• Title/Summary/Keyword: nitrogen budget

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Carbon Budget of Pine Forest in Serpentine Area (사문암 지역 소나무림의 탄소수지 연구)

  • Yang, Keum-Chul;Namkung, Hyunmin;Kim, Jeong-Seob;Han, Mi-Kyoung;Shim, Jae-Kuk
    • Korean Journal of Environment and Ecology
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    • v.32 no.6
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    • pp.676-685
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    • 2018
  • This study is to compare carbon budget between serpentine sites and non-serpentine sites dominated by Pinus densiflora forest in the Andong serpentine area where has high values of magnesium and low values of calcium, and are usually deficient in nitrogen and phosphorus, but rich in heavy metals such as nickel, chrome, cobalt, etc. and to measure soil $CO_2$ efflux and environmental factors between January 2017 and December 2017. Soil $CO_2$ efflux was measured with LI-6400 once a month; the soil temperature at 10 cm depth, air temperature, soil moisture contents, and solar radiation were measured in continuum. Soil $CO_2$ efflux in the serpentine area and non-serpentine were $151.71{\pm}75.09g\;CO_2{\cdot}m^{-2}month^{-1}$(42.48 ~ 262.61 g $CO_2{\cdot}m^{-2}month^{-1}$) and $165.09{\pm}118.96g\;CO_2{\cdot}m^{-2}month^{-1}$(20.94 ~ 449.24 g $CO_2{\cdot}m^{-2}month^{-1}$), respectively. Carbon storage in the serpentine area and non-serpentine area were 91.90, $222.85ton{\cdot}ha^{-1}$, respectively. Carbon absorption in the serpentine area and non-serpentine area were 7.99, $17.41ton{\cdot}ha^{-1}yr^{-1}$, respectively. Carbon budget in the serpentine area and non-serpentine area were absorbs 5.3, $14.49ton{\cdot}Cha^{-1}yr^{-1}$, respectively.

Physiological Changes and Energy Budget of the Sea Squirt Halocynthia roretzi from Tongyeong, South Coast of Korea (멍게(Halocynthia roretzi)의 계절별 생리적 변화 및 에너지 수지)

  • Shin, Yun-Kyung;Jun, Je-Cheon;Kim, Eung-Oh;Hur, Young-Baek
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.44 no.4
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    • pp.366-371
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    • 2011
  • The sea squirt Halocynthia roretzi is mainly cultured in Tongyeong, Southern coastal area of Korea. This study presents the physiological rates of respiration, excretion, feeding and assimilation efficiency of the sea squirt Halocynthia roretzi to analyze the SFG(scope for growth) and net growth efficiency, determined during 2007. Oxygen consumption and nitrogen excretion rates increased with a rise in temperature during the summer period whereas feeding rates decreased. The O:N ratio was high during winter(October to February). Assimilation efficiency showed an annual average of 75.4% during the experimental period, except during a period of elevated temperature in July to September(average $25^{\circ}C$). Net growth efficiency($K_2$) was 8.7 to 64.2% except for May to September, when temperature increased at the aquaculture farm. SFG was negative from May to September, reflecting high temperatures and low feeding rates during this period; its highest positive values occurred during winter.

Rational budgeting approach as a nutrient management tool for mixed crop-swine farms in Korea

  • Reza, Arif;Shim, Soomin;Kim, Seungsoo;Ahn, Sungil;Won, Seunggun;Ra, Changsix
    • Asian-Australasian Journal of Animal Sciences
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    • v.33 no.9
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    • pp.1520-1532
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    • 2020
  • Objective: Due to rapid economic return, mixed crop-swine farming systems in Korea have become more intensive. Intensive farming practices often cause nutrient surpluses and lead to environmental pollution. Nutrient budgets can be used to evaluate the environmental impact and as a regulatory policy instrument for nutrient management. This study was conducted to select a nutrient budgeting approach applicable to the mixed crop-swine farms in Korea and suggest an effective manure treatment method to reduce on-farm nutrient production. Methods: In this study, we compared current and ideal gross nutrient balance (GNB) approaches of Organisation for Economic Co-operation and Development and soil system budget (SSB) approach with reference to on-farm manure treatment processes. Data obtained from farm census and published literature were used to develop the farm nutrient budgets. Results: The average nitrogen (N) and phosphorus (P) surpluses were approximately 11 times and over 7 times respectively higher in the GNB approaches than the SSB. After solid-liquid separation of manure, during liquid composting a change in aeration method from intermittent to continuous reduced the N and P loading about 50% and 47%, respectively. Although changing in solid composting method from turning only to turning+aeration improved the N removal efficiency by 30.5%, not much improvement in P removal efficiency was observed. Conclusion: Although the GNB approaches depict the impact of nutrients produced in the mixed crop-swine farms on the overall agricultural environment, the SSB approach shows the partitioning among different nutrient loss pathways and storage of nutrients within the soil system; thus, can help design sustainable nutrient management plans for the mixed cropswine farms. The study also suggests that continuous aeration for liquid composting and turning+aeration for solid composting can reduce nutrient loading to the soil.

A Study on the Inflowing Pollution Load and Material Budgets in Hampyeong Bay (함평만의 유입오염부하량 및 물질수지에 관한 연구)

  • Kim, Jong-Gu;Jang, Hyo-Sang
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.1
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    • pp.1-10
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    • 2016
  • In this paper, an analysis of the inflowing pollution load of the rivers in Hampyeong bay showed the average organic matter pollution loads of BOD, COD, and TOC to be 79.7 kg-BOD/day, 144.06 kg-COD/day, and 93.0 kg-TOC/day, respectively. The inflowing organic matter pollution load was the heaviest in Sonbul dike, followed by Jupo bridge and Yangman complex. With regard to season, the load characteristics were outstanding in July, the rainy period in the summer. The average inflowing pollution loads of nutrients were 20.9 kg-DIN/day, 17.1 kg-DIP/day, 148 kg-TN/day, and 37.4 kg-TP/day A comparison of the inflowing nutrients loads for each river showed the load to be the heaviest in Yangman complex, followed by Baegok bridge and Jupo bridge. In the experiment on the material budgets of Hampyeong bridge conducted using a box model, the detention time of fresh water was found to be 52.4 days, with the bay displaying the characteristics of a so dissolved inorganic nitrogen (DIN) in the nutrients material budgets, ${\Delta}DIN$ values were found to be negative, indicating the tendency of consumption and open sea leak by photosynthesis to be higher than the nitrogen that flowed in. As for dissolved inorganic phosphorus (DIP), ${\Delta}DIP$ showed positive values, indicating a tendency for accumulation as the supply through organic matter decomposition, elution load of sediments, and inflowing load of the river turned out to be higher than the consumption by phytoplankton and outflow to open sea.

Effects of PCBs (Polychlorinated Biphenyls) on Energy Budget in Mysid, Neomysis awatschensis I. Acute and Chronic Effects of PCBs on Mysid, Neomysis awatschensis (곤쟁이, Neomysis awatschensis의 에너지수지에 미치는 PCBs의 영향 I. 곤쟁이에 미치는 PCBs의 급성 및 만성영향)

  • CHIN Pyung;SHIN Yun-Kyung;JEON Eun-Mi
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.1
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    • pp.95-103
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    • 1998
  • Acute and chronic responses to PCB toxicity of Neomysis awatschensis were studied by measurement of bioassay, growth, oxygen consumption and nitrogen excretion with concentrations of PCB at 10 and $20^{\circ}C$. 96 hr.-$LC_50$ at 10 and $20^{\circ}C$ were 28.7492 pub and 10.6742 pub, respectively. Survival rates during 60 days exposured to chronic PCB concentrations of 0.5 pub, 1.0 pub, 1.5 pub and 2,0 pub at $10^{\circ}C$ were $85\%,\;80\%,\;75\%$ and $75\%$, respectively and suwival rates at $20^{\circ}C$ $85\%,\;75\%,\;75\%$ and $65\%$, respectively. Average daily growth rate of N. awatschensis exposed to chronic PCB concentrations at $10^{\circ}C$ were 0.039 mm/day in control group and 0.036 mm/day at concentration of 2.0 ppb, while their rates at $20^{\circ}C$ showed 0.072 mm/day in central group and 0.039 mm/day at 2,0 ppb. The growth factors were some similarities between the chronic PCB concentrations, but intermolt periods were related to body size of mysids, temperature and PCB toxicity. Changes in oxygen consumption and nitrogen excretion rates during 60 days exposure to PCB toxicity showed higher in high groups of PCB concentrations. Assimilation and feeding rates of N. awatschensis fed Artemia sp. decreased with increase of PCB concentration at 10 and $20^{\circ}C$.

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Encapsulation of OLEDs Using Multi-Layers Consisting of Digital CVD $Si_3N_4$ and C:N Films

  • Seo, Jeong-Han;O, Jae-Eung;Seo, Sang-Jun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.538-539
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    • 2013
  • 여러 장점으로 인해 OLED는 디스플레이 및 조명 등 적용분야가 넓어지고 있지만, 수분 및 산소에 취약하여 그 수명이 제한되는 단점이 있다. 이를 해결하고자 현재까지는 glass cap을 이용한 encapsulation 기술이 적용되고 있지만, flexible 기판에 적용하지 못하는 문제가 있다. 이러한 문제를 해결하고자 여러 가지 thin film encapsulation 기술이 적용되고 있으나 보다 신뢰성이 높은 기술의 개발이 절실한 때이다. Encapsulation 무기 박막 물질로서 $Si_3N_4$ 박막은 PE-CVD (Plasma Enhanced Chemical Vapor Deposition) 등의 박막 증착법을 사용한 많은 연구가 진행되어, 저온에서의 좋은 품질의 박막 증착이 가능하지만, 100도 이하의 thermal budget을 갖는 OLED Encapsulation에 사용하기에는 충분하지 않았다. CVD 박막의 특성을 더욱 개선하기 위해 최근 ALD (Atomic Layer Deposition) 방법을 통한 $Al_2O_3$ film 증착 방법이 연구되고 있지만, 낮은 증착 속도로 인해 양산에 걸림돌이 되고 있다. 본 연구에서는 또 다른 해결책으로서 Digital CVD 방법을 이용한 양질의 $Si_3N_4$ 박막의 증착을 연구하였다. 이것은 ALD 증착법과 유사하며, 1st step에서 PECVD 방법으로 4~5 ${\AA}$의 얇은 silicon 박막을 증착하고, 2nd step에서 nitrogen plasma를 이용하여 질화 반응을 진행하고, 이러한 cycle을 원하는 두께가 될 때까지 반복적으로 진행된다. 이 때 1 cycle 당 증착속도는 7 ${\AA}$/cycle 정도였다. 최적의 증착 방법과 조건으로 기존의 CVD $Si_3N_4$ 박막 대비 1/5 이하로 pinhole을 최소화 할 수는 있지만 완벽하게 제거하기는 힘든 문제가 있고, 이를 해결하기 위한 개선을 위한 접근 방법이 필요하다고 판단하였다. 본 연구에서는 무기물 박막인 carbon nitride를 이용한 SiN/C:N multilayer 증착 연구를 진행하였다. Fig. 1은 CVD 조건으로 증착된 두께 750 nm SiN film에서 여러 층의 C:N film layer를 삽입했을 때, 38 시간의 85%/$85^{\circ}C$ 가속실험에 따라 OLED의 발광 사진이다. 그림에서 볼 수 있듯이 C:N 층을 삽입하고 또한 그 박막의 수가 증가함에 따라서 OLED에 대한 encapsulation 특성이 크게 개선됨을 확인할 수 있다.

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Analysis of Nutrient Dynamics and Development of Model for Estimating Nutrient Loading from Paddy Field

  • Jeon, Ji-Hong;Yoon, Chun-G.;Hwang, Ha-Sun;Jung, Kwang-Wook
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.7
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    • pp.57-69
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    • 2003
  • To evaluate nutrient dynamics with different fertilization in paddy field and develop water quality model, mass balance analysis was performed during growing season of 2001-2002 in field experimental plots irrigated with groundwater. As a result of water balance analysis, most of outflow was surface drainage as about half of total outflow and about 500mm was lost by evapotranspiration. The water budget was well balanced. The runoff from paddy field was influenced by rainfall and forced drain. Especially runoff during early cultural periods more depends on the forced drain. As a result of mass balance analysis, most of nutrient was input by fertilization and lost by plant uptake. Significant amount of nitrogen were supplied by precipitation and input from upper paddy field, comprising 12%∼28% of total inflow. Nutrient loading by surface drainage was occurred showing about 15%∼29% for T-N and 6%∼13% for T-P. The response of rice yield with different fertilization was not significant in this study. Water quality model for paddy field developed using Dirac delta function and continuous source was calibrated and validated to surface water quality monitoring data. It demonstrates good agreement between observed and simulated. The nutrient concentration of surface water at paddy field was significantly influenced by fertilization. During early cultural periods when significant amount of fertilizer was applied, surface drainage from paddy field can cause serious water quality problem. Therefore, reducing surface drainage during fertilization period can reduce nutrient loading from paddy fields. Shallow irrigation, raising the weir height in diked rice fields, and minimizing forced surface drainage are suggested to reduce surface drainage outflow.

Material Budgets in the Nakdong River Estuary with Simple Box Model (낙동강 하구해역에서의 단순 박스모델에 의한 물질수지)

  • Hong Suk-Jin;Lee Dae-In;Kim Dong-Myung;Park Chung-Kil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.3
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    • pp.50-57
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    • 2000
  • Budgets of fresh water, salt, DIN and DIP in the Nakdong river estuary were estimated in order to clarify the characteristics of material cycling and fluxes of nutrients with a simple box model. Freshwater inflow into this system was approximately 1.1E+10m³/y, water exchange was 3.3E+10m³/y and water residence time was 2.03 day assumed with salinity between estuary and adjacent ocean. Nutrients loadings were 3.2E+09mol DIN/y3.7×10³, 2.7E+07mo1 DIP/y, respectively. net ecosystem metabolism was 2.4E+07mo1 C/y. Although the Nakdong river discharge was the main source of nutrients but Jang-rim sewage treatment plant effluent take parts of 16% of nitrogen and 10.2% of phosphorus loadings.

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Calibration of the WASP4 Model Applied to Lake Paldang (WASP4 모형의 매개변수 추정 - 팔당호(八堂湖)를 중심으로 -)

  • Cho, Hong Yeon;Jun, Kyung Soo;Lee, Kil Seong;Han, Kwang Suk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.4
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    • pp.177-188
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    • 1993
  • Model parameters of the WASP4 applied to Lake Paldang were estimated. The methodology is based on grouping water quality constituents and relevant parameters and successively estimating each group of parameters by a trial-and-error procedure. Chlorophyll a, nitrogen cycles, phosphorus cycles, BOD and DO were simulated at the complexity level 4. A water budget analysis using the monthly records of reservoir inflows and outflows in 1989 and 1990 was made to determine seasonally-averaged flowrates at model boundaries. Estimated flowrates were used, together with the seasonal average of water quality measurements in 1989 and 1990 for the calibration and verification, respectively, of the model. Grouping water quality constituents and associated parameters proved to be efficient in estimating a number of model parameters. From the results of model calibration and verification, it was found that quantitative evaluations of nonpoint and benthic sources of organic matters are essential. Benthic sources near the entrance of the Kyeongancheon were the most significant.

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Calibration of QUAL2E Reaction Coefficients by the Influence Coefficient Algorithm (영향계수(影響係數)를 이용한 QUAL2E 모형의 반응계수(反應係數) 추정(推定))

  • Jun, Kyung Soo;Lee, Kil Seong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.4
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    • pp.163-176
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    • 1993
  • A methodology based on the influence coefficient algorithm was established for the optimal calibration of QUAL2E reaction coefficients. It was applied to the stream sections from the Chungju Dam to the downstream end of the South Han River. A water budget analysis using the monthly records of reservoir inflows and outflows in 1990 was made to determine tributary inflows. Estimated tributary inflows were used, together with the monthly records of water quality measurements in 1990, for the calibration of reaction coefficients. Simulated quality constituents were chl.a. nitrogen cycles, phosphorus cycles. BOD and DO. A sensitivity analysis was made to determine significant reaction coefficients, and as a result 11 reaction coefficients were selected as calibration parameters. The influence coefficient algorithm applied to the calibration of QUAL2E reaction coefficients proved to be a useful one yielding a rapid convergence. Each calibration parameter converged to an optimum value within 3 iterations.

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