• Title/Summary/Keyword: nitrogen dynamics

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Estimation of N Mineralization Potential and N Mineralization Rate of Organic Amendments as Affected by C:N Ratio and Temperature in Paddy Soil

  • Shin, Jae-Hoon;An, Nan-Hee;Lee, Sang-Min;Ok, Jung-Hun;Lee, Byun-Woo
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.6
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    • pp.712-719
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    • 2016
  • Understanding N mineralization dynamics in soil is essential for efficient nutrient management. An anaerobic incubation experiment was conducted to examine N mineralization potential and N mineralization rate of the organic amendments with different C:N ratio in paddy soil. Inorganic N in the soil sample was measured periodically under three temperature conditions ($20^{\circ}C$, $25^{\circ}C$, $30^{\circ}C$) for 90 days. N mineralization was accelerated as the temperature rises by approximately $10%^{\circ}C^{-1}$ in average. Negative correlation ($R^2=0.707$) was observed between soil inorganic N and C:N ratio, while total organic carbon extract ($R^2=0.947$) and microbial biomass C ($R^2=0.824$) in the soil were positively related to C:N ratio. Single exponential model was applied for quantitative evaluation of N mineralization process. Model parameter for N mineralization rate, k, increased in proportion to temperature. N mineralization potential, $N_p$, was very different depending on C:N ratio of organic input. $N_p$ value decreased as C:N ratio increased, ranged from $74.3mg\;kg^{-1}$ in a low C:N ratio (12.0 in hairy vetch) to $15.1mg\;kg^{-1}$ in a high C:N ratio (78.2 in rice straw). This result indicated that the amount of inorganic N available for crop uptake can be predicted by temperature and C:N ratio of organic amendment. Consequently, it is suggested that the amount of organic fertilizer application in paddy soil would be determined based on temperature observations and C:N ratio, which represent the decomposition characteristics of organic amendments.

Forest Floor Biomass, Litterfall and Physico-chemical Properties of Soil along the Anthropogenic Disturbance Regimes in Tropics of Chhattisgarh, India

  • Oraon, P.R.;Singh, Lalji;Jhariya, Manoj Kumar
    • Journal of Forest and Environmental Science
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    • v.34 no.5
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    • pp.359-375
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    • 2018
  • The long term ecological effects have been reported in natural forest ecosystem due to various anthropogenic disturbances, especially in tropics of the world. The present study was carried out in the sanctuary area of central India to assess the changes on litter biomass, litterfall pattern and soil attributes under different disturbance regimes. The study area includes three forest circles i.e., Bhoramdeo, Jamunpani and Salehwara each comprising three disturbances regimes viz., high, medium and low severity of biotic pressure. A noticeable variation and impact were recorded in different sites. The impact varies significantly from least disturbed sites to highly disturbed sites across the circle and among different disturbances level. The seasonal mean total forest floor biomass across the forest circles varied from 2.18 to $3.30t\;ha^{-1}$. It was found highest under lightly disturbed site and lowest under heavily disturbed site. Total litterfall varied from 5.11 to $7.06t\;ha^{-1}\;yr^{-1}$ across the forest circle. Lowest litterfall was recorded at heavily disturbed site while highest in lightly disturbed site. Annual turnover of litter varied from 69-73% and the turnover time ranged between 1.37-1.45 years. The turn over time was higher for heavily disturbed site and lower for lightly disturbed site. The heavily disturbed site of all the circle showed the sandy loam soil texture, whereas moderately and lightly disturbed site comprised of sandy loam, sandy clay loam and clay soil texture, respectively. The bulk density decreases from heavily disturbed site to lightly disturbed site and the pH of soils ranged from 5.57-6.89 across the circle. Across the circle the total soil nitrogen ranged from 0.12-0.21%, phosphorus from 10.03-24.00 kg and Potassium from $139.88-448.35kg\;ha^{-1}$, respectively. Our results demonstrate that anthropogenic disturbances regime significantly influences forest floors in terms of mass, composition and dynamics along with litterfall rate and soil properties.

Litterfall and Nutrient Dynamics in Pine (Pinus rigida) and Larch (Larix leptolepis) Plantations

  • Kim, Choonsig;Koo, Kyo-Sang;Byun, Jae-Kyung
    • Journal of Korean Society of Forest Science
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    • v.94 no.5 s.162
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    • pp.302-306
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    • 2005
  • Litterfall and nutrient inputs were measured in even-aged coniferous plantations (a 31-year-old Pinus rigida and a 31-year-old Larix leptolepis) on a similar site condition in the Forest Practice Research Center, Gyeonggi Province. Litterfall was collected monthly from circular littertraps (collecting area: $0.50m^2$) for three years between April 1997 and February 2000. Average total annual litterfall was significantly higher for pine (5,802 kg/ha/yr) than for larch (4,562 kg/ha/yr) plantations. Needle litter in both plantations accounted for about 63% of total litterfall. Litterfall in the larch was distributed as follows: needle > other leaf > branch > miscellaneous > bark, while it was needle > miscellaneous > other leaf > branch > bark in the pine plantation. There was no temporal variation in needle litter, other leaf and bark during the 3 year study period. The concentrations of all nutrients (N, P, K, Ca, Mg) in needle litter were significantly higher in the larch than in the pine plantations. The annual nutrient concentration of needle litter in the larch varied among the years, whereas no year variation of needle litter was in the pine except for phosphorus (P). Nitrogen (N) and P inputs by needle litter were significantly higher for larch than for pine plantations established on a similar soil. The differences in N and P inputs were attributed to lower nutrient concentration in pine needle litter compared with larch needle litter, not to total needle litter mass. Annual inputs of nutrient in both plantations were not significantly different among years except for K of the larch although there was yearly different in needlefall mass and nutrient concentration during the 3-year observed period. The results indicate that the mechanisms of litterfall and nutrient inputs vary considerably between pine and larch plantations established on a similar site condition.

Decomposition and, Nitrogen, Phosphorus and Potassium Dynamics of Pinus thundbergii Needle Litter (해송엽(海松葉) Litter의 분해(分解)와 N, P 및 K의 동태(動態))

  • Yi, Myong-Jong
    • Journal of Korean Society of Forest Science
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    • v.80 no.3
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    • pp.303-310
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    • 1991
  • Seasonal patterns of decomposition and nutrient release from the needle litter were examined using litter-bags in coastal Pinus thunbergii forests in nothern Kyushu, Japan. Dry matter losses from decomposing needle litter were smillar in all standsover a experimental period. Mass loss in dry weight is lost rapidly during the first year, and thereafter the rate of loss slows. Litter lost approximately 40% of initial mass in 1 yr. The predicted decay constant, k values ranged from 0.5 to 0.6 Decomposition half-times($t_{0.50}$) ranged from 1.1 to 1.4 year. In the decomposing needle litter, the concentrations of N and P generally increased with time while the concentration of K decreased. A decrease in absolute amount was noted for K during decomposition while in an increase was found for N. The order of mobility of elements was K>P>N. Mineralization phase of N had not appeared during the experiment.

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The Effect of Cattle Slurry on N-Dynamics and $NO_3$ Leaching in Pasture Mixtures (목초 생산성과 액상분뇨 시용이 토양의 질소동태와 $NO_3$ 용탈에 미치는 영향)

  • 류종원
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.17 no.1
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    • pp.43-50
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    • 1997
  • The aim of the study is to describe the fate and transformation of nitrogen in grassland ecosystems. Field experiments were conducted using sandyloam soil under variabling conditions: Zen, fertilization, reduced slurry application(l20kg N $ha^{-1}\;yr^{-1}$), usual sluny application (240 kg N $ha^{-1}\;yr^{-1}$).Soil water samples were gathered with 120cm ceramic cups with initial pressure of 0.5 bar. Samples were collected twice a month and analysed for NO, colormetrically. Percolation was calculated as the difference between precipitation and potential evapotranspiration, and leaching as the product of percolation and nitrate content of the water h m the ceramic cups. The N$H_4$-N content in soil had no significant effect on slurry application, but high slurry application on grassland resulted in high N$O_3$-N content in soil. The NO, concentration in soil water was remarkably variable during the year. The average N$O_3$, concentration during experiment became the lowest(8.5 mg/e ) without slurry application and highest with 240kOa cattle sluny(25.3 mg4 ). For each of the three different amounts of cattle sluny applied (0, 120, and 240kOa), the amount of N$O_3$-N leached per year were 12, 23 and 29kg/ha respectively. On grassland under the climatic conditions of Allgau showed enormous nitrate leaching, which has a p a t potential of polluting the ground water. The high pool of mineral N in the soil are the source for N$O_3$ leaching. The leaching of N$O_3$ cannot be avoided completely, but minimized by optimizing N fertilization rate.

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Population Dynamics of Zacco platypus in Gap-Stream and Its Relation with Water Quality

  • Shin, Young-Eun; Choi, Ji-Woon;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.42 no.4
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    • pp.422-431
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    • 2009
  • This study was to provide basic data for aquatic ecosystem research using fishes. Field sampling was carried out at five selected sites of Gap Stream, and fish samples, especially for a selection of sentinel species were collected three times in June, September, and October 2007. We analyzed total length distribution of Zacco platypus in relation with the season and the sampling sites, and then compared with total body weight, condition factor (K), and age distribution of the fish. The fish population data were compared with physico-chemical water quality, obtained from the Ministry of Environment, Korea. Water quality analysis showed a significant nutrient enrichment, based on total nitrogen (TN) and total phosphorus (TP), and organic matter pollution, based on biological oxygen demand (BOD) and chemical oxygen demand (COD) in the Site 5, which is directly influenced by wastewater disposal plant (WDP). Population analysis of the sentinel species showed that the total number of individuals, age distribution, and the population size-structure were influenced by the effluents from the WDP, and that reproductive failure of young-age population were evident in Site 5. According to the relation analysis of total weight to K, the disturbed population was mainly attributed to combined effects of habitat modifications and chemical degradations. Regression analysis of K values against water quality parameters showed significant (p<0.05) positive relations with nutrient and organic matter contents. Our data suggest that the population structure using a sentinel fish species reflected the ambient water quality in the stream and that diagnosis of aquatic ecosystem health using Z. platypus population may be practical for water resource and ecosystem conservations.

Calculation and Application of Partial Charges (부분 전하의 계산과 응용)

  • Cho, Seung Joo
    • Journal of Integrative Natural Science
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    • v.3 no.4
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    • pp.226-230
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    • 2010
  • Calculation of partial charge is important in chemistry. However, because there are many methods developed, it is of considerable interest to know how to calculate and apply properly to address various chemical problems. For basis set, usually double zeta quality is acceptable, and double zeta polarization function would be enough for most cases. To describe electronic state more accurately, Many electron configurations would be necessary to describe highly strained or anionic species. The NPA population introduced new concept about amide bonds, i.e., the planar geometry of nitrogen atom may not come from resonance, but from the lowering of p-orbital energy by electronegative carbonyl carbon atom. The issues for hypervalent atomic charges was also addressed by various charge derivation scheme. When the charge schemes were applied to organolithium compounds, the ionic nature of boding was revealed. This comes from the fact that previous Mulliken partial atomic charges overemphasized the covalent character, wihout much justification. The other partial charge derivation schemes such as NPA(natural population analysis), IPP (Integrated Projected Population) showed that much more ionic picture. ESP potential derived charges are generally believed to be suitable to describe intermolecular interactions, therefore they are used for molecular dynamics simulations and CoMFA (comparative molecular field analysis). The charge derivation schemes using multipole polarization was mainly applied to reproduce experimental infrared spectroscopy. In some reports these schemes are also suitable for intermecular electrostatic interactions. Charges derived from electron density gradient have shown the some bonds are not straight, but actually bent. The proper choice of charge-calculation method along with suitable level of theory and basis set are briefly discussed.

Daily influent variation for dynamic modeling of wastewater treatment plants

  • Dzubur, Alma;Serdarevic, Amra
    • Coupled systems mechanics
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    • v.9 no.2
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    • pp.111-123
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    • 2020
  • Wastewater treatment plants (WWTPs) with activated sludge system are widely used throughout the most common technologies in the world. Most treatment plants require optimization of certain treatment processes using dynamic modeling. A lot of examples of dynamic simulations require reliable data base of diurnal variation of the inflow and typical concentrations of parameters such as Chemical Oxygen Demand (COD), Total Kjeldahl Nitrogen (TKN), etc. Such detailed data are not available, which leads to problemsin the application of dynamic simulations. In many examples of plants, continuous flow measurements are only performed after the primary clarifier, whereas measurements from influent to the plant are missing, as is the case with the examples in this paper. In some cases, a simpler, faster and cheaper way can be applied to determine influent variations, such as the "HSG-Sim" method ("Hochschulgruppe Simulation"). "Hochschulgruppe Simulation" is a group of researchers from Germany, Austria, Switzerland, Luxembourg, Netherlands and Poland (see http://www.hsgsim.org). This paper presents a model for generating daily variations of inflow and concentration of municipal wastewater quality parameters, applied to several existing WWTPs in Bosnia and Herzegovina (B&H). The main goal of the applied method is to generate realistic influent data of the existing plants in B&H, in terms of flow and quality, without any prior comprehensive survey and measurements at the site. The examples of plants show the influence of overflow facilities on the dynamics of input flow and quality of wastewater, and a strong influence of the problems of the sewerage systems.

Internal Flow Characteristics of Simulated Dual Pulse Rocket Motor by Using the Hot Gas and Cold Gas (Hot Gas와 Cold Gas를 이용한 모사 이중펄스 로켓 추진기관의 내부 유동 특성)

  • Cho, Kihong;Park, Jungho;Kim, Euiyong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.2
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    • pp.1-8
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    • 2015
  • Dual pulse rocket motor is a variant of solid rocket motor with two propellant grain separated by a pulse separation device. The major performance of such a rocket motor is influenced by the change in the hole area of pulse separation device to nozzle throat area ratio. In this study, we performed flow analysis to investigate the internal flow characteristics according to the pulse separation device hole area to nozzle throat area ratio change. Gases used flow analysis were used combustion gas of HTPB/AP composite propellant and nitrogen gas. Flow analysis results of the dual pulse rocket motor were validated by comparison with experimental results of pneumatics. Commercial CFD code ANSYS FLUENT 14.5 is used in this study to simulate flow analysis.

Dynamics of Organic Carbon and Nutrients in Litterfall of Quercus mongolica Forest in Mt. Songnisan National Park

  • Kang, Sang-Joon;Han, Dong-Yeoul
    • The Korean Journal of Ecology
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    • v.28 no.6
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    • pp.347-351
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    • 2005
  • The amounts of organic carbon and several nutrients in litterfall on the forest floor of Quercus mongolica forest were assessed for two years from 1998 through 2000 in Mt. Songnisan National Park in Korea. The amounts of organic carbon (C) in litterfall were the highest in autumn with the values of $150.4g/m^2$ (62.6%) in 1998 and $219.2g/m^2$ (61.0%) in 1999. In winter, organic C was the lowest with the values of $16.3g/m^2$ (6.8%) in 1998 and $12.5g/m^2$ (6.7%) in 1999. It was estimated that the organic C added to forest floor via litterfall was 240.1 $g{\cdot}m^{-2}yr^{-1}$ and 186.6 $g{\cdot}m^{-2}yr^{-1}$ 1998 and 1999, respectively. The amounts of nitrogen (N) in litterfall were the highest in autumn with the values of 5.9 $g/m^2$ (58.0%) in 1998 and 5.2 $g/m^2$ (62.3%) in 1999. The amount of phosphorus (P) in litterfall showed its peak in autumn with 0.19 $g/m^2$ (52.9%) in 1998 and 0.11 $g/m^2$ (52.6%) in 1999. The amount of P returned to forest floor via litterfall was 0.35 $g{\cdot}m^{-2}yr^{-1}$ in 1998 and 0.22 $g{\cdot}m^{-2}yr^{-1}$ in 1999. The amount of potassium (K) in litterfall showed its peak in autumn with 0.57 $g/m^{2}$ (53.8%) in 1998 and 0.42 $g/m^2$ (55.3%) in 1999. The amounts of K returned to forest floor via litterfall was 1.11 $g{\cdot}m^{-2}yr^{-1}$ in 1998 and 0.81 $g{\cdot}m^{-2}yr^{-1}$ in 1999.