• 제목/요약/키워드: nitrogen balance method

검색결과 56건 처리시간 0.022초

주택에서 Box Model을 이용한 평균 환기율 및 이산화질소 발생량 추정 (Estimation of Mean Air Exchange Rate and Generation Rate of Nitrogen Dioxide Using Box Model in Residence)

  • 배현주;양원호;손부순;김대원
    • 한국환경과학회지
    • /
    • 제13권7호
    • /
    • pp.645-653
    • /
    • 2004
  • Indoor air quality is affected by source strength of pollutants, ventilation rate, decay rate, outdoor level, and so on. Although technologies measuring these factors exist directly, direct measurements of all factors are not always practical in most field studies. The purpose of this study was to develop an alternative method to estimate these factors by application of multiple measurements. For the total duration of 30 days, daily indoor and outdoor $NO_2$ concentrations were measured in 30 houses in Brisbane, Australia, and for 21 days in 40 houses in Seoul, Korea, respectively. Using a box model by mass balance and linear regression analysis, penetration factor (ventilation divided by sum of air exchange rate and deposition constant) and source strength factor (emission rate divided by sum of air exchange rate and deposition constant) were calculated, Sub-sequently, the ventilation and source strength were estimated. In Brisbane, the penetration factors were $0.59\pm0.14$ and they were unaffected by the presence of a gas range. During sampling period, geometric mean of natural ventilation was estimated to be $l.l0\pm1.5l$ ACH, assuming a residential $NO_2$ decay rate of 0.8 hr^{-1}$ in Brisbane. In Seoul, natural ventilation was $1.15\pm1.73$ ACH with residential $NO_2$ decay rate of 0.94 hr^{-1}$ Source strength of $NO_2$ in the houses with gas range $(12.7\pm9.8$ ppb/hr) were significantly higher than those in houses with an electric range $(2.8\pm2,6$ ppb/hr) in Brisbane. In Seoul, source strength in the houses with gas range were $l6.8\pm8.2$ ppb/hr. Conclusively, indoor air quality using box model by mass balance was effectively characterized.

토지(土地) 이용(利用) 형태(形態)의 변화(變化)와 토양(土壤) 내(內) 탄소(炭素)와 질소(窒素의 관계(關係) (Relationship between Land-Use Change and Soil Carbon and Nitrogen)

  • 손요환;이숙희
    • 한국산림과학회지
    • /
    • 제90권3호
    • /
    • pp.242-248
    • /
    • 2001
  • 토지 이용 변화는 토양 내 유기물과 양분 상태에 영향을 줄 것으로 기대된다. 본 연구에서는 경기도 광주군 검단산 일대에서 과거 논으로 이용되다가 현재는 버드나무-신나무 우점의 산림으로 변한 지역, 밭에서 잣나무 인공조림지로 변한 지역, 그리고 과거부터 지속적으로 참나무류가 우점하고 있는 산림 지역 등 세 가지 토지 이용 형태를 선정하고 여기에서 토양 내 탄소와 질소의 농도, 토양 호흡, 그리고 질소 유효도 등을 측정, 비교하였다. 경작지의 휴경 후 20년이 경과한 다음, 토양 내 탄소와 질소의 농도는 토양 깊이 0-10cm, 10-20cm에서 과거 논이었던 지역이 다른 지역에 비하여 높은 것으로 나타났다. 또한 일반적으로 탄소와 질소의 농도는 표층에서 높고 토양 깊이가 증가할수록 점차 낮아지는 경향을 보였다. 이것은 유기물의 유입과 분해의 차이로 인한 축적량이 과거 논이었던 지역에서 가장 많기 때문이며, 탄소와 질소의 증가는 주로 표층에 국한한데에 기인하는 것으로 보인다. 토양 발생 이산화탄소량은 논에서 산림으로 변한 지역에서 가장 높게 나타났으며, 이는 토양 내 높은 탄소 농도와 습윤한 수분 조건 때문인 것으로 보인다. 이온교환수지봉지법으로 측정한 토양 내 질소 유효도는 토지 이용 형태에 따라 유의한 차이를 나타내었는데, 무기태 질소 $NH_4{^+}+NO_3{^-}$)의 유효도와 암모니움태 질소의 농도는 산림지역에서 가장 높고, 밭에서 산림으로 변한 지역, 논에서 산림으로 변한 지역의 순으로 점차 감소하였다.

  • PDF

OECD 양분수지를 이용한 축산선진국의 농경지 축산분뇨 이용실태 평가 (Evaluation of Livestock Manure Utilization Rates as Agricultural Purpose in Developed OECD Countries by Using Nutrient Balances)

  • 김필주;이용복;이연;윤홍배;이경동
    • 한국환경농학회지
    • /
    • 제27권4호
    • /
    • pp.337-342
    • /
    • 2008
  • OECD 양분수지분석법인 Surface Balance법에 의해 분석된 우리나라의 질소와 인산수지는 1985년 이후 지속적으로 증가하여 2006년 현재 OECD 회원국 중에서 가장 높은 수준인 것으로 예측되었다. 주요 축산 선진국의 질소와 인산수지는 강력한 가축사육두수 및 농경지 양분사용량 제한 법률 등의 운영으로 지속적으로 감소하고 있으나, 우리나라는 화학비료 사용량 감소에도 불구하고 가축사육두수 증가에 의해 상대적으로 높은 수준을 유지하고 있다. 축산선진국인 벨기에, 덴마크, 독일, 네덜란드의 전체 인산투입량에 대한 축산분뇨 유래 인산의 비율이 최근 60-70% 까지 증가하고 있어 농경지 양분의 절대량을 축분뇨에 의존하고 있는 것으로 예측된다. 인산수지와 인산투입량에 대한 축산분뇨의 부하율이 높은 벨기에와 네덜란드의 농경지 축분뇨 인산 시용량은 2004년 $31-33\;kg\;P\;ha^{-1}$로 우리나라와 비슷한 수준이었다. 벨기에와 네덜란드의 농경지 축산분뇨 시용수준은 지속적으로 감소하고 있으나, 우리나라는 지속적으로 증가하고 있어 가축사육두수 조절을 통한 양분수지 저감을 위한 적극적 정책수립이 필요할 것으로 판단된다.

Basic Study on the Heat Transfer During Rapid Freezing of Syobean Seed by Liquid Nitrogen

  • Kawano, Toshio;Nakano, Kohei;Murata, Satoshi
    • 한국농업기계학회:학술대회논문집
    • /
    • 한국농업기계학회 1993년도 Proceedings of International Conference for Agricultural Machinery and Process Engineering
    • /
    • pp.443-452
    • /
    • 1993
  • Direct freezing tests of soybean seed by liquid nitrogen were carried out at various moisture contents and the following important conclusions were drawn from the results of temperature measurements of soybean seed and photographs of bubbles generated on its surface : 1) Assuming that the temperature gradient in a soybean seed is negligible because of its small seed size and the freezing ratio is followed the Heiss's formula, and a differential equation based on the heat energy balance was introduced . The equation was easily solved by the Runge-Kutta-Gill method and the predicted values of the temperature were in good agreement with the observed data. 2) The photographs of bubble generation during freezing showed the boiling mode was nucleate, and then the most suitable formula on the nucleate boiling heat transfer was introduced from many formulate proposed up to now by fitting the calculated values based on the formula to the observed data. The formula used for the predict on of the seed temperature was as follows: $\frac{{\partial}T_s}{\partial\theta}\;=\;-\frac{{\alpha}(T_s\;-\;T_L)^{3.3}}{W(C_s\;-\;\frac{{\delta}m(CT_s\;+\;{\sigma})}{T_s^2})}$ where C = difference of the specific heat between pure ice and water m=moisture content of soybean seed $T_s$ = seed temperature $T_L$ = Temperature of liquid nitrogen W = mass of soybean seed $\alpha$ = proportional constant $\delta$ = constant depends on variety or the type of seed $\theta$ = time $\sigma$ = latent heat of melting of pure ice This study will give important information in the hydro-freezing technique by liquid nitrogen, available as a new technique of processing agricultural products in the near future.

  • PDF

거주지역 실내공기 특성 및 이산화질소 노출에 관한 연구 (Residence s Exposure to Nitrogen Dioxide and Indoor Air Characteristics)

  • 양원호;배현주;정문호
    • 한국환경보건학회지
    • /
    • 제28권2호
    • /
    • pp.183-192
    • /
    • 2002
  • Indoor air quality is affected by source strength of pollutants, ventilation rate, decay rate, outdoor level and so on. Although technologies exist to measure these factors directly, direct measurements of all factors are impractical in most field studies. The purpose of this study was to develop an alternative methods to estimate these factors by multiple measurements. Daily indoor and outdoor NO$_2$concentrations for 21 days in 20 houses in summer and winter, Seoul. Using a mass balance model and linear regression analysis, penetration factor (ventilation divided by sum of air exchange rate and deposition constant) and source strength factor(emission rate divided by sum of air exchange rate and deposition constant) were calculated. Subsequently, the ventilation and source strength were estimated. During sampling period, geometric mean of natural ventilation was estimated to be 1.10$\pm$1.53 ACH, assuming a residential NO$_2$decay rate of 0.8 hr$^{-1}$ in summer. In winter, natural ventilation was 0.75$\pm$1.31 ACH. And mean source strengths in summer and winter were 14.8ppb/hr and 22.4ppb/hr, respectively. Although the method showed similar finding previous studies, the study did not measure ACH or the source strength of the house directly. As validation of natural ventilations, infiltrations were measured with $CO_2$tracer gas in 18 houses. Relationship between ventilation and infiltration was statistically correlated (Pearson r=0.63, p=0.02).

Estimation of Nitrite Concentration in the Biological Nitritation Process Using Enzymatic Inhibition Kinetics

  • GIL, KYUNG-IK;EUI-SO CHOI
    • Journal of Microbiology and Biotechnology
    • /
    • 제12권3호
    • /
    • pp.377-381
    • /
    • 2002
  • Recently, interests to remove nitrogen in the nitritation process have increased because of its economical advantages, since it could be a short-cut process to save both oxygen for nitrification and carbon for denitrification compared to a typical nitrification. However, the kinetics related with the nitritation process has not yet been fully understood. Furthermore, many useful models which have been successfully used for wastewater treatment processes cannot be used to estimate effluent nitrite concentration for evaluating performance of the nitritation process, since the process rate equations and population of microorganisms for nitrogen removal in these models have been set up only for the condition of full nitrification. Therefore, the present study was conducted to estimate an effluent nitrite concentration in the nitritation process with a concept of enzymatic inhibition kinetics based on long-term laboratory experiments. Using a nonlinear least squares regression method, kinetic parameters were accurately determined. By setting up a process rate equation along with a mass balance equation of the nitrite-oxidizing step, an effluent nitrite concentration in the nitritation process was then successfully estimated.

비예혼합 역류화염에서 열전대 측정을 적용하기 위한 복사보정에 관한 연구 (A Study On the Radiation Corrections Applied to Thermocouple Measurements in Non-premixed Counterflow Flames)

  • 오율권;허준영;차경옥
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제26권2호
    • /
    • pp.209-218
    • /
    • 2002
  • The temperature field of a counterflow non-premixed flame is investigated using thermocouples of two sizes. A thermal balance is performed on the thermocouple in order to calculate the magnitude of the radiation corrections involved. Both the thermocouple wire and bead are separately considered to be the relevant thermal surface to which convective heat transfer takes place, and from which radiation lasses occur. The flame is also simulated by using a detailed chemical kinetic mechanism in a previously developed computer code. The local thermo-physical properties of the gas mixture, required to calculate the corrections, are determined both from the simulation, and by approximating the properties of the mixture as those of molecular nitrogen at the measured temperatures. It is concluded that the thermocouple wire is the appropriate thermal surface to which radiation corrections apply, in the absence of information about the gas mixture, its properties can be reasonably approximated by those of nitrogen rm ($N_2$), and the radiation corrections are very sensitive to misalignments in the temperature and velocity fields.

구획모델을 이용한 주택에서 이산화질소의 발생강도 및 감소상수 동시 추정 (Estimation of Source Strength and Deposition Constant of Nitrogen Dioxide Using Compartment Model)

  • 양원호;손부순;손종렬
    • 한국환경보건학회지
    • /
    • 제31권4호
    • /
    • pp.260-265
    • /
    • 2005
  • Indoor air quality might be affected by source strength of indoor pollutants, ventilation rate, decay rate, outdoor level, and so on. Although technologies measuring these factors exist directly, direct measurements of all factors are not always practical in most field studies. The purpose of this study was to develop an alternative method to estimate the source strength and deposition constant by application of multiple measurements. For the total duration of 60 days, indoor and outdoor $NO_2$ concentrations every 3 days were measured in 30 houses in Seoul, Asan and Daegu. Using a compartment model by mass balance and linear regression analysis, penetration factor (ventilation divided by sum of air exchange rate and deposition constant) and source strength factor (emission rate divided by sum of air exchange rate and deposition constant) were calculated. Subsequently, the source strength and deposition constant were estimated. Natural ventilation was $1.80{\pm}0.42\;ACH,\;1.11{\pm}0.50\;ACH,\;0.92{\pm}0.26\;ACH$ in Seoul, Asan and Daegu, respectively. Calculated deposition constant(K) and source strength of $NO_2,$ in this study were $0.98{\pm}0.28\;hr^{1}\;and\;16.28{\pm}7.47\;ppb/h,$ respectively.

하천 수질모형에 의한 비점 오염 부하량과 모형 매개변수의 동시 추정 (Simultaneous Estimation of Diffuse Pollution Loads and Model Parameters for River Water Quality Modeling)

  • 전경수;강주환
    • 한국수자원학회논문집
    • /
    • 제37권12호
    • /
    • pp.1009-1018
    • /
    • 2004
  • 하천을 따라 분포된 비점 오염원을 하천 수질모형의 매개변수들과 동시에 추정하는 체계적인 방법을 제안하였다. 수립된 방법을 QUAL2E 모형과 함께 충주댐 하류의 남한강 구간에 적용하여 모형의 반응계수와 비점 오염 부하량에 대한 최적 추정을 수행하였다. 민감도 분석 결과로부터 선정된 반응계수들에 대한 초기 추정 결과에 따르면 하천 시스템에 대한 질량수지가 만족되기 위해서는 질소와 인의 비점 오염 부하량의 입력이 필요한 것으로 나타났다. 이에 따라 총질소와 총인에 대한 비점 오염 부하를 포함하여 확장된 추정 문제의 해로써 비점 오염 부하량을 추정하였다. 비점 오염 부하량과 동시에 추정된 반응계수들과 비점 오염원을 고려하지 않고 추정된 반응계수의 비친 결과, 그 자체에 대한 추정을 위해서 뿐만 아니라 수질모형의 적절한 보정을 위하여 비점 오염 부하량이 최적 추정 과정에 포함될 필요가 있음을 알 수 있었다. 하천수질 의형에 대한 최적추정 방법의 적용성을 민감도계수 행렬 구조의 관점에서 논하였다.

Effects of Rice Straw Supplemented with Urea and Molasses on Intermediary Metabolism of Plasma Glucose and Leucine in Sheep

  • Alam, Mohammad Khairul;Ogata, Yasumichi;Sato, Yukari;Sano, Hiroaki
    • Asian-Australasian Journal of Animal Sciences
    • /
    • 제29권4호
    • /
    • pp.523-529
    • /
    • 2016
  • An isotope dilution method using $[U-^{13}C]glucose$ and $[1-^{13}C]leucine$ (Leu) was conducted to evaluate the effects of rice straw supplemented with urea and molasses (RSUM-diet) on plasma glucose and Leu turnover rates in sheep. Nitrogen (N) balance, rumen fermentation characteristics and blood metabolite concentrations were also determined. Four sheep were fed either mixed hay (MH-diet), or a RSUM-diet with a crossover design for two 21 days period. Feed allowance was computed on the basis of metabolizable energy at maintenance level. The isotope dilution method was performed as the primed-continuous infusion on day 21 of each dietary period. Nitrogen intake was lower (p = 0.01) for the RSUM-diet and N digestibility did not differ (p = 0.57) between diets. Concentrations of rumen total volatile fatty acids tended to be higher (p = 0.09) for the RSUM-diet than the MH-diet. Acetate concentration in the rumen did not differ (p = 0.38) between diets, whereas propionate concentration was higher (p = 0.01) for the RSUM-diet compared to the MH-diet. Turnover rates as well as concentrations of plasma glucose and Leu did not differ between diets. It can be concluded that kinetics of plasma glucose and Leu metabolism were comparable between the RSUM-diet and the MH-diet, and rumen fermentation characteristics were improved in sheep fed the RSUM-diet compared to the MH-diet.