• Title/Summary/Keyword: nitrogen ion

Search Result 601, Processing Time 0.024 seconds

Effect of Nitrogen Ion Implantation on Corrosion Resistance of Biocompatible Ti Implant (질소이온의 주입이 생체안전성 티타늄임플란트의 내식성에 미치는 영향)

  • 최종운;손선희
    • Journal of the Korean Society of Safety
    • /
    • v.14 no.3
    • /
    • pp.134-139
    • /
    • 1999
  • In this study, PSII(plasma source ion implantation) was used to improve the biocompatibility of bone-anchored Ti implant. According to potentiodynamic anodic polarization test in deaerated Hank's solution, open circuit potential of ion implanted specimens were increased compare to that of unimplanted specimen ; besides, passive current density and critical anodic current density of ion implanted specimens were lower than unimplanted specimen.

  • PDF

Response-Improved Electrochromic Display Device Based on Organic Materials (고응답성 유기계 전기변색성 소자의 제작과 특성)

  • 권태선
    • Journal of the Korean Graphic Arts Communication Society
    • /
    • v.12 no.1
    • /
    • pp.81.1-91
    • /
    • 1994
  • Irradiation of aromatic diazonium salts resulted in an effcient elimination of nitrogen, yielding substitution products. This paper was not only studies about photolysis of aromatic diazonium with double salts but also coexistence of ion and radical when they was photolysis. Photolysis of aromatic diazonium was depend on excite wave length therefore photolysis products out put different absorption intensity such other. We also confirmed coexistence of ion and radical when they was accomplished photolysis. In case of BD, there are ion decomposition process about 90 percentage, decreased ion decomposition process the other side radical`s it was becomeing increased according to excite of short-wave length.

  • PDF

The removal of Nitrate-nitrogen from ground water by electrodialysis (전기투석을 이용한 지하수 중의 질산성질소 제거)

  • Min, Ji-Hee;Kim, Han-Seung
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.22 no.3
    • /
    • pp.307-314
    • /
    • 2008
  • In this study, the effects of applied voltage, solution pH and coexistence of other ions such as sulfate ion (${SO_4}^{2-}$) and chloride ion ($Cl^-$) were investigated on the removal of nitrate-nitrogen ($NO_3{^-}-N$) from ground water by electrodialysis. The examined operating conditions were evaluated for optimizing the removal efficiency of $NO_3{^-}-N$. Real ground water samples taken from a rural area of Yongin city and artificial ones with components similar to the real ground water were tested for the study, which contained $NO_3{^-}-N$ concentration of 17mg/L that exceeds current drinking water quality standard of 10 mg/L. The increase in the removal rate of $NO_3{^-}-N$ was observed as the applied voltage increased from 5V to 30V, while no significant increase in the removal rate appeared at the applied voltage beyond 20V during a given operating time. The removal rate appeared to get lower at both acidic and basic condition, compared to neutral pH. Coexistence of of ${SO_4}^{2-}$and $Cl^-$ demanded much longer operating time to achieve a given removal rate or to meet a certain level of treated water concentration. When nitrate ion was combined with ${SO_4}^{2-}$and $Cl^-$, the removal rate was reduced by 4.29% and 10.83%, respectively.

Evaluation on Design Factors of Electrolytic Flotation Reactor by Measuring Polarization Curve (분극곡선 측정을 통한 전해부상조의 설계인자 평가)

  • Lim, Bong-Su;Jin, Jing-Zhu;Choi, Chan-Soo
    • Journal of Korean Society on Water Environment
    • /
    • v.23 no.2
    • /
    • pp.244-250
    • /
    • 2007
  • This study was carried out to obtain the optimum design factors for an eletrolytric flotation reactor. When the effluent of the leachate treatment facility was treated under the condition of 10 volts, 30 minutes, at the Al-Al electrode system; COD removal efficiency was 45%, and total phosphorus removal efficiency was 98%. The high removal efficiency was caused by the fact that phosphate was removed by leaching $Al^{3+}$ from two electrodes. The leachate containing high ammonium nitrogen concentration was treated by a batch test under the condition of 60 minutes reaction time and added chloride ion; ammonium nitrogen removal efficiency was 89%. This high efficiency was affected by added chloride ion to wastewater. To find the optimum current density and voltage of the leachate containing chloride ion (ratio of $Cl^-/NH_4-N$ is 11) a electrochemical polarization curve was used. These values were found to be $4.5mA/cm^2$ and about 2.1 V, respectively. When C-Al electrode system was used at a batch test, the total nitrogen removal efficiency was increased by 1.8 to 3.3 times, compared to Al-Al electrode system due to high $Cl_2$ gas production.

Preparation of New Corrosive Resistive Magnesium Coating Films (고내식성의 신 마그네슘 코팅막 제작)

  • Lee, Myeong-Hun
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.20 no.5
    • /
    • pp.103-113
    • /
    • 1996
  • The properties of the deposited film depend on the deposition condition and these, in turn depend critically on the morphology and crystal orientation of the films. Therefore, it is important to clarify the nucleation occurrence and growth stage of the morphology and orientation of the film affected by deposition parameters, e.g. the gas pressure and bias voltage etc. In this work, magnesium thin flims were prepared on cold-rolled steel substrates by a thermo-eletron activation ion plating technique. The influence of nitrogen gas pressure and substrate bias voltage on their crystal orientation and morphology of the coated films were investigated by scanning electron microscopy (SEM) and X-ray diffraction, respectively. The diffraction peaks of magnesium film became less sharp and broadened with the increase of nitrogen gas pressure. With an increase in nitrogen gas pressure, flim morphology changed from colum nar to granular structure, and surface crystal grain-size decreased. The morphology of films depended not only on gas pressure but also on bias voltage, i.e., the effect of increasing bias voltage was similar to that of decreasing gas pressure. The effect of crystal orientation and morphology of magnesium films on corrosion behaviors was estimated by measuring anodic polarization curves in deaerated 3%NaCl solution. Magnesium, in general, has not a good corrosion resistance in all environments. However, these magnesium films prepared by changing nitrogen gas pressure showed good corrosion resistance. Among the films, magnesium films which exhibited granular structure had the highest corrosion resistance. The above phenomena can be explained by applying the effects of adsorption, occlusion and ion sputter of nitrogen gas.

  • PDF

Lifetime Enhancement of Aerospace Components Using a Dual Nitrogen Plasma Immersion ion Implantation Process

  • Honghui Tong;Qinchuan Chen;Shen, Li-Lu;Yanfeng Huo;Ke Wang;Tanmin Feng;Lilan Mu;Jun Zha;Paul K. Chu
    • Journal of Korean Vacuum Science & Technology
    • /
    • v.6 no.2
    • /
    • pp.62-66
    • /
    • 2002
  • Hydraulic pumps are used to control the landing wheels of aircrafts, and their proper operation is vital to plane safety It is well hewn that adhesive wear failure is a major cause of pump failure. A dual nitrogen plasma immersion ion implantation process calling for the implantation of nitrogen at two different energies and doses has been developed to enhance the surface properties of the disks in the pumps. The procedures meet the strict temperature requirement of <200$^{\circ}C$, and after the treatment, the working lifetime of the pumps increases by more than a factor of two. This experimental protocol has been adopted by the hydraulic pump factory as a standard manufacturing procedure.

  • PDF

Ootimization of Mekium Components for Lactic Acid Production (젖산 생산을 위한 배지 최적화)

  • Cho, Yun-Kyung;Cho, Kyu-Hong;Hong, Seung-Suh;Lee, Hyun-Soo
    • Microbiology and Biotechnology Letters
    • /
    • v.23 no.1
    • /
    • pp.12-16
    • /
    • 1995
  • Medium components for lactic acid production were optimized with a strain of Lactobacillus sp., isolated by our Lab. Nitrogen source was the key component and manganese ion was also important for lactic acid production in this strain. Optimal concentration of manganese ion was 0.03 g/l as MnSO$_{4}$ 4 - 5 H$_{2}$O base. Other mineral elements, however, had little effect on it. Among the nitrogen sources we examined, yeast extract showed the highest productivity. Yeast extract, the exellent but very expensive medium component, could be partially replaced by soytone until 60% dry base with higher productivity, or by tryptone enforced with vitamines and nucleic acids. In order to replace yeast extract completely, we examined several inexpensive nitrogen sources and their enzymatic hydrolyzates. The hydrolyzate of vital wheat gluten was the best of them.

  • PDF

HCD Ion Plating of Ti(C, N) Films for Cutting Tools (절삭공구용 Ti(C, N)피막의 HCD식 이온도금시 공정변수의 영향)

  • 강형호;고경현;안재환
    • Journal of Surface Science and Engineering
    • /
    • v.27 no.3
    • /
    • pp.143-148
    • /
    • 1994
  • Effects of process variables of HCD ion plating on the film composition of Ti(C, N) were analyzed. The mole ratio of carbon to nitrogen and that of non-metal to titanium in the film primarily depend on the partial pressure ratio of ($C-2H_2$/ $N_2$) and total reactive gas pressure, respectively. The amount of nonmetallic com-ponents increases in nonlinear fashion as the total gas pressure due to the different reactivity of $C-2H_2$ and $N_2$ gases with Ti. The nonmetallic components was saturated dwith nitrogen when the nitrogen gas was more than 60% of total reactive gas. These two process variables could be related systematically using the concept of effective pressure in which the difference of reactivity of each gas was normalized.

  • PDF

Detection of Al3+ by fluorescent turn-on nitrogen/sulphur-binary doped carbon dots

  • Siti Raudhatul Kamali;Chang-Nan Chen;Tai-Huei Wei
    • Analytical Science and Technology
    • /
    • v.36 no.4
    • /
    • pp.161-169
    • /
    • 2023
  • In this study, a straightforward and precise nitrogen/sulphur-codoped carbon dots (N/S-CD) was produced using a microwave irradiation approach. The N/S-CD was formulated from succinic acid (SA), bis-(3-aminopropyl)-amine (BAPA), and sodium thiosulphate (STS) as sources of carbon, nitrogen, and sulphur, respectively. The synthesized N/S-CD established a valuable quantum yield (QY) of 70 % and was sensitive to aluminium ion (Al3+) with a detection limit of 0.21 µM and a linear concentration range of 0-100 µM. When detecting Al3+ in real water samples, the N/S-CD resulted in a satisfactory recovery in the range of 91.14 %-103.37 %. Thus, the proposed study is very promising for Al3+ detection in environmental water samples.

The Formation Rate and Activation Energy of Diffusion Layer and Compound Layer in Ion-Nitriding (이온질화 에 있어 확산층 및 합성층 의 생성속도 및 질소 의 활성화에너지)

  • 성환태;유봉환;조규식
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.8 no.5
    • /
    • pp.476-480
    • /
    • 1984
  • This paper deals with nitrogen diffusion velocity and activation energy in diffusion layer and compound layer in ion-nitriding, and presents observations on the effect of deformation according to nitriding methods. During the experiment the activation energy and diffusion velocity of nitrogen have been examined in S45C steel samples. It is found that the results of an investigation correspond with the theoretical data and the ion-nitriding method offers less deformation than conventional salt-bath method of nitriding.