• Title/Summary/Keyword: nitrogen ($N_2$)

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Phase Changes of the STS 431 Martensitic Stainless Steel after High Temperature Gas Nitriding Treatment (STS 431 마르텐사이트계 스테인리스강의 고온 가스 질화 열처리에 따른 상변화)

  • Yoo, D.K.;Kong, J.H.;Lee, H.W.;Kang, C.Y.;Kim, Y.H.;Sung, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.21 no.5
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    • pp.244-250
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    • 2008
  • This study has investigated the surface phase change, hardness variation, surface precipitates, nitrogen content and corrosion resistance in STS 431 (17Cr-2Ni-0.2C-0.01Nb) martensitic stainless steel after high temperature gas nitriding (HTGN) treatment at the temperature range between $1050^{\circ}C$ and $1150^{\circ}C$. The HTGN-treated surface layer appeared $Cr_2N$ of rod type, carbo-nitride of round type and fine precipitates in the austenite matrix. On the other hand the interior region where the nitrogen was not permeated, exhibited martensite phase. The surface hardness showed 250~590 HV, depending on the HTGN treatment conditions, while the interior martensitic phase represented 520 HV. The permeation depth of nitrogen increased with increasing the HTGN-treated temperature. The nitrogen concentration of the surface layer appeared approximately ~0.17% at $1100^{\circ}C$. On comparing the corrosion resistance between solution-annealed and HTGN-treated steels, the corrosion resistance of HTGN-treated steel was superior to that of solution-annealed specimens.

Effects of Nitrogen Recovery of Satuma Mandarins with Different Nitrogen Rates and Application Methods (질소시비량과 시비방법에 따른 온주밀감의 질소회수율)

  • Kang, Young-Kil;U, Zang-Kual
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.4
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    • pp.342-349
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    • 1998
  • In order to evaluate the effects of nitrogen (N) rate and application method on the recovery of N fertilizer applied in spring and summer by Satsuma mandarins (cv. Miyakawa Wase), N as urea was surface-applied at the rates of 50 (applied with 20 mm water; 50% N application) and 100% (three treatments; applied as solid, with 5 or 20 mm water) of the recommended rate ($150kg\;ha^{-1}\;yr^{-1}$) on 25 March and 12 June with an application ratio of 50 and 20%. The labeled N was applied only once in spring or summer. There were no differences among the four treatments in fruit yield, fruit quality except acid content of juice, and N content of leaves. The recovery of fertilizer N applied in spring by a tree ranged from 7.8 to 8.3% and that of N applied in summer ranged from 11.3 to 14.2% at the three recommended N rates and was 18.0% for the 50% N application. The recovery of fertilizer N applied in spring in the upper 40 cm of soil ranged from 32.1 to 37.7% at the three recommended N rates and was 55.8% at the 50% N application. For N applied in summer, it was 69.8% for surface application of the recommended N rate and ranged from 80.7 to 84.4% for the three N applications with water. The total (tree+soil) recovery of N fertilizer applied in spring was highest (64.1%) for the 50% N application and ranged from 40.3 to 45.5% for the three recommended N rates. The total recovery of N fertilizer applied in summer was also highest (99.4%) for the 50% N application and tended to be higher for the application of N with water than surface application and to increase with increasing irrigation amount of N application.

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Effect of Ureaform, SCU and Melamine on Barley Growth and their Nitrogen Supplying Ability (Ureaform, SCU, Melamine의 질소공급력(窒素供給力)과 보리 생육(生育)에 대(對)한 효과(效果))

  • Lim, Sun-Uk;Oh, Nam-Soon
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.3
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    • pp.265-273
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    • 1984
  • To investigate nitrogen supplying effect of some slowrelease N-fertilizers on barley in upland soil sulfurcoated urea(SCU), ureaform and melamine (1,3,5-Triazine-2,4,6-triamine) were treated and compared to urea. In addition, thiourea as a nitrification inhibitor was also tested. Effects of variable soil condition such as moisture content, pH and temperature on nitrogen supplying ability of the fertilizers and on growth of barley were studied through incubation test and pot culture and the obtained results were summarized as follows: The releasing rate of ammonia from urea, SCU, ureaform and melamine were resulted as 27-59%, 25-39%, 9-34% and 0.7-4.3% at maximum conversion rate, respectively. Nitrification rate of the tested fertilizers was higher at pH 6.54 markedly than at pH 4.73. Addition of thourea depressed the formation of $NO_3$ during four weeks of incubation period. Mixed application of ureaform with small amount of urea contributed to nitrogen supply till latter growth stage of barely Basal application of melamine showed lowest nitrogen supplying ability and injurious response on barley growth.

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A study on enhancement of nitrogen removal efficiency on low concentration influent sewage (단계유입과 내부순환을 이용한 저농도 하수의 질소처리효율 향상을 위한 연구)

  • Choo, Tai-Ho;Kim, Tae-Ki;Ok, Chi-Youl
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.2
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    • pp.675-680
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    • 2010
  • This study was investigated to complement nitrogen removal of low concentration influent municipal sewage. The following are the results of the effect of Internal Recircularion and Step Feed rates on Treatment efficiency at a BOD low concentration influent municipal sewage. Up to 90.0% of BOD, 87.8% of COD, 71.0% of T-N, 75.3% of T-P were removed on average at a low concentration influent. Whereas BOD and T-P were removed without any relations to Step Feed rates, T-N was influenced. Nitrogen removal efficiencies in 80% of Step Feed rates was 65%, which was caused by the lack of Carbon Source for denitrification. Nitrogen removal efficiency in 40% of Step Feed rates was 58%, which means it was not removed but dischared. Consequently, the efficiency was 73%, 80%, and 78% in 70%, 60% and 50% of Step Feed rates, which was concluded as the best range of Step Feed rates. Nitrogen removal efficiency increased under the condition of Internal Recircularion. At over 150% of Internal Recircularion rate, the efficiencies were not affected any more. It is believed that lots of Recircularion caused inflow of DO to anoxic tank. Therefore, the most appropriate Internal Recircularion rate can be concluded as 50~150%.

Optimization of Growth and Astaxanthin Production by Phaffia rhodozyma AJ-6 in Fed-batch Culture

  • Kim, Su-Jin;Yu, Yeon-U
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.271-274
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    • 2000
  • A study was carried out to select a nitrogen source and the optimize the C/N ratio for the maximum cell growth of Phaffia rhodozyma in fed-batch culture. The yeast extract was the best organic nitrogen source. In the batch culture experiments, the highest cell yield was obtained 0.575 g-cell/g-glucose from 10 g/L and 10 g/L yeast extract. In the fed-batch experiments, the maximum cell concentration was obtained 33.1 g/L from the C/N ratio of 2:1 while the astaxanthin concentration of cell was Increased by increasing the C/N ratio, of feed medium.

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Utilization of Deodorized Poultry Feces with Tolura sp. CH-30

  • Choi, Moo-Young;Lee, Eun
    • Journal of Microbiology and Biotechnology
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    • v.2 no.4
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    • pp.273-277
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    • 1992
  • Treatment of poultry feces with Tolura sp. CH-30 produced a material that was significantly deodorized and showed a promotive effect on plant growth. Tolura sp. CH-30 grew on the poultry feces, deodorizing the feces by assimilation of volatile fatty acids, which are the source of the offensive odor, as a carbon source. Significant degradation of uric acid also occurred. In the treatment of feces with Tolura sp. CH-30, it was possible to deodorize feces in a short time, but reduction in the amount of urate-N was not enough. Urate-N inhibited plant growth due to an excessive nitrogen content produced as a result of rapid decomposition. Therefore, we propose a recycle-treatment plan using poultry feces treated with Tolura sp. CH-30. After the recycle-treatment, the amount of urate-N contained in the recycle-treated poultry feces was small and the recycle-treated poultry feces showed a promotive effect on plant growth when it was added at a nitrogen content of 1.6 g/600 g soil/pot.

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The study on cryogenic properties of austenitic stainless steels by the addition of Nitrogen (Austenite계 Stainless강의 저온특성변화에 관한 N의 영향)

  • Kim, J.O.;Chol, Y.;Choe, J.I.
    • Journal of the Korean Society for Heat Treatment
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    • v.15 no.4
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    • pp.166-171
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    • 2002
  • The effects of Ni and N addition to 304 stainless steel on mechanical properties and microstructure were investigated within temperature ranged from $-196^{\circ}C$ to $25^{\circ}C$. The addition of nickel and nitrogen induced the stability against the formation of provide significantly enhanced ductility at $-196^{\circ}C$ and reduce the Md temperature. Fe-18Cr-10Ni-0.2N alloy showed the ${\gamma}$ phase in deformed structure which it was beneficial to enhance the tensile strength and elongation at $25^{\circ}C$ and $-196^{\circ}C$.

Covalently-Bonded Solid Solution Formed by Combustion Synthesis

  • Ohyanagi, Manshi;Munir, Zuhair A.
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.250-257
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    • 2000
  • The feasibility of synthesizing SiC-AlN solid solution by field-activated combustion synthesis was demonstrated. At lower fields of 8-16.5V/cm, composites of AlN-rich and SiC-rich phases were synthesized, but at fields of 25-30 V/cm, the product was a 2H structure solid solution. Combustion synthesis of the solid solution by nitridation of aluminum with silicon carbide under a nitrogen gas pressure of 4-8 MPa was also investigated. The maximum combustion temperature and wave propagation velocity were found to be influenced by the electric field in the field-activated combustion synthesis, and by the green density and nitrogen pressure in the combustion nitridation. In both cases the formation of solid solutions is complete within seconds, considerably faster than in conventional methods which require hours.

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Kinetic Studies on the Addition of Potassium Cyanide to α,N-Diphenylnitrone

  • 김태린;김영호;변상용
    • Bulletin of the Korean Chemical Society
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    • v.20 no.6
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    • pp.712-714
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    • 1999
  • The rate constants for the nucleophilic addition of potassium cyanide to α,N-diphenylnitrone and its derivatives (p-OCH3, p-CH3, p-Cl, and p-NO2) were determined by ultraviolet spectrophotometer at 25℃, and the rate equations which can be applied over a wide pH range were obtained. On the basis of pH-rate profile, adduct analysis, general base catalysis and substituent effect, a plausible mechanism of this addition reaction was proposed: At high pH, the cyanide ion to carbon-nitrogen double bond was rate controlling, however, in acidic media, the reaction proceeded by the addition of hydrogen cyanide molecule to carbon-nitrogen double bond after protonation at oxygen of a,N-diphenylnitrone. In the range of neutral pH, these two reactions occured competitively.

Effects of Levels of Feed Intake and Inclusion of Corn on Rumen Environment, Nutrient Digestibility, Methane Emission and Energy and Protein Utilization by Goats Fed Alfalfa Pellets

  • Islam, M.;Abe, H.;Terada, F.;Iwasaki, K.;Tano, R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.7
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    • pp.948-956
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    • 2000
  • The effect of high and low level of feed intakes on nutrient digestibility, nutrient losses through methane, energy and protein utilization by goats fed on alfalfa (Medicago sativa L.) pellets based diets was investigated in this study. Twelve castrated Japanese goats were employed in two subsequent digestion and metabolism trials. The goats were divided into three groups, offered three diets. Diet 1 consisted of 100% alfalfa pellet, Diet 2 was 70% alfalfa pellet and 30% corn, and Diet 3 was 40% alfalfa pellet and 60% corn. The two intake levels were high (1.6 times) and low (0.9 times) the maintenance requirement of total digestible nutrients (TON). Rumen ammonia nitrogen ($NH_3$-N) level of Diet 1 was lower (p<0.001) compared to Diets 2 and 3, but the values were always above the critical level (I50 mg/liter), The pH values of rumen liquor ranged from 6.02 to 7.30. Apparent digestibility of nutrient components did not show differences (p>0.05) between the two intake levels but inclusion of corn significantly altered the nutrient digestibility. Diet 3 had highest (p<0.001) dry matter (DM), organic matter (OM), ether extract (EE) and nitrogen fee extract (NFE) digestibility followed by the Diet 2 and Diet 1. The crude protein (CP) digestibility values among the three diets were in a narrow range (70.1 to 70.8%). Crude fiber (CF) digestibility for Diet 3 was slight higher (p>0.05) than that for other two diets. When alfalfa was replaced by corn, there were highly significant (p<0.001) increases in DM, OM, EE and NFE apparent digestibility and a slight increase in the CF digestibility (p>0.05). There were no differences (p>0.05) in energy losses as methane ($CH_4$) and heat production among the diets but energy loss through urine was higher for the Diet 1. The total energy loss as $CH_4$ and heat production were higher for the high intake level but the energy loss as $CH_4$ per gram DM intake were same (0.305 kcal/g) between the high and low intake level. Retained energy (RE) was higher for Diet 3 and Diet 2. Nitrogen (N) losses through feces and urine were higher (p<0.001) for Diet 1. Consequently, N retention was lower (p>0.05) for Diet 1 and higher in Diets 3 and 2. It is concluded that inclusion of corn with alfalfa increased the metabolizable energy (ME) and RE, and retained N through reducing the energy and N losses. The high level of intake reduced the rate of nutrient losses through feces and urine.