• 한국재료학회지
• /
• 제26권4호
• /
• pp.200-206
• /
• 2016

This study was carried out to investigate the effect of W substitution on the precipitation behavior of ${\chi}$ and ${\sigma}$ phases in super duplex stainless steel. The ${\chi}$ phase was precipitated at the interface of ferrite / austenite phases and inside the ferrite phase at the initial stage of aging. With an increase in the aging time, the volume fraction of the ${\chi}$ phase increased, and then decreased with the transformation from the ${\chi}$ phase to the ${\sigma}$ phase. The ${\sigma}$ phase was precipitated later than the ${\chi}$ phase, and the volume fraction of x phase increased with the increase in the aging time. The ferrite phase was decomposed into the new austenite (${\gamma}2$) and ${\sigma}$ phases by aging treatment. The decomposition of the ferrite phase into the ${\gamma}2$ and ${\sigma}$ phases was retarded by W substitution for Mo. The volume fraction of the ${\chi}$ phase increased and that of the ${\sigma}$ phase decreased due to W substitution. The ${\chi}$ and ${\sigma}$ phases were intermetallic compounds, which had lower nickel concentration, and higher chromium, molybdenum, and tungsten concentrations. The ${\chi}$ phase has higher molybdenum and tungsten concentrations than those of the ${\sigma}$ phase. The amounts of chromium and nickel in the ${\chi}$ and ${\sigma}$ phases did not change, but these phases have higher concentrations of molybdenum and tungsten due to W substitution for Mo.

• Journal of Magnetics
• /
• 제18권1호
• /
• pp.21-25
• /
• 2013

Nickel substituted manganese ferrites, $Mn_{1-x}Ni_xFe_2O_4$ ($0.0{\leq}x{\leq}0.6$), were fabricated by sol-gel method. The effects of sintering and substitution on their crystallographic and magnetic properties were studied. X-ray diffractometry of $Mn_{0.6}Ni_{0.4}Fe_2O_4$ ferrite sintered above 523 K indicated a spinel structure; particles increased in size with hotter sintering. The M$\ddot{o}$ssbauer spectrum of this ferrite sintered at 523 K could be fitted as a single quadrupole doublet, indicative of a superparamagnetic phase. Sintering at 573 K led to spectrum fitted as the superposition of two Zeeman sextets and a single quadrupole doublet, indicating both ferrimagnetic and paramagnetic phase. Sintering at 673 K and at 773 K led to spectra fitted as two Zeeman sextets due to a ferrimagnetic phase. The saturation magnetization and the coercivity of $Mn_{0.6}Ni_{0.4}Fe_2O_4$ ferrite sintered at 773 K were 53.05 emu/g and 142.08 Oe. In $Mn_{1-x}Ni_xFe_2O_4$ ($0.0{\leq}x{\leq}0.6$) ferrites, sintering of any composition at 773 K led to a single spinel structure. Increased Ni substitution decreased the ferrites' lattice constants and increased their particle sizes. The M$\ddot{o}$ssbauer spectra could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and the octahedral sites of the $Fe^{3+}$ ions. The variations of saturation magnetization and coercivity with changing Ni content could be explained using the changes of particle size.

• 한국결정학회지
• /
• 제12권1호
• /
• pp.20-24
• /
• 2001

NiZn-ferrite was synthesized usign waste iron oxide catalysts which were produced from styrene monomer process and buried underground as an industrial wastes. The spinel type ferrite was obtained by calcination and sintering of the mixture of finely ground waste catalysts, nickel oxide and zinc oxide powders. The sintered body of Ni/sub 0.5/Zn/sub 0.5/Fe₂O₄ composition at 1230℃ for 5 hours showed the density of 5.38g/㎤, and initial permeability of 59 at 1 kHz. Not only cerium oxide, which existed as a major component in the catalyst, but also unicorporated NiO and ZnO into spinel structure remained as second phases after sintering.

• 한국주조공학회지
• /
• 제9권6호
• /
• pp.483-489
• /
• 1989

In the stable eutectoid transformation of austenite in ductile cast iron, ferrite forms around the graphite spheroid. As carbon diffuses through the ferrite ring, the graphite spheroid must eularge and the ferrite ring must deform plastically to accomodate this growth. A model has been proposed to clarify this mechanism. The alloying effects of molybdenum, nickel and copper were studied in a series of heats cast into a range of casting section sizes. Regression analysis was used to illustrate the effects of alloying and cooling rate on the microstructure of ductile cast iron.

• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 2006년도 동계학술연구발표회 및 자성 스핀트로닉스 국제학술대회
• /
• pp.116-117
• /
• 2006

• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 2008년도 Asian Magnetics Conference
• /
• pp.234.1-234.1
• /
• 2008

• Journal of Radiation Protection and Research
• /
• 제14권2호
• /
• pp.37-44
• /
• 1989

원자로 냉각재에서의 방사능 누적 저감을 위한 수질 관리 개선 방안으로 현재의 coordinated lithium-boron 운전 방식을 elevated lithium 방식으로 전환시켜 냉각재의 pH를 높게 유지시키는 기법에 대해 검토하였다. 국내 PWR원전에서의 pH와 원자로 냉각재내의 방사능 누적 관계를 분석하였으며 그 결과, 고 pH 운전이 현재의 pH 운전 방법보다는 방사능 누적 저감에 유리하다는 것을 알 수 있었다. 이러한 결과는 냉각재중의 부식생성물의 구성이 magnetite 보다는 nickel ferrite 쪽이 지배적인 비중을 차지하고 있음을 보여주는 것이며, 고 pH 운전 범위는 pH 7.0-7.4가 적합한 것으로 나타났다.

• 한국자기학회지
• /
• 제9권4호
• /
• pp.217-222
• /
• 1999

공업적으로 세라믹공정에 많이 사용되고 있는 습식 볼밀링으로 NiCuZn ferrite 제조과정 중 혼입되는 불순물의 양을 조사 검토하였다. NiO, CuO, ZnO 및 Fe2O3의 화학조성을 변화시켜 25 vol%로 혼합하고 스테인레스 볼밀로 습식방법을 이용하여 18시간 분쇄한 후 건조시켜 $700^{\circ}C$ 3시간 하소하였다. 하소한 분말을 다시 상기와 같은 방법으로 65시간 스테인레스 볼밀로 최종 분쇄하여 저온소결용 NiCuZn ferrite(NCZF) 소재를 제조하였다. NCZF 연자성 소재를 만드는 동안 혼합 분쇄과정에서 혼입되는 불순물의 스테인레스 스틸의 양은 산화철 및 산화니켈의 함량에 많은 영향을 받았고, 하소 후의 분쇄과정에서 혼입되는 불순물의 양은 결정화된 정도에 따라 영향을 받았다. 전자기적 특성을 갖는 화학조성의 조절을 위하여, 출발원료의 함량에 따라 분쇄과정에서 혼입되는 스테인레스 스틸의 함량을 도출하는 형식을 유도하였다.

• 한국수소및신에너지학회논문집
• /
• 제19권6호
• /
• pp.520-528
• /
• 2008

2-step methane reforming, consisting of syn-gas production and water splitting step, was carried out over Cu-ferrite/$ZrO_2$. To improve the reactivity over Cu-ferrite/$ZrO_2$ presenting low reactivity in 2-step methane reforming, the addition of Ni was considered. As the results, the added Ni to Cu-ferrite/$ZrO_2$ improved the reactivity in syn-gas production step. However, (Cu, Ni) ferrite/$ZrO_2$ showed carbon deposition in syn-gas production step when an excess Ni was added. Furthermore, (Cu, Ni) ferrite/$ZrO_2$ showed the high durability without the deactivation of the medium during repeated ten cycles, although it showed more deposited carbon than the medium without Ni.

• Advances in nano research
• /
• 제12권4호
• /
• pp.415-426
• /
• 2022

Nickel substituted cobalt-zinc ferrite nanoparticles with composition Co_0.5Zn_0.5Ni_xFe_2-xO₄ (x = 0.25, 0.5, 0.75, 1.0) were synthesized using a wet chemical method named citrate precursor method. Various characterizations of the prepared nanoferrites were done using X-ray powder diffractometry (XRD), Scanning electron microscopy (SEM), UV visible spectroscopy and Fourier transform spectroscopy technique (FT-IR). XRD confirmed the formation of cubic spinel structure of the samples with single phase having one characteristic peak at (311). The value of optical band gap (E_g) was found to decrease with Ni substitution and have values in the range 2.30eV to 1.69eV. A Fenton-type system was created by photocatalytic activity using source of visible light for removal of methylene blue dye. Observations revealed increase in the degradation of methylene blue dye with increasing nickel content in the samples. The degradation percentage was increased from 77.32% for x = 0.25 to 90.16% for x = 1.0 in one hour under the irradiation of visible light. Also, the degradation process was found to have pseudo first order kinetics model. Hence, it can be observed that synthesized nickel doped cobalt-zinc ferrites have good capability for water purification and its degradation efficiency enhanced with increase in nickel concentration.