• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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• pp.856-857
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• 1998

Hydrogenated amorphous carbon nitride [a-C:H(N)] films were deposited on pretreated silicon(100) substrate in activated gas phase using. RF plasma-assisted CVD. We measured the FT-IR spectrum to investigate $C{\equiv}N$ stretching mode(nitrile), C-H stretching mode, C-H bending mode, C=C stretching mode C=N(imino) mode, and the EDX to investigate the ratio of N to C(0.25). By the results of FT-IR and EDX spectrum, We confirmed that hydrogenated amorphous carbon nitride films successfully were synthesized by RF-PACVD

• 통합자연과학논문집
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• 제8권4호
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• pp.250-257
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• 2015

The crystal structure of the potential active 3-(4-ethylphenyl)-3H-chromeno[4,3-c]isoxazole-3a(4H)-carbonitrile ($C_{19}H_{16}N_2O_2$) has been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the monoclinic space group $P2_1/c$ with unit cell dimension a=6.6869 (8) ${\AA}$, b=15.8326 (19) ${\AA}$ and c= 15.237 (2) ${\AA}$ [${\alpha}=90^{\circ}$, ${\beta}=100.663^{\circ}$ and ${\gamma}=90^{\circ}$]. In the structure chromene, isoxazole and carboxylate are almost coplanar each other. All geometrical parameters revelled that chromene ring of pyran ring adopt sofa conformation. The crystal packing is stabilized by intermolecular C-H...N and C-H...O hydrogen bond interaction.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 1998년도 제27회 춘계학술대회
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• pp.307-313
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• 1998

This paper presents the experimental results of the friction characteristics of double lip-type oil seals which show an improvement in sealing performance over single lip-type oil seals. The major differences between two oil seals are the number of contact lip and seal materials; Nitrile Butadine Rubber(NBR) and urethane rubber. The measured results show that the friction torque of double lip seals shows 12-17% increases compared with those of single lip-type seals. But the sealing performance and service life of double tip oil seals have been increased and stabilized due to an optimized design of the seal lip and material properties.

• Archives of Pharmacal Research
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• 제12권3호
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• pp.201-206
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• 1989

The reaction of acetoacetanilide (1) with the $\alpha$-cyanocinnamonitrile derivatives 2 yielded the Michael adducts 4 which could be converted into the pyrano [2, 3, -c] pyrazole derivatives 5 via their reaction with hydrazine hydrate. Cyclisation of 4 afforded the derivatives 10. The pyranopyrazoles 9 reacted with different activated nitrile derivatives (3a-c) to give the pyrano [2, 3-c] pyridine derivatives 13. 16 and 19 respectively. The biological activity of the synthesised heterocyclic derivatives was investigated and discussed.

• Elastomers and Composites
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• 제53권1호
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• pp.13-18
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• 2018

A face seal comprising a metal ring and acrylonitrile butadiene rubber (NBR) was installed in the driving part and suspension unit. The seal serves as a bearing and simultaneously prevents entry of foreign matter from external environment as well as internal oil leakage. Subsequently, the rubber-rod ring generates axial pressure owing to rubber elasticity (hardness), performs static sealing function between housing details and outer diameter of seal, and transmits rotational torque to the rotating support ring. In order to improve the durability of NBR, which performs the above tasks, and to effectively use it in tracked-vehicle applications at extreme temperatures, this study reports a mixing design approach to enhance cold and oil resistances of NBR.

• Tribology and Lubricants
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• 제22권1호
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• pp.20-25
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• 2006

The stress behavior analysis of a-rings and packing for a LPG filling unit has been presented using a finite element analysis technique by non-linear MSC/MARC program. The sealing performance and endurance of a-rings and packing are affected by working conditions such as filling pressure, friction coefficient, compression ratio, and material properties. The elastomeric polymers of O-rings and packing are nitrile butadiene rubber (NBR) and polytetrafluoroethylene (PTFE), which are selected as proper materials of a-rings and packing based on the stress analysis results. The calculated FEM results showed that the proper material of O-ring is NBR as a secondary sealing component and the recommended material of packing is PTFE as a primary sealing unit during a LPG filling process.

• 농약과학회지
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• 제2권1호
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• pp.104-106
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• 1998

3-Aryltetrahydro-1,2-benzisoxazolin-4-one derivatives were prepared by regioselective 1,3-dipolar cycloaddition reactions of various aryl nitrile oxides with 2-cyclohexen-1-one. The structures of these compounds were designed as a modifications of triketone herbicides and showed good herbicidal activity.

• 생약학회지
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• 제32권2호통권125호
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• pp.140-144
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• 2001

The composition of essential oils in the leaves of three cultivars (Ban-Chung-Gat, Chung-Gat and Dolsan-Gat) of Brassica juncea L. were analyzed and their antifungal activity were investigated in this study. Allyl isothiocyanate, 2-phenyl ethyl isothiocyanate, 4-isothiocyanato-1-butene, 5-methyl isothiazole, benzene acetaldehyde, benzene propane nitrile and beta-ionone have been identified in all of the experimented oils. The main component of the oils from Ban-Chung-Gat and Chung-Gat was 2-phenyl ethyl isothiocyanate while allyl isothiocyanate was the representing compound in the oil of Dolsan-Gat. The antifungal activities of the oils were tested by micro broth dilution method and disc diffusion method. As the result the oils exhibited significant inhibiting activities against Aspergillus niger, A. flavus, Trichoderma viride, Candida albicans, C. utilis, C. tropicalis, Cryptococcus neoformans, Trichosporon mucoides, Trichophyton tonsurans and Geotrichum capitatum.

• 분석과학
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• 제8권4호
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• pp.649-654
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• 1995

The reactivity of superoxide ion($O{_2}^{-.}$) with halogenated substrates is investigated by cyclic voltammetry and rotated ring-disk electrode method in aprotic solvents. The more positive the reduction potential of the substituted nitrile, the more facile is nucleophilic displacement by $O{_2}^{-.}$. The reaction rates of halogenonitriles with $O{_2}^{-.}$ vary according to the leaving-group propensity of halide (Br>Cl>F). The relative reaction rates of other substituted nitriles are in the order of electron-withdrawing propensity of the substituent group (CN> $C(O)NH_2$ >Ph, $CH_2CN$). The reaction of $O{_2}^{-.}$ with dihalocarbons indicates that five-membered rings can be rapidly formed by the cyclization of substrate and $O{_2}^{-.}$, and the relative rates of cyclization depend on the number of methylenic carbons {$Br(CH_2)_nBr$, [n=1<2<3>4>5]}. Mechanisms are proposed for the reaction of $O{_2}^{-.}$ with halogenated substrates.

• 공업화학
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• 제2권2호
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• pp.147-154
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• 1991

Poly acrylo-nitrile계(系) 섬유를 전구체로 하여 비등온과정(比等溫過程)에 의한 안정화(安定化) 및 탄화(炭化)를 승온속도(昇溫速度)를 달리한 TGA(thermogravimetric analysis)방법(方法)으로 연구하였다. 안정화과정(安定化過程)에서 cyclization과 탈수소(脫水素) 반응(反應)은 탄화과정중(炭化過程中) 세공발달(細孔發達)을 결정하는 주요한 요인(要因)이었으며, 세공(細孔) 및 탄화과정(炭化過程)의 $400^{\circ}C$ 이상에서 형성되기 시작하였다.