the LF site, farmland discharging rate (FDR) was computed as 0.006 in CODcr, 0.015 in TN, and 0.029 in TP, resulted from the mass balance among total injection mass, surface runoff and groundwater. In the CM site, 29% of the nitrogen and phosphorus in each were discharged to the surface, and 64% and 58% of them were remained in the farmland. Surface runoff rate of the CM was higher than that of the LF, resulted from the solid form of the CM.

A Study on Energy expenditure in Korean Adult (한국인의 에너지 소비량에 관한 연구)

  • 오승호
    • Journal of Nutrition and Health
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    • v.22 no.6
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    • pp.423-437
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    • 1989
  • A 4-week energy balance study was conducted to estimate the energy expenditure (EE) of 16 college age men and women, 20 to 26 year of age, by measurement of energy intakes and changes in body energy(BE) content(intake/balance technique), keeping their normal living pattern and maintenance body weight. Energy intake was measured by bomb calorimetry and estimated by food table. Fecal energy loss was calculated from nitrogen excreted. Fat mass was determined from body density estimated from skinfold tickness. 1) Gross energy (GE) intakes calculated from food table was not only 13.4% lower than those of bomb calorimetry but also lower 4 and 5% than metabolizable energy(ME) intakes for the male and female subjects, respectively. 2) Fecal energy loss was 7.2% and 6.9% proportion of the gross energy intake for the male and female subjects, respectively. 3) Mean daily metabolizable energy intakes estimated by subtract fecal and urinary energy loss was 2467kcal for the male subjects and 1897kcal for the female subjects. 4) Total body energy change estimated from body composition change over 31 days was decreased 7672kcal for the male subjects and 2689kcal for the female subjects. 5) Mean daily energy expenditure was 2714kcal (45kcal/kg of body weight) for the male subjects and 1984kcal(40kcal/kg of body weight) for the female subjects. 6) The estimated energy expenditure of college-age subjects in this study provide evidence to support the Recommended Dietary Allowances for energy of Korean normal adult.

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The characteristic analysis and model of PEM fuel cell for residential application (가정용 고분자 연료전지의 모델과 특성해석)

  • Cho, Y.R.;Kim, N.H.;Han, K.H.;Joo, K.D.;Yun, S.Y.;Baek, S.H.
    • Proceedings of the KIEE Conference
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    • 2005.04a
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    • pp.277-279
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    • 2005
  • The imbalance of energy demand and supply caused by rapid industrialization around the world and the associated environmental issues require and alternative energy source with possible renewable fuels. Political instability and depletion of cruel oils are other factors that cause fluctuation of oil price. Securing a new alternative energy source for the next century became an urgent issue that our nation is confronting with. As a matter of fact, the fuel cell technology can be widely used as next generation energy regardless of regions and climate. Specially, the ability of expansion and quick installation enable one to apply it for distributed power, where the technology is already gaining remarkable attentions for the application. Particularly, leading industrialized nations are focusing on the PEM fuel dell with anticipation that this technology will find their place of applications in the vehicles and homes. In this study, demonstrate the multi physics modeling of a proton exchange membrane(PEM) fuel cell with interdigitated flow field design. The model uses current balances, mass balance(Maxwell-Stefan diffusion for reactant, water and nitrogen gas) and momentum balance(gas flow) to simulate the PEM fuel cell behavior.

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Maximization of Poly-$\beta$-Hydroxybutyrate Accumulation by Potassium Limitation in Methylobacterium organophilum and Its Related Metabolic Analysis

  • Kim, Seon-Won;Kim, Pil;Kim, Jung-Hoe
    • Journal of Microbiology and Biotechnology
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    • v.9 no.2
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    • pp.140-146
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    • 1999
  • When methanol was the sole carbon source, Methylobacterium organophilum NCIB 11278, a facultative methylotroph, accumulated Poly-$\beta$-hydroxybutyrate (PHB) as 59% (w/w) of dry cell weight under potassium limitation, 37% under sulfate limitation, and 33% under nitrogen limitation. Based on a stoichiometric analysis of PHB synthesis from methanol, it was suspected that PHB synthesis is accompanied by the overproduction of energy, either 6-10 ATP and 1 $FADH_2$ or 6 ATP and 3 NADPH to balance the NADH requirement, per PHB monomer. This was confirmed by observation of increased intracellular ATP levels during PHB accumulation. The intracellular ATP with limited potassium, sulfate, and ammonium increased to 0.185, 0.452, and 0.390 $\mu$moles ATP/g Xr (residual cell mass) during PHB accumulation, respectively. The intracellular ATP level under potassium limitation was similar to that when there was no nutrient limitation and no PHB accumulation, 0.152- 0.186 $\mu$moles ATP/g Xr. We propose that the maximum PHB accumulation observed when potassium was limited is a result of the energy balance during PHB accumulation. Microorganisms have high energy requirements under potassium limitation. Enhanced PHB accumulation, in ammonium and sulfate limited conditions with the addition of 2,4-dinitrophenol, which dissipates surplus energy, proves this assumption. With the addition of 1 mM of 2,4-dinitrophenol, the PHB content increased from 32.4% to 58.5% of dry cell weight when nitrogen limited and from 15.1 % to 31.0% of dry cell weight when sulfate limited.

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Estimation of Nitrite Concentration in the Biological Nitritation Process Using Enzymatic Inhibition Kinetics

  • GIL, KYUNG-IK;EUI-SO CHOI
    • Journal of Microbiology and Biotechnology
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    • v.12 no.3
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    • pp.377-381
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    • 2002
  • Recently, interests to remove nitrogen in the nitritation process have increased because of its economical advantages, since it could be a short-cut process to save both oxygen for nitrification and carbon for denitrification compared to a typical nitrification. However, the kinetics related with the nitritation process has not yet been fully understood. Furthermore, many useful models which have been successfully used for wastewater treatment processes cannot be used to estimate effluent nitrite concentration for evaluating performance of the nitritation process, since the process rate equations and population of microorganisms for nitrogen removal in these models have been set up only for the condition of full nitrification. Therefore, the present study was conducted to estimate an effluent nitrite concentration in the nitritation process with a concept of enzymatic inhibition kinetics based on long-term laboratory experiments. Using a nonlinear least squares regression method, kinetic parameters were accurately determined. By setting up a process rate equation along with a mass balance equation of the nitrite-oxidizing step, an effluent nitrite concentration in the nitritation process was then successfully estimated.