• Title/Summary/Keyword: nitrogen flow rate

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Effect of Air-flow on Enhanced Nutrient Removal and Simultaneous Nitrification/Denitrification in DMR Biofilm Process (DMR 생물막 공정에서 포기량에 따른 질산화 동시 탈질화 및 영양염류 제거특성)

  • Kim, Il-Kyu;Lee, Sang-Min;Lim, Kyeong-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.10
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    • pp.992-998
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    • 2008
  • Recently, a new concept for nitrogen removal that is simultaneous nitrification and denitrification(SND) has been studied for wastewater treatment process. The DMR(Daiho Microbic Revolution) process that used in this study consists of two suspended anoxic, anaerobic reactors and an aerobic biofilm reactor. The function of aerobic environment and the intensity of air flow rate(2.0, 1.0, 0.5, 0.4, 0.2 L/min) were studied in the biofilm reactor; also SND and nutrient removal efficiencies were investigated. Experimental results indicated that the change in air flow did not affect COD$_{Cr}$ removal significantly. Thus sustained at 93%. The lower the air flow rate, the higher T-N removal efficiency was attained(i.e.80% at 0.2 L/min). SND efficiency was 62, 65, 72 and 78% corresponding to each air flow rate. T-P removal was sensitive to aeration intensity and removal enhanced from 75% to 96% when the air flow rate was changed from 2.0 to 0.5 L/m; however second release occured in the clarifier at 0.2 L/min. Phosphorus content of activated sludge was 5.0%, as P releases and acetate uptake a ratio of 0.75 mg P/ mg HAc.

Numerical Studies of a Separator for Stack Temperature Control in a Molten Carbonate Fuel Cell (용융탄산염 연료전지 스택 온도 조절을 위한 분리판에 관한 수치 해석 연구)

  • Kim, Do-Hyung;Kim, Beom-Joo;Lim, Hee-Chun
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.305-312
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    • 2011
  • The use of a separator to control stack temperature in a molten carbonate fuel cell was studied by numerical simulation using a computational fluid dynamics code. The stack model assumed steady-state and constant-load operation of a co-flow stack with an external reformer at atmospheric pressure. Representing a conventional cell type, separators with two flow paths, one each for the anode and cathode gas, were simulated under conditions in which the cathode gas was composed of either air and carbon dioxide (case I) or oxygen and carbon dioxide (case II). The results showed that the average cell potential in case II was higher than that in case I due to the higher partial pressures of oxygen and carbon dioxide in the cathode gas. This result indicates that the amount of heat released during the electrochemical reactions was less for case II than for case I under the same load. However, simulated results showed that the maximum stack temperature in case I was lower than that in case II due to a reduction in the total flow rate of the cathode gas. To control the stack temperature and retain a high cell potential, we proposed the use of a separator with three flow paths (case III); two flow paths for the electrodes and a path in the center of the separator for the flow of nitrogen for cooling. The simulated results for case III showed that the average cell potential was similar to that in case II, indicating that the amount of heat released in the stack was similar to that in case II, and that the maximum stack temperature was the lowest of the three cases due to the nitrogen gas flow in the center of the separator. In summary, the simulated results showed that the use of a separator with three flow paths enabled temperature control in a co-flow stack with an external reformer at atmospheric pressure.

A Study on the Combustion Flow Characteristics of a Exhaust Gas Recirculation Burner with the Change of Outlet Opening Position (배기가스 재순환 버너에서 연소가스 출구 위치에 따른 연소 유동 특성에 관한 연구)

  • Ha, Ji-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.8
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    • pp.8-13
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    • 2018
  • Nitrogen oxides (NOx) have recently been very influential in the generation of ultrafine dust, which is of great social interest in terms of improving the atmospheric environment. Nitrogen oxides are generated mainly by the reaction of nitrogen and oxygen in air in a combustion gas atmosphere of high temperature in a combustion apparatus such as thermal power generation. Recently, research has been conducted on the combustion that recirculates the exhaust gas to the cylindrical burner by using a piping using a Coanda nozzle. In this study, three types of burners were carried out through computational fluid analysis. Case 1 burner with the outlet of the combustion gas to the right, Case 2 burner with both sides as gas exit, Case 3 burner with left side gas exit. The pressure, flow, temperature, combustion reaction rate and distribution characteristics of nitrogen oxides were compared and analyzed. The combustion reaction occurred in Case 1 and Case 2 burner in the right direction with combustion gas recirculation inlet and Case 3 burner in the vicinity of mixed gas inlet. The temperature at the outlet was about $100^{\circ}C$ lower than that of the other burners as the Case 2 burner was exhausted to both sides. The NOx concentration of Case 1 burner at the exit was about 20 times larger than that of the other burners. From the present study, it could be seen that it is effective for the NOx reduction to exhaust the exhaust gas to both side gas exits or to exhaust the exhaust gas to the opposite direction of inlet of recirculation gas.

Performance of a 5 L Liquid Hydrogen Storage Vessel (5 L급 액체수소 저장용기의 성능특성 연구)

  • KARNG, SARNG WOO;GARCEAU, NATHANIEL;LIM, CHANG MU;BAIK, JONG HOON;KIM, SEO YOUNG;OH, IN-HWAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.3
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    • pp.234-240
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    • 2015
  • In the face of the world's growing energy storage needs, liquid hydrogen offers a high energy density solution for the storage and transport of energy throughout society. A 5 L liquid hydrogen storage tank has been designed, fabricated and tested to investigate boil-off rate of liquid hydrogen. As the insulation plays a key role on the cryogenic vessels, various insulation methods have been employed. To reduce heat conduction loss, the epoxy resin-based insulation supports G-10 were used. To minimize radiation heat loss, vapor cooled radiation shield, multi-layer insulation, and high vacuum were adopted. Mass flow meter was used to measure boil-off rate of the 5 L cryogenic vessel. A series of performance tests were done for liquid nitrogen and liquid hydrogen to compare with design parameters, resulting in the boil-off rate of 1.7%/day for liquid nitrogen and 16.8%/day for liquid hydrogen at maximum.

Analysis of the water quality and correlation of impact factors during summer season in changnyeong-haman weir section (하절기 낙동강 창녕함안보 구간에서의 수질특성 및 영향인자의 상관관계 분석)

  • Jung, Sun-Young;Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.1
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    • pp.83-91
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    • 2017
  • This study analyzed the correlation between Chl-a and water quality factors using characteristics of climate data, water quality factors, and various statistical analysis techniques during the summer season in the Nakdong River during the 2-year period. The purpose of this study is to provide the basic data for establishing water quality management policy in the Changnyeong-Haman weir section. From the end of July to the middle of August when algae mainly occur, both the years 2015 and 2016 are in the temperature range of $25{\sim}30^{\circ}C$, and the total precipitation of 2015 is less than that of 2016 in this period. As a result of comparing the concentration of Chl-a, the average Chl-a concentration of 2015 was higher than that of 2016, which seems to be related to the total precipitation in the occurrence of algae. The results of the correlation analysis showed that the correlation with PO4-P was significant at most points. As a result of the factor analysis, the first principal factor group classified PO4-P, NH3-N, TP, pH, flow rate, TN and this section seems to be influenced by phosphorus and nitrogen and flow rate.

The Effect of V/III Ratio on Growth Mechanism of Gas Source MBE (가스소스 MBE에서 원료공급량이 결정성장 기구에 미치는 영향)

  • Choi, Sungkuk;Yoo, Jinyeop;Jung, Soohoon;Chang, Wonbeom;Chang, Jiho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.6
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    • pp.446-450
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    • 2013
  • Growth mechanism of GS-MBE(Gas source-Molecular Beam Epitaxy) has been investigated. We observed that the growth rate of GaN films is changing from 520 nm/h to 440 nm/h by the variation of V/III ratio under nitrogen-rich growth condition. It was explained that the amount of hydrogen on the growth front varies by the ammonia flow, and gallium hydrides are generated on the surface by a reaction of hydrogen and gallium, resultantly the amount of gallium supplying is changing along with the $NH_3$ flow. Reflection high energy electron diffraction (RHEED) observation was used to confirm the N-rich condition. The crystal quality of GaN was estimated by photoluminescence (PL) and X-ray diffraction (XRD).

Density Measurement Comparisons of Specific Gravity Meter and Gas Chromatography in the Field (실제조건에서 기준 밀도계와 가스 분석기에 의한 밀도 측정 결과 비교)

  • Lee, Kang-Jin;Her, Jae-Young;Ha, Young-Cheol
    • 유체기계공업학회:학술대회논문집
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    • 1999.12a
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    • pp.90-96
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    • 1999
  • In contracts for sales of natural gas between sellers and buyers, it is not suncient to only measure a volumetric quantity of gas in flowing conditions in metering station. Therefore the measured volumetric quantity must be converted to that of reference conditions. The density of the natural gas required in such a calculation can be measured directly or estimated from the equation of sate or any other experimental methods. The specific gravity meter is the apparatus used to measure the density of fluids under the reference conditions and it can be widely used in industrial areas, especially in massive flow rate natural gas industry. This study has been carried out in an attempt to improve measurement accuracy of natural gas flow rate calculation, providing the adequate installation and proper operation conditions of specific gravity meter. The test results are 1) the density measurement errors in case of using methane and standard gas as calibration gases are smaller than using methane and nitrogen gas, 2) the periodical calibration to maintain accurate density measurements is essential, and 3) the specific gravity meter is sensitive to changes of environmental conditions, especially environmental temperature surrounding the specific gravity meter.

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Off-design performance evaluation of multistage axial gas turbines for a closed Brayton cycle of sodium-cooled fast reactor

  • Jae Hyun Choi;Jung Yoon;Sungkun Chung;Namhyeong Kim;HangJin Jo
    • Nuclear Engineering and Technology
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    • v.55 no.7
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    • pp.2697-2711
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    • 2023
  • In this study, the validity of reducing the number of gas turbine stages designed for a nitrogen Brayton cycle coupled to a sodium-cooled fast reactor was assessed. The turbine performance was evaluated through computational fluid dynamics (CFD) simulations under different off-design conditions controlled by a reduced flow rate and reduced rotational speed. Two different multistage gas turbines designed to extract almost the same specific work were selected: two- and three-stage turbines (mid-span stage loading coefficient: 1.23 and 1.0, respectively). Real gas properties were considered in the CFD simulation in accordance with the Peng-Robinson's equation of state. According to the CFD results, the off-design performance of the two-stage turbine is comparable to that of the three-stage turbine. Moreover, compared to the three-stage turbine, the two-stage turbine generates less entropy across the shock wave. The results indicate that under both design and off-design conditions, increasing the stage loading coefficient for a fewer number of turbine stages is effective in terms of performance and size. Furthermore, the Ellipse law can be used to assess off-design performance and increasing exponent of the expansion ratio term better predicts the off-design performance with a few stages (two or three).

A Study on Nitrification of Raw Waters Containing Linear Alkyl Sulfate in Biological Activated Carbon (생물활성탄을 이용한 Linear Alkyl Sulfate함유 원수에서의 질산화에 관한 연구)

  • Park, Seong Sun;Chang, Ji Soo;Yu, Myong Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.3
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    • pp.116-126
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    • 1995
  • The purpose of this study was to investigate the removal of ammonium nitrogen by biological nitrification in raw water containing LAS using BAC. At batch teats, LAS removal by ozone followed the first order reaction, and the rate constants(k) by ozone dose 1, 3mg/min.L were $0.040min^{-1}$, $0.062min^{-1}$ respectively. Therefore, the more ozone was dosed, the higher LAS was removed The reaction between ozone and ammonium nitrogen also followed the first order, and rate constants(k) at pH7,8 and 9 were $8.9{\times}10^{-4}min-1$, $3.8{\times}10^{-3}min^{-1}$, and $2.9{\times}10^{-2}min^{-1}$ respectively at ozone dose of 3mg/min.L . Therefore, ammonium nitrogen was little removed by ozone under neutral pH of 7. The continuous flow apparatus had four sets composed of a ozone contacter and a GAC column. Through continuous filtration test for 50days, the following conclusions were derived; (1) LAS was removed 23%, 30% respectively by ozone dose 1, 3mg/L, and was not detected in all column effluents during the period of experiment. Therefore, it appeared that adsorption capacities of each column still remained. (2) Ammonium nitrogen concentration after ozone contact varied little in raw Water because pH of raw water was from 6 to 7, and was transfered to nitrite and nitrate within GAC columns as the result of staged nitrification. After 30days, nitrite was not detected in all column effluents due to biological equilbrium between nitro semonas and nitrobacter Average removals of ammonium nitrogen in each column after the lapse of 30days were the following; ${\cdot}$ column A (ozone dose 3mg/L, EBCT 9.5min): about 100% ${\cdot}$ column B (ozone dose 1mg/L, EBCT 9.5min): 91% ${\cdot}$ column C (ozone dose 3mg/L, EBCT 14.2min): about 100% ${\cdot}$ column D (ozone dose 0mg/L, EBCT 9.5min): 53% Though column A and C reached nitrification of about 100%, column C (longer EBCT than column A) was more stable than column A. (3) After backwash, nitrification reached steady state within 5 to 8 hours. Therefore, nitrification was not greatly affected by backwash. (4) According to the nitrification capacity in depth of column A, C, where 100% nitrification occured. LAS was removed within 20cm, while ammonium nitrogen required more depth to be removed by nitrification.

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Improvement of adhesion strength of Butadiene Rubber using Atmospheric Plasma (대기압 플라즈마를 이용한 부타디엔고무 소재의 접착력 개선)

  • Seul, Soo Duk
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.556-560
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    • 2010
  • An atmospheric surface modification using plasma treatment method was applied to butadiene rubber to improve its adhesion strength by plate type reactor. In order to investigate the optimum reaction condition of plasma treatment, type of reaction gas(nitrogen, argon, oxygen, air), gas flow rate(30~100 mL/min), treated time(0~30 s) and primer modification method(GMA, 2-HEMA) were examined in a plate type plasma reactor. The results of the surface modification with respect to the treatment procedure was characterized by using SEM and ATR-FTIR. As the gas flow rate and treated time increases the contact angle decreases. The greatest adhesion strength was achieved at optimum condition such as flow rate of 60 mL/min, treated time 5 s and modification primer containing 2-HEMA for air. Due to the atmospheric surface modification using plate plasma method consequently reduced the wettability of butadiene rubber and resulted in the improvement of the adhesion.