• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.519-519
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• 2003

We performed a hydrochemical study on a total of 89 bedrock groundwaters collected from preexisting wells (30 to 300 m deep) in the Boeun area. Hydrochemical data showed significant variations in the area, due to varying degrees of anthropogenic pollution. The waters were mostly enriched in Ca and HCO$_3$ but locally contained significant concentrations of anthropogenic constituents in the general order of Cl >NO$_3$>SO$_4$. In particular, about 11% of the examined wells exceeded the drinking water standard with respect to nitrate. We consider that aquifers in the area are locally highly susceptible to the contamination related to agricultural activities. Diagrams showing the relationships between the summation of cations (∑cations) and the concentration of several anions with different origin (natural versus anthropogenic) were used to estimate the relative role of anthropogenic contamination. A good correlation was observed for the relationship between ∑cations and bicarbonate, indicating that water-rock interaction (namely, hydrolysis of silicate minerals) is most important to control the water quality. Thus, we made an assumption that the equivalent of dissolved cations for a water should be equal to the alkalinity, if the chemistry were controlled solely by a set of natural weathering reactions. If we excluded the equivalent quantities of cations and bicarbonate (natural origin) from the acquired data for each sample, the remainder therefore could be considered to reflect the degree of anthropogenic contamination. Finally, we performed a multiple regression approach for hydrochemical data using the ∑cations as a dependent variable and the concentration data of each anion (natural or anthropogenic) as an independent variable. Using this approach, we could estimate the relative roles of anthropogenic and natural processes. Rather than the conventional evaluation scheme based on water quality criteria, this approach will be more useful and reasonable for the evaluation of groundwater quality in a specific region and also can be used for planning appropriate protection and remedial actions.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.E3
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• pp.137-148
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• 2003

In this study, we examined the influence of long-range transport of dust particles and air pollutants on the photochemistry of NO$_3$on Jeju Island, Korea (33.17 N, 126.10$^{\circ}$E) during the Asian Dust-Storm (ADS) period of April 2001. Three ADS events were observed during the periods of 10∼12, 13∼14, and 25∼26 April. Average concentration level of nighttime NO$_3$on Jeju Island during the ADS period was estimated to be about 2 x 10$^{8}$ molecules cm$^{-3}$ ( - 9 pptv). Decreases in NO$_3$levels during the ADS period was likely to be determined mainly by the enhancement of the $N_2$O$_{5}$ heterogeneous reaction on dust aerosol surfaces. The reaction of N20s on aerosol surfaces was a more important sink for nighttime N03 during the ADS due to the significant loading of dust particles. The reaction of $N_2$O$_{5}$ with NMHCs and the gas-phase reaction of N20s with water vapor were both significant loss mechanisms during the study period, especially during the NADS. However, dry deposition of these oxidized nitrogen species and a heterogeneous reaction of NO$_3$were of no importance. Short-term observations of $O_3$, NO$_2$, DMS, and SO$_2$in the MBL indicated that concentrations of most of these chemical species were different between the ADS and non - Asian - Dust-Storm (NADS) periods, implying that their levels were affected sensitively by the differences in air mass trajectories.

• 한국해양학회지
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• v.26 no.2
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• pp.144-154
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• 1991

After the completion of the Nakdong River estuary barrage, environmental characteristics and phytoplankton communities in the estuary were investigated from April to December, 1989. dissolved oxygen seems to have decreased in the just lower region of the barrage off Janglim, while ammonia and phosphate concentration increased, probably due to the waste discharge from the Janglim stream and stagnation of water after the barrage construction. Concentrations of nitrate and dissolved silicate were negatively correlated with salinity, suggesting that major source is the Nakdong River discharge. In April, there was a diatom (Asterinella sp.) bloom in the upper region of the barrage, while in July, a diatom (Skeletonema costatum) bloom in the estuary mouth. The green and blue-green algae in species composition seem to have increased after the barrage construction. The relatively high concentration of chlorophyll b in the upper region of the barrage probably result from the high density of freshwater green-algae there. Among the species occurred in the study area, many were indicative of water pollution. It seems that environmental characters and phytoplankton communities are changing after the barrage construction.

• Journal of Korea Water Resources Association
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• v.32 no.4
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• pp.501-510
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• 1999

Stream and groundwater qualities of small agricultural watershed in Kangwon Probince, Korea were monitored 1 to 2 years, and the relationships between stream and groundwater qualities and seasonal water quality changes analyzed. Flooded paddy fields influenced groundwater level and quality during rice culture. The differences between groundwater levels during rice culture and non-culture spans were between 0.8 and 2.91 m. Seasonal changes of total nitrogen and nitrate nitrogen concentrations of stream and groundwater were very similar and groundwater quality was thought to have a profound impact on stream quality of the research watersheds. Suspended solids and BOD maintained the first degree stream water quality throughout the monitoring period except for a few and short flooding spans. The concentrations of total phosphorus and total bacteria of both waters showed wide variations and any seasonal trends were not observed. Long-term monitoring studies on small rural watersheds were recommended to understand the pattern of both stream and groundwater quality changes with respect to land use, season and cultural practice, and to apply the results to develop effective water quality management policies for large river and domestic water supply systems.

• Journal of Crop Science and Biotechnology
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• v.10 no.2
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• pp.57-63
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• 2007

Due to the strong influence of nitrogen(N) on plant productivity, a vast amount of N fertilizers is used to maximize crop yield. Over-use of N fertilizers leads to severe pollution of the environment, especially the aquatic ecosystem, as well as reducing farmer's income. Growing of N-efficient cultivars is an important prerequisite for integrated nutrient management strategies in both low- and high-input agriculture. Taking maize as a sample crop, this paper reviews the response of plants to low N stress, the physiological processes which may control N-use efficiency in low-N input conditions, and the genetic and molecular biological aspects of N-use efficiency. Since the harvest index(HI) of modern cultivars is quite high, further improvement of these cultivars to adapt to low N soils should aim to increase their capacity to accumulate N at low N levels. To achieve this goal, establishment and maintenance of a large root system during the growth period may be essential. To reduce the cost of N and carbon for root growth, a strong response of lateral root growth to nitrate-rich patches may be desired. Furthermore, a large proportion of N accumulated in roots at early growth stages should be remobilized for grain growth in the late filling stage to increase N-utilization efficiency. Some QTLs and genes related to maize yield as well as root traits have been identified. However, their significance in improving maize NUE at low N inputs in the field need to be elucidated.

• Journal of Korean Society of Water and Wastewater
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• v.12 no.4
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• pp.86-96
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• 1998

In this study, an intermittently aerated activated sludge process, modified process from conventional activated sludge process, was developed to treat high strength swine wastewater, which has been blamed as major pollutant for stream pollution. Therefore, the optimum cycle for oxic and anoxic period, SRT, and OLR were studied as design parameters. The effects of different time interval for oxic and anoxic period on nitrification and denitrification were examined by operating two reactors with 60/60min and 60/90min as oxic/anoxic period. Although the reactor with 60/60min showed complete denitrification of $NO_x-N$ generated during oxic period, the reactor with 60/90min showed incomplete nitrification due to the inactivity of nitrifier by accumulated $NH_3-N$ toxicity during anoxic period. Therefore, it is recommended to operate same interval for oxic and anoxic period. In order to determine the optimum cycle for oxic/anoxic period, four different reactors with 30/30, 60/60, 90/90 and 120/120min were examined. The reactor operation with 90/90min was optimum to get the most stable results in this study. However, the optimum cycle for oxic and anoxic period should be changed with characteristics of influent wastewater and operating conditions. According to lie operation results of three reactors with SRT of 15, 20 and 30days. The reactor with 2Odays SRT showed best removal efficiency of T-N. The optimum OLR would be $2.5Kg\;COD/m^3/day$ which showed the most stable nitrification and denitrification. Since characteristics of influent wastewater in the real system has a severe fluctuation, so it is very difficult to determine each interval for oxic and anoxic period. Therefore, ORP curves, describing the change of oxidation/reduction potential in reactor, can be used as a control parameter for automatic control of oxic and anoxic period. In other words, bending point (Nitrate Knee) of ORP curve during anoxic period could be used as a starting point of oxic period.

• Korean Journal of Agricultural Science
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• v.49 no.2
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• pp.379-387
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• 2022

A large amount of the mineral nitrogen is necessary for crop growth. With the use of nitrogen fertilizers, agricultural yield has increased during the last few decades. However, at the same time, nitrate from the cultivated land can be a source of environmental pollution, especially in water systems. For nitrogen management, it is necessary to analyze the pattern of nitrogen movement in soil. In this study, nitrogen leaching in upland soils was evaluated using undisturbed lysimeters with different soil textures during sesame cultivation. The soil texture of the lysimeters was clay loam (Songjung series) and sandy loam (Sangju series) soils. Sesame was cultivated from May 25 to August 24 in 2020. The standard amount of NPK fertilizer (N-P₂O₅-K₂O = 2.9-3.1-3.2 kg·10 a^-1) was applied before sowing. The amount of nitrogen leaching was calculated by multiplying the nitrogen (NO₃-N + NH₄-N) concentration and the amount of water drained below 1.5 m soil depth. The water was drained through percolation into macropores in the clay loam lysimeter. In contrast, in the sandy loam lysimeter, water drained more slowly than in the clay loam lysimeter. There was a slight difference in the total amount of leachate during the cultivation period, but the amount of nitrogen leaching was high in sandy loam soil. During the sesame cultivation period, the amount of nitrogen leaching from clay soil was 5.64 kg·10 a^-1, and 10.70 kg·10 a^-1 for sandy soil. We found that there was a difference in leaching depending on the soil physical characteristics. Therefore, it is necessary to consider the characteristics of soil to evaluate the leaching of nitrogen.

• The Journal of the Korea institute of electronic communication sciences
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• v.19 no.3
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• pp.531-538
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• 2024

While the importance of the water quality environment is being emphasized, the water quality index for improving the water quality of urban rivers in Gwangju Metropolitan City is an important factor affecting the aquatic ecosystem and requires accurate prediction. In this paper, the XGBoost and LightGBM machine learning algorithms were used to compare the performance of the water quality inspection items of the downstream Pyeongchon Bridge and upstream BanghakBr_Gwangjucheon1 water systems, which are important points of Gwangju Stream, as a result of statistical verification, three water quality indicators, Nitrogen(TN), Nitrate(NO3), and Ammonia amount(NH3) were predicted, and the performance of the predictive model was evaluated by using RMSE, a regression model evaluation index. As a result of comparing the performance after cross-validation by implementing individual models for each water system, the XGBoost model showed excellent predictive ability.

• Korean Journal of Soil Science and Fertilizer
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• v.40 no.1
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• pp.85-94
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• 2007

To determine the influence of food waste compost (FWC) application on paddy soil, FWC was applied to the paddy soil and then compared with farmer's practice as to the effects on rice and soil environment. Initially, pig manure compost (PMC) had high content of phosphorus ($15g\;kg^{-1}$) and potassium ($23g\;kg^{-1}$), while FWC had high content of total nitrogen ($13g\;kg^{-1}$) and salinity ($18.5g\;kg^{-1}$). Comparison was also made between chemical fertilizer and FWC use as a trial in the paddy field under the clay loam and sandy loam soil. In the panicle formation stage, chemical fertilizer application was proper in clay loam while PMC application was proper in sandy loam. However, chemical fertilizer produced higher yield compared to compost treatment, both on clay loam and sandy loam with 20~25% and 17~19%, respectively. The lower yield in sandy loam maybe due to slow mineralization of compost such that the crop did not effectively use it. Organic matter content in paddy soil after experiment was higher in FWC and PMC plots compared to that in chemical fertilizer plots. But the other soil properties were comparable. Therefore, the FWC compost had little effect on soil when it use as a trial in paddy field. Likewise, after the application of FWC as a trial, analysis of nitrate nitrogen and ammonium nitrogen in the surface water and 60 cm depth of paddy soil water nine days after planting was done. Results revealed that concentration of ammonium nitrogen was similar to irrigation water while nitrate nitrogen concentration was not detected, and hence did not contribute to water pollution. It is concluded that the application of FWC in the paddy field had not affected on environmental pollution in the paddy field. But its use as compost during rice culture reduced yield quantity. Such study should include selection of compost material, amount and method of compost application.

• Economic and Environmental Geology
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• v.56 no.2
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• pp.139-153
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• 2023

This study aimed to understand the spatiotemporal variations in nitrogen content in the Gyeongan stream along the main stream and at the discharge points of the sub-basins, and to identify the origin of the nitrogen. Field surveys and laboratory analyses, including chemical compositions and isotope ratios of nitrate and boron, were performed from November 2021 to November 2022. Based on the flow duration curve (FDC) derived for the Gyeongan stream, the dry season (mid-December 2021 to mid-June 2022) and wet season (mid-June to early November 2022) were established. In the dry season, most samples had the highest total nitrogen(T-N) concentrations, specifically in January and February, and the concentrations continued to decrease until May and June. However, after the flood season from July to September, the uppermost subbasin points (Group 1: MS-0, OS-0, GS-0) where T-N concentrations continually decreased were separated from the main stream and lower sub-basin points (Group 2: MS-1~8, OS-1, GS-1) where concentrations increased. Along the main stream, the T-N concentration showed an increasing trend from the upper to the lower reaches. However, it was affected by those of the Osan-cheon and Gonjiamcheon, the tributaries that flow into the main stream, resulting in respective increases or decreases in T-N concentration in the main stream. The nitrate and boron isotope ratios indicated that the nitrogen in all samples originated from manure. Mechanisms for nitrogen inflow from manure-related sources to the stream were suggested, including (1) manure from livestock wastes and rainfall runoff, (2) inflow through the discharge of wastewater treatment plants, and (3) inflow through the groundwater discharge (baseflow) of accumulated nitrogen during agricultural activities. Ultimately, water quality management of the Gyeongan stream basin requires pollution source management at the sub-basin level, including its tributaries, from a regional context. To manage the pollution load effectively, it is necessary to separate the hydrological components of the stream discharge and establish a monitoring system to track the flow and water quality of each component.