• Title/Summary/Keyword: nitrogen compounds

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Removal of nitrogen and sulfur odorous compounds and their precursors using an electrolytic oxidation process (산화전리수를 이용한 질소와 황 계열 악취 및 악취전구물질의 제거)

  • Shin, Seung-Kyu;An, Hea-Yung;Kim, Han-Seung;Song, Ji-Hyeon
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.2
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    • pp.223-230
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    • 2011
  • An electrolytic oxidation process was applied to remove odorous compounds from non-point odor sources including wastewater pipelines and manholes. In this study, a distance between the anode and the cathode of the electrolytic process was varied as a system operating parameters, and its effects on odor removal efficiencies and reaction characteristics were investigated. Odor precursors such as sediment organic matters and reduced sulfur/nitrogen compounds were effectively oxidized in the electrolytic process, and a change in oxidation-reduction potential (ORP) indicated that an stringent anaerobic condition shifted to a mild anoxic condition rapidly. At an electrode distance of 1 cm and an applied voltage of 30 V, a system current was maintained at 1 A, and the current density was 23.1 $mA/cm^{2}$. Under the condition, the removal efficiency of hydrogen sulfide in gas phase was found to be 100%, and 93% of ammonium ion was removed from the liquid phase during the 120 minute operating period. Moreover, the sulfate ion (${SO_4}^{2-}$) concentration increased about three times from its initial value due to the active oxidation. As the specific power consumption (i.e., the energy input normalized by the effective volume) increased, the oxidation progressed rapidly, however, the oxidation rate was varied depending on target compounds. Consequently, a threshold power consumption for each odorous compound needs to be experimentally determined for an effective application of the electrolytic oxidation.

Prediction of Sensory Characteristics from Leaf Chemical Compounds in Oriental Tobacco (오리엔트종 잎담배의 화학성분에 의한 관능 특성 예측)

  • Jeong, Kee-Taeg;Cho, Soo-Heon;Kim, Si-Mong;Park, Seong-Weon;Lee, Chul-Hee
    • Journal of the Korean Society of Tobacco Science
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    • v.29 no.2
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    • pp.85-89
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    • 2007
  • This study was conducted to evaluate the prediction of sensory characteristics of smoke from the leaf chemical compounds and characterize leaf chemical components for the best tobacco taste's leaves in oriental tobacco. For analytical and sensory evaluations, seventy two grades were used. Sensory evaluation of tobacco smoke for six attributes were scored on fifteen-point scale by $10{\sim}14$ expert panels trained to estimate smoking quality quantitatively. The major leaf chemical compounds to predict the sensory characteristics of smoke were ether extract for tobacco-like, nicotine for impact and total nitrogen/nicotine ratio for irritation, and total sugar for off taste & odor. Within ${\pm}20%$ range of difference, the predictable probabilities of sensory characteristics of smoke from the leaf chemical compounds were 87.5 % for off taste & odor and $94.4{\sim}98.6\;%$ for tobacco-like, impact and irritation. As a result of K-means cluster analysis on the basis of tobacco taste, the desirable leaf chemical compound contents were $5.9{\sim}8.3\;%$ in ether extract, $1.35{\sim}2.27\;%$ in nicotine and $1.17{\sim}2.24$ in total nitrogen/nicotine ratio. This study suggest that the some regression equations may be useful to predict the sensory characteristics of tobacco smoke with a few selected leaf chemical compounds in oriental tobacco and to select the oriental tobacco leaves by means of enhancing the tobacco taste of cigarette.

EFFECTS OF FIELD PRODUCTIVITY, VARIETY AND NITROGEN RATE ON THE YIELD, QUALITY AND PHYSICO-CHEMICAL CHARACTERISTICS OF BURLEY TOBACCO (버어리종 잎담배의 수량, 품질 및 이화학성에 미치는 포지비옥도, 품종 및 질소시용량의 영향)

  • Kim, Sang-Beom;Kim, Yong-Kyoo;Han, Chul-Soo
    • Journal of the Korean Society of Tobacco Science
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    • v.12 no.2
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    • pp.91-101
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    • 1990
  • A field experiment was conducted to find out the effects of field productivity, variety and nitrogen rate on the yield, quality, chemical constituents and physical properties of burley cured leaf in three field with different productivity(Degree of field productivity: A ; high, B ; medium, C : low) during successive two years(1988~89). The yield and quality were remarkably lowered when nitrogen fertilizer being applied much in low productive field. As compared with Burley 21, KB101 showed high yield, particularly the yield of KB101 in low productive field was relatively high. The effect of nitrogen rate on the yield was somewhat different according to field productivity and production year. When the nitrogen fertilizer being applied above 22.5kg/10a, the added nitrogen had no effect on the yield. Total nitrogen content of cured leaf grown in low productive field was high while total alkaloid was low, therefore total alkaloid/total nitrogen ratio was remarkably low. The lightness, red and yellow color of cured leaf grown in low productive field was remarkably low. As compared with Burley 21, the contents of total alkaloid and total nitrogen and shatter resistance index of cured leaf was somewhat low, while the filling power, lightness, red and yellow color were slightly high. Total nitrogen content of cured leaf was increased remarkably by nitrogen addition, but total alkaloid was not increased though the nitrogen fertilizer being applied above 22.5kg/10a. The filling power and shatter resistance index of cured leaf grown in high nitrogen plot, and the lightness and yellow color were low while the red color was relatively high. It comes into question that the visual quality being increased as well as increment of yield and nitrogenous compounds by nitrogen addition in high productive field. In low productive field, it is considerable that nitrogen addition for high yield should be prohibited because it causes the decrement of yield and quality, on the contrary.

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A study on the distribution of organic compounds, nitrogen, phosphorus and heavy metal in Ballast Water (밸러스트수내 유기물, 영양염류 및 중금속 농도 분포에 관한 연구)

  • Cheong, Kwang-Hyun;Ahn, Jong-Gil
    • Proceedings of KOSOMES biannual meeting
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    • 2006.05a
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    • pp.71-77
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    • 2006
  • There is a growing concern about the damage to aquatic ecosystem caused by immigration of non-indigenous species. It is estimated that more than 10,000 million tons of ballast water is transported by shipping activities annually, and ballast water has been recognised as a major vector for the transplant of aquatic species across bio-geographical boundaries. The problem of harmful aquatic organism in ballast water for the control and management of ships' ballast water and sediments was adopted and diplomatic conference of IMO at February 2004. At once ballast water is transported by shipping activities for organic compounds, nitrogen, phosphorus and heavy metal etc. but, It's fixing a focus only for the transported of pathogenic bacteria and non-indigenous species. Hence, this studies on the distribution of organic compounds, nitrogen, phosphorus and heavy metal in ballast water during the shipping activity with the basic data which is necessary to the systemic manage of ballast water.

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Determination of Analytical Approach for Ambient PM2.5 Free Amino Acids using LC-MSMS (LC-MSMS를 이용한 대기 중 PM2.5 유리아미노산 분석 방법 연구)

  • Bae, Min-Suk;Park, Da-Jeong;Lee, Kwon-Ho;Cho, Seung-Sik;Lee, Kwang-Yul;Park, Kihong
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.1
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    • pp.54-63
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    • 2017
  • Atmospheric nitrogen containing organic compounds(e.g. amino acids) has attracted considerable attention from the viewpoint of the oceanic biogeochemical cycle of nitrogen as well as the long range transfer. However, only a few measurements of organic nitrogen compounds have been conducted due to analytical difficulties. In this study, total of nine amino acids such as Glutamic acid, Histidine, Arginine, Tyrosine, Cystine, Valine, Methionine, Phenylalanine, Lysine have been analytically determined by Liquid Chromatography - Mass Spectrometry Mass Spectrometry (LC-MSMS). As results, Fragmentor Voltage (FV), Precursor Ion, Collision Energy, Product Ion related to individual amino acid compounds are shown. Based on the operational conditions, Lysine, Glutamine Acid, Tyrosine were analyzed during the China Oriented Smog Period. High concentrations of Lysine, Glutamine Acid, and Tyrosine are discussed with organic carbon (OC), elemental carbon (EC), and water soluble ions. The results can provide to understand the sources with aging process related to amino acids influenced by the long-range transport from the Yellow Sea area.

Estimation of Nitrogen and Sulfur Dry Deposition over the Watershed of Lake Paldang (팔당호 유역에 대한 질소와 황의 건식 침적량 추정)

  • Kim J.Y;Ghim Y. S;Won J.-G;Yoon S.-C;Woo J.-H;Cho K.-T
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.49-62
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    • 2005
  • Lake Paldang is a main resource of drinking water for 20 million people in the greater Seoul area. Dry deposition amounts of nitrogen and sulfur were estimated for three typical days in each season over the watershed of Lake Paldang. Models- 3/CMAQ (Community Multiscale Air Quality) and MM5 (Mesoscale Model) were used to predict air quality and meteorology, respectively. Aerosols as well as gaseous pollutants were considered. Nitrogen was mainly deposited in the form of HNO, while most of sulfur was deposited in the form of SO$_2$. Contribution of secondary pollutants was the largest in fall since they were transported from the greater Seoul area. However, contribution of secondarily-formed particulate pollutants to the nitrogen deposition was the largest in winter because semi-volatile ammonium nitrate favors lower temperature. Annual deposition amounts of nitrogen and sulfur were 37% and 26% of their emission amounts, respectively, over the watershed of Lake Paldang. Higher value of the nitrogen deposition showed a more influence of pollutants emitted in the greater Seoul area.

Removal of Ammonia Nitrogen and Organics from Piggery Wastewater Using BACC Process-II. Effect of COD/N on Removal of NItrogen and Organics (BACC를 이용한 축산폐수의 암모니아성 질소 및 유기물의 제거 II. COD/N비가 질소 및 유기물 제거에 미치는 영향)

  • 성기달;류원률;김인환;조무환
    • KSBB Journal
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    • v.16 no.2
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    • pp.140-145
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    • 2001
  • To treat piggery wastewater containing refractory compounds including nitrogen, physical treatments using zeolite and biological processes were investigated. In biogical treatment, the removal efficiencies of organics and nitrogen in bioreador using BACC (Biological Activated Carbon Cartridge) media filled with granule activated carbon were examined. The best removal efficiencies achieved for TKN and COD(sub)cr were 82% and 53% respectively, when zeolite dosage was 300 g/L. Specific nitrogen removal ability was 3.2 mg/g at a zeolite dosage of 50 g/L, whereas specific nitrogen removal ability was 1.8 mg/g at a zeolite dosage of 300 g/L. The increased of C/N ratio resulting from the removal of nitrogen using zeolite led to an increase in removal efficiency of organics. As C/N ratio was increased to 2.0, 2.44 and 6.58 at a HRT of 48 hours in a BACC bioreactor, removal efficiencies of COD(sub)cr were increased to 53.5%, 57.4% and 80.6%. The removal efficiency of wastewater using a zeolite dosage of 399 g/L was increased by 27.1% compared to that of control treatment.

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A Study on the Volatile Organic Compounds Analysis Method for Visible Light-Responsive Photocatalyst Treated Vehicle Interior Materials (가시광촉매가 처리된 자동차 내장재의 VOC 분석방법에 대한 연구)

  • Choi, Sei Young
    • Elastomers and Composites
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    • v.48 no.3
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    • pp.221-224
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    • 2013
  • In this study, VOC analysis method of vehicle interior materials and parts treated to visible-light responsive photocatalyst was tested by sample bag filled with air instead of nitrogen. As a result, when analyzed VOC of vehicle interior materials and parts, sample bag filled with the nitrogen was not confirmed of effect reducing VOCs and formaldehyde. However, VOCs and formaldehyde of sample bag that was filled with air instead of nitrogen, decreased significantly. Reaction effect for visible light-responsive photocatalyst was confirmed that sample bag of vehicle interior materials and parts should be filled with air instead of nitrogen.

Synthesis of 2,5Bis(2'-piperidymethyl)piperidine and Related Compounds

  • Hammouda, Metwally;Kandeel, Ex-el-Din;Hamama, Wafaa;Afsah, Elsayed
    • Archives of Pharmacal Research
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    • v.16 no.1
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    • pp.68-70
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    • 1993
  • The triketones 3-6 were obtained by alkylation of cyclopentanone or cyclohexanone with the appropriate cycloalkanone bis-mannich base (1) or (2). Schmidt reaction of the tricketones 3-6 afforded the corresponding trcyclic lactames 7-10 respectively. reduction of 7 and 9 gave compounds 11 and 12 respectively.

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Anti inflammatory Activity of Flavonoids from the Seeds of Astragalus sinicus Linne

  • Yeom, Seung-Hwan;Kim, Min-Kee;Kim, Hyun-Jung;Shim, Jae-Geul;Lee, Jae-Hee;Lee, Min-Won
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.266.2-266.2
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    • 2003
  • The seeds of Astragalus sinicus grows in Korea have been used for oriental traditional medicine as the remedies for inflammation. Eight flavonoids were isolated from the Seeds of Astragalus sinicus and studied its anti-inflammatory activity. Some flavonoid compounds showed significant nitrogen monoxide(NO) production inhibitory activity in IFN-${\gamma}$, LPS stimulated RAW 264.7 cell. There compounds also showed significant antioxidative in DPPH assay. (omitted)

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