• Title/Summary/Keyword: nitrogen ($N_2$)

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Pilot-scale Study on Nitrogen Removal of Effluent from Biogas Plant (바이오가스 플랜트 처리수의 고농도 질소 제거)

  • Yoo, Sungin;Yu, Youngseob;Lee, Yongsei;Park, Hyunsu;Yoo, Heechan
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.175.1-175.1
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    • 2011
  • A rotating activated bacillus contactor (RABC) process with a series of aerobic reactors was tested in pilot scale to treat digested liquid from an anaerobic digester treating swine wastewater and sewage sludge. The influent (digested liquid) for the RABC process showed C/N ratios less than 2 as a typical feature of effluent from anaerobic digesters. The pilot process, which consists of three 3 RABC reactors, four aerobic tanks and a sedimentation tank, was operated for 210 days with a hydraulic retention time of 20 days without pH and temperature control. Since the Bacillus-enriched aerobic reactors shows high efficiencies of nitrogen removal at low DO levels less than 1.0 mg/L, they were operated at reduced aeration intensities. With relatively low concentrations of organics in comparison with nitrogen concentrations, the RABC process tested in this study showed stable and high nitrogen and organics removal efficiencies over 80%. The nitrogen removal process tested in this study was proven to be an effective and operation-cost saving (lower aeration) method to remove nitrogen without adding external carbon sources to meet the optimum C/N ratio.

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Field Emission Characteristics of Nitrogen-Doped and Micro-Patterned Diamond-Like Carbon Films Prepared by Pulsed Laser Deposition

  • Shin, Ik-Ho;Lee, Taek-Dong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.133-134
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    • 2000
  • Effect of nitrogen doping on field emission characteristics of patterned Diamond-like Carbon (DLC) films was studied. The patterned DLC films were fabricated by the method reported previously[1]. Nitrogen doping in DLC film was carried out by introducing $N_2$ gas into the vacuum chamber during deposition. Higher emission current density of $0.3{\sim}0.4$ $mA/cm^2$ was observed for the films with 6 at % N than the undoped films but the emission current density decreased with further increase of N contents. Some changes in CN bonding characteristics with increasing N contents were observed. The CN bonding characteristics which seem to affect the electron emission properties of these films were studied by Raman spectroscopy, x-ray photoemission spectroscopy (XPS) and Fourier transform infrared spectroscopy (FT-IR). The electrical resistivity and the optical band gap measurements showed consistence with the above analyses.

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Effects of Lime Compounds on the Reduction of Ammonia Gas Formation and Nitrogen Loss During the Formation of Poultry Manure-Sawdust (가축분에 몇가지 석회 화합물 처리에 의한 질소손실 경감과 $NH_3$ 가스 발생 감소에 미치는 영향)

  • 박창규;양장석;조광래;원선이
    • Korean Journal of Organic Agriculture
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    • v.8 no.2
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    • pp.89-96
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    • 2000
  • To reduce loss of nitrogen and generation of ammonia gas during composting, poultry manure and sawdust were mixed at the equivalent ratio and calcium chloride, fused superphosphate and vermiculite were added. Ammonia and sulfurous gas during composting, and NH4-N and NO3-N contents of composts were periodically measured. With the treatments of 0.5∼3% calcium chloride and 3% fused superphosphate, ammonia and sulfurous gas during composting significantly decreased, and especially generation of gases sharply reduced and a increase of calcium chlorde. Extractable NH4-N content in composts treasted with calcium chloride and fused superphosphate were high but extractable NO3-N markedly decreased. In conclusion, the results suggest that it is necessary the additon of 1∼3% calcium chloride or 3% fused superphosphate to reduce loss of nirogen and generation of offensive odor during composting of poultry manure mixed with sawdust.

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Determination of Nitrogen Abundance Ratio from Low-Resolution Stellar Spectra

  • Kim, Changmin;Lee, Young Sun
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.58.2-58.2
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    • 2020
  • We present a method for determining the abundance ratio of nitrogen to iron ([N/Fe]) from low-resolution (R~2000) stellar spectra from large spectroscopic surveys such as Sloan Digital Sky Survey (SDSS) and Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST). The basic idea of the method is to match a grid of synthetic spectra with an observed spectrum in the CN band region around 3883 Å. To calibrate our estimate of [N/Fe], we make use of the giants observed in Apache Point Observatory Galaxy Evolution Experiment (APOGEE), which are also observed in the SDSS. This method will be applied to the Galactic halo stars to determine [N/Fe], and the measured nitrogen abundance ratios will be used to investigate the C-N anti-correlation, which is observed in globular clusters, to trace their origin with their kinematic properties.

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A Study for Joining of Silicon Nitride with Crystallized Glass Solder of $SiO_2-Al_2O_3-MgO$ System ($SiO_2-Al_2O_3-MgO$계 결정화 유리 솔더에 의한 질화규소의 접합에 관한 연구)

  • 안병국
    • Journal of Welding and Joining
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    • v.21 no.1
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    • pp.107-113
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    • 2003
  • Joining of $Si_3N_4$ to $Si_3N_4$ with crystallized glass solder was studied. $SiO_2-Al_2O_3-MgO$ glass with $P_2O_5$ as a crystallizing reagent was used as a solder. To improve the hish temperature toughness of joined specimen, two stage heat treatment was applied to Joined sample for the crystallization of joined layer, Two factors, i.e. thickness of soldered layer and crystallization were taken and thier effects on joining strength were investigated by a SEM-EDX observation of joined interface and bending strength both at room and elevated temperatures. Obtained results are summarized as follows: (1) Nitrogen diffused from $Si_3N_4$ to solder during the Joining process. Average amount of nitrogen in soldered layer depended on the thickness of the soldered layer and increased with decrease of the thickness. (2) Joining strength of the specimen having a thinner soldered layer was stronger than that of thicker layer. This can be mainly attributed to the difference of the nitrogen content in the soldered layer. (3) Higher content of nitrogen in solder brought forth higher viscosity of the solder. Hence the crystallization of the solder become more difficult in thinner layer of the solder than thicker one. (4) Thus, the effect of crystallization was evaluated mostly by the thicker layer specimen. Crystallization of soldered layer improved markedly the fracure strength of joining at higher temperatures than the softening temperature of glass solder.

Effect of Concentration of Carbon and Nitrogen Sources on the Sporulation and the Life Cycles of Zygosaccharomyces (Zygosaccharomyces 의 포자형성(胞子形成)과 Life Cycle 에 미치는 배지중(培地中)의 당농도(糖濃度) 및 질소농도(窒素濃度)의 영향(影響))

  • Ha, Duk-Mo
    • Applied Biological Chemistry
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    • v.10
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    • pp.101-105
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    • 1968
  • The effect of concentration of carbon and nitrogen sources on the sporulation and the life cycles of three strains of Zygosaccharomyces was investigated. The results are as follows: 1) The good sporulation of Zygosaccharomyces bisporus, delbruekii, and Z. steineri was obtained on solid medium containing 0 to 0.001% of nitrogen and 10 to 20% of glucose. The high content of nitrogen was detrimental to sporulation and asci were formed under 0.01% of nitrogen. 2) It is widely accepted that the life cycle of Zygosaccharomyces proceeds in the following way: Ascospore...Vegetative cells...Conjugation of vegetative cells...Sporulation...Ascopores But zygotes of Z. bisporus proceeded to vegetative cells when transfered to the suitable medium for vegetative reproduction, and then formed asci.

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Evaluation of Organic Matter Sources of Phytoplankton in Paldang Reservoir using Stable Isotope Analysis (팔당호 내 식물플랑크톤 안정동위원소 분석을 통한 유기물 기원 평가)

  • Kim, Jongmin;Kim, Bokyong;Kim, Minseob;Shin, Kisik
    • Journal of Korean Society on Water Environment
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    • v.31 no.2
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    • pp.159-165
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    • 2015
  • The organic matter sources of phytoplankton and related environmental factors influencing algal bloom in Paldang reservoir were studied using nitrogen and carbon isotope ratio(${\delta}^{15}N$, ${\delta}^{13}C$). Phytoplankton samples for stable isotope analysis were collected from four points in reservoir using a plankton net. Physicochemical water quality, algal taxa and hydrological data were collected from published monitoring material. Phytoplankton samples were analyzed by IRMS. CN ratio of each sample was very similar to that of phytoplankton from literature cited. ${\delta}^{15}N$ of each sample was decreased during July. Mixing and dilution of nitrogen sources due to increment of influx by concentrated rainfall were considered as the main reason for the decline of ${\delta}^{15}N$. Based on analyzed ${\delta}^{15}N$ value of each sample, nitrogen source of Bughan river sample was presumed to come from soil. The nitrogen sources of Namhan river and Kyeongan stream samples seemed to be sewage or animal waste. Low ${\delta}^{15}N$ value in August (2012) seemed to be influenced by isotope fractionation due to the blooming of nitrogen-fixation blue-green algae (Anabaena spp.). Variation in ${\delta}^{15}N$ values particularly by blue-green algal bloom was considered the important factor for estimating the organic matter sources of phytoplankton.

A Study on the Properties of AlN Films Deposited with Nitrogen Ion Beam Assisted RF Magnetron Sputtering (질소이온 빔 보조 마그네트론 스퍼터로 증착 된 AlN 박막의 물성연구)

  • Heo, Sung-Bo;Lee, Hak-Min;Jeong, Chul-Woo;Choi, Dae-Han;Lee, Byung-Hoon;Kim, Min-Gyu;You, Yong-Zoo;Kim, Daeil
    • Journal of the Korean Society for Heat Treatment
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    • v.24 no.2
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    • pp.77-81
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    • 2011
  • Aluminum nitride (AlN) thin films were prepared by using nitrogen ion beam assisted reactive radio frequency (RF) magnetron sputtering on the glass substrates without intentional substrate heating. After deposition, the effect of nitrogen ion beam energy on the structural and optical properties of AlN films were investigated by x-ray diffraction (XRD), atomic force microscope (AFM) and UV-Vis. spectrophotometer, respectively. AlN films deposited with $N^+$ ion irradiation at 100 eV show the higher (002) peak intensity in XRD pattern than other films. It means that $N^+$ ion energy of 100 eV is the favorable condition for low temperature crystallization. AFM images also show that surface average roughness is increased from 1.5 to 9.6 nm with $N^+$ ion energy in this study. In an optical observation, AlN films which deposited by $N^+$ ion beam energy of 100 eV show the higher transmittance than that of the films prepared with the other $N^+$ ion beam conditions.

Effect of Ammonium and Nitrate Nitrogen on the Volatile Oil of Flue-cured Tobacco under Vinyl Mulching Cultivation (질소비료형태(窒素肥料形態)가 Vinyl Mulching 재배시황색종(栽培時黃色種) 입담배의 휘발성 (揮發性) 향기성분(香氣成分)에 미치는 영향(影響))

  • Chang, Ki Woon
    • Korean Journal of Soil Science and Fertilizer
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    • v.21 no.1
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    • pp.31-40
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    • 1988
  • This study was focussed to compare the concentrations of the volatile oil components of flue-cured tobacco grown by two types of nitrogen-ammonium and nitrate-under vinyl mulching. The results were summarized as follows; 1. The content of nicotine was lower and reducing sugars degraded from starch was higher content in $NO_3-N$ application than $NH_4-N$. 2. The concentrations of furfural, benzyl alcohol, and phenethyl alcohol in the cured leaf were not different between $NH_4-N$ and $NO_3-N$ treatments. 3. Some of the important flavour components-linalool, solanone, damascenone, neophytadiene, and oxyolanone + megastigmatriene-one - had much higher concentrations in $NO_3-N$ than $NH_4-N$ application. 4. In conclusion, nitrate nitrogen was more favorable to decrease nicotine and to increase some important flavour components of cured leaf than ammonium nitrogen.

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Ammonium Production During the Nitrogen-Fixing Process by Wild Paenibacillus Strains and Cell-Free Extract Adsorbed on Nano $TiO_2$ Particles

  • Shokri, Dariush;Emtiazi, Giti
    • Journal of Microbiology and Biotechnology
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    • v.20 no.8
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    • pp.1251-1258
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    • 2010
  • During the nitrogen-fixing process, ammonia ($NH_3$) is incorporated into glutamate to yield glutamine and is generally not secreted. However, in this study, $NH_3$-excreting strains of nitrogen-fixing Paenibacillus were isolated from soil. The ammonium production by the Paenibacillus strains was assayed in different experiments (dry biomass, wet biomass, cell-free extract, and cell-free extract adsorbed on nano $TiO_2$ particles) inside an innovative bioreactor containing capsules of $N_2$ and $H_2$. In addition, the effects of different $N_2$ and $H_2$ treatments on the formation of $NH_3$ were assayed. The results showed that the dry biomass of the strains produced the most $NH_3$. The dry biomass of the Paenibacillus strain E produced the most $NH_3$ at 1.50, 0.34, and 0.27 ${\mu}M$ $NH_3$/mg biomass/h in the presence of $N_2$ + $H_2$, $N_2$, and $H_2$, respectively, indicating that a combined effluent of $N_2$ and $H_2$ was vital for $NH_3$ production. Notwithstanding, a cell-free extract (CFE) adsorbed on nano $TiO_2$ particles produced the most $NH_3$ and preserved the enzyme activities for a longer period of time, where the $NH_3$ production was 2.45 ${\mu}M$/mg CFE/h over 17 h. Therefore, the present study provides a new, simple, and inexpensive method of $NH_3$ production.