• Journal of the Korean Society for Heat Treatment
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• v.36 no.1
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• pp.40-46
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• 2023

Controlled nitriding is a technology that controls the nitriding potential based on the gas partial pressure received through an IOT-based sensor. Controlled nitriding is characterized by easy control of the phase of the nitride compound and excellent reproducibility of quality. In particular, it is possible to form a compound layer of excellent quality with fewer pores on the surface. However, despite these advantages, the application of controlled nitriding still needs to be improved in Korea. This paper explains the characteristics of controlled nitriding and describes the future direction and the problems of controlled nitriding in Korea.

• Journal of the Korean Society for Heat Treatment
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• v.18 no.1
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• pp.24-28
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• 2005

New post plasma nitriding can achieve a high uniformity that have been difficult in DC nitriding and have a high productivity comparable to gas nitriding. However, it has not a enough high nitriding potential for a rapid nitriding, because surface activation or ion etching in the general plasma nitriding cannot be expected. Thus, in this study, the effects of pre-treatments with oxidation and reduction gas have been investigated to improve the nitriding kinetics of post plasma nitriding. An effective pre-treatment consisting of oxidation and reduction resulted in the increase of surface energy of STD 11. This induced the surface hardness and the effective nitriding depth of STD 11. It is thought that the increase of the surface energy and the surface area with pre-treatment promote the nucleation of nitriding layer.

• Journal of the Korean Society for Heat Treatment
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• v.36 no.2
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• pp.86-95
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• 2023

This paper explained the equipment and process development to secure the source technology of controlled nitrification technology. The nitriding potential in the furnace was controlled only by adjusting the flow rate of ammonia gas introduced into the furnace. In addition, a control system was introduced to automate the nitriding process. The equipment's hardware was designed to enable controlled nitriding based on the conventional gas nitriding furnace, and an automation device was attached. As a result of measuring the temperature and quality uniformity for the equipment, the temperature and compound uniformity were ±1.2℃ and 14.3 ± 0.2 ㎛, respectively. And, it was confirmed that nitriding potential was controlled within the tolerance range of AMS2759-10B standard. In addition to parts for controlled nitriding, it was applied to products produced in existing conventional nitriding furnaces, and as a result, gas consumption was reduced by up to 80%.

• Journal of the Korean Society for Heat Treatment
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• v.23 no.3
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• pp.142-149
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• 2010

Austenitic stainless steel is more or less difficult with conventional gas nitriding treatment, but it can be nitrided after appropriate pre-heat treatment. The pretreatment was more effective upon nitriding for austenitic stainless steel than martensitic stainless steel. Both thickness and microhardness measurements indicated that effect of the nitriding treatment was more sensitive in austenitic stainless steel than martensitic stainless steel with nitriding time. Fatigue strength was most increased with SACM 645 steel among three steels.

• Journal of the Korean institute of surface engineering
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• v.53 no.6
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• pp.306-311
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• 2020

In this work, diamond-like carbon (DLC) films are coated onto plasma nitrided AISI 4140 steel by DC-pulsed PECVD. One problem of DLC films is their very poor adhesion on steel substrates. The purpose of the nitriding was to enhance adhesion between the substrate and the DLC films. The white layer formation is avoided. Plasma nitriding increased adhesion from 8 N for DLC coating to 25 N for duplex coating. Duplex plasma nitriding/DLC coating was proven to be more effective in improving the adhesion. The purpose of the bond layer was to enhance adhesion between the substrate and the DLC films.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.05a
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• pp.177-178
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• 2012

In this experiment, post-nitriding treatment has been performed at $400^{\circ}C$ on AISI 316 stainless steel which is plasma carburized previously at $430^{\circ}C$ for 15 hours. Plasma nitriding was implemented on AISI 316 stainless steel at various gas compositions (25% N2, 50% N2 and 75% N2) for 4 hours. Additionally, during post nitriding Ar gas was used with H2 and N2 to observe the improvement of treatment. After treatment, the behavior of the hybrid layer was investigated by optical microscopy, X-ray diffraction, and micro-hardness testing. Potentiodynamic polarization test was also used to evaluate the corrosion resistance of the samples. Meanwhile, it was found that the surface hardness increased with increasing the nitrogen gas content. Also small percentage of Ar gas was introduced in the post nitriding process which improved the hardness of the hardened layer but reduces the corrosion resistance compared with the carburized sample. The experiment revealed that AISI 316L stainless steel showed better hardness and excellent corrosion resistance compared with the carburized sample, when 75% N2 gas was used during the post nitriding treatment. Also addition of Ar gas during post nitriding treatment were degraded the corrosion resistance of the sample compared with the carburized sample.

• Journal of the Korean Society for Heat Treatment
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• v.7 no.3
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• pp.184-189
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• 1994

The heat treatment charaterristic of SCM 440 and B 16 steels has been investigated in various condition(A, B and C) to the effect of heat treatment on mechanical properties, and the following results were obtained. 1. We are obtained a good nitriding characteristic in bainitic structure than other heat treatment cycle in our experiment. 2. Fatigue characteristic has shown in order of B)C)A condition as heat treatment cycle. 3. The effective hardening depth and fatigue characteristic has been excellented in B 16 than SCM 440 after the nitriding and Q. T for Band C condition. 4. Nitriding depth has been increased in addition of Cr, V and the nitriding efficiency is increased as easiness of banite formation to wide range of cooling rate by addition of Mo. 5. The depth of compound layer in parallel surface, notched slop plane and notched bottom has been varied to the nitriding depth of 5, 4 and 3 ${\mu}$ in relatively uniform pattern after 10h nitriding treatment for SCM 440 into A condition.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09b
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• pp.1163-1164
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• 2006

TZM alloy having elongated coarse-grain structure was developed by three-step internal nitriding treatment at 1423 to 1873 K in $N_2$ and subsequent recrystallization treatment at 2173 K in vacuum. Some specimens were subjected to re-nitriding treatment at 1873 K for 16 h. After the recrystallization treatment, aspect ratio (L/W) of grains for rolling direction was about 50 at the maximum. Yield stress obtained at 1773 K after re-nitriding treatment was about 6 times as large as that of recrystallized specimen. Re-nitriding was very effective in the improvement in strength of TZM alloy having elongated coarse-grain structure.

• Journal of the Korean Society for Heat Treatment
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• v.22 no.5
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• pp.298-306
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• 2009

Gas nitriding and post oxidation were performed on stainless steels and SACM 645 steel. With increasing gas nitriding time, the increasing rate of nitrided layer was most rapid on SACM 645 steel and the nitriding depth of nitrided layer was most narrow on STS 304 steel among three steels. Corrosion resistance was increased with post oxidation on stainless steels and with increasing time the effect of corrosion resistance was decreased to compare with relatively short gas nitriding time. An improvement effect of corrosion resistance was consisted of predominantly on austenitic stainless steel by post oxidation after gas nitriding among three steels and it was relatively less influenced on martensitic stainless steel.

• Journal of the Korean institute of surface engineering
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• v.48 no.6
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• pp.269-274
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• 2015

In this experiment, post-nitriding treatment was performed at $400^{\circ}C$ on AISI 316 stainless steel which was plasma carburized previously at $430^{\circ}C$ for 15 hours. Plasma nitriding was implemented on AISI 316 stainless steel at various gas compositions (25% $N_2$, 50% $N_2$ and 75% $N_2$) for 4 hours. Additionally, during post nitriding Ar gas was used with $H_2$ and $N_2$ to observe the improvement of surface properties. After treatment, the behavior of the hybrid layer was investigated by optical microscopy, X-ray diffraction, and micro-hardness testing. Potentiodynamic polarization test was also used to evaluate the corrosion resistance of the samples. Meanwhile, it was found that the surface hardness increased with increasing the nitrogen gas content. Also small percentage of Ar gas was introduced in the post nitriding process which improved the hardness of the hardened layer but reduced the corrosion resistance compared with the carburized sample. The experiment revealed that AISI 316L stainless steel showed better hardness and excellent corrosion resistance compared with the carburized sample, when 75% $N_2$ gas was used during the post nitriding treatment. Also addition of Ar gas during post nitriding treatment degraded the corrosion resistance of the sample compared with the carburized sample.